Copper Oxide Research Articles

Model development and heat transfer characteristics in renewable energy systems conveying hybrid nanofluids subject to nonlinear thermal radiation

PurposeIn today’s world, the demand for energy to power industrial and domestic activities is increasing. To meet this need and enhance thermal transport, solar energy conservation can be tapped into via solar collector coating for thermal productivity. Hybrid nanofluids (HNFs), which combine nanoparticles with conventional heat transfer fluids, offer promising opportunities for improving the efficiency and sustainability of renewable energy systems. Thus, this paper explores fluid modeling application techniques to analyze and optimize heat transfer enhancement using HNFs. A model comprising solar energy radiation with nanoparticles of copper (Cu) and alumina oxide (Al2O3) suspended in water (H2O) over an extending material device is developed.Design/methodology/approachThe model is formulated using conservation laws to build relevant equations, which are then solved using the Galerkin numerical technique simulated via Maple software. The computational results are displayed in various graphs and tables to showcase the heat transfer mechanism in the system.FindingsThe results reveal the thermal-radiation-boost heat transfer phenomenon in the system. The simulations of the theoretical fluid models can help researchers understand how HNFs facilitate heat transfer in renewable energy systems.Originality/valueThe originality of this study is in exploring the heat transfer properties within renewable energy systems using HNFs under the influence of nonlinear thermal radiation.

An Experimental Mice Model for Ovalbumin‐Induced Allergic Rhinitis Imbued With Copper Oxide Green Nanoparticles From Leaf Extract of Laurus nobilis

ABSTRACTThis study aims to develop a safer and more effective treatment for allergic rhinitis using green‐synthesized copper oxide nanoparticles (CuO NPs) derived from Laurus nobilis (L. nobilis), addressing the limitations of current therapies. The environmentally friendly CuO NPs were evaluated for their antiallergic, anti‐inflammatory, and antimicrobial properties. Various analytical techniques confirmed the successful synthesis of CuO NPs. Phytoconstituents were identified using GC–MS, and molecular docking studies indicated that eugenol and 1H‐cyclopropazulen‐7‐ol, present in L. nobilis leaf extract, could be potential therapeutics targeting the FGFR2 protein. The antibacterial activity of CuO NPs was significant against Gram‐positive (Bacillus subtilis [B. subtilis] and Staphylococcus aureus [S. aureus]) and Gram‐negative (Escherichia coli [E. coli] and Klebsiella pneumoniae [K. pneumoniae]) bacterial strains. In a mouse model, the antiallergic effects were demonstrated by a significant reduction in symptoms like rubbing and sneezing and a decrease in inflammatory cell counts and mediators, including neutrophils, eosinophils, macrophages, lymphocytes, RORc, IL‐17A, IL‐5, IL‐13, and IL‐6. The preclinical results suggest that CuO NPs possess promising antibacterial, antiallergenic, and anti‐inflammatory properties.

A Comparative Study About Physical Properties of Copper Oxide and Zinc Oxide Nanoparticles on Fagus orientalis L. as Bioindicator

A Comparative Study About Physical Properties of Copper Oxide and Zinc Oxide Nanoparticles on Fagus orientalis L. as Bioindicator

A magnetohydrodynamic flow of a water-based hybrid nanofluid past a convectively heated rotating disk surface: A passive control of nanoparticles

Abstract One of the basic fluid mechanics problems of fluid flows over a revolving disk has both theoretical and real-world applications. The flow over a rotating disk has been the subject of numerous theoretical studies because it has many real-world applications in areas like rotating machinery, medical equipment, electronic devices, and computer storage. It is also crucial for engineering processes. Therefore, this article deals with a time-independent water-based hybrid nanofluid flow containing copper oxide and silver nanoparticles past a spinning disk. The Newtonian flow is taken into consideration in this analysis. The influence of magnetic field, thermophoresis, nonlinear thermal radiation, Brownian motion, and activation energy has been considered. The present analysis is modeled in a partial differential equation form and is then converted to ordinary differential equations using appropriate variables. A numerical solution using the bvp4c technique is accomplished using MATLAB software. The current results are matched with the previous literature and established a close relationship with previous studies. The purpose of this investigation is to numerically investigate the time-independent hybrid nanofluid flow comprising copper oxide and silver nanoparticles over a rotating disk surface. The results show that the increased magnetic parameters increase the friction force at the surface, which decreases the radial and azimuthal velocity distribution. At the sheet surface, the radial velocity of the hybrid nanofluid shows dominant performance compared to the nanofluid. On the other hand, the magnetic factor has dominant behavior on the azimuthal velocity component of the nanofluid flow compared to the hybrid nanofluid flow. The higher volume fraction and magnetic factor enhance the skin friction at the disk surface. Furthermore, greater surface drag is found for the hybrid nanofluid flow. The higher solid volume fraction, temperature ratio, and Biot number enhance the rate of heat transmission. Also, a higher rate of heat transmission is observed for the hybrid nanofluid flow.

