Oxidation Of Carbon Monoxide Research Articles

Pengaruh Modifikasi Permukaan Piston terhadap Emisi Gas Buang Motor Bakar Kapasitas 100 cc

Technological advances in motorized transportation are progressing rapidly, making motorized vehicles the main mode of transportation. The increasing number of motorized vehicles in society results in a significant increase in exhaust emissions. Combustion in vehicle engines is not always perfect, producing exhaust gases containing compounds harmful to human health, such as carbon monoxide (CO), hydrocarbons (HC), carbon dioxide (CO2), and nitrogen oxides (NOx). This study investigates the effect of variations in piston dome shape on exhaust emissions in a 100cc internal combustion engine using RON 90 fuel. The goal is to find the optimal compression ratio to produce cleaner exhaust emissions. The research data are presented in tabular form and analyzed using one-way ANOVA and graphs. The results showed a significant reduction in CO and HC emissions at all engine speeds (1000, 2000, 4000, and 5000 rpm) with variations in piston dome shape. The reduction in CO emissions ranged from 55.07% to 85.73%, while the reduction in HC emissions ranged from 54.14% to 86.10%. These results suggest that variations in piston dome shape can be an effective solution to minimize harmful exhaust emissions in internal combustion engines.

Carbon monoxide (CO) and particulate matter (PM) emissions during the combustion of wood pellets in a small-scale combustion unit – Influence of aluminum-(silicate-)based fuel additivation

The additivation of solid biofuels has proven to be an effective method for reducing total particulate matter (TPM) and carbon monoxide (CO) emissions, as well as for reducing ash-related problems related to, e.g., fouling and slagging. During the combustion with additives, potassium (K) released from the solid biofuels is bound into temperature-stable compounds, thus preventing the formation of inorganic (i.e., K-based) TPM. Simultaneously by reducing K in the gas phase, the inhibition of gas-phase oxidation (e.g., CO oxidation) due to interference of K within the existing radical pool is hindered. Particularly kaolin, an aluminum-silicate-based additive has proven effective in reducing not only TPM but also CO emissions. The mitigation effects on CO emissions have previously been reported mostly in a subordinate role and explanations are given in the form of hypotheses. In this study, seven additives (i.e., kaolin, kaolinite, meta-kaolinite, aluminum hydroxide, muscovite, muscovite coated with titanium dioxide and kalsilite, each at 0.3 wt%a.r.) were investigated during wood pellet combustion in a small-scale furnace (7.8 kW). For both CO and TPM emissions, kaolin proved to be most effective (i.e., −52% CO, −49% TPM), followed by muscovite, kaolinite, TiO2 coated muscovite, aluminum hydroxide, and meta-kaolinite.

SMMP: A Deep-Coverage Marine Metaproteome Method for Microbial Community Analysis throughout the Water Column Using 1 L of Seawater.

Marine microbes drive pivotal transformations in planetary-scale elemental cycles and have crucial impacts on global biogeochemical processes. Metaproteomics is a powerful tool for assessing the metabolic diversity and function of marine microbes. However, hundreds of liters of seawater are required for normal metaproteomic analysis due to the sparsity of microbial populations in seawater, which poses a substantial challenge to the widespread application of marine metaproteomics, particularly for deep seawater. Herein, a sensitive marine metaproteomics workflow, named sensitive marine metaproteome analysis (SMMP), was developed by integrating polycarbonate filter-assisted microbial enrichment, solid-phase alkylation-based anti-interference sample preparation, and narrow-bore nanoLC column for trace peptide separation and characterization. The method provided more than 8500 proteins from 1 L of bathypelagic seawater samples, which covered diverse microorganisms and crucial functions, e.g., the detection of key enzymes associated with the Wood-Ljungdahl pathway. Then, we applied SMMP to investigate vertical variations in the metabolic expression patterns of marine microorganisms from the euphotic zone to the bathypelagic zone. Methane oxidation and carbon monoxide (CO) oxidation were active processes, especially in the bathypelagic zone, which provided a remarkable energy supply for the growth and proliferation of heterotrophic microorganisms. In addition, marker protein profiles detected related to ammonia transport, ammonia oxidation, and carbon fixation highlighted that Thaumarchaeota played a critical role in primary production based on the coupled carbon-nitrogen process, contributing to the storage of carbon and nitrogen in the bathypelagic regions. SMMP has low microbial input requirements and yields in-depth metaproteome analysis, making it a prospective approach for comprehensive marine metaproteomic investigations.

