Oxide Coatings Research Articles

Influence of Additives on the Macroscopic Color and Corrosion Resistance of 6061 Aluminum Alloy Micro-Arc Oxidation Coatings.

In this study, we successfully employed the plasma electrolytic oxidation (PEO) technique to create a uniform white ceramic layer on the surface of the 6061 aluminum alloy using K2ZrF6 and Na2WO4 as colorants. A scanning electron microscope (SEM) equipped with an energy-dispersive X-ray spectrometer (EDS) and X-ray diffraction (XRD) were used to characterize the coatings, and we used an electrochemical workstation to test their corrosion protection properties. The corrosion resistance of the coatings was analyzed using potentiodynamic polarization curves. The results showed that K2ZrF6 addition whitened the coating with ZrO2 as the main phase composition, inhibiting Al substrate depletion and enhancing coating corrosion resistance. A small amount of Na2WO4 decreased the coating's L* value, successfully constructing ceramic coatings with L* (coating brightness) values ranging from 70 to 86, offering broad application prospects for decorative coatings.

Influence of precursor aging and condensation progression on silica thin films grown by electrochemically induced sol-gel deposition

Electrochemically induced sol-gel enables the fast synthesis of functional oxide coatings. In the case of silica, the condensation reaction can be catalysed by electrogenerated hydroxides. Using this technique, highly organized nanostructured thin films can be deposited onto conductive substrates by combining structure-directing templates with the electrochemically induced silica sol-gel process that occurs locally at the electrode surface. This specific template-directed process, called electrochemically assisted self-assembly (EASA), utilizes a sol-gel precursor solution optimized for a minimal spontaneous condensation (and gelation) rate in the absence of an electrochemical trigger. Despite the slow kinetics of the condensation reaction, the solution remains unstable and some incipient condensation reactions will still occur over time, continuously modifying the Si(IV) precursor solution. In this work, we discuss how precursor's aging affects the deposition rate and the properties of the deposited coatings. Two distinct aging effects are observed: an aging effect which occurs over time and an aging effect which occurs through electrochemical activation during preceding depositions. Both these aging effects result in accelerated film growth rates, up to 200 × faster than the deposition rate from a fresh precursor solution. Additionally, it was observed that time aging yields less resistive, weaker films, while electrochemical aging leads to films which retain similar properties as films grown using fresh precursor solutions. The time aging effect could be inhibited by storing the precursor solution at -35 °C. These observations are explained based on the different condensation pathways during acidic and alkaline condensation, which is known to yield inherently different silica oligomer products. The results and insights described here contribute to upscaling the electrochemical sol-gel process for mesoporous silica films and provides further fundamental insights into the underlying silica condensation reactions.

Exploring the Impact of Potential, Ammonium Fluoride Concentration, and Anodization Time on the Structure, Surface Characteristics, and Corrosion Resistance of Nanotubular Titanium Oxide Coatings on Biomedical Alloy Ti-6Al-4V ELI

The current research delves into assessing the impact of applied potential, ammonium fluoride concentration, and anodization duration on the structural, phase compositional, microhardness, and surface roughness attributes of nanotubular titanium oxide coatings on anodized Ti-6Al-4V ELI. A meticulous experimental design was executed to systematically investigate the varied effects of these factors. Scanning electron microscopy (SEM) unveiled the presence of well-defined titania nanotubes on the surfaces of the anodized specimens. X-ray diffraction (XRD) analysis discerned the composition of the nanotubular oxide layer, revealing the presence of both anatase and a mixture of anatase and rutile phases contingent upon the anodization parameters. Notably, surface microhardness, surface roughness, and corrosion resistance manifested noticeable variations in response to alterations in applied voltage, NH4F concentration, and anodization duration within the designated experimental ranges.

Study on the thermal insulation property of lanthanum–cerium oxide coatings

Functional fillers with low thermal conductivity and high near-infrared reflectance play a vital role in high temperature thermal insulation coatings and make an outstanding contribution to achieving efficient comprehensive thermal insulation. In this work, the thermal insulation and bonding properties of lanthanum–cerium oxide (LCO) coatings were regulated by composition design. The effects of the La/Ce mole ratio on phase composition, the thermal conductivity and near-infrared reflectivity of LCO coatings were investigated systematically. The results showed that coating with a La/Ce mole ratio of 1:1 possess the excellent thermal insulation properties (ΔT ≈ 115°C) due to the formation of a LCO solid solution and a lanthanum phosphate mesophase with low thermal conductivity and high near-infrared reflectivity. In addition, the mortise and tenon structure was formed between the coating and the substrate, which led to the remarkable bonding properties. The LCO coating offers excellent thermal insulation properties and broad application prospects in the fields of high temperature and energy conservation.

