Field Of Packaging Research Articles

Multifunctional fructose-crosslinked fibroin film with a developed β-sheet structure for advanced food packaging

The replacement of petroleum-based plastic packaging with sustainable biopolymer-based materials is still a significant challenge. In the current study, we present a novel approach to impart the multifunctionality of fibroin film through a facile fructose-mediated crosslinking process. By generating a synergistic effect by inducing the transition to β-sheet structure and introducing covalent bonds within the fibroin chain, we effectively controlled the physicochemical characteristics of fibroin film, resulting in exceptional mechanical properties surpassing previous fibroin-based films. The fructose-crosslinked fibroin films exhibited exceptional mechanical properties, including a toughness of 3767.73 kPa and a Young's modulus of 3.06 GPa, surpassing previously reported fibroin-based films. The films also demonstrated excellent optical properties, with 98.49 % transmittance at 700 nm. Moisture stability was significantly enhanced, as the incorporation of fructose reduced water solubility by increasing β-sheet crystallinity and improved bulk water retention through its hygroscopic properties. Additionally, Maillard reaction products formed during crosslinking provided superior ultraviolet shielding and enhanced antioxidant properties, making the films ideal for active food packaging. The multifunctionality of fructose-crosslinked fibroin film significantly improves food storage stability when used in sustainable and eco-friendly food packaging applications. This high-performance fructose-mediated crosslinked fibroin film with a developed β-sheet structure emerges as a promising alternative to petroleum-based materials, offering a sustainable solution for the advanced packaging field.

Effect of adding Ni nanoparticles on the melting characteristics, mechanical properties and intermetallic compound growth of Sn58Bi solder

Purpose This paper aims to investigate the improvement of Sn58Bi solder properties by Ni nanoparticle to provide theoretical support in the field of electronic packaging. Design/methodology/approach In this study, nickel nanoparticles (Ni NPs) were doped into Sn58Bi solder as a reinforcing agent to prepare a composite solder. The wettability of composite solder, melting characteristics of solder alloy, microstructure of joints, mechanical properties and intermetallics growth at the interface were investigated. Findings Test results show that Ni had little substantial effect on the solders alloy melting temperature yet decreased the alloy undercooling. Notably, Ni enhanced solders wettability on Cu substrates. The spreading area increased by 14% at 0.6 wt.% Ni. The Ni refined the microstructure of Sn58Bi solder joints and inhibited the coarsening of the Bi-rich phase in the solder. At the same time, it also led to the production of free intermetallic compounds, increasing growth of the intermetallic compound (IMC) layer. However, upon surpassing 0.6 wt.% Ni, (Cu, Ni)6Sn5 accumulated and formed irregular clumps in the matrix. The grain size of the IMC layer gradually decreased as Ni was added. In shear tests, the fracture of joints occurred mainly inside the solder matrix. Sn58Bi-0.6Ni joints displayed a 40% rise in shear strength and a 25% rise in Vickers hardness. In addition, the appearance of dimples at the fracture indicated the improved flexibility of joints. Originality/value In this paper, Ni nanoparticle with different contents were added to Sn58Bi solder to prepare a composite solder, and the properties of the composite solder were investigated from different perspectives.

Tetrapanax papyriferus lignocellulosic skeleton aerogel enhanced with polyvinyl alcohol of high mechanical performance and thermal insulating