Facile one-step solvothermal synthesis of Co3O4/CuO nanoflowers as an excellent catalyst for CO oxidation in coal mines

In the present study, Cobalt oxide (Co3O4)/Copper oxide (CuO) nanoflower catalysts were synthesized through a one-step solvothermal method, and the impact of various factors, including reaction time, on the catalytic activity of the catalysts towards carbon monoxide (CO) was investigated. The results showed that the catalysts synthesized at 140 °C and a reaction time of 4 h provided the best catalytic performance for carbon monoxide, and the regular nanoflower-like morphology provided a larger specific surface area as well as a greater number of active sites, allowing the instantaneous 100 % elimination of CO at 200 °C. Additionally, a plausible reaction mechanism was elucidated, wherein CO initially adsorbed onto the sample's surface, subsequently reacting with lattice oxygen to form intermediate carbonate species. This process ultimately led to the production of carbon dioxide (CO2), followed by the desorption of CO2 molecules from the sample's surface. The results demonstrate that these composite catalysts effectively mitigate CO levels during CO over limit in coal mines, thereby enhancing the safety of production personnel.

Mutagenicity evaluation of methyl tertiary- butyl ether in multiple tissues of transgenic rats following whole body inhalation exposure.

Methyl tertiary-butyl ether (MTBE) is used as a component of motor vehicle fuel to enhance combustion efficiency and to reduce emissions of carbon monoxide and nitrogen oxides. Although MTBE was largely negative in the in vitro and in vivo genotoxicity studies, isolated reports of positive findings along with the observation of tumors in the rat cancer bioassays raised concern for its in vivo mutagenic potential. To investigate this, transgenic male Big Blue Fischer 344 rats were exposed to 0 (negative control), 400, 1000, and 3000 ppm MTBE via whole body inhalation for 28 consecutive days, 6 h/day. Mutant frequencies (MF) at the cII locus of the transgene in the nasal epithelium (portal of entry tissue), liver (site of primary metabolism), bone marrow (rapidly proliferating tissue), and kidney (tumor target) were analyzed (5 rats/exposure group) following a 3-day post-exposure manifestation period. MTBE did not induce a mutagenic response in any of the tissues investigated. The adequacy of the experimental conditions to detect induced mutations was confirmed by utilizing tissue samples from animals treated with the known mutagen ethyl nitrosourea. These data provide support to the conclusion that MTBE is not an in vivo mutagen and male rat kidney tumors are not likely the result of a mutagenic mode of action.

Enhanced Catalytic Oxidation Reactivity over Atomically Dispersed Pt/CeO2 Catalysts by CO Activation.

The elevation of the low-temperature oxidation activity for Pt/CeO2 catalysts is challenging to meet the increasingly stringent requirements for effectively eliminating carbon monoxide (CO) from automobile exhaust. Although reducing activation is a facile strategy for boosting reactivity, past research has mainly concentrated on applying H2 as the reductant, ignoring the reduction capabilities of CO itself, a prevalent component of automobile exhaust. Herein, atomically dispersed Pt/CeO2 was fabricated and activated by CO, which could lower the 90% conversion temperature (T90) by 256 °C and achieve a 20-fold higher CO consumption rate at 200 °C. The activated Pt/CeO2 catalysts showed exceptional catalytic oxidation activity and robust hydrothermal stability under the simulated working conditions for gasoline or diesel exhausts. Characterization results illustrated that the CO activation triggered the formation of a large portion of Pt0 terrace sites, acting as inherent active sites for CO oxidation. Besides, CO activation weakened the Pt-O-Ce bond strength to generate a surface oxygen vacancy (Vo). It served as the oxygen reservoir to store the dissociated oxygen and convert it into active dioxygen intermediates. Conversely, H2 activation failed to stimulate Vo, but triggered a deactivating transformation of the Pt nanocluster into inactive PtxOy in the presence of oxygen. The present work offers coherent insight into the upsurging effect of CO activation on Pt/CeO2, aiming to set up a valuable avenue in elevating the efficiency of eliminating CO, C3H6, and NH3 from automobile exhaust.