Antimony Trisulfide with Graphene Oxide Coated Titania Nanotube Arrays as Anode Material for Lithium-ion Batteries

AbstractThe performance of the Lithium Ion Batteries (LiBs) is significantly influenced with the synergetic chemical properties of two different materials in a composite form. The specific capacity of both titanium dioxide arrays (TNAs) and Antimony trisulfide (Sb2S3) bottleneck the performance of LiB due to the low conductivity after the implantation as anode material. Herein, a novel multifunctional composite composed of highly dispersed Sb2S3 on freestanding tubular TNAs host via chemical bath deposition method (CBD) for use as anode material in lithium-ion batteries (LIBs). The loading quantity of Sb2S3 with reduced graphene oxide (rGO) was regulated to achieve adjustable outcomes. The composite anode consisting of TNAs/ Sb2S3/G in lithium-ion batteries (LIBs) has a specific capacity that is three times greater than conventional anodes. Furthermore, this composite anode maintains stable cyclic performance even after undergoing 300 cycles. The initial coulombic efficiency of the composite electrode is 100%, whereas the bare TNAs had a coulombic efficiency of 45%. The cycle performance analysis demonstrated that the TNAs/ Sb2S3/G composite has superior specific capacity and efficiency, even under high current density conditions of 500 µA/cm2. The rate performance is greatly improved, indicating the efficacy of this innovative composite anode material for high-performance LIBs.

Improved Corrosion Behavior of Biodegradable Mg-4Zn-1Mn Alloy Modified by Sr/F co-doped CaP Micro-arc Oxidation Coatings

Improved Corrosion Behavior of Biodegradable Mg-4Zn-1Mn Alloy Modified by Sr/F co-doped CaP Micro-arc Oxidation Coatings

Tuning biomechanical behavior and biocompatibility of Mg–Zn–Ca alloys by Mn3O4 incorporated plasma electrolytic oxidation coatings

In this study, the mechanical behavior and biocompatibility of plasma electrolytic oxidation (PEO)-coated Mg–Zn–Ca alloy specimens were investigated. The coatings were synthesized by incorporating KMnO4 and Mn3O4 nanoparticles into an electrolytic solution. An indentation test revealed a significant increase in the reduced elastic modulus of the PEO coatings with incorporated Mn3O4 under various loads. This increase was attributed to the higher coating thickness and reduced porosity achieved by the addition of Mn-based additives to the electrolyte. The composite PEO coatings prepared with Mn3O4 nanoparticles exhibited a more pronounced reduction in elastic modulus under pressure. Wettability tests showed that the prepared coatings maintained their hydrophilic nature with water contact angles in the range of 25–63°. The presence of Mn3O4 in the PEO coatings provided a conducive environment for cell viability. The enhanced biocompatibility of the composite coatings achieved by incorporating KMnO4 into the electrolyte was particularly noteworthy. This improvement was attributed to the controlled release of Mn ions, which generates a microenvironment that favors cellular activities. The study showed that incorporating Mn3O4 into PEO coatings enhances mechanical properties, preserves hydrophilicity, and improves biocompatibility, thus indicating its potential for orthopedic implant applications.

Визначення білків гострої фази в крові щурів після імплантації поліпропіленових хірургічних сіток із покриттям на основі танталу та його похідних

