Abstract

Abstract. The aim of paleoclimate studies resolving climate variability from noisy proxy records can in essence be reduced to a statistical problem. The challenge is to extract meaningful information about climate variability from these records by reducing measurement uncertainty through combining measurements for proxies while retaining the temporal resolution needed to assess the timing and duration of variations in climate parameters. In this study, we explore the limits of this compromise by testing different methods for combining proxy data (smoothing, binning, and sample size optimization) on a particularly challenging paleoclimate problem: resolving seasonal variability in stable isotope records. We test and evaluate the effects of changes in the seasonal temperature and the hydrological cycle as well as changes in the accretion rate of the archive and parameters such as sampling resolution and age model uncertainty in the reliability of seasonality reconstructions based on clumped and oxygen isotope analyses in 33 real and virtual datasets. Our results show that strategic combinations of clumped isotope analyses can significantly improve the accuracy of seasonality reconstructions compared to conventional stable oxygen isotope analyses, especially in settings in which the isotopic composition of the water is poorly constrained. Smoothing data using a moving average often leads to an apparent dampening of the seasonal cycle, significantly reducing the accuracy of reconstructions. A statistical sample size optimization protocol yields more precise results than smoothing. However, the most accurate results are obtained through monthly binning of proxy data, especially in cases in which growth rate or water composition cycles obscure the seasonal temperature cycle. Our analysis of a wide range of natural situations reveals that the effect of temperature seasonality on oxygen isotope records almost invariably exceeds that of changes in water composition. Thus, in most cases, oxygen isotope records allow reliable identification of growth seasonality as a basis for age modeling in the absence of independent chronological markers in the record. These specific findings allow us to formulate general recommendations for sampling and combining data in paleoclimate research and have implications beyond the reconstruction of seasonality. We briefly discuss the implications of our results for solving common problems in paleoclimatology and stratigraphy.

Highlights

  • Improving the resolution of climate reconstructions is a key objective in paleoclimate studies because it allows climate variability to be studied on different timescales and sheds light on the continuum of climate variability (Huybers and Curry, 2006)

  • Our results show that strategic combinations of clumped isotope analyses can significantly improve the accuracy of seasonality reconstructions compared to conventional stable oxygen isotope analyses, especially in settings in which the isotopic composition of the water is poorly constrained

  • The performance of three 47-based approaches to reconstruct seasonality from accretionary carbonate archives was evaluated in comparison with conventional δ18Oc-based reconstructions in a wide range of case studies

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Summary

Introduction

Improving the resolution of climate reconstructions is a key objective in paleoclimate studies because it allows climate variability to be studied on different timescales and sheds light on the continuum of climate variability (Huybers and Curry, 2006). The temporal resolution of climate records is limited by the accretion rate (growth or sedimentation rate) of the archive and the spatial resolution of sampling for climate reconstructions, which is a function of the sample size required for a given climate proxy This tradeoff between sample size and sampling resolution is especially prevalent when using state-of-the-art climate proxies which require large sample sizes, such as the carbonate clumped isotope paleothermometer ( 47; see applications in Rodríguez-Sanz et al, 2017; Briard et al, 2020; Caldarescu et al, 2021) and stable isotope ratios in specific compounds or of rare isotopes What constitutes “high resolution” is largely dependent on the specifics of the climate archive

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