Organic Compounds Research Articles

Effect of landfill leachates on urban soil: A review

The increasing generation of Municipal Solid Waste (MSW) is a significant global concern, with landfills receiving around 1.4 billion tonnes of MSW yearly. Inadequate landfill management contributes to environmental degradation, with landfill leachate being a substantial outcome of MSW decomposition. Leachate contains inorganic nutrients, volatile and dissolved organic molecules and heavy metals and its properties vary depending on waste composition, moisture content and seasonal elements. Heavy metals found in leachate include Pb, Cu, Cr, Ni, Mn, Hg, Fe, Zn and Cd and Emerging Organic Contaminants (EOCs) such as Persistent Organic Pollutants (POPs), Endocrine Disrupting Chemicals (EDC), pharmaceuticals and Personal Care Products (PCPs) are also prevalent. Microplastics (MPs) have been found in raw leachate samples at concentrations ranging from 49.0 ± 24.3 to 507.6 ± 37.3 items/L. Landfill leachate production ranks among the most aggressive pollutants to the environment, particularly to soil and poses a danger of contaminating both surface and groundwater. This review examines the potential impacts of landfill leachate on soil quality and the broader implications of this phenomenon, summarizing recent scientific studies and presenting the direct and indirect effects of leachate on soil based on the literature. Bibliometric analysis of publications in the Scopus database reveals a growing scholarly interest in this topic, with the number of publications in the Science Citation Index (SCI) database increasing dramatically to over 464 articles between 2009 and 2024.

Are Hazard Assessment Methods in the Assessment of Chemical Alternatives Suitable for REACH?

The assessment of chemical alternatives for hazardous substances is an important prerequisite for avoiding regrettable substitution, and several methods have been developed in the past to perform such a hazard assessment for chemical alternatives. We investigate here whether GreenScreen, Cradle to Cradle, multiple-criteria decision analysis (MCDA), the Pollution Prevention Options Analysis System, the U.S. EPA Safer Choice Standard and Criteria, and the GHS column model 2020 from IFA use similar criteria for the evaluation of substances as Article 57 of the European chemicals regulation, REACH, and how suitable these