At present, more than 30 types of polypropylene surgical meshes are available in the world, but the statistics regarding the secondary inflammatory process after implantation still remain disappointing. Since polypropylene surgical meshes do not decompose well in the body, they can stimulate the surrounding tissuesto develop an inflammatory process that causes adhesions. For the past 50 years, tantalum has been successfully used to produce biocompatible medical implants in surgery, orthopedics, and dentistry. Its excellent anti-inflammatory and antibacterial properties have been repeatedly noted, indicating the possibility of its use as a coating for mesh implants. In order to better predict the outcome after implantation of biomedical materials, it is important to determine the content of acute phase proteins, namely C-reactive protein, haptoglobin and ceruloplasmin. The aim of the study is to determine the content of acute phase proteins, namely C-reactive protein, haptoglobin and ceruloplasmin in the blood of rats after implantation of surgical meshes coated on the basis of tantalum, tantalum oxide and tantalum nitride. Materials and methods. The experimental group included 40 male rats of the WAG population. With the help of surgical intervention, a polypropylene surgical mesh measuring 15x15 mm was implanted between the abdominal wall and various sections of the colon. 28 days after surgery, the experimental animals were decapitated by cervical dislocation. Blood samples were used to determine the content of C-reactive protein, the content of haptoglobin and the content of ceruloplasmin. Results and discussion. The content of C-reactive protein in the blood of rats was statistically 260 % higher in the experimental group implanted with uncoated surgical mesh and 228.8 % higher in the experimental group implanted with polypropylene surgical mesh with tantalum nitride coating in compared with the results in the group of intact animals. Haptoglobin content was statistically 110.5 % higher and ceruloplasmin was statistically 52.6 % higher in the uncoated surgical mesh group compared to the results of the intact animal group. We obtained similar results in the experimental group, which was implanted with a polypropylene surgical mesh with a coating based on tantalum nitride. The content of haptoglobin was 130 % higher and the content of ceruloplasmin was 50.6 % higher statistically compared to the results of the group of intact animals. The C-reactive protein content was 113.3 % and 95.5 % higher, respectively, in the groups implanted with polypropylene surgical meshes with a coating based on tantalum and tantalum oxide compared to the results in the group of intact animals. The content of haptoglobin in the tantalum-based coating group was 83.8 % higher and the content of ceruloplasmin was 32.6 % higher compared to the results obtained in the group of intact animals. In the tantalum oxide- based group, the haptoglobin content was 60.1 % higher and the ceruloplasmin content was 29.3 % higher compared to the results obtained in the intact animal group. Conclusion. Based on the results of the study, it was established that polypropylene surgical meshes coated with tantalum and tantalum oxide significantly reduce the inflammatory reaction compared to uncoated meshes and meshes coated with tantalum nitride. This is supported by lower levels of key inflammatory markers, indicating improved biocompatibility and anti-inflammatory effects of tantalum and tantalum oxide coatings.

IrO2-ZrO2-SiO2 ternary oxide composites- based DSAs: Activity toward oxygen evolution reaction with long-term stability

BackgroundHigher purity of copper is produced by Electrowinning (EW) in the cathode. A major challenge in this technique is the anodic structure that causes in the energy consumption, corrosion resistance, and contamination of the copper produced in the cathode. MethodsTernary metallic oxide (IrO2-ZrO2-SiO2) composites with the different molar percentages of IrO2: SiO2 (10:60, 15:55, and 20:50%) were prepared on titanium substrate by the sol-gel technique, and then thermal decomposition to study the impact of IrO2 and SiO2 contents on the electrocatalyst performances of the dimensionally stable anodes (DSAs). The physicochemical properties of the DSAs were determined by X-ray diffraction (XRD), Field emission scanning electron microscope (FE-SEM), Atomic force microscopy (AFM), and electrochemical measurements. Significant findingsFE-SEM and AFM images display the impact of SiO2 on the crystallization and crystal growth of IrO2, leading to the formation of finer oxide particles and the porous morphology of the ternary oxide coatings. The DSA composed of 50 % SiO2 and 20 % IrO2 (IZS (20–30–50)) with a more porous surface area represented high apparent electrocatalytic activity toward the oxygen evolution reaction with long-term stability as analyzed under cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and accelerated lifetime (ALT) plots.

Enhancing Carbon Fiber Fabrics with ALD AlxOy Coatings: An Investigation of Thickness Effects on Weight, Morphology, Coloration, and Thermal Properties

This study explores the impact of non-stoichiometric aluminum oxide (AlxOy) coatings applied via thermal atomic layer deposition (ALD) on carbon fiber fabrics (CFFs), emphasizing volume per cycle, FESEM analyses, color transitions, and thermal stability enhancements. Using trimethylaluminum and water at 100 °C, AlxOy was deposited across a range of 1000 to 5000 ALD cycles, with film thicknesses extending up to 500 nm. This notable increase in the volume of material deposited per cycle was observed for the 3D CFFs, highlighting ALD’s capability to coat complex structures effectively. FESEM analyses revealed the morphological evolution of CFF surfaces post-coating, showing a transition from individual grains to a dense, continuous layer as ALD cycles increased. This morphological transformation led to significant color shifts from green to red to blue, attributed to structural coloration effects arising from variations in film thickness and surface morphology. Thermogravimetric analyses (TGA and dTG) indicated that the AlxOy coatings enhanced the thermal stability of CFFs, with a postponement in degradation onset observed in samples subjected to more ALD cycles. In essence, this research highlights the nuanced relationship between ALD processing parameters and their collective influence on both the aesthetic and functional properties of CFFs. This study illustrates ALD’s potential in customizing CFFs for applications requiring specific color and thermal resilience, balancing the discussion between the surface morphological changes and their implications for color and thermal behavior.