Biodegradable and renewable biomass aerogel has attracted significant attention because of its excellent characteristics. However, most aerogels were limited by poor mechanical strength and complex fabrication process. Herein, two delignified Tetrapanax papyriferus (TP) lignocellulosic samples (TP-SC, TP-FA/HAC) served as renewable porous skeletons with polyvinyl alcohol (PVA) modification to prepare high performance aerogels. The excellent pore structure facilitates the penetration of polyvinyl alcohol, which enhances the mechanical property and thermal stability of the resulting aerogel. The SC-8 h exhibited excellent mechanical strength with a bending stress of 102.9 MPa, 26.7 % increase in strain and 2.5 % in bending modulus compared to the TP-SC. The maximum thermal decomposition temperature of the FA/HAC-4 h was 358.6 °C, which was showed an outstanding thermal stability of the aerogel. Furthermore, these aerogels exhibited thermal insulating properties, and the maximum surface heating temperature after impregnation modification is lower than that of the original wood. This performance has a development prospect in the field of thermal insulation packaging and building structural materials. The high strength lignocellulosic skeleton aerogel could be prepared by a simple and effective strategy that preserved the original distinctive structure, offering a novel approach to the efficient utilization of TP.

Carboxymethyl chitosan: Synthesis, functional properties, and applications in sustainable food packaging material.

Global environmental concerns about non-degradable packaging materials are increasing. Carboxymethyl chitosan (CMCS), a polysaccharide widely used in the food industry, has gained attention in the field of food packaging. Due to its biodegradability, film-forming ability, and biocompatibility, CMCS has emerged as a sustainable option for degradable and functional food packaging materials, offering solutions to plastic pollution and food waste issues. This review explores CMCS as a food packaging and delivery material, detailing its synthesis methods, optimal preparation conditions, functional properties post-carboxymethylation, and applications in the food industry, alongside safety assessments. It summarizes the physicochemical interactions of CMCS-based composites and their impact on relevant properties, highlighting CMCS's potential as a green strategy for smart and active food packaging materials. Additionally, it presents the latest advancements in CMCS applications in the food industry over the past decade. CMCS exhibits good biocompatibility and antibacterial properties, and its functionality in food packaging films and delivery materials is enhanced through functional modification and polymerization. CMCS is widely used as a matrix for food preservation films or coatings and as a carrier for active ingredients, thereby improving the encapsulation efficiency and storage stability of functional food components. This review comprehensively outlines the applications of CMCS in the food industry, filling gaps in the existing literature, and laying a theoretical foundation for the development of CMCS technology. It provides a reference for further research, emphasizing the need to further investigate its molecular structure and chemical properties to optimize functionality and safety, thereby fully tapping into the potential of CMCS in the food industry.

Improving interfacial thermal transport in silicon-reinforced epoxy resin composites with self-assembled monolayers

Epoxy resin (EP) based composite materials, due to their advantages such as light weight, ease of processing, and mechanical properties, have been widely applied across thermal packaging field. However, the overall thermal conductivity is constrained by the interfacial thermal resistance between the filler and the substrate. Existing studies suggest that self-assembled monolayers (SAM) can enhance the interfacial thermal conductance (ITC) by forming covalent bonds. Nevertheless, limited research has focused on using SAM to form bilateral covalent bonds to regulate ITC. Therefore, SAM capable of forming bilateral covalent bonds at the EP/silicon (Si) interface were employed to enhance ITC. In this study, time-domain thermoreflectance (TDTR) experiments and molecular dynamics (MD) simulations were conducted to investigate the EP/SAM/Si system. The results demonstrate that SAM-NH2 modification, which forms bilateral covalent bonds at the EP/Si interface, increased the interfacial adhesion strength and enhanced ITC to 140%, thereby significantly promoting interfacial heat transfer. Conversely, ITC was reduced with SAM-CH3 due to the formation of single covalent bond. Subsequently, the differential effective medium (DEM) model was used to determine that the thermal conductivity of the composite modified with SAM-NH2 was improved by 11%. This study provides new insights into adjusting ITC using SAM.

