Copper Oxide Research Articles

Feeding nanoparticles of copper oxide coated with lysine with or without added antagonists affects the copper status but not performance of Holstein dairy cows

The apparent absorption of copper (Cu) in ruminants is low, with between 0.01 and 0.07 g/g absorbed from sources such as copper oxide (CuO) under typical feeding conditions, resulting in high levels of excretion. Improving the bioavailability of Cu could reduce the supplemental amount required to maintain Cu status and reduce excretion, particularly in the presence of dietary antagonists such as sulfur (S) and molybdenum (Mo). The objective of our study was to determine the Cu status of cows when fed nanoparticle CuO coated with Lys compared with conventional CuO when fed without or in combination with antagonists to Cu absorption (S and Mo) in the diet of dairy cows. Fifty-six multiparous Holstein-Friesian cows that were 48 d ± 17.4 (mean ± SD) post calving and yielding 40.6 ± 6.9 kg milk/d were used in a 2 × 2 factorial design. The 4 treatment groups were; CuO (O-), CuO with added antagonists (O+), nano CuO with a lysine coating (N-), and nano CuO with a Lys coating with added antagonists (N+), fed for 16 wks. We formulated the diets to contain approximately 17 mg Cu/kg dry matter (DM) and diets with antagonists contained an additional 1 g S/kg DM and 6 mg Mo/kg DM, with Lys added to O- and O+ to provide the same daily supply as N- and N+. Blood samples were collected at wk 0, 2, 4, 6, 10 and 16, and liver biopsy samples at wk 0 and 16. We found no effect of dietary treatment on DM intake, milk yield, live weight or body condition score, with mean values of 23.3 kg/d, 40.1 kg/d, 646 kg and 2.68, but milk SCC was higher in cows fed conventional compared with non CuO, or with added antagonist. We also found no effect of treatment on blood activity of gamma glutamyl transferase, superoxide dismutase or ceruloplasmin, hematology profile, or plasma Cu and iron concentration. We found that plasma Mo concentration was increased from 0.36 µmol/L in cows fed O- or N- to 0.80 µmol/L in those receiving O+ or N+. Additional dietary antagonists also decreased the concentration of Cu in the liver of cows fed conventional CuO (C+) over the study period by 1.3 mg/kg DM/d, but in cows fed dietary antagonists and nano CuO coated with Lys (N+), liver Cu concentration was increased by 1.1 mg/kg DM/d. Our study is the first to demonstrate that reducing the particle size of CuO into the nano scale with a lysine coating improves the bioavailability of CuO in the presence of dietary antagonists in dairy cattle, and we did not observe any negative effects on performance or health.

Response Of the Cocoa Crop to The Application of Foliar Biostimulants for Fruit Set and Setting, City of Vinces

The present research work was carried out during the rainy season in the province of Los Ríos, Vinces canton in the Anchoveta area. The purpose of this study was to evaluate the flowering of the CCN51 cocoa crop (Theobroma cacaco L.), in addition to evaluating the number of fruit set and fruit set with the use of the following foliar biostimulant: biostimulant based on humic acid, biostimulant a amino acid base and foliar fertilizer based on copper oxide. A DBCA experimental design (completely randomized block design) was used with seven treatments and three repetitions. The statistical analysis indicated a significant difference in the number of flowers and fruit set and fruit set between the treatments in the studies. The treatment with the highest number of flowers was T7 with the use of Ferticacao edaphic fertilizer, while the treatment with the highest number of fruit set and fruit set was treatment T6 with the use of the amino acid-based biostimulant accompanied with the foliar fertilizer. copper oxide base.