Preparation and properties of micro-arc oxidation ceramic coatings using machine vision technology

In this paper, a machine vision system is combined with non-immersion micro-arc oxidation (MAO) technology, using color as a visual feature, and automatically determining the MAO process through a self-developed color image segmentation program for HSV channel. The robotic arm accurately regulates the machining position and duration. Dense ceramic oxide coatings of similar quality to the artificially prepared coatings were successfully prepared on aluminum (Al) surface. The surface morphology and elemental composition of the samples were characterized using scanning electron microscopy (SEM), energy dispersive spectrometry (EDS) and X-ray diffraction (XRD). The performance of the coatings was tested through thickness tests, hardness tests, and roughness tests. The tribological properties were tested by friction experiments, and its corrosion resistance was tested by electrochemical corrosion tests. The results confirm the effectiveness of a machine vision system for MAO process control, which is capable of preparing high-quality coatings comparable to manual operations. This not only solves the need for precise film formation in different application scenarios, but also provides a more efficient, controllable and innovative solution for the MAO process.

Predicted Fracture Tendency of Naturally Occurring Aluminum Surface Coatings under Tensile Loading.

Naturally occurring coatings on aluminum metal, such as its oxide or hydroxide, serve to protect the material from corrosion. Understanding the conditions under which these coatings mechanically fail is therefore expected to be an important aspect of predictive models for aluminum component lifetimes. To this end, we develop and apply a molecular dynamics (MD) modeling framework for conducting tension tests that is capable of isolating factors governing the mechanical strength as a function of coating chemistry, defect morphology, and variables associated with the loading path. We consider two representative materials, including γ-Al2O3 and γ-Al(OH)3 (i.e., oxide and hydroxide), both of which form readily as aluminum surface coatings. Our results indicate that defects have a significant bearing on the strength of aluminum oxide, with grain boundaries serving to reduce the strain at failure from εzz = 0.300 to 0.219, relative to perfect single crystal. Our simulations also predict that porosity lowers the elastic stiffness and yield strength of the oxide. Relative to perfect crystal, we find porosity factors of 5%, 10% and 20% decrease the yield stress by 26%, 36% and 53%, respectively. MD predicts that perfect hydroxide and oxide single crystal have respective strains at failure of 0.08 and 0.31 under tensile uniaxial strain loading, and that the corresponding yield stresses are respectively 1.6 and 11.1 GPa. These data indicate that the hydroxide is substantially more susceptible to mechanical failure than the oxide. Our results, coupled with literature findings that indicate hot and humid conditions favor formation of hydroxide and defective oxide coatings, indicate the potential for a complicated dependence of aluminum corrosion susceptibility and stress corrosion cracking on aging history.

Effect of adding K2TiF6 and K2ZrF6 to neutral electrolyte on the performance of plasma electrolytic oxidation coatings on AZ91 Mg alloy

The traditional alkaline electrolyte preparation of plasma electrolytic oxidation (PEO) coating ignites a significant spark, and the increase of micro-defects leads to a decrease in corrosion resistance. In this study, the preparation of PEO coating with neutral electrolyte was studied, and the effects of K2TiF6 and K2ZrF6 doping on the microstructure, phase composition, corrosion resistance and mechanical properties of the coating were explored. It was found that in neutral solution, the size and number of sparks decreased significantly, and the compactness of the coating increased. The phase composition was mainly MgF2. After the addition of K2TiF6 and K2ZrF6, the corrosion current density dropped from 256 to 28 and 61 nA/cm2. The long-term corrosion resistance of the coating was significantly improved. The hardness and adhesion of the coating were significantly improved.