Effect of Gd2O3 substitution for La2O3 on structure, physicochemical and electrical properties in aluminoborosilicate glasses for advanced microelectronics packaging

Currently, to develop new glass materials with lower dielectric constant (εr) and dielectric loss (tanδ), low coefficient of thermal expansion (CTE), excellent thermal stability and chemical stability for advanced microelectronics packaging has been significant pursuits of many researchers. In this work, novel 58SiO2-20B2O3-8Al2O3-10CaO-1Na2O-(3-x) La2O3-x Gd2O3 (x=0, 0.5, 1, 1.5, 2, 2.5 and 3 mol%) were successfully fabricated by the conventional melt annealing method. The results revealed that single addition of Gd2O3 or La2O3 (x=0, 3 mol%) strengthened glass network structure, which in turn improved performances of the glass. It was interestingly found that similar to the mixed-base effect, double-doped Gd2O3 and La2O3 played a greater role in improving glass structure and properties. The glass with x=1.5 mol% Gd2O3 exhibited the lowest dielectric permittivity, dielectric loss and low coefficient of thermal expansion (εr = 4.72, tanδ = 0.0004 (@1 MHz), CTE = 3.78 ppm/°C) and good chemical stability, which is optimal for the comprehensive performance compared with other aluminoborosilicate (Al-B-Si) glasses reported so far. These findings highlight that this glass is expected to be used in the microelectronics packaging field.

Characterization of anti bacterial biocomposite films based on poly lactic acid and prosopis juliflora bark powder

Biocomposites can be a solution for environmental pollution and sustainability by acting as an alternative to petroleum-based products used in the field of packaging and biomedical applications. Herein, an attempt to valorize the potential of Prosopis juliflora plant to fabricate Polylactic acid (PLA) based biocomposites. The biocomposites comprised of Prosopis juliflora bark powder (PJBP) and PLA were fabricated by solution casting method with various weight percentages (Wt%) of PJBP. PJBP/PLA films show uniform functional group interactions through FTIR analysis. The 25 % PJBP/ PLA biocomposite shows the highest crystalline size of 8.9 nm. The 25 wt% included PJBP increases the thermal stability by 6.9 %, surface roughness by 212 %, and tensile strength by 45.5 % compared to PLA film. The 25 % PJBP film shows increment in the water absorption and water vapor permeability test. In addition, the antibacterial behavior of 25 % PJBP bio composite shows higher inhibition zones against the gram-positive and gram-negative pathogens. Biocomposite films with PJBP content show 40 % degradation in soil for degradation analysis. This PLA/25 % PJBP biodegradable film can be used as an alternative for petroleum-based products in the field of packaging as well as the biomedical field.

Toughening Mechanism of CaAl12O19 in Red Mud–Al2O3 Composite Ceramics

The utilization of red mud in the production of ceramic products represents an efficient approach for harnessing red mud resources. Composite ceramics were prepared from Al2O3, red mud, and Cr2O3 by atmospheric pressure sintering, and the phase composition and microscopic morphology of the composite ceramics were investigated by XRD, SEM, and EDS. The flexural strength and fracture toughness of composite ceramics were measured by three-point bending and SENB methods. The results showed that the composite ceramics sintered at 1500 °C with the addition of 1.5 wt.% Cr2O3 had a flexural strength of 297.03 MPa, a hardness of 17.44 GPa, and a densification of 97.75% and fracture toughness of 6.57 MPa·m1/2. The addition of Cr2O3 helps to improve the low strength of red mud composite ceramic samples. The CaAl12O19 phase can form a similar “endo-crystalline” structure with Al2O3 grains, which changes the fracture mode of the ceramics and thus significantly improves the fracture toughness. The wettability tests conducted on Cu and RM–Al2O3 composite ceramic materials revealed that the composites exhibited non-wetting behavior towards Cu at elevated temperatures, while no interfacial reactions or elemental diffusion were observed. Composites have higher surface energy than Al2O3 ceramic at high temperatures. The present study provides a crucial foundation for enhancing the comprehensive utilization value of red mud and the application of red mud ceramics in the field of electronic packaging.

