As complementary metal oxide semiconductor (CMOS) devices are scaled beyond the 50-nm gate length node, the effective oxide thickness must be below 10 A to reduce short-channel effect and to improve device performance. Polysilicon has been extensively employed as a gate electrode, however, it has recently shown to suffer from instability on high-K dielectrics [1]. In addition, the inversion oxide thickness is increased by about 3–5 A due to polysilicon gate depletion [2]. Based on the above reasons, the investigation of metal gates is critical for scaling of advanced gate stacks [3]. Metal gate electrodes must have suitable work function, process compatibility and thermal/chemical interface stability with underlying gate dielectrics. In order to replace the polysilicon gate while maintaining the proper threshold voltage, work functions of the metal gates for n-channel MOS (NMOS) and p-channel MOS (PMOS) must be close to those of n+ and p+ doped polysilicon, which are close to 4 and 5 eV, respectively [4]. Metals with mid-gap work functions are known to be unsuitable for advanced CMOS devices due to severely degraded short channel characteristics [5]. While several thermally stable metals have been reported as possible gate electrodes for PMOS devices [6], metals having NMOS compatible work function typically suffer from thermal instability. Their high affinity towards oxygen promotes the reduction of the underlying dielectric and the formation of a metal oxide layer [7]. Binary metal alloys have been recently reported [6] and may provide a possible route for NMOS electrodes. In this work, we have investigated the electrical/material properties and thermal stability of a novel binary metal alloy, Ta–Mo, for NMOS gate electrode. Field oxide of 3500 A was grown to define active area on (100) p-type silicon substrate. The gate dielectric was 100 A SiO2 which was thermally grown at 900 . The binary metal alloys were deposited using a UHVPVD sputtering tool with a base pressure of 3 × 10−9 Torr. Sputtering was performed using a Ta target (purity of 99.5%) and a Mo target (purity of 99.95%). As shown