The Surface/Interface Modulation of Platinum Group Metal (PGM)-Free Catalysts for VOCs and CO Catalytic Oxidation.

Effective management of volatile organic compounds (VOCs) and carbon monoxide (CO) is critical to human health and the ecological environment. Catalytic oxidation is one of the most promising technologies for achieving efficient VOCs and CO emission control. Platinum group metal (PGM)-free catalysts are recently receiving sustainable attention in catalyzing VOCs and CO removal due to their low cost, superior catalytic activity, and excellent stability, but PGM-free catalysts face challenges in low-temperature catalytic efficiency. In this mini-review, starting with discussing the catalytic mechanism of VOCs and CO oxidation, we summarize the surface/interface modulation strategies of PGM-free catalysts to promote oxygen and VOCs/CO molecule activation for enhanced low-temperature oxidation activity, including oxygen vacancy engineering, heteroatom doping, surface acidity modification, and active interface construction. We highlight the currently remaining challenges and prospects of advanced PGM-free catalyst development for highly efficient VOCs and CO emission control in practical applications.

Enhancing the Carbon Monoxide Oxidation Performance through Surface Defect Enrichment of Ceria-Based Supports for Platinum Catalyst.

Effective synthesis and application of single-atom catalysts on supports lacking enough defects remain a significant challenge in environmental catalysis. Herein, we present a universal defect-enrichment strategy to increase the surface defects of CeO2-based supports through H2 reduction pretreatment. The Pt catalysts supported by defective CeO2-based supports, including CeO2, CeZrOx, and CeO2/Al2O3 (CA), exhibit much higher Pt dispersion and CO oxidation activity upon reduction activation compared to their counterpart catalysts without defect enrichment. Specifically, Pt is present as embedded single atoms on the CA support with enriched surface defects (CA-HD) based on which the highly active catalyst showing embedded Pt clusters (PtC) with the bottom layer of Pt atoms substituting the Ce cations in the CeO2 surface lattice can be obtained through reduction activation. Embedded PtC can better facilitate CO adsorption and promote O2 activation at PtC-CeO2 interfaces, thereby contributing to the superior low-temperature CO oxidation activity of the Pt/CA-HD catalyst after activation.

The Impact of Incorporating Varying Proportions of Sugar Beet Waste on the Combustion Process and Emissions in Industrial Burner Fuelled with Conventional Diesel Fuel

Abstract The main objective of the case study is to investigate the effectiveness of using solid fuel additives in conventional diesel fuel for industrial furnaces. The study focuses on utilizing agricultural waste derived from sugar beet plant waste as additives to enhance the combustion process and reduce emissions from industrial burners. In this study, experimental measurent for the flame temperatures inside the furnace while altering the proportions of the solid materials have ben achived. The goal was to assess the impact of different loading from these additives on the combustionprocess. Furthermore, the study involved measuring exhaust gases such as carbon monoxide (CO), carbon dioxide (CO2), unburned hydrocarbon (UH), and nitrogen oxides (NOx). The experimental facility arranment allowed the researchers to evaluate the emissions resulting from the combustion process with the addition of solid fuel additives. By measuring these parameters, the study aimed to understand the effect of utilizing agricultural waste as additives on the burning processes and emission formation in industrial furnaces. These findings can contribute to improving the efficiency of combustion processes, reducing emissions, and promoting the utilization of renewable and sustainable fuel sources in industrial settings. In this study, varying the proportions of solid materials used as additives had an impact on the levels of carbon monoxide (CO), carbon dioxide (CO2), and nitrogen oxides (NOx) in the exhaust gases. By increasing the proportion of solid materials in the fuel mixture resulted in changes in the emission levels. The levels of carbon monoxide in the exhaust gases decreased as the proportion of solid materials increased. While the addition of solid fuel additives did contribute to the production of CO2 due to the combustion of the additives, the overall effect on its levels varied depending on the specific proportions used. Also, the levels of nitrogen oxides in the exhaust gases showed different trends depending on the proportions of solid materials used. Typically, increasing the proportion of solid fuel additives led to reduce NOx emissions. However, this may also depend on other factors such as combustion temperature and the composition of the solid materials.