Mechanism analysis of dual wavelength laser welding AlN-PC joint based on microtexture treatment

High-strength interfacial bonding between ceramics and transparent polymers is hardly to be achieved, especially in the field of optical packaging of biochips. This paper proposes a novel laser welding method that enhances the joint strength between aluminum nitride (AlN) ceramic and polycarbonate (PC) by laser surface microtexturing. The study investigates the influence of welding methods and microtextures on welding effectiveness, elucidating the bonding mechanisms of the joints. The obtained results showed that dual wavelength laser welding effectively achieves the connection between AlN ceramic and PC. Laser microtexturing increases surface roughness and contact area, leading to stronger mechanical interlocking and overall joint strength. The highest shear strength reached up to 14.66 MPa with longitudinal grooves microtexture. The laser microtexturing improves the hydrophilicity of the AlN surface, facilitating more effective bonding between the materials. The bonding mechanisms at the joint interface include both mechanical interlocking and chemical bonding. Microtexturing improves the stress distribution at the joint interface. The formation of C-O-Al chemical bonds at the interface effectively enhances the joint strength. Longitudinal grooves microtexture exhibit a higher substrate fracture rate due to stress concentration and capillary pores. In contrast, staggered square holes microtexture provide superior mechanical performance through uniform stress distribution and robust mechanical interlocking.

Sputtering of (111) highly-oriented nanotwinned Ag on polycrystalline Si3N4 substrates for high-power electronic packaging

Nanotwinned silver (NT-Ag) exhibits excellent mechanical and electrical properties, attributed to its high-density and (111) highly-oriented twinning structure in nanoscale. Therefore, it has recently drawn much attention in the field of electronic packaging, where it can be utilized as interconnection or metallization materials. However, it has been a critical challenge to fabricate the high-density and highly-oriented NT-Ag onto polycrystalline ceramic substrates, whose crystal structure does not support the epitaxial growth of NT-Ag films. In the current work, a high-density and highly-oriented NT-Ag film has been fabricated onto a polycrystalline ceramic substrate, i.e., NT-Ag on silicon nitride (NT-Ag@Si3N4), using the magnetron sputtering method. As results, a close-packed arrangement of high-density NT-Ag has been observed within columnar grains aligned along its growth direction, whereas the nanoindentation hardness of the NT-Ag film reached 1.82 GPa, with an electrical resistivity of 2.06 μΩ‧cm. Moreover, this study has discussed and explained the growth kinetics and mechanism of NT-Ag films, by controlling magnetron sputtering process parameters, such as sputtering power and argon flow rate. Additionally, the differences in the growth mechanism of NT-Ag on (100) Si and polycrystalline Si3N4 have also been investigated. With its superior material properties, NT-Ag@Si3N4 holds great promise in the applications of advanced packaging technology for high-power electronics.

Preparation and Performance of PBAT/PLA/CaCO3 Composites via Solid-State Shear Milling Technology

Replacing traditional disposable, non-biodegradable plastic packaging with biodegradable plastic packaging is one of the key approaches to address the issue of “white pollution”. PBAT/PLA/inorganic filler composites are widely utilized as a biodegradable material, commonly employed in the field of packaging films. However, the poor dispersion of inorganic fillers in the polymer matrix and the limited compatibility between PBAT and PLA have led to inferior mechanical properties and elevated costs. In this work, we propose a simple and effective strategy to improve the dispersion of nano-CaCO3 in a PBAT/PLA matrix through solid-state shear- milling (S3M) technology, combined with mechanochemical modification and in situ compatibilization to enhance the compatibility between PBAT and PLA. The impact of varying milling conditions on the structure and performance of the PBAT/PLA/CaCO3 composites was investigated. During the milling process, PBAT and PLA undergo partial molecular chain fragmentation, generating more active functional groups. In the presence of the chain extender ADR during melt blending, more branched PBAT-g-PLA is formed, thereby enhancing matrix compatibility. The results indicate that the choice of milling materials significantly affects the structure and properties of the composite. The film obtained by milling only PBAT and CaCO3 exhibited the best performance, with its longitudinal tensile strength and fracture elongation reaching 22 MPa and 437%, respectively. This film holds great potential for application in the field of green packaging.