Alginate/CuO-gC3N4 composite: a novel, reusable, non-toxic photocatalyst for methylene blue degradation.

Increasing industrial contamination necessitates development of sustainable water treatment solutions. Photocatalysis is a green technology utilizing light-activated materials (photocatalysts), which can degrade pollutants into harmless by-products. It is an emergent need to develop a photocatalyst that presents a significant advancement for sustainable water treatment and non-toxic to the environment. This study investigates the photocatalytic activity and in vitro cytotoxicity of a novel hybrid material comprising of alginate, copper oxide (CuO) and graphitic carbon nitride (gC3N4) for methylene blue (MB) degradation. The hybrid material was synthesized by a two-step process: (i) doping of CuO on gC3N4 through co-precipitation method formed CuO-gC3N4 (CG) and (ii) incorporation of CG in the calcium alginate (A) by ionotropic gelation method that is named as ACG. The characteristic features of the synthesized A, CG and ACG were studied using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). The optical characteristic of A, CG and ACG was studied using UV-diffuse reflectance spectroscopy (UV-DRS). The morphology and elemental composition of ACG was evaluated by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). To assess the environmental impact of ACG, a two-step approach was employed. First, the photocatalytic activity of ACG under UV-visible light (UV-vis) irradiation for MB degradation was evaluated. ACG exhibited photocatalytic activity by achieving 86.26% of degradation efficiency for MB within 60min. Second, the in vitro cytotoxicity of ACG, MB and MB degraded products towards tilapia gill cell lines were assessed. By comparing the toxicity of the MB and the secondary products, it is concluded that the overall process leads to a sustainable outcome.

Antibacterial Activity of Green Synthesized Copper Oxide Nanoparticles Using Muntingia calabura Leaf Extracts against Staphylococcus aureus and Escherichia coli

Antibacterial Activity of Green Synthesized Copper Oxide Nanoparticles Using Muntingia calabura Leaf Extracts against Staphylococcus aureus and Escherichia coli

Transformation of Engineered Copper Oxide Nanoparticles in Surface Waters.

Copper oxide nanoparticles (CuO-NPs) are widely used for their catalytic properties, conductive capacity, and innovations in the fields of superconductors, alloys, and solar energy sensors. To better understand the impact of water chemistry on the stability of CuO nanoparticles, a series of measurements were carried out on nanoparticles suspended in pure water, natural water, and water enriched with natural organic matter fulvic acid (FA). ICP-MS characterization in single-particle mode (SP-ICP-MS) was performed to determine the stability or transformation of nanoparticles in contrasting water conditions. We first observed that particle sedimentation was very fast in pure Milli-Q water. The addition of FA favored the dissolution of CuO-NPs with an increase in the dissolved copper concentration, for both Milli-Q water and natural water. The presence of FA also reduced the size of CuO-NPs (i.e., less aggregation) measured in natural water. By comparing signals of single particles, FA decreased nanoparticle numbers as well, confirming the increase in dissolution of CuO-NPs over time. The transformation products of CuO-NPs are important in the ecological context since the uptake and toxicity of parent nanoparticles differ from those of the chemical species in solution. Further considerations are needed on the fate of released NPs to better assess their exposure pathways to aquatic organisms and potential environmental risks.