Properties of silicon dioxide coatings obtained by nano physical vapor deposition (PVD) method on the titanium 13‐niobium 13‐zirconium alloy

AbstractSurface modification techniques play an important role in adjusting the physicochemical properties of titanium and its alloys. To reduce the penetration of alloying element ions into the body, various types of oxide coatings are used to protect it from the corrosive environment. Another important issue related to the surface layer requirement is ensuring an appropriate set of mechanical properties. Accordingly, in this study, the mechanical and electrochemical properties of the silicon dioxide layers formed by the deposition of nano physical vapor deposition on the surface of titanium and titanium 13‐niobium 13‐zirconium alloy samples were investigated. To evaluate the mechanical properties of the layers produced by this method, hardness tests were carried out, as well as tests on the adhesion of these layers to the metal substrate. On the other hand, electrochemical properties were studied using potentiodynamic measurements to assess the resistance to pitting corrosion, followed by impedance measurements to interpret the processes and phenomena occurring at the silicon dioxide layer/electrolyte interface. The data obtained showed different mechanical and electrochemical properties of the silicon dioxide layers generated with varying process parameters.

Experimental Design of the Adhesion between a PEI/Glass Fiber Composite and the AA1100 Aluminum Alloy with Oxide Coating Produced via Plasma Electrolytic Oxidation (PEO)

In this study, the AA1100 aluminum alloy underwent the plasma electrolytic oxidation (PEO) process to enhance its adhesion to a thermoplastic composite of polyetherimide (PEI) reinforced with glass fiber, following ASTM D1002:10 standards. A 23 factorial design was employed, varying three parameters in the oxidation process: immersion time, applied electric potential, and electrolyte concentration (Na2B4O7). The joining of aluminum and thermoplastic composite samples was achieved through oxy-fuel welding (OFW), using oxygen and acetylene gases. For the characterization of the joined samples, a universal tensile testing machine was utilized with a displacement speed of 1.5 mm/min. The analysis of the oxide coating involved scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and Fourier transform infrared spectroscopy (FT-IR). Through variance analysis, it was determined that the statistical model encompasses approximately 80% of the variability in the adhesion process between materials. An improvement of up to 104% in adhesion between the materials was observed with the process, indicating an effective bond due to the presence of the thermoplastic matrix in the treated aluminum sample. This improvement is attributed to the morphology of the oxide coating, resembling corals, with micro-pores and recesses that facilitated mechanical anchoring.

The influence of rolling on the corrosion and wear resistance of the MAO coating on ZM5 alloy

PurposeThe impact of rolling on the performance of micro arc oxidation (MAO) coatings on ZM5 alloy has been underreported. The purpose of this study is to explore the correlation between rolling and the failure mechanism of MAO coatings in greater depth.Design/methodology/approachThe influence of rolling on the corrosion and wear properties of MAO coating was investigated by phase structure, bond strength test (initial bond strength and wet adhesion), electrochemical impedance spectroscopy and wear test. The change of the surface electrochemical properties was studied by first principles analysis.FindingsThe results showed that the MAO coating on rolled alloy had better corrosion and wear resistance compared to cast alloy, although the structure and component content of two kinds of MAO coating are nearly identical. The difference in interface bonding between MAO coating and Mg substrate is the primary factor contributing to the disparity in performance between the two types of samples. Finally, the impact of the rolling process on MAO coating properties is explained through first-principle calculation.Originality/valueA comprehensive explanation of the impact of the rolling process on MAO coating properties will provide substantial support for enhancing the application of Mg alloy anticorrosion.Graphical abstract

Large amplitude voltage oscillations during plasma electrolytic oxidation (PEO) of niobium and their correlation with the porous morphology

Plasma electrolytic oxidation (PEO) is a technique that has been widely studied to obtain thick anodic oxide coatings based on aluminum, titanium, niobium, and other valve metals. In the case of niobium oxides, they are attractive because of their properties as semiconductors, biocompatibility, and high corrosion resistance. The electrochemical behavior during this process can vary according to the PEO parameters and influence characteristics such as coating thickness, adherence, morphology, and crystalline structure of the oxide film. In this study, unusual voltage oscillation transients are observed during the anodization of niobium under a galvanostatic PEO regime. The niobium substrates were anodized in three different electrolytic solutions (H3PO4, KOH, and C2H2O4), and the influence of temperature on the oscillation aspects in each one was investigated. In addition, three different current densities were tested to check the effect of this parameter on voltage oscillations. Scanning Electron Microscope (SEM), Energy Dispersive Spectrometer (EDS), and X-ray Diffraction (XRD) are used to characterize the samples. The results indicate a relationship between the exposed surface area and the pore morphology during the film growth in the oscillatory regime. A simultaneous process of oxide dissolution/pore filling and the micro-discharges observed during the PEO process is proposed.