Development and preservative applications of polysaccharide-based bilayer packaging films: Enhanced functional properties through metal-phenolic network-coated zein nanoparticles and biomimetic hydrophobic surfaces

This study develops an innovative bilayer biomimetic hydrophobic film, tailored to provide a sustainable and eco-friendly packaging solution for fresh produce. The outer layer, crafted from chitosan, utilized polydimethylsiloxane templating to mimic the ultra-hydrophobic surface of a lotus leaf, achieving a water contact angle exceeding 130°. The inner layer comprised sodium alginate and zein nanoparticles, enriched with citral and fortified by a metal-phenolic network to facilitate uniform dispersion and controlled release of bioactive agents. The structural design of the film significantly improved mechanical properties, evidenced by a maximum tensile strength of 29.3 ± 3.6 MPa, and enhanced hydrophobicity, reducing water solubility to 28.3 ± 1.5% and substantially decreasing water absorption. The barrier functionality of film was also strengthened, demonstrated by a lowered water vapor transmission rate of 289.3 ± 1.5 g m−2 24 h−1, and it supported extended citral release in acidic media up to 70 h. Moreover, the film exhibited robust antioxidant and antibacterial properties. In practical tests, it effectively mitigated weight loss, browning, and hardness degradation in fresh-cut apples and lotus roots, concurrently inhibiting microbial growth and extending shelf life. This study presents an effective strategy for enhancing the hydrophobicity and bioactivity of bio-based films, contributing valuable insights to the field of sustainable food packaging.

An entropy- TOPSIS approach to find PMMA/cellulose based biocomposite with optimum mechanical and bio-degradation properties

Poly methyl methacrylate based biocomposite has been manufactured using nanocellulose as reinforcement, which has been extracted from bagasse. The biocomposites are formed by bulk polymerization using benzoyl peroxide as initiator. The composites are evaluated by FTIR, X-ray diffraction, mechanical properties, UV analysis, scanning electron microscope, polarizing light microscope and thermo-gravimetric analysis. Variation in properties is an inherent drawback of natural fibers, for which this MCDM technique is very effective to decipher, the biocomposite with optimum properties. It has been found that when the bagasse fiber is treated with 3.5 % of sodium chlorite solution, it can produce biocomposite with PMMA. It has been observed that, cellulose grafting takes place in the PMMA chain in presence of benzoyl peroxide. Further the work has been extended with loading variation of the said cellulose fibers and 1.5 % loading has been found as the best. The novelty of the work lies in the fact that these evaluations have been substantiated by Multi-Criteria Decision Making (MCDM) technique involving ENTROPY and TOPSIS approach and successfully selected 1.5 wt % loading to fabricate the optimum biocomposite. This composite exhibited around 13.5 % biodegradation within 90 days. This film can find application in packaging field.

Electrospun gelatin/tea polyphenol@pullulan nanofibers for fast-dissolving antibacterial and antioxidant applications.

Bio-based active food packaging materials have a high market demand. We use coaxial electrospinning technology to prepare core-shell structured nanofibers with sustained antibacterial and antioxidant properties. The fiber core layer was composed of gelatin and tea polyphenols, whereas tea polyphenols provide antibacterial and antioxidant properties; the fiber sheath was composed of pullulan polysaccharides with antioxidant properties. By using a scanning electron microscope, it can be seen that the diameter distribution of the prepared nanofibers was uniform and the surface is smooth; using a transmission electron microscope, it can be clearly seen that the nanofibers have a core-shell structure; Fourier Transform Infrared and X-ray diffraction analysis indicate that the nanofibers have an amorphous structure; the 2,2-diphenyl-1-picrylhydrazyl free radical scavenging shows that nanofibers have higher antioxidant properties with the addition of tea polyphenols; antibacterial test showed that nanofibers had obvious inhibitory effect on the growth of Staphylococcus aureus and Escherichia coli; and the nanofiber film dissolution test shows that nanofibers can be used as fast soluble active packaging. Finally, core-sheath-structured nanofibers can serve as active packaging for instant food, possessing both rapid water solubility and excellent antibacterial and antioxidant activity, making water-soluble nanofibers interesting applications in the field of food packaging.