Carbon taxation on high utility transport fuels: An implementation of enviro-economic analysis for the sustainable environment”

The humongous increase in carbon emissions in the past few decades presents an environmental challenge to the scientific community. The current study proposes a method of taxation on high-carbon emission fuels. For this purpose, a comparative enviro-economic analysis is carried out on the three most commonly used fuels (gasoline, Liquefied Petroleum Gas (LPG), and Compressed Natural Gas (CNG)). The speed of the test engine varied from 1800 to 4200 Revolution per Minute (RPM) in increments of 400 RPM. Performance parameters (Brake Power (BP), Brake Thermal Efficiency (BTHE), and Brake Specific Fuel Consumption (BSFC)) were measured using a hydro dynamometer. Emission analysis, including Carbon Dioxide (CO2), Carbon Monoxide (CO), Unburned Hydrocarbons (HC), and Nitrogen Oxide (NOx), was conducted using the TESTO 350 analyzer. The application of Weibull distribution with a 95 % confidence interval, on emission data, explained the adequacy of the data. Among test fuels, CNG emerged as an environment-friendly fuel with an emission reduction of 16, 42, and 43 percent for CO2, CO, and HC in comparison to gasoline. Also, BTHE and BSFC of CNG were better than other alternatives. Moreover, the carbon penalty for CNG fuel showed a price reduction of 32 and 20.8 percent in comparison to gasoline and LPG respectively. The study provides a novel approach to assess the environmental impact of fuels by economic analysis based on emitted carbon quantity. In addition, this very idea is novel in promoting the Sustainable Development Goals (SDG) of the United Nations (UN) through carbon taxation.

Ultralow doping of Zr species into Co3O4 catalyst enhance the CO oxidation performance

The oxidation of carbon monoxide (CO) has garnered significant interest for its application in treating automobile exhaust. In this study, we employed the sol-gel method to synthesize a series of cobalt-zirconium oxide catalysts with various Co/Zr ratios, aiming to catalyze the oxidation of CO effectively. The findings showed that the Co90Zr10 catalyst, with a cobalt-to-zirconium ratio of 90:10, not only exhibited exceptional catalytic efficiency, achieving a 90 % conversion of CO at 94 °C, but also sustained superior thermal stability and resistance to water. The presence of both cobalt defects and oxygen vacancies significantly enhances the catalytic activity, which is attributed to the doping of zirconium. The characterization analyses indicated the incorporation of zirconium into the Co3O4 spinel lattice modifies the valence states (Co3+/Co2+) and geometries (CoOh/CoTd) of the cobalt cations. This alteration results from a variety of partial electron transfers and substitution sites. Enhanced ratios of Co3+/Co2+ and CoOh/CoTd in the CoxZry catalysts lead to improved reducibility and oxygen mobility. Consequently, this facilitates the lower-temperature oxidation of intermediates during the catalytic conversion of CO. DFT result showed that the Co3O4 after Zr doped has lower adsorption energy and revealed the reaction mechanism of CO catalytic oxidation.

Unraveling oxygen-driven surface segregation dynamics in platinum-gold alloys

In this study we use high-energy resolution and fast X-ray Photoelectron Spectroscopy (XPS) measurements combined with Density Functional Theory (DFT) calculations to investigate the interplay between surface segregation and bulk migration of Pt atoms on Au(111) in an oxygen environment. We demonstrate that the segregation of Pt atoms is significantly influenced by the oxygen partial pressure and identify a range of O2 pressure where PtAu surface alloy formation is inhibited while promoting the formation of Au oxide. These findings are essential to understand the compositional changes in the bimetallic surface alloy, which could potentially lead to modifying the catalytic properties of PtAu up to catalyst deactivation. Our results offer a strategy to control Pt surface coverage on Au(111), a quantity that is of paramount relevance given the applications of PtAu alloys as catalysts in reactions such as the oxygen reduction reaction or the oxidation of methanol and carbon monoxide. Additionally, our findings indicate a method for controlling the composition and properties of the surface of PtAu catalysts through adjustments made during the formation of the PtAu alloy.