Fabrication and Characterization of Nanostructured Tin doped Indium Oxide Coatings by the Instrument of Spray Pyrolysis

Nanostructured indium tin oxide (ITO) coating is one of the transparent conductive oxides (TCO) materials utilized as a transparent electrode. Due to its high demand in various applications like liquid crystal displays, touch screens, light emitting devices, and solar cells, ITO coatings have garnered significant research attention, owing to their excellent properties of high visible light transmittance and low resistance. Nanostructured coating of tin -doped Indium Oxide (ITO) was fabricated on glass slides utilizing the instrument of chemical spray pyrolysis (CSP), with varying levels of Sn-doping at 0, 3, 6, and 9 wt%. The effect of tin content on the many physical characteristics of the resulting coatings has been examined. The analysis of x-ray diffraction (XRD) displayed the characteristic orientations. The coatings have a polycrystalline cubic lattice structure along (400) as the preferred growth direction. Morphological measurements indicate that the samples possess a highly uniform surface and the grain size for the ITO samples is 100 nm displaying a nanostructure for all samples. The optical transmittance was measured over 75% for coating with tin content equal to 0wt%, while the transmittance of the Sn-doped films can range from 78% to 84% at 700 nm and the values of the direct bandgap were measured as 3.6, 3.65, 3.675, and 3.7eV for Sn doping 0, 3, 6, and 9 wt% respectively. In the visible area, the nanostructured ITO coatings exhibit elevated values of transmittance which makes them suitable for various optoelectronic applications such as window materials in solar cells. The results indicate a desirable reduction in the electrical resistivity with rising the number of carriers per unit volume and mobility with increasing tin content in the samples. The minimum electrical resistivity and maximum carrier concentration were achieved for ITO coating with tin content equal to 9wt%. The incorporation of Sn dopant significantly changes the overall electrical properties of indium oxide films, this is favorable for transparent conducting oxide.

High-performance ceramic coatings for additive manufacturing biofunctional titanium alloy by regulating precipitation orientation

To prepare high-performance plasma electrolytic oxidation (PEO) coatings with excellent wear resistance and antibacterial activity on biofunctional alloys, Ti-Cu alloy was fabricated by additive manufacturing (AM) technique with controlled crystalline orientation of precipitates to enhance Cu ions release during PEO. In contrast to ingot metallurgical (IM) Ti-Cu alloy with Ti2Cu-(103)-oriented, the Ti2Cu-(110)-oriented in AM-Ti-Cu alloy exhibits a lower work function and inferior corrosion resistance due to its low atomic close-packing. This facilitates the release of Cu ions by promoting valence electron escape from the 4 s energy level during PEO to promote forming a higher content copper oxide (CuO). Subsequent to the PEO treatment, the AM-PEO coating contains more CuO (44.44 wt%) compared to the IM-PEO coating (3.6 wt%), resulting in better corrosion resistance and a lower friction coefficient (0.13 for AM-PEO and 0.34 for IM-PEO). The antibacterial efficacy of AM-PEO coating reached 99.62 %. This study highlights the advantage of regulating precipitate phase orientation in AM processes as an innovative approach to efficiently fabricate functional PEO coatings for alloys.

Influence of graphene on corrosion properties of micro arc oxidation coatings on 7075 aluminum alloy

AbstractThis study uses 7075 aluminum alloy as the base material and employs micro arc oxidation technology to prepare ceramic coatings with different concentrations of graphene particles on the surface of the 7075 aluminum alloy. The effects of graphene particle concentration on micro arc oxidation behavior and coating performance were investigated through X‐ray diffraction, scanning electron microscope, electrochemical testing, and other performance characterization methods. The research results show that the addition of graphene particles helps to promote the transformation of metastable γ‐Al2O3 to stable α‐Al2O3, thereby enhancing the corrosion properties of the coating. When the concentration of graphene particles is 3 g/L, the prepared micro arc oxidation coating has the maximum thickness and hardness, which are 17.13 µm and 886.76 HV0.3, respectively, while the porosity and roughness are the smallest, which are .39 µm and 4.79%, respectively. Electrochemical test results show that the self‐corrosion current density is the smallest at this concentration, which is 2.323 × 10−9A/cm2. Therefore, the addition of graphene particles can effectively improve the corrosion properties of 7075 aluminum alloy.