Unlocking superior preservation: The synergy of lignin and zeolite in chitosan-based composite films for perishable foods

Chitosan-based films are confronted with several technical challenges that impede their broad application in the preservation of perishable foods, such as suboptimal mechanical properties and insufficient antioxidant activity. In this work, we have introduced lignin (LG) and natural clinoptilolite zeolite (NCZ) into pure chitosan-based films to address the above limitations. The synergistic incorporation of LG and NCZ has endowed the composite films, designated as CTSLC, with a suite of enhanced attributes, including improved thermostability, enhanced UV-shielding capability and hydrophobicity, augmented antioxidant activity, refined gas selectivity, and bolstered mechanical properties. The enhancements in the antioxidant activity, gas selectivity, and mechanical properties of CTSLC are notably pronounced, reflecting a substantial advancement in their overall performance. These attributes surpass those of both pure chitosan-based film or commercial polyethylene film. Consequently, CTSLC could keep the freshness and appearance of strawberries and mangoes at least 60 hours and 10 days, respectively. The findings suggest that CTSLC has the potential to be a promising material for the preservation of perishable foods, offering a significant advancement in the field of food packaging and preservation technology.

Effect of hydroxylated boron nitride and boron nitride nanosheets on the properties of doped organosilicone rubber composites

As the electronic industry develops rapidly, the miniaturisation, integration and multifunctionality of electronic devices have resulted in a dramatic increase in power density, and the heat dispersal of electronic devices has attracted much attention. In this work, hydroxylated hexagonal boron nitride (BN-H) was obtained by hot alkali treatment, and boron nitride nanosheets (BNNS) with a thickness of about 4 nm were obtained by boric acid-assisted ball milling stripping. The effects of different types of fillers as well as filler contents on the thermally conductive and mechanical performance of organosilicon composites were also compared. Notably, when BN-H and BNNS thermally conductive fillers were added at 12 wt%, the thermally conductive coefficients of the composites were 0.4831 W·m−1·K−1 and 0.7131 W·m−1 K−1, respectively, which were 183% and 318% of higher than that for the pure silicone rubber (SR, with a thermally conductive coefficient of 0.1706 W·m−1·K−1). In addition, in respect of mechanical performance, the tensile strengths of SR/BN-H and SR/BNNS composites with a filling level of 12 wt% were 3.59 MPa and 3.89 MPa, respectively, and the storage moduli were 4501 MPa and 4583 MPa, respectively, which were improved to a certain extent compared with pure SR. The present work provides an effective way to develop organosilicone rubber composites with good thermal conductivity and mechanical properties by boric acid assisted ball milling to strip boron nitride in the field of electronics packages.

Antioxidant packaging films based upon starch-montmorillonite with forsythia flower extract: characterization and application

Plastic pollution is one of the most acute environmental problems in the world, so active packaging materials made from biodegradable natural polymers have received widespread attention in recent years. In this paper, forsythia flower extract, serving as an active ingredient, was integrated into the starch-sodium alginate-montmorillonite composite film. The physicochemical properties and functional packaging applications of the composite films were investigated. The results demonstrate the formation of a tightly-knit network structure through molecular interactions among forsythia flowers, starch, sodium alginate, and montmorillonite. Notably, the addition of forsythia flower extracts conferred better UV resistance (from 200 nm to 400 nm) and outstanding antioxidant properties to the composite films. After 18 days of storage, in comparison with the control group, the decay rate of fresh cherry tomatoes packaged with the composite film containing forsythia flower extract showed a significant reduction of 40%, the hardness increased by 25%, and the content of vitamin C was enhanced by 33%. Hence, the forsythia flower extract composite film offers a novel perspective for the design and development of bio-based packaging films for preserving fresh fruits. The results serve as a foundation for the subsequent advancement and application of forsythia flower in the field of packaging.