One-pot fabrication of open-spherical shapes based on the decoration of copper sulfide/poly-O-amino benzenethiol on copper oxide as a promising photocathode for hydrogen generation from the natural source of Red Sea water

Abstract Harnessing green hydrogen production from natural Red Sea water offers an innovative solution to address energy challenges. A one-pot fabrication method is used to create novel nanocomposite thin films with open-spherical shapes, utilizing copper sulfide/poly-O-amino benzenethiol decorated on copper oxide as a promising photocathode. After thorough analysis, a unique morphology characterized by open spherical shapes is projected, which contributes to improved optical absorption. The bandgap of the nanocomposite is 1.17 eV, enabling efficient absorption of light across the entire optical spectrum, extending up to 950 nm. Utilizing Red Sea water as an electrolyte, the generated J ph serves as an indicator of H2 gas production. The substantial J ph value of −0.82 mA cm−2 is achieved at −0.85 V under light illumination. Furthermore, J ph values exhibit variability, starting at −0.58 mA cm−2 (at 730 nm) and increasing to −0.75 mA cm−2 at a wavelength of 340 nm. The estimated hydrogen gas production rate reaches 1.5 µmole h−1 cm−2, translating to an impressive 15 µmole h−1 for every 10 cm². This remarkable rate underscores the effectiveness of the photocathode, especially given its fabrication through a single-step process that is suitable for mass production. In addition, its cost-effectiveness further enhances its appeal as a viable solution for renewable energy production for hydrogen gas generation from seawater.

A numerical investigation of the polyethylene glycol‐based tetra hybrid nanofluid flow over a stretched porous rotatory disk

AbstractPolyethylene glycol (PEG) is a great heat and mass transmissive fluid that has promising applications in medical, pharmaceutical, and electronic industries. Tetra‐hybrid nanofluids (HNFs) are the most upgraded version of heat and mass transmissive nanofluids that are synthesized by dispersing four distinct nanoparticles in the carrier fluid. The study of the flow of nanofluids and their advanced classes across rotatory disks is receiving remarkable interest in research and innovation due to their considerable applications like gas turbine rotors, aeronautical, medical equipment, rotating machinery, thermal power developing systems, and so forth. Therefore, the present paper aims to inspect the magnetohydrodynamic, steady, three‐dimensional, and incompressible flow of a non‐Newtonian tetra‐HNF over a stretched porous rotating disk. The chosen tetra‐HNF consists of four distinct nanoparticles namely, molybdenum disulfide, copper oxide, magnesium oxide, and zirconium oxide with PEG as the carrier fluid. The flow model is modified with innovative impacts of variable thermal conductivity, thermal radiation, chemical reaction, variable mass diffusivity, and suction/injection to make this research more convenient. The mathematical computation is conducted via the bvp4c numerical method, and the outputs are determined via tables and graphs. Mounting values of the Deborah number amplify the axial velocity while augmentation is noticed in the fluid's radial and azimuthal velocities for rising values of the rotation parameter. Besides, the rotation parameter aids in enhancing both the heat and mass transportation rates while the chemical reaction parameter significantly aids the mass transportation rate. One of the significant results of this inspection is that tetra‐HNF exhibits better heat and mass transportation rates than the ternary‐HNF, and the HNF whereas it has lesser skin friction than the ternary‐HNF, and the HNF.

Thermal transport analysis for ternary hybrid nanomaterial flow subject to radiation and convective condition

Ternary nanomaterials are now recognized as useful not only for thermal efficiency importance but also to enhance physical characteristics of liquids. Insertion of three nanoparticles in base liquid is characterized as ternary hybrid nanomaterial. Such materials have better magnet properties, electrical conducting and mechanical resistance. Here we discuss three-dimensional magnetized stretched flow of ternary nanofluid through porous space is addressed. Porous space is scrutinized by Darcy-Forchheimer relation. Convective condition is imposed. Nanoparticles here include copper, polyphenol coated and aluminum oxide and water as conventional liquid. Energy equation consists of radiation, magnetohydrodynamics, dissipation and heat generation. Resulting dimensionless system is computed by Newton built in-shooting technique. Outcomes of velocity, temperature, skin friction and Nusselt number for emerging parameters of interest are organized. Comparison of results for ternary nanofluid (CoFe2O3+Cu+Al2O3/H2O), hybrid (CoFe2O3+Cu/H2O) and nanofluid (CoFe2O3/H2O) is examined. It is found that temperature and velocity against Hartman number have reverse trends. Temperature and Nusselt number for radiation have increasing features. Similar characteristics for temperature through heat generation and Eckert number is noticed. Larger thermal Biot number corresponds to rise the Nusselt number and temperature. An increase in temperature through Forchheimer number is witnessed while reverse trend holds for velocity.