Testing and Evaluation of Hybrid Polymer Composites Reinforced with Moringa oleifera and Boehmeria nivea Fibers, Embedded with Copper Oxide Particulates, for Thermal, Structural, and Biological Properties

Abstract The increasing need for sustainable materials in industrial applications has prompted a significant shift in attention from synthetic to natural fibers. This study examines the problems and opportunities arising from the utilization of natural fiber-reinforced polymer composites in several industrial sectors. The objective of this work is to fabricate a hybrid composite using a conventional hand layup technique with natural reinforcement of Moringa oleifera (MO) and ramie (Boehmeria nivea) fibers, an epoxy matrix blended with copper oxide filler, utilized to enhance material stability and antimicrobial activity. To quantify the effect of five different weight fractions of MO and ramie fibers on this hybrid composite, its mechanical, thermal, functional, and antifungal properties were examined. The superior tensile strength (61.34 MPa), flexural strength (64.78 MPa), and impact energy (23 J) results indicate that ramie fiber loading should be increased. Additionally, enhanced thermal properties such as thermal conductivity (0.93 W/mK), heat deflection temperature (97°C), thermal expansion coefficient (1.7210−5/°C), and maximal thermal stability were observed at 347°C as a result of the increased ramie fiber loading. This analysis demonstrates that this hybrid composite possesses the antifungal activity necessary to form an inhibition zone against Candida albicans. Scanning electron microscopy analysis was conducted to determine the hybrid composites’ bonding strength and failure mode.

Copper oxide decorated one-dimensional mineral nanorods: Construction of strengthened gas-phase and condensed-phase coupled intumescent flame retardant

Polycarbonate/acrylonitrile–butadiene–styrene (PC/ABS) features superior mechanical properties but suffers from high flammability, presenting a grand challenge in enhancing its flame retardancy with halogen-free additives. Herein, we developed an efficient flame-retardant system (BH/CuATP) by incorporating phosphazene additive (HP), copper oxide modified attapulgite (CuATP) and bisphenol A bis (diphenyl phosphate) (BDP). This system achieves a UL-94V-0 rating without melt-dripping and leads to reductions in the peak heat release rate (43.1 %), total heat release (29.8 %) and total smoke production (5.7 %). The strength effect of CuATP in both gas-phase and condensed-phase significantly contributes to its enhanced fire safety. Additionally, the mechanical properties of PC/ABS/B1H1/CuATP1 are improved due to the rod-like CuATP, showing enhanced comprehensive properties superior to other reported systems. This work presents valuable insights into the effectiveness of mineral-strength intumescent flame retardancy for PC/ABS, offering practical guidance for the development of high-performance PC/ABS composites.

Geochemical indices and sedimentation rates in the Pardo River basin, São Paulo state, Brazil

Sediment geochemical indices and sedimentation rates data from the Pardo River watershed, São Paulo State, Brazil, provide relevant reference guidelines for stakeholders to plan future actions aiming to achieve the appropriate management of that hydrographic basin. The watershed includes 20 municipalities where about 650,000 inhabitants are living and whose waters after withdrawal and treatment supply ∼300,000 people in that region. Six sediment cores provided the geochemical and radiometric dataset, which was obtained from sampling sites located in the following cities: Ourinhos, Santa Cruz do Rio Pardo, Águas de Santa Bárbara, Avaré, Botucatu, and Pardinho. The concentration data for some metals were compared with the reference values established by the Brazilian environmental legislation for sediment dredging because currently there is a lack of specific quality guidelines for marine or fluvial sediment in Brazil. Also, the entire dataset was used in the calculation of two traditional geochemical indices, i.e., the enrichment factor (EF) and contamination factor (CF). In some cores, both indices provided insight revealing possible anthropogenic inputs of magnesium oxide (MgO), potassium oxide (K2O), sulfur trioxide (SO3), vanadium oxide (V2O5), copper (II) oxide (CuO), and other constituents due to development of activities related to the crop production. The constant rate of supply (CRS) of the unsupported/excess lead 210 (210Pb) model has been successfully applied to the obtained a radiometric 210Pb dataset, yielding mean values of the mass accumulation rate (MAR) between 0.86 and 7.23 g/(cm2·y) and linear sedimentation rates (LSR) ranging from 2.9 to 7.1 cm/y. Both of these rates exhibited a significant correlation, representing physical weathering processes occurring in the basin. Chemical weathering rates reported in the literature indicate values much lower than the physical weathering rates and such findings have also been confirmed in the current study when the obtained data were compared with results from previous investigations in the Pardo River watershed. The CRS 210Pb chronological model was useful to track historical changes in the MgO and CuO concentration in the sediment cores, allowing curves to be plotted exhibiting major peaks in core 1 (1980–2010) and core 3 (2000–2010), a continuous increase from 1970 onwards until 2010 (core 4), and a sharp increase at the end of the monitoring period, 2017 (cores 5 and 6). Data available for the harvested area at a municipality located within the basin for the period 1990–2022 have indicated a more pronounced increase over the last years in the production of sugar cane, soybeans, and oranges, implying an increasing use of fertilizers and agricultural correctives for crop production, whose chemical composition would justify the trends observed for MgO and CuO concentrations in the sediment cores. The current study also revealed a wide range of significant relations involving the concentration of ferric oxide (Fe2O3) and other analyzed constituents, with iron tending to accumulate in the finer grain sizes (from 0.125 to <0.037 mm) of the sediment. The CRS 210Pb chronological model permitted evaluation of the history of the iron flux up to the present, which could represent baseline guidance levels for indicating future anthropic inputs in the basin.