A high-efficiency strategy for fruit preservation using green, natural raw materials

Straw is an abundant renewable biomass resource material. Lignin contained in straw is a unique natural aromatic compound in nature. At present, it is urgent to find ways to realize the higher value of natural lignin resources. In this study, alkali lignin was separated from rice straw by hydrothermal method in NaOH solution, which was prepared lignin nanoparticles by a simple green anti-solvent method. The obtained lignin nanoparticles had excellent anti-tyrosinase activity (IC50 = 0.329 mg mL−1) and anti-oxidation performance (IC50 = 0.0451 mg mL−1). Meanwhile, through the analysis of tyrosinase inhibition kinetics, it is concluded that the tyrosinase inhibition by lignin nanoparticles belongs to mixed inhibition. The affinity of lignin nanoparticles to the free enzyme is greater than that of enzyme and substrate complex. In addition, lignin nanoparticles were added to chitosan solution for compounding, then the composite films for fruit preservation were prepared by casting method. The experimental results show that the composite membrane can effectively extend the shelf life of fruits, which is expected to achieve a broader application in the field of fruit preservation and food packaging.

Recent Advances in the Development of 1,4-Cyclohexanedimethanol (CHDM) and Cyclic-Monomer-Based Advanced Amorphous and Semi-Crystalline Polyesters for Smart Film Applications.

Polyester-based advanced thin films have versatile industrial applications, especially in the fields of textiles, packaging, and electronics. Recent advances in polymer science and engineering have resulted in the development of advanced amorphous and semi-crystalline polyesters with exceptional performance compared to those of conventional polymeric films. Among these, 1,4-cyclohexanedimethanol (CHDM) and cyclic-monomer-based polyesters have gained considerable attention for their exceptional characteristics and potential applications in smart films. This review article provides a comprehensive overview of the recent advances in the synthesis, characterization, and applications of CHDM and cyclic-monomer-based advanced polymers for smart film applications. It discusses the structure-property relationships of these innovative polyesters and highlights their unique characteristics, including thermal, mechanical, and barrier characteristics. Furthermore, this article also emphasizes the solution, melt, and solid-state polymerizations of the polymers. Special emphasis is placed on the influence of the addition of a second diol or second diacid on the performance characteristics of synthesized polyesters/copolyesters to explore their versatile industrial applications. Additionally, the impact of the stereochemistry of the monomers is explored to optimize the characterization of polyesters suitable for industrial applications. Furthermore, this article explores the potential of these advanced polyesters to be considered as materials for smart film applications, especially in the field of flexible electronics. Finally, this article examines the challenges and future recommendations for the development of CHDM and cyclic-monomer-based polyesters for smart film applications. It discusses potential avenues for further research, including in-depth studies for the synthesis and characterization of polyesters, the development of sustainable and biodegradable alternatives to cyclic monomers, alternative green approaches for the synthesis of polymers, etc. This review article provides valuable insight for researchers in academia and industry who are working in the fields of polymer science and materials engineering.

Slow-release antimicrobial preservation composite coating based on bamboo-derived xylan–A new way to preserve blueberry freshness

In recent years, the biocompatibility and environmental friendliness of xylan-based materials have demonstrated great potential in the field of food packaging and coatings. In this study, the cationized xylan based composite coating (CXC) was developed using a hybrid system of cationic-modified bamboo xylan (CMX) and sodium alginate (SA) combined with thyme oil microcapsules (TM). The optimized CXC-B was composed of 1.27 % TM, 2.42 % CMX (CMX: SA = 3:2), and 96.31 % distilled water. When applied to the surface of a blueberry, the CXC-B treatment extended the ambient storage time of the fruit to 10 days while substantially reducing its morbidity (P < 0.05) and protecting its texture, flavor, and nutritional integrity. The resulting composite coating provides a promising solution to the problem of blueberry perishability during ambient storage.