Green synthesis of copper oxide nanoparticles using solanum melongena seeds extract and its applications in degradation of Rose Bengal dye, antibacterial, catalytic reduction and antioxidant activity

The generation of copper oxide (CuO) nanoparticles using a biogenic extract (solanum melongena seeds) was the primary focus of this study. As prepared catalyst has been utilized for dye degradation of Rose Bengal and studies on Antibacterial and Antioxidants. The catalyst was characterized for its structural aspects by using Scanning electron microscopy - energy dispersive spectroscopy (SEM-EDS), Powder X-ray Diffraction (PXRD), Fourier Transform - InfraRed spectroscopy (FT-IR), Thermogravimetric Analysis (TGA), Brunauer-Emmett-Teller (BET) and UV–Visible DRS. The characterization results of XRD shows that the catalyst is in monoclinic phase. Copper Oxide is irregular in morphology and the average particle size is 47.97 nm which can be obtained using the SEM images and EDS spectra shows the Oxygen and Copper atoms presence which indicates the free from impurities of the fabricated biogenic CuO nanoparticles. FT-IR result indicated the stretching frequency of Cu–O appears at 487 cm−1. TGA data reveal that high-purity and thermally stable nanoparticles were fabricated, by the absence of significant weight losses at temperatures greater than 400 °C. Through UV–Visible DRS the calculate band gap was found to be 2.8eV. Based on the characterisation results the best catalyst was used to degrade the Rose Bengal dye within 60 min and also carried out the antibacterial and antioxidant activity which was found to be satisfactory when compared with their standard values.

Development of a 1D-WO3 and CuO nanocomposite modified electrode for enhanced detection of 2,4-dichlorophenol

A common chlorinated phenol known as 2,4-dichlorophenol (2,4-DCP) was investigated electrochemically using cyclic voltammetry (CV) and square wave voltammetry (SWV). The electrochemical investigation was carried out at 1D nanostructured tungsten dioxide (WO3) and copper (II) oxide (CuO) nanocomposite-modified carbon paste electrode (CPE). The electrode's sensitivity was improved by the WO3/CuO nanocomposite, enabling investigators to more precisely measure the 2,4-DCP's electrochemical characteristics. The hydrothermal method was utilized to synthesize the WO3 NPs. The XRD, AFM, SEM, and EDS techniques were used to characterize the nanocomposite and WO3 NPs. Numerous parameters have been studied, including pH, concentration variation, scan rate variation, and accumulation time. Samples of soil, fruits, and vegetables were examined using the fabricated WO3/CuO/CPE. In the concentration range of 7.0 × 10−8 M to 2.6 × 10−7 M, a linear relationship was established along with the lower limit of detection of 0.17 × 10−8 M and the limit of quantification of 0.57 × 10−7 M. The 0.2 M phosphate buffer (PB) of pH 10.4 increased the peak current, which contributed to the WO3/CuO/CPE sensor's sensing performance and was highly sensitive with respect to 2,4-DCP detection. Anodic peak current was observed for the WO3/CuO/CPE is at -7.45 µA whereas for unmodified CPE is at -1.31 µA. According to the findings, the nanostructured WO3 and CuO nanocomposite showed exceptional sensitivity in identifying the electrochemical characteristics and reactions of 2,4-DCP.