Ultra-selective hydrogen sensors based on CuO - ZnO hetero-structures grown by surface conversion

Synergistic effects of mixed oxides have the potential to improve sensing performances of environmental, domestic and industrial monitoring devices. However, mixed oxides often come in the form of separate particles and are thus addressed separately by the environment, instead of capitalizing on the interface between the metal oxides. This paper describes a new core@shell gas sensing material of tetrapodal zinc oxide with a surface coating of crystalline copper oxide(t-ZnO@CuO). The special surface conversion strategy yields a unique, self-assembled and pinhole-free coating of CuO nanoplatelets. The morphologies, structural, chemical and gas sensing properties of the heterostructure were investigated. To evaluate the sensing properties of the heterostructure, t-ZnO@CuO was fabricated as nanosensors, consisting of one core-shell rod of CuO-coated crystalline ZnO. The single core@shell rod showed high selectivity towards hydrogen already at comparatively low operation temperatures of 150 °C. Computational calculations based on the density functional theory (DFT) have been carried out to understand the interaction of the H2 gas molecule with the surface of the CuO nanostructures. The surface conversion was done wet chemically and is a novel method for generating heterostructures that can be potentially transferred to heterojunctions with unique properties for chemosensors.

Biogenic Synthesis of Copper Oxide Nanoparticles from Aloe vera: Antibacterial Activity, Molecular Docking, and Photocatalytic Dye Degradation.

Green synthesis methods offer a cost-effective and environmentally friendly approach to producing nanoparticles (NPs), particularly metal-based oxides. This study explores the green synthesis of copper oxide nanoparticles using Aloe vera (Aloe barbadensis Miller) leaf extract. The characterization revealed a unique sago-shaped morphology revealed by field-emission scanning electron microscopy and X-ray diffraction analysis. Distinctive metal-oxygen bonds at 521 and 601 cm-1 were confirmed by Fourier-transform infrared (FT-IR) spectroscopy. Furthermore, UV-visible spectroscopy revealed absorbance at 248 nm, suggesting electron transitions across energy bands and varying surface conduction electrons. The band gap value indicated the presence of quantum confinement effects, which were probably caused by the distinctive morphology and surface structure of the biogenic NPs. Additionally, molecular docking studies were carried out against key proteins of Salmonella typhi and Listeria monocytogenes, namely, listeriolysin O (PDB ID: 4CDB), internalin (InlA) (PDB ID: 1O6T), Salmonella effector protein (SopB) (PDB ID: 4DID), and YfdX (PDB ID: 6A07) using AutoDock 4.2. The results revealed binding energies against S. typhi and L. monocytogenes proteins, indicating potential interactions establishing the foundation for further in-depth understanding of the molecular basis underlying the observed antibacterial effects in vitro against S. typhi, Klebsiella pneumoniae, Pseudomonas aeruginosa, and L. monocytogenes. Antibacterial activity evaluation yielded impressive results, with CuO NPs displaying significant activity against S. typhi and L. monocytogenes, exhibiting zones of inhibition values of 13 ± 0.02 and 15 ± 0.04 mm, respectively. Moreover, the CuO NPs demonstrated remarkable photocatalytic efficacy, resulting in the degradation of 77% of the methylene blue dye when exposed to UV irradiation. This study highlighted the potential of green-synthesized CuO NPs derived from A. vera with their unique morphology, interesting spectroscopic properties, and promising antibacterial and photocatalytic activities.

Unlocking Wearable Microbial Fuel Cells for Advanced Wound Infection Treatment.

Better infection control will accelerate wound healing and alleviate associated healthcare burdens. Traditional antibacterial dressings often inadequately control infections, inadvertently promoting antibacterial resistance. Our research unveils a novel, dual-functional living dressing that autonomously generates antibacterial agents and delivers electrical stimulation, harnessing the power of spore-forming Bacillus subtilis. This dressing is built on an innovative wearable microbial fuel cell (MFC) framework, using B. subtilis endospores as a powerful, dormant biocatalyst. The endospores are resilient, reactivating in nutrient-rich wound exudate to produce electricity and antibacterial compounds. The combination allows B. subtilis to outcompete pathogens for food and other resources, thus fighting infections. The strategy is enhanced by the extracellular synthesis of tin oxide and copper oxide nanoparticles on the endospore surface, boosting antibacterial action, and electrical stimulation. Moreover, the MFC framework introduces a pioneering dressing design featuring a conductive hydrogel embedded within a paper-based substrate. The arrangement ensures cell stability and sustains a healing-friendly moist environment. Our approach has proven very effective against three key pathogens in biofilms: Pseudomonas aeruginosa, Escherichia coli, and Staphylococcus aureus demonstrating exceptional capabilities in both in vitro and ex vivo models. Our innovation marks a significant leap forward in wearable MFC-based wound care, offering a potent solution for treating infected wounds.

Onion Peel Extract/Copper Oxide Nanoparticles as Corrosion Inhibitors for Carbon Steel in Hydrochloric Acid: Extraction, Characterization, Electrochemical Study, and Theoretical Explorations

The effectiveness of onion peel extract (OPE) as a corrosion inhibitor for carbon steel in a 1 M hydrochloric acid solution was investigated using weight loss (WL) techniques, potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), and surface morphological examination. Additionally, this process was characterized by Fourier transform infrared (FT-IR) spectroscopy, energy dispersive X-ray spectroscopy (EDX), thermogravimetric analysis (TGA), atomic force microscopy (AFM), and transmission electron microscopy (TEM). According to weight loss measurements, the protective efficiency of OPE increases with rising OPE concentration and decreases with increasing temperature of the corrosive solution. Polarization curves indicate that OPE acts as a mixed-type inhibitor in hydrochloric acid. The adsorption mechanism, supported by EIS results, shows that charge-transfer resistance increases and double-layer capacitance decreases with higher inhibitor concentration. The adherence of OPE to carbon steel follows the Langmuir isotherm, indicating a physical adsorption process, and the spontaneous adsorption of the inhibitor molecules is evidenced by the negative values of Gibb’s free energy of adsorption. The synergistic effect of copper oxide nanoparticles (CuO–NPs) in combination with OPE on the corrosion inhibition of carbon steel was also evaluated. The results demonstrated that the inhibition efficiency of OPE is enhanced in the presence of CuO–NPs due to synergistic interactions between OPE extract molecules and CuO–NPs. The electron-donating capacity of the chemical components in OPE was confirmed through theoretical studies employing quantum chemistry methods.

Effect of vacuum-ultraviolet irradiation on structure and resistivity of epitaxial copper oxide thin films

Effect of vacuum-ultraviolet irradiation on structure and resistivity of epitaxial copper oxide thin films

Synthesis and characterization of a composite incorporating metal organic frameworks, copper oxide nanoparticles, and graphene oxide and evaluating its multifaceted potential in photocatalysis and electrochemical sensing

Synthesis and characterization of a composite incorporating metal organic frameworks, copper oxide nanoparticles, and graphene oxide and evaluating its multifaceted potential in photocatalysis and electrochemical sensing

Integrated in silico analysis of transcriptomic alterations in nanoparticle toxicity across human and mouse models

Nanoparticles, due to their exceptional physicochemical properties are used in our day-to-day environment. They are currently not regulated which might lead to increased levels in the biological systems causing adverse effects. However, the overall mechanism behind nanotoxicity remains elusive. Previously, we analysed the transcriptome datasets of copper oxide nanoparticles using in silico tools and identified IL-17, chemokine signaling pathway, and cytokine-cytokine receptor interaction as the key pathways altered. Based on the findings, we hypothesized a common pathway could be involved in transition metal oxide nanoparticles toxicity irrespective of the variables. Further, there could be unique transcriptome changes between metal oxide nanoparticles and other nanoparticles. To accomplish this, the overall transcriptome datasets of nanoparticles consisting of microarray and RNA-Seq were obtained. >90 studies for 17 different nanoparticles, performed in humans, rats, and mice were assessed. After initial screening, 24 mouse studies (with 196 datasets) and 34 human studies (with 200 datasets) were used for further analyses. The common genes that are dysregulated upon NPs exposure were identified for human and mouse datasets separately. Further, an overrepresentation functional enrichment analysis was performed. The common genes, their gene ontology, gene-gene, and protein-protein interactions were assessed. The overall results suggest that IL-17 and its related pathways might be commonly altered in nanoparticle exposure with lung as one of the major organs affected.

Irradiation effects on copper oxide superconductors including high-entropy REBCO(HE-REBCO)

Polycrystalline specimens of copper oxide superconductors YBa2Cu3O7-δ(YBCO), Y0.39Sm0.30Eu0.31Ba2Cu3O7-δ(ME-REBCO), Y0.18La0.24Nd0.14Sm0.14Eu0.15Gd0.15Ba2Cu3O7-δ (HE-REBCO) were irradiated with 1 MeV-He ions at room temperature. Magnetization measurement using superconducting quantum interference device (SQUID) and microstructure observation using transmission electron microscope (TEM) were conducted before and after irradiation. The improvement of properties in HE-REBCO and degradations in YBCO, ME-REBCO were suggested by SQUID measurement. HE-REBCO had smaller irradiation defects and volume fractions although disappearance of twin boundaries due to tetragonal transition occurred in peak-damage area as well as YBCO. These defects work as optimal flux pinning centers leading to improve properties in HEREBCO.

Influence of low copper oxide additives on B2O3-Li2O-Na2O-CaO-SrO-As2O3 glasses: a physical, structural, and radiological study

Influence of low copper oxide additives on B2O3-Li2O-Na2O-CaO-SrO-As2O3 glasses: a physical, structural, and radiological study

Synergistic photocatalysis and superior supercapacitor performance of cerium-enriched monodispersed nanoarchitectures: Dual excellence

Researchers are being focused on designing sustainable and renewable energy storage systems, especially electronically tuned energy storage devices, due to increased electricity demand and fossil fuel depletion. Batteries and supercapacitors have substantially improved energy storage in recent years. In the course of developing nanomaterials with sustainable dual functionality, this study reviews the synthetic and dual applications of cerium-enriched copper oxide monodispersed nanomaterials, especially their synergic photocatalysis, which is much better than their superior supercapacitor storage. The sol-gel method was used for the preparation of nanoarchitectures, in which the crystalline structure and morphology were studied using X-Ray diffraction spectroscopy (XRD) and Scanning electron microscope (SEM) techniques. An important fact is that the nanoarchitectures with 10 % cerium showed their crystallite size, which was reported to be 17.30 nm, implying accuracy in the synthesis. The results of SEM indicate single-phase particles with slight agglomeration. The corresponding 10 % CeO2@CuO nanostructures were then comprehensively evaluated for both photocatalytic activities and energy storage purposes. In relation to photocatalysis, nanoarchitectures proved to be efficient for Rhodamine B (RhB) dye with 92 % degradation after 200 min of the reaction time. Moreover, the synthesized nanoparticles demonstrated excellent supercapacitor performance. The tailor-synthesized nanoarchitectures had a specific capacitance of 875 F/g and energy density achieved 78 Wh/g, which clearly shows the prospect for such materials used in high-energy storage devices. The10 % CeO2@CuO nanoarchitecture retained 88 % of capacitance for 2000 cycles, which made it possible to demonstrate the good robustness and durability of the materials for long-term utilization in energy storage. These findings contribute to the field of nanoscience and nanotechnology, offering a hopeful channel for the future development of advanced materials that have dual functionality.