Investigation of the effect of ether oxygenated additives on diesel engine performance, combustion, and exhaust emissions - An experimental approach

Conventional energy sources, including diesel and petrol, are decreasing day by day, while their reserves are limited. However, it is difficult to find alternative fuels to replace them. Hence, to fulfill the growing energy demand and reduce environmental emissions, it is vital to find a wide variety of oxygenated compounds to conventional diesel fuels that show low emission potential from transport engines. In this research, we investigated diesel engine performance, combustion, and exhaust emissions with the addition of 10 %, 15 %, 25 %, and 30 % of three different oxygenated blends, including Diethylene Glycol Dimethyl ether (DGM), Di-n-Butyl Ether (DBE), and Tripropylene-Glycol Monomethyl ether (TPGM). This paper presents the brake-specific fuel consumption (BSFC), Brake Thermal Efficiency (BTE), Brake Mean Effective Pressure (BMEP), and Brake Specific Energy Consumption (BSEC) for these fuel blends. The generated emissions of carbon dioxide (CO2), Carbon Monoxide (CO), and nitrogen oxide (NO) were quantified for four different engine speeds of 1500, 1800, 2000, and 2400 rpm for neat (100 %) oxygenated blends. This research also shows the in-cylinder pressure and heat release rate (HRR) of these three oxygenated blends. The outcome of this paper will help future researchers to develop automobiles and vehicles for oxygenated blends with conventional fuels.

In situ and Operando Characterisation in the Preferential Oxidation of Carbon Monoxide over Base Metal Oxide Catalysts: A Review

AbstractPolymer electrolyte membrane fuel cells (PEMFCs) are the core technology of the steadily growing hydrogen (H2) economy as they can convert chemical energy, in the form of H2, to electrical energy. If the H2 is derived from (green) hydrocarbons, via steam reforming and the water‐gas‐shift reaction, then it would contain small amounts of carbon monoxide (CO, 0.5–2 %), among other gases. CO poisons the platinum‐based anode catalyst in the PEMFC, and the current recommendation is to decrease its concentration to below 0.01 % (or 100 ppm) in the H2‐rich PEMFC feed. The preferential oxidation of CO (CO‐PrOx) is a promising strategy for decreasing the CO concentration, and base metal oxide catalysts have shown great potential in this regard. However, such catalysts tend to undergo physicochemical changes that cause undesirable catalytic activity and selectivity changes. This review discusses the different base metal oxide catalysts that have been evaluated in CO‐PrOx, while paying special attention to the various in situ and operando techniques that have been used to monitor the physicochemical changes of base metal oxides during operation. We conclude the review by highlighting the recent and possible future attempts of circumventing the undesired physicochemical changes of base metal oxides during CO‐PrOx.

Sub-ppt level detection of carbon monoxide and nitrous oxide enabled by mid-infrared doubly resonant photoacoustic spectroscopy.

We report highly sensitive detection of carbon monoxide (CO) and nitrous oxide (N2O) using doubly resonant photoacoustic spectroscopy paired with a quantum cascade laser (QCL) at 4.57 μm. The butterfly-packaged QCL is used to exploit the CO absorption line at 2190.02 cm-1 and the N2O absorption line at 2191.42 cm-1 by scanning the injection current. Leveraging the simultaneous acoustic and optical resonances and adopting a lower photoacoustic detection frequency, we achieve a minimum detection limit of 0.85 part-per-trillion (ppt) for CO over the 500 s averaging time, and 0.7 ppt for N2O over the 200 s averaging time. Our approach demonstrates record sensitivity for CO and N2O detection compared to state-of-the-art optical gas sensors.

In Silico Analysis of the Phylogenetic and Physiological Characteristics of Sphingobium indicum B90A: A Hexachlorocyclohexane-Degrading Bacterium.