Development of a high current density, high temperature superconducting cable for pulsed magnets

Abstract A low AC loss Rare Earth Barium Copper Oxide (REBCO) cable, based on the VIPER cable technology has been developed by Commonwealth Fusion Systems for use in high field, REBCO based tokamaks. The new cable is composed of partitioned and transposed copper ‘petals’ shaped to fit together in a circular pattern with each petal containing a REBCO tape stack and insulated from each other to reduce AC losses. A stainless steel jacket adds mechanical robustness—also serving as a vessel for solder impregnation—while a tube runs through the middle for cooling purposes. Additionally, fiber optic sensors are placed under the tape stacks for quench detection. To qualify this design, a series of experiments were conducted as part of the SPARC tokamak Central Solenoid Model Coil program—to retire the risks associated with full scale, fast ramping, high flux HTS Central Solenoid (CS) and Poloidal Field (PF) coils for tokamak fusion power plants and net energy demonstrators. These risk study and risk reduction experiments include (1) AC loss measurement and model validation in the range of ~5 T/s, (2) an IxB electromagnetic loading of over 850 kN/m at the cable level and up to 300 kN/m at the stack level, (3) a transverse compression resilience of over 350 MPa, (4) manufacturability at tokamak relevant speeds and scales, (5) cable to cable joint performance, (6) fiber optic based quench detection speed, accuracy, and feasibility, and (7) overall winding pack integration and magnet assembly. The result is a cable technology, now referred to as PIT VIPER, with AC losses that measure fifteen times lower (at ~5 T/s) than its predecessor technology; a 2% or lower degradation of critical current (Ic) at high IxB electromagnetic loads; no detectable Ic degradation up to 570 MPa of transverse compression on the cable unit cell; end to end magnet manufacturing, consistently producing Ic values within 7% of the model prediction; cable to cable joint resistances at 20 K on the order of ~15 nΩ; and fast, functional quench detection capabilities that do not involve voltage taps. This cable technology will be tested comprehensively in a Central Solenoid Model Coil to prove its readiness for compact, high field tokamak operation.

Development and Characterization of a Novel Bio-Based Brake Fluid Using Roselle Oil with Copper Oxide Nano Additive

Development and Characterization of a Novel Bio-Based Brake Fluid Using Roselle Oil with Copper Oxide Nano Additive

Use of Metallic Nanoparticles Against Eimeria-the Coccidiosis-Causing Agents: A Comprehensive Review.

Coccidiosis is a protozoan disease caused by Eimeria species and is a major threat to the poultry industry. Different anti-coccidial drugs (diclazuril, amprolium, halofuginone, ionophores, sulphaquinoxaline, clopidol, and ethopabate) and vaccines have been used for their control. Still, due to the development of resistance, their efficacy has been limited. It is continuously damaging the economy of the poultry industry because under its control, almost $14 billion is spent, globally. Recent research has been introducing better and more effective control of coccidiosis by using metallic and metallic oxide nanoparticles. Zinc, zinc oxide, copper, copper oxide, silver, iron, and iron oxide are commonly used because of their drug delivery mechanism. These nanoparticles combined with other drugs enhance the effect of these drugs and give their better results. Moreover, by using nanotechnology, the resistance issue is also solved because by using several mechanisms at a time, protozoa cannot evolve and thus resistance cannot develop. Green nanotechnology has been giving better results due to its less toxic effects. Utilization of metallic and metallic oxide nanoparticles may present a new, profitable, and economical method of controlling chicken coccidiosis, thus by changing established treatment approaches and improving the health and production of chickens. Thus, the objective of this review is to discuss about economic burden of avian coccidiosis, zinc, zinc oxide, iron, iron oxide, copper, copper oxide, silver nanoparticles use in the treatment of coccidiosis, their benefits, and toxicity.

Visible Light-Triggered Catalytic Performance of Reduced Graphene Oxide Decorated With Copper Oxide Nanocomposite for Degradation of Rhodamine B Dye and Kinetics Studies.

Herein, novel nanocomposites based on reduced graphene oxide decorated copper oxide nanoparticles (rGO/CuO) were prepared by the in situ co-precipitation method. The structural, morphological, and optical characterization of as-prepared nanocomposites was performed by powdered x-ray diffraction (p-XRD), scanning electron microscopy (SEM), and Fourier-transform infrared (FTIR), Raman, and ultraviolet-visible (UV-Vis) spectroscopy, respectively. The as-prepared nanocomposites exhibited better photocatalytic activity of rhodamine B dye with maximum ~94% degradation in 120 min with a rate constant of 0.2353 min-1 under optimized conditions. Furthermore, the effects of solution pH and catalyst loading are studied on the degradation process. Therefore, this state-of-the-art strategy for the decoration of CuO nanoparticles onto the surface of rGO nanosheets could be an ideal platform for fabricating highly efficient photocatalysts.