A nano-sensor for copper oxide was manufactured and developed using a new organic precipitant via green chemistry methods

Green chemistry methods were applied to fabricate a nanoelectrode to capture copper ions for the first time using the new organic reagent (4-(3-(2-(3-nitrophenyl)-4,7-dioxo-1,3-oxazepin-3(2H, 4H, (7H)- yl) thioureido. The ionic double was prepared to manufacture the new copper oxide nanoelectrode from the reaction of the new organic reagent and used it as an organic precipitant with CuO-NP nanoparticles prepared from cinnamon extract using the simple green aqueous method. Several techniques were used (XRD, FTIR, SEM) to characterize these particles. This electrode shows excellent selectivity and sensitivity with a linear range of (10-3 -10-13) M, correlation coefficient (0.9998), electrode life of 77 days, ideal temperatures (30) °C and range Optimum pH (3-9), slope (11.082 mV/decade), limit of detection (9.79×10-13) M. The average crystal size measured by the XRD device was (25) nm. The particles were seen by SEM as spherical. Or almost spherical in shape. UV-Visible spectroscopy, the peak was at wave length at (798) nm. This confirms that nanoparticles have been obtained for Copper material. Functional aggregates were determined by FTIR measurement. Recovery value of (101.1) %. This method was successfully applied to estimate copper ions in polluted water.

Impact of surface treatment and addition of CuO NPs of surface roughness of acrylic denture base bonded to soft liner

Background: The import of the rough surface makes the application of several elements to enhance this feature vital for the adhesion of soft liners. Aim: The study's goal was to to ascertain the impact of copper oxide nanoparticles added in two ratios to heated-cured acrylic resin and fiber laser surface treatment on surface roughness. Materials and methods:60 acrylic specimens in the shape of discs were manufactured and divided into three groups: one received no addition; the other two received the addition of 0.3% CuO NPs; and a third group that received the addition of 0.5% CuO NPs. Each group was divided into two categories: those that were laser treatment and those who did not. The surface roughness test was then examined using a roughness tester called a profilometer. Results: The average roughness values were high for the control groups and low for the CuO NPs 0.5% groups. The mean values in the laser-treated groups had greater roughness than the control groups, according to the laser application.Conclusion:. As the fraction of CuO NPs increased, the surface roughness reduced. The laser treatment also reduced surface roughness.

Comparative analysis of the antimicrobial activity of copper and copper oxide nanoparticles against Botrytis cinerea

Comparative analysis of the antimicrobial activity of copper and copper oxide nanoparticles against Botrytis cinerea

Synthesis of copper hexacyanoferrate from copper oxide catalyzed by trimesic acid for removal of radioactive cesium

Synthesis of copper hexacyanoferrate from copper oxide catalyzed by trimesic acid for removal of radioactive cesium

Antioxidant, antiglycation, and antibacterial of copper oxide nanoparticles synthesized using Caesalpinia Sappan extract.

Synthesis of metal nanoparticles using plant extracts is environmentally friendly and of increasing interest. However, not all plant extracts can meet successfully on the synthesis. Therefore, searching for the high potential extracts that can reduce the metal salt precursor in the synthesis reaction is essential. The present study explores the synthesis of copper oxide nanoparticles (CuONPs) using Caesalpinia sappan heartwood extract. Phytochemical analysis and determination of the total phenolic content of the extract were performed before use as a reducing agent. Under the suitable synthesized condition, a color change in the color of the solutions to brown confirmed the formation of CuONPs. The obtained CuONPs were confirmed using ultraviolet-visible spectroscopy, photon correlation spectroscopy, X-ray diffraction, scanning electron microscope, energy dispersive X-ray, and Fourier transform infrared analysis. The synthesized CuONPs investigated for antioxidant, antiglycation, and antibacterial activities. CuONPs possessed antioxidant activities by quenching free radicals with an IC50 value of 63.35 µg/mL and reducing activity with an EC range of 3.19-10.27 mM/mg. CuONPs also inhibited the formation of advanced glycation end products in the bovine serum albumin/ribose model with an IC50 value of 17.05 µg/mL. In addition, CuONPs showed inhibition of human pathogens, including Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli, and prevention of biofilm formation and biofilm eradication, with maximum inhibition of approx. 75%. Our findings suggest that C. sappan extract can be used to obtain highly bioactive CuONPs for the development of certain medical devices and therapeutic agents.