The study focuses on the in silico genomic characterization of Sphingobium indicum B90A, revealing a wealth of genes involved in stress response, carbon monoxide oxidation, β-carotene biosynthesis, heavy metal resistance, and aromatic compound degradation, suggesting its potential as a bioremediation agent. Furthermore, genomic adaptations among nine Sphingomonad strains were explored, highlighting shared core genes via pangenome analysis, including those related to the shikimate pathway and heavy metal resistance. The majority of genes associated with aromatic compound degradation, heavy metal resistance, and stress response were found within genomic islands across all strains. Sphingobium indicum UT26S exhibited the highest number of genomic islands, while Sphingopyxis alaskensis RB2256 had the maximum fraction of its genome covered by genomic islands. The distribution of lin genes varied among the strains, indicating diverse genetic responses to environmental pressures. Additionally, in silico evidence of horizontal gene transfer (HGT) between plasmids pSRL3 and pISP3 of the Sphingobium and Sphingomonas genera, respectively, has been provided. The manuscript offers novel insights into strain B90A, highlighting its role in horizontal gene transfer and refining evolutionary relationships among Sphingomonad strains. The discovery of stress response genes and the czcABCD operon emphasizes the potential of Sphingomonads in consortia development, supported by genomic island analysis.

Realizing the high loading amount of active Cu on Al2O3 to boost its CO catalytic oxidation

Catalytic oxidation of carbon monoxide (CO) by Cu/Al2O3 has garnered increasing interest in recent years due to its promising application prospects. Numerous investigations conducted on the Cu/Al2O3 system, but its catalytic performance for CO oxidation is still not as promising as that of precious metal catalysts. Increasing the loading amount of the active Cu on Al2O3 surface is a feasible method for improving its activity. However, with the increase of Cu loading, the agglomeration and enlargement of Cu particles is inevitable, which reduces the active Cu amount. Therefore, the utilization rate of Cu atoms is not high and the catalytic performance often can not further rise. Enhancing active Cu loading amount as high as possible is a prerequisite to further enlarge the activity of Cu/Al2O3 catalyst. Herein, self-synthesized Al2O3 nanofibers (Al2O3-nf) with high specific surface area and abundant penta-coordinated aluminum (AlV) are used as the support to maximize the Cu loading amount by chemical vapor deposition (CVD). And commercially available α-Al2O3 is used for comparative experiment. The high specific surface area could make Cu high dispersion on Al2O3, even at 20 wt% Cu loads, which is beneficial to high concentration load of active Cu. The catalytic activity of Cu/Al2O3-nf-CVD gradually increases with the increase of Cu loading from 2 wt% to 20 wt%, exhibiting a clear linear correlation with the surface content of Cu0 on the catalyst. Meanwhile, this result confirms that Cu0 plays a crucial role in CO oxidation of Cu/Al2O3. However, commercial α-Al2O3 reaches its highest activity when the Cu load is 5%, and then its activity begins to decrease due to the agglomeration of particles. Moreover, Cu/Al2O3-nf-CVD also exhibits remarkable thermal stability for CO oxidation. This work highlights a new strategy to synthesis of high Cu loading amount, high activity and thermostable Cu/Al2O3 catalyst for low-temperature oxidation of CO.

Conjoint impact of modified HHO system, compression ratio variation, and tribological enhancement of steel piston ring substrates on performance and emission characteristics of a spark-ignition engine

In these times of efforts to develop high-efficiency hydrogen-adopted or hydrogen-fueled internal combustion engines (ICEs), and concerns related to electric vehicles such as battery cost, drawbacks in harsh winter climates, low range, etc., it is important to generate original ideas in line with the manufacturing of ICEs with improved efficacy. Accordingly, this study presents a comprehensive experimental investigation to observe the cooperated effects of pulse width modulation (PWM)-controlled hydroxy (HHO) gas introduction and improvement in tribological performance of piston ring-cylinder liner mechanism on performance and emission characteristics of a spark-ignition (SI) engine (co-system). The variation of compression ratio (CR), influence of two electrolyzer types of tube electrolyzer (TE) and plate electrolyzer (PE) for production of HHO gas, and zeta potential (ZP)-based dynamic light scattering (DLS) analysis to specify the optimal catalyst concentration in de-ionized water were also observed. Electron cyclotron resonance-chemical vapor deposition (ECR-CVD) method was utilized to bombard the piston ring substrates with diamond-like carbon (DLC) atoms under high energy plasma to improve the mechanical strength of the friction surface. Using linear tribometer, the uncoated (UPR) and coated piston rings (CPR) underwent friction tests to determine the wear rate (WR), and coefficient of friction (COF) which have substantial contribution to frictional losses. The surfaces of the samples were visualized via scanning electron microscopy (SEM) and atomic force microscopy (AFM) before and after abrasion tests to analyze carbon coating and its effects on tribological performance. The observations depicted that HHO flowrate needs to be varied as the engine load and CR change, and based on these observations, PWM control unit was designed, manufactured and reprogrammed so as to adjust electrical power consumption of HHO system when needed. The aforementioned analyses ensured optimization of the overall system so as to maximize the efficiency of the test engine. The co-system with optimized parameters (CPR + HHO + PWM) yielded an increase in average brake power (Pe) up to 31%, and average reductions in specific fuel consumption (β), carbon monoxide (CO), unburned hydrocarbon (UHC), and nitrogen oxide (NOx) emissions by 17%, 25%, 19%, and 14%, respectively at engine load range from 20% to 100%. It is expected that this study will be a good guide in terms of developing high-efficient ICEs due to promising results provided by the co-system.