Copper oxide–modified screen-printed carbon electrodes for the detection of mycobacterium tuberculosis infection treating drug: Isoniazid

Copper oxide–modified screen-printed carbon electrodes for the detection of mycobacterium tuberculosis infection treating drug: Isoniazid

Bismuth doping unlocks stability of copper oxides in anodic reaction: A case analysis of glucose electrooxidation

The instability of transition metal oxides during long-term electrolysis significantly impedes their application in various electrochemical reactions. This study demonstrates an interfacial doping strategy utilizing bismuth to enhance the stability of CuO catalyst during glucose electrooxidation in alkaline media. This methodology reduces activity decay from 55% to 6% after 8 h of electrolysis, lowering charge transfer resistance without compromising the intrinsic catalytic activity of the Cu sites. The enhanced stability can be attributed to the formation of a Cu−O−Bi interface on the catalyst surface, which mitigates the interfacial Cu dissolution, as evidenced by in situ electrochemical impedance analysis. These findings underscore the potential efficacy of bismuth doping strategies in advancing the development of robust and efficient catalysts for anodic catalysis. Furthermore, this research highlights the prospect of employing main group metals as dopants in transition metal oxides, thereby expanding the horizon of possibilities in catalyst design.

Development, characterization and themo-physical analysis of energy storage material doped with TiO2 and CuO nano-additives

The paper presents the results of an experimental investigation on chemical stability, surface morphology, and thermo-physical properties of phase change material integrated with nano additives. The research aims to evaluate impact of varying nano-particle concentration on thermal performance of phase change material. The phase change material magnesium dichloride hexahydrate and potassium chloride mixed in different mass ratio along with different wt% concentration of nano-additives titanium dioxide and copper oxide to prepare novel phase change material. Characterization methods such as Fourier Transform Infrared Spectroscopy, Scanning electron microscope, Energy-dispersive X-ray analysis, and Differential scanning calorimeter analysis were employed. The Fourier transform infrared spectra indicated physical interactions between phase change material and nano-additives, while Energy-dispersive X-ray analysis confirmed elemental composition, and Scanning electron microscope demonstrated uniform distribution. The improved thermal properties of samples were reflected in their phase change enthalpy (284.57 J/g to 324.63 J/g), minimal energy loss (0.91 %–2.96 %), and low supercooling (0.3 %–5.26 %). Notably, doping with 1.5 wt% of titanium dioxide and copper oxide enhanced thermal conductivity by up to 117.07 % and specific heat capacity by up to 48.09 %. The introduction of nanoparticles significantly improves heat transfer characteristics, resulting in enhanced energy retention, reduced energy loss during phase transitions, decreased supercooling, and increased physical stability. These results suggest that optimized phase change material with nano-additives is highly effective for applications requiring stable and efficient thermal management.

Obtaining antimicrobial polymer composites based on copper oxide nanoparticles for sports medical devices.

Abstract The beneficial effects of using antimicrobial materials in eliminating or inhibiting microbial proliferation on surfaces are well known, thus contributing to reducing the risk of diseases resulting from accidents involving pathogenic microorganisms. The addition of certain metal particles in various proportions, (for example, silver, copper, or their oxides), in polymer matrices represents an effective method for producing new high-quality antimicrobial materials. In this study, the aim was to obtain a polymer/copper oxide composite with superior biocidal behaviour by using proportions ranging from 3-10% of copper oxides and polymers with different characteristics. The composites were prepared by melt mixing at various temperatures, durations, and homogenization speeds. Subsequently, the necessary samples for investigations were obtained through thermoforming. To evaluate the composite, tests were performed to determine mechanical characteristics, to verify the uniformity of particles in the composite material, and to test antimicrobial efficacy. The results demonstrated that the PP/CuO composite exhibited improved properties compared to pure polymers. These obtained characteristics recommend its potential use in medical devices for prevention or protection (examples include finger, ankle, or tendon prostheses), which can be produced through additive manufacturing or thermoforming.