Organic Solderability Preservative Research Articles

Surface finishes in a lead‐free world

PurposeThe aim of this paper is to detail the changes needed to ensure compatibility of printed‐circuit board (PCB) surface finishes with the use of lead‐free solders and in lead‐free assembly processes.Design/methodology/approachThe paper describes the various popular solderable surface finishes that are currently available. It then reviews them in terms of the required adaptations necessary to meet the requirements of the Restriction of Hazardous Substance (RoHS) Directive and to ensure compliance, whilst meeting the performance needs of the product.FindingsSome of the available and popular finishes, such as organic solderability preservatives and tin require modifications while, others including silver, direct immersion gold and electroless nickel immersion gold are transitioning well into the world of lead‐free. Electroless nickel, electroless palladium, immersion gold is one finish that performs better with lead‐free assembly than it did with conventional eutectic solder‐based approaches.Originality/valueThe paper provides a concise overview of the implications for specific surface finishes when making choices for use with lead‐free and RoHS compliant PCB soldering and assembly.

Morphology and Growth of Intermetallics at the Interface of Sn-based Solders and Cu with Different Surface Finishes

Several types of surface finishes have been applied on Cu substrates in an effort to facilitate bonding and improve the reliability of lead-free solder joints. In the current research, the effects of printed circuit board surface finishes on the reliability of the solder joints were investigated by examining the morphology and growth behavior of the intermetallic compounds (IMCs) between Sn-based solders and different surface finishes on Cu. Three types of Cu substrates with different surface finishes were fabricated in this study: organic solderability preservative (OSP)/Cu, Ni/Cu, and electroless nickel immersion gold (ENIG)/Cu. Sn-3.5Ag and Sn-3.0Ag-0.5Cu were used as the solders. In the experiment, the solder joint specimens were aged isothermally at 150°C for up to 1000 h. Experimental results revealed that the OSP surface finish promoted the interdiffusion between Cu and Sn during soldering. The composition and morphology of the IMC layer at the solder/Ni/Cu interface were sensitive to the Cu concentration in the solder. Meanwhile, the solder joints with different morphological features of the IMCs exhibited significant differences in shear strengths. The Au-containing ENIG surface finish affected the shear strength of the solder joint significantly at the initial stage of isothermal aging.

Effects of isothermal aging and temperature–humidity treatment of substrate on joint reliability of Sn–3.0Ag–0.5Cu/OSP-finished Cu CSP solder joint

This study examined the effects of isothermal aging and temperature–humidity (TH) treatment of substrate on the joint reliability of a Sn–3.0Ag–0.5Cu (wt.%)/organic solderability preservative (OSP)-finished Cu solder joint. Two types of OSP-finished chip-scale-package (CSP) substrates were used, those subjected and not subjected to the TH test. This study revealed an association between the interfacial reaction behaviors, void formation and mechanical reliability of the solder joint. Many voids were formed at the interface of the OSP-finished Cu joint subjected to the TH test. These voids were caused by the oxidation of the OSP-finished Cu substrate during the TH test. In the shear tests, the shear force of the joint with the substrate not subjected to the TH test was slightly higher than that with the TH test. The mechanical reliability of the solder joint was degraded by voids at the interface.

Electrical and reliability properties of isotropic conductive adhesives on immersion silver printed-circuit boards

Electrically conductive adhesive (ECAs) have been used for many years in both the anisotropic conductive adhesive (ACA) and isotropic conductive adhesive (ICA) forms for microelectronic packaging applications and as an alternative to lead (Pb) soldering technology. Especially, environmentally friendly ICAs offer many advantages over solder, such as simple and low temperature process conditions and better thermo-mechanical performance. However, a number of reliability questions linger, and continue to be studied. In particular, the ICA-to-pad contact resistance can increase with time due to the galvanic corrosion of dissimilar contact and ICA-filler metals (Lu et al., IEEE Trans Electron Packag Manuf 22:228–232, 1999). ICAs are usually silver (Ag) epoxy composites, and the corrosion potential should be completely eliminated by the use of Ag contact pads. To completely eliminate lead (Pb) from electronics, the printed wiring board (PWB) must also change from hot-air-leveled solder (SnPb) to alternative metallic finishes, such as immersion-silver (Ag), immersion-tin (Sn), electroless nickel (Ni)/immersion-gold (Au) and organic solderability preservative (OSP) (Pas, in European institute of printed circuits summer conference, 2005). Especially, immersion-Ag is one of the leading Pb-free final finish choices for many OEMs in the telecommunications, computer, automotive and consumer electronics industries, because of its excellent properties and reasonable cost. This paper presents the electrical properties of Ag epoxy composite ICAs materials on Cu-finished and immersion-Ag finished PWBs, as solder replacements for SMT or flip chip technologies. All PWBs were subjected to 85°C/85% relative humidity (RH) aging testing, with junction resistance monitored for comparison of the immersion-Ag board to the Cu-finished board as a control. We expected that the corrosion potential, which is one of main causes to degrade conductivity between ICAs and PWB, should be eliminated by the use of Ag contact pads with the Ag epoxy composite ICAs materials. Not only is the junction resistance of immersion-Ag finished boards lower than that of Cu finished boards, but its junction resistance changes are smaller than those of Cu-finished boards, as expected.

Board level reliability of lead‐free designs of BGAs, CSPs, QFPs and TSOPs

PurposeThe purpose of this paper is to describe the board level reliability test results of four IC packages with lead‐free balls/platings, soldered with lead‐free solder paste, during thermal cycling. The board level reliability test results of tin‐lead balled/plated packages soldered with lead‐free solder paste have also been included for comparison.Design/methodology/approachFour different packages, i.e. ball grid array (BGA), chip scale package (CSP), quad flat package (QFP) and thin small outline package (TSOP), were assembled on a test printed circuit board (PCB) as the test vehicle. Lead‐free and tin‐lead BGA/CSP packages were equipped with Sn‐3.0Ag‐0.5Cu and Sn‐37Pb solder balls, respectively. The lead‐frames of lead‐free QFP/TSOP leaded‐packages were plated with Sn‐58Bi and those of tin‐lead QFP/TSOP leaded‐packages, Sn‐37Pb. The lead‐free solder paste used in this study was Sn‐3.0Ag‐0.5Cu. Two kinds of surface finishes, immersion gold over electroless nickel (Au/Ni) and organic solderability preservative, were used on the PCBs. The test PCBs were thermal cycled 5,000 times within the temperature range of −40 to 125°C and electrically monitored during the thermal cycling.FindingsIt was found that the tin‐lead balled/plated BGAs, CSPs, QFPs and TSOPs soldered with lead‐free solder paste showed serious board level reliability risks as their abilities to withstand thermal cycling stresses are much weaker than those of entirely lead‐free assemblies. Neither package nor surface finish was found to have any effects on the board level reliability of test vehicles with lead‐free balled/plated BGAs, CSPs, QFPs and TSOPs. Metallographic examinations were conducted to investigate the effect of thermal cycling on the failure modes of solder joints.Originality/valueThe paper is of value by contributing to research in the use of lead‐free solder paste with lead‐containing packages in the industry. Currently, there is a deficiency of knowledge in this area.

Intermetallics Characterization of Lead-Free Solder Joints under Isothermal Aging

Solder interconnect reliability is influenced by environmentally imposed loads, solder material properties, and the intermetallics formed within the solder and the metal surfaces to which the solder is bonded. Several lead-free metallurgies are being used for component terminal plating, board pad plating, and solder materials. These metallurgies react together and form intermetallic compounds (IMCs) that affect the metallurgical bond strength and the reliability of solder joint connections. This study evaluates the composition and extent of intermetallic growth in solder joints of ball grid array components for several printed circuit board pad finishes and solder materials. Intermetallic growth during solid state aging at 100°C and 125°C up to 1000 h for two solder alloys, Sn-3.5Ag and Sn-3.0Ag-0.5Cu, was investigated. For Sn-3.5Ag solder, the electroless nickel immersion gold (ENIG) pad finish was found to result in the lowest IMC thickness compared to immersion tin (ImSn), immersion silver (ImAg), and organic solderability preservative (OSP). Due to the brittle nature of the IMC, a lower IMC thickness is generally preferred for optimal solder joint reliability. A lower IMC thickness may make ENIG a desirable finish for long-life applications. Activation energies of IMC growth in solid-state aging were found to be 0.54 ± 0.1 eV for ENIG, 0.91 ± 0.12 eV for ImSn, and 1.03 ± 0.1 eV for ImAg. Cu3Sn and Cu6Sn5 IMCs were found between the solder and the copper pad on boards with the ImSn and ImAg pad finishes. Ternary (Cu,Ni)6Sn5 intermetallics were found for the ENIG pad finish on the board side. On the component side, a ternary IMC layer composed of Ni-Cu-Sn was found. Along with intermetallics, microvoids were observed at the interface between the copper pad and solder, which presents some concern if devices are subject to shock and vibration loading.

Effects of multiple reflows on interfacial reaction and shear strength of SnAgCu and SnPb solder joints with different PCB surface finishes

Abstract The effects of multiple reflows (1, 2, 4, 6, 8, 10 numbers of reflow) on interfacial reaction and shear strength of Sn3.8Ag0.7Cu (SAC) and Sn37Pb (SP) joints were systematically investigated using electrolytic Ni/Au and organic solderability preservative (OSP) finished pad. In the case of OSP finished substrate, the well-known intermetallic compound (IMC) Cu6Sn5 was observed for both solders. While for the Ni/Au finished substrate, the IMC Ni3Sn4 and (CuNi)6Sn5 were formed on the interface of SP and SAC joints, respectively. With the increasing number of reflows, the thickness of IMCs on all reaction couples increased gradually and the IMC grain coarsened. The IMC growth kinetics showed that the interfacial IMC Cu6Sn5 was controlled by grain boundary diffusion and that the IMCs (Ni3Sn4 and (CuNi)6Sn5) near Ni layer had interactive diffusion control of grain boundary and volume diffusion. Moreover, IMC growth at Cu interface was faster than that at Ni interface, irrespective of the solder type. Shear test results showed that the shear force did not change much until eight numbers of reflow for each reaction couple. The ductile fracture indicated that the shear strength of solder joints could not be significantly influenced by the thickness and morphology of the interfacial IMC.

Adhesion and Reliability of Anisotropic Conductive Films (ACFs) Joints on Organic Solderability Preservatives (OSPs) Metal Surface Finish

The effect of final metal finishes of Cu electrodes on the adhesion and reliability of anisotropic conductive film (ACF) joints was investigated. Two different metal surface finishes, electroless Ni/immersion Au (ENIG) and organic solderability preservatives (OSPs) coated on Cu, were selected in this study for ACF bonding. The adhesion strength of ACF/OSP joints was higher than that of ACF/bare Cu and ACF/ENIG joints. The fracture sites of the ACF/bare Cu and ACF/ENIG joints were ACF/metal interfaces, while those of ACF/OSP joints were inside the ACF. Transmission electron microscope (TEM) and Fourier-transform infrared (FT-IR) analyses showed that the OSP coating layer on the Cu electrodes reacted with the epoxy resin of the ACFs but still remained at the bonding interface. According to the in-depth X-ray photoelectron spectroscopy (XPS) analysis, additional C-N bonds formed after the OSP-epoxy reaction and the outermost nitrogen of the OSP layer participated in curing of the epoxy resin of the ACF. Therefore, the OSP layer acted as an adhesion promoter to ACFs. Furthermore, this role of the OSP layer enhanced the reliability of the ACF/OSP joints under high temperature and humid environments, as compared to the ACF/ENIG joints.

Evaluation on Influencing Factors of Board-Level Drop Reliability for Chip Scale Packages (Fine-Pitch Ball Grid Array)

Board-level drop testing is an effective method to characterize the solder joint reliability performance of miniature handheld products. In this study, drop test of printed circuit boards (PCBs) with a four-screw support condition was conducted for a 15 mm times 15 mm fine-pitch ball grid array (FBGA) package assembly with solder ball compositions of 36Pb-62Sn-2Ag and Sn-4Ag-0.5Cu on printed circuit board (PCB) surface finishes of organic solderability preservative, electroless nickel immersion gold, and immersion tin. Finite element modeling of the FBGA assembly was performed to study the stress-strain behavior of the solder joints during drop test. The drop test results revealed a strong influence of different intermetallic compound formation on soldered assemblies drop durability. The lead-based solder supersedes the lead-free composition regardless of the types of surface finish. Joints on organic solderability preservative were found to be strongest for each solder type. Other factors affecting drop reliability such as component location on the board and thermal cycling aging effects are reported. Finite element modeling results showed that a solder joint is more prone to failure on the PCB side, and the predicted solder joint stresses are location dependent. Predicted failure sites based on simulation results are consistent with experimental observations.

Implementing 0201s On High-Density Lead-Free Memory Modules

The introduction of 0201 components is another step taken in the world of electronics to aid the miniaturization of electronic products. Capacitors and resistors are now being produced in a 0201 package size; in dimensions, it means a length of 0.02 in and a width of 0.01 in. The assembly of miniature components on printed circuit boards (PCBs) poses numerous process challenges. Legislative measures to eliminate the usage of lead from electronics products compel electronics manufacturers to implement lead-free assembly. This mandates the use of lead-free 0201 components and a lead-free soldering process. The current research focuses on high-density lead-free memory module assemblies using a 1.27-mm-thick organic solderability preservative (OSP)-coated boards. The spacing between components is as low as 0.25 mm. The objective of this research is to develop a robust assembly process for lead-free 0201 components used in memory modules. The stencil, PCB land pattern designs, solder paste printing, component placement, and reflow soldering processes were studied. The process and design changes required for achieving a robust manufacturing process for assembling lead-free 0201 components on high-density assemblies have been identified and reported.

Additive Effect of Kirkendall Void Formation in Sn-3.5Ag Solder Joints on Common Substrates

The Sn-3.5Ag and Sn-3.5Ag-0.2Co-0.1Ni lead-free solders were investigated on common electronics substrates, namely, organic solderability preservative (OSP) and electroless Ni/immersion Au (ENIG) surface finishes. The formation of Kirkendall voids at the interfacial region during isothermal solid aging was explored. For the Sn-3.5Ag-0.2Co-0.1Ni/OSP solder joint, the Kirkendall voids were present after isothermal solid-state aging at higher temperature (e.g., 150°C); however, the size of voids did not change remarkably with prolonged aging time due to the depressed Cu 3 Sn layer growth. For ENIG surface finishes, the 0.2Co-0.1Ni additions seemed to enhance the longitudinal groove-shaped voids at the Ni 3 P layer; however, void formation at the solder/Ni 3 Sn 4 interface was effectively reduced. This might be attributed to the reduced Sn activity in the solder matrix and the suppressed Ni-P-Sn layer formation.

Intermetallics Evolution in Sn-3.5Ag Based Lead-Free Solder Matrix on an OSP Cu Finish

The 0.2Co + 0.1Ni dual additives were used to dope a Sn-3.5Ag solder matrix to modify the alloy microstructure and the solder joint on an organic solderability preservative (OSP) Cu pad. The refined microstructure of the Sn-3.5Ag-0.2Co-0.1Ni solder alloy or the reduced β-Sn size was attributed to the depressed undercooling achieved by the Co-Ni addition. After soldering on the OSP Cu pad, a large Ag3Sn plate was formed at the Sn-3.5Ag/OSP solder joint, whereas it was absent at the Sn-3.5Ag-0.2Co-0.1Ni/OSP solder joints. With isothermal aging at 150°C, large Ag3Sn plates formed at the Sn-3.5Ag/OSP solder joint were still observed. A coarsened and dispersed Ag3Sn phase was found in the solder joints with Co-Ni additions as well. Compared to Cu6Sn5, the (Co,Ni)Sn2 intermetallic compound showed much lower microhardness values. However, (Co,Ni)Sn2 hardness was comparable to that of the Ag3Sn phase. Pull strength testing of Sn-3.5Ag-0.2Co-0.1Ni/OSP revealed slightly lower values than for Sn-3.5Ag/OSP during aging. Such results are thought be due to the phase transformation of (Co,Ni)Sn2 to (Cu,Co,Ni)6Sn5.

Isothermal Cyclic Bend Fatigue Test Method for Lead-Free Solder Joints

Isothermal three-point and four-point cyclic bend fatigue test methods have been developed for Sn–Ag–Cu solder joints. Reported bend tests from the literature were conducted at room temperature (25°C) and there is lack of data for lead-free solder joints. In this study, very-thin quad flat no-lead (VQFN) assembly with Sn–Ag–Cu lead-free solder was tested under three-point and four-point cyclic bending loads at both room temperature (25°C) and high temperature (125°C). The correlation between three-point and four-point bend tests was developed. Two different board surface finishes of electroless Ni and immersion gold (ENIG) and organic solderability preservatives (OSP) were investigated. Bending fatigue resistance of VQFN with OSP finish is slightly better than ENIG finish case. The acceleration factor of failure at high temperature (125°C) is higher than that at room temperature (25°C). Finite element analysis modeling and simulation were performed for different test conditions to investigate the solder joint stress-strain behavior. Volume-averaged energy density was used as a fatigue damage parameter and energy-based bending fatigue models were developed for VQFN with Sn–Ag–Cu solder joint under cyclic bending load at both 25°C and 125°C.

Effect of Interfacial Reactions on the Reliability of Lead-Free Assemblies after Board Level Drop Tests

The reliability of lead-free electronic assemblies after board level drop tests was investigated. Thin small outline package (TSOP) components with 42 FeNi alloy leads were reflow soldered on FR4 printed circuit boards (PCBs) with Sn3.0Ag0.5Cu (wt%) solder. The effects of different PCB finishes [organic solderability preservative (OSP) and electroless nickel immersion gold (ENIG)], multiple reflow (once and three times), and isothermal aging (500 h at 125°C after one time reflow) were studied. The ENIG finish showed better performance than its OSP counterparts. With the OSP finish, solder joints reflowed three times showed obvious improvement compared to those of the sample reflowed once, while aging led to apparent degradation. The results showed that intermetallic compound (IMC) types, IMC microstructure and solder microstructure compete with each other, all playing very important roles in the solder joint lifetime. The results also showed that it is important to specify adequate conditions for a given reliability assessment program, to allow meaningful comparison between results of different investigators.

Failure Analysis of Lead-Free Solder Joints of an 1657CCGA (Ceramic Column Grid Array) Package

In this study, failure analysis of the 1657CCGA package with 95.5wt%Sn3.9wt%Ag0.6wt%Cu and 63wt%Sn37wt%Pb solder pastes on lead-free PCBs with the Entek OSP (organic solderability preservative) surface finish is investigated. Emphasis is placed on determining the failure locations and failure modes of the solder joints of the 1657CCGA assemblies after they have been through 7,000 cycles of temperature cycling.

Press-Fit Connector for Automobile Electronic Control Units

A press-fit connection is a solderless electrical connection technology, which utilizes the mechanical contact force generated between through-holes on a printed circuit board (PCB) and terminals with a width slightly larger than the through-hole diameter. This technology has been widely noted recently as a measure against the Lead Free Requirement of materials comprising electric/electronic devices, especially in the area of automobile connector. For the application of this technology to automobile connectors, we have to take into account the severe requirement, such as (1) the adaptation to wider through-hole diameter tolerance range and (2) the establishment of connection reliability for the various PCB surface treatments. As a result, we have determined the minimum and maximum contact forces satisfying the long term connection reliability and designed the terminal shape, which has been refined the N-shape cross section developed before, by using three dimensional finite element methods (FEM). Furthermore, we have developed a new type of hard tin plating on terminals, thus preventing the scraping-off of tin during the insertion process, that could result in a short-circuit on the PCB, for the Organic Solderability Preservative (OSP) treated PCB. The press-fit connector for the automobile airbag Electronic Control Units (ECUs) we developed has been able to transfer to the mass-production phase successfully from August 2005.

Forward and Backward Compatibility of Solder Alloys With Component and Board Finishes

The primary objective of the research presented in this paper is to qualify the reliability of mixed assemblies by comparing them to the conventional Sn-Pb assembly and completely Pb-free assembly. The research investigates both forward and backward compatibility in electronic assemblies using a design of experiments (DOE) approach. The investigation utilized a test vehicle containing an area array component (BGA169) and chip components (0603 resistors). Hot air solder leveling (HASL) and organic solderability preservative (OSP) surface finishes were used on the test vehicles to represent Sn-Pb and Pb-free alternatives, respectively. The assembled test vehicles were cut into two panels - one containing a resistor section for isothermal aging and the other containing a BGA and another resistor section for thermal shock. The assemblies were subjected to isothermal aging and thermal shock tests as per Interconnecting and Packaging Electronic Circuits/Joint Electronic Device Engineering Council (IPC/JEDEC) standards. The resistors were sheared in the as-soldered condition, and at various isothermal aging intervals and thermal shock cycles. In order to simulate an intermetallic failure in isothermal aging, a reduced shear height (20 mum) was used for the shear test. The performance of the resistor solder joints were quantified in terms of the shear force. The performance of the ball grid array (BGA) solder joint during thermal shock testing was quantified in terms of the number of cycles to failure. Experimental results from shear analysis of resistor solder joints show that Pb-free alloy assemblies' performance is superior to those assembled using Sn-Pb alloy. Also, the ductile nature of the Sn-Ag-Cu (SAC) alloy provides the joints a better fatigue life. With the area array components, Pb-free assembly joints outlived the traditional Sn-Pb joints when subjected to thermal shock loading. Among the mixed assemblies, backward-compatible assemblies (Pb-free bumps and Sn-Pb solder alloy) showed superior performance. The microstructural analysis of the solder joints indicate a uniform distribution of lead in the solder joint matrix.

Endurance of lead-free assembly under board level drop test and thermal cycling

The reliability of lead-free electronic assemblies under board level drop test and thermal cycling was investigated. TSOP (thin small outline package) devices with FeNi leads were reflow soldered on FR4 PCB (printed circuit board) with Sn3.0Ag0.5Cu (wt%) solder. The effects of different PCB finishes (organic solderability preservative (OSP) and electroless nickel immersion gold (ENIG)) on the reliability performance were studied. The results show that the assemblies with ENIG finishes reveal better reliability performance than its OSP counterparts under drop test, however, the OSP samples outperform those with ENIG finishes under thermal cycling. The failure mechanism is different under these two test conditions: the solder joints fracture into the intermetallic compounds (IMCs) layer under drop test, and cracks initiate in the bulk solder under thermal cycling. The surface finishes have an effect on the failure mode. The propagation of crack in the ENIG case is along the device/solder interface, while in the case of OSP, the crack extends parallel to the solder/PCB interface.

Reliability of lead-free solder joints with different PCB surface finishes under thermal cycling

The reliability of lead-free electronic assemblies under thermal cycling was investigated. Thin small outline package (TSOP) devices with FeNi leads were reflow soldered on FR4 PCB (printed circuit board) with Sn3.0Ag0.5Cu (wt%) solder. The effects of different PCB finishes (organic solderability preservative (OSP) and electroless nickel immersion gold (ENIG)) were studied. The results show that OSP finish reveals better performance than its ENIG counterparts. The crack originates at the fringe of heel fillet in both cases. The propagation of crack in the ENIG case is along the device/solder interface, while in the case of OSP, the crack extends parallel to the solder/PCB interface. When the OSP finishes are employed, many Cu6Sn5 precipitates form inside the bulk solder and have a strengthening effect on the solder joint, resulting in better reliability performance as compared to those with ENIG finishes.

Effect of surface finish of substrate on mechanical reliability of In-48Sn solder joints in MOEMS package

The interfacial reactions and shear properties of the In-48Sn (wt.%) ball grid array (BGA) solder joints after bonding were investigated with four different surface finishes of the substrate over an underlying Cu pad: electroplated Ni/Au (hereafter E-NG), electroless Ni/immersion Au (hereafter ENIG), immersion Ag (hereafter I-Ag) and organic solderability preservative (hereafter OSP). During bonding, continuous AuIn2, Ni3(Sn,In)4, and Cu6(Sn,In)5 intermetallic compound (IMC) layers were formed at the solder/E-NG, solder/ENIG and solder/OSP interfaces, respectively. The interfacial reactions between the solder and I-Ag substrate during bonding resulted in the formation of Cu6(Sn,In)5 and Cu(Sn,In)2 IMCs with a minor Ag. The In-48Sn/I-Ag solder joint showed the best shear properties among the four solder joints after bonding, whereas the solder/ENIG solder joint exhibited the weakest mechanical integrity.