Spatiotemporal variability of surface ozone and associated meteorological conditions over the Arabian Peninsula

This study investigates the spatiotemporal variability of surface ozone (O3) over the Arabian Peninsula (AP) between 2005 and 2019, focusing on the Arabian Gulf (AG). The analysis explores the relationship between surface O3 data from the Copernicus Atmosphere Monitoring Service (CAMS) with boundary layer height (BLH), 2 m temperature (T2M), downward ultraviolet radiation at the surface (UVB), and 10 m wind speed (WS) and direction from the fifth generation European Centre for Medium-Range Weather Forecasts (ECMWF) atmospheric reanalysis (ERA5). Also, the study considers Carbon Monoxide (CO) and Nitrogen Oxides (NOx) surface emissions from the Tropospheric Chemical Reanalysis version 2 (TCR-2). Furthermore, it investigates the impact of El Niño Southern Oscillation (ENSO) and the Indian Ocean Dipole (IOD) on surface O3 variations on a seasonal scale. Surface O3 observations from 15 ground-based stations across the AP were used to evaluate CAMS-O3, showing a good agreement between CAMS and the observations. The analysis of mean diurnal variations of CAMS-O3 and ERA5 reveals that surface O3 is highest over the eastern parts of the AP, mainly the AG, peaking during summer, followed by spring, fall, and winter. This seasonal cycle is also observed, to a large degree, in BLH, T2M, UVB, and WS. The results also reveal insignificant correlation between surface O3 and ENSO, but stronger correlation with IOD, especially over the AG during summer and fall. The analysis indicates that elevated T2M and UVB during daytime and elevated BLH during nighttime are significant contributors to increased levels of O3 over the AG.

Nano Technolgy Application to Enhance the Emission Control by Using Activated Carbons Modified by Magnesium Oxide

One of the fundamental processes for planet safety is the catalytic conversion of carbon monoxide (CO). CO has even been named one of the unseen toxins of this century. Inhaling CO can lead to hypoxic damage, neurological break, and even death. CO poisoning decays greenery life and accumulations in global warming and ozone layer depletion. CO is created in the atmosphere by the partial oxidation of carbon-containing mixtures. The primary origin of CO emissions is vehicles. Therefore, oxidizing contaminated CO to nonpoisonous CO2 under ambient conditions is essential for life protection in multiple applications. Additionally, low-temperature CO oxidation is crucial in reducing emissions at the cold start of an internal explosion in the engine. For controlling pollution, the available methods are pre-pollution control and post-pollution. This project depends on the post-pollution control method in Peugeot ROA automobiles using Activated Carbons Modified by Magnesium Oxide as a catalyst. An innovative catalytic converter design activated carbons modified by magnesium oxide nanoparticles as a catalyst to control pollution with different NPs lodgings and carbon structures. This proposed method aims for the reduction environmental pollution contributed by automobiles. It involves using more affordable materials than the existing rhodium nanoparticles, platinum, and palladium technique. The dispersion states of the grafted nanoparticles were examined with scanning electron microscopy (SEM) and X-ray diffraction analysis (XRD), confirming the correlation between high grafted ratio states and improved properties. The nanocomposites' desired properties were significantly enhanced when the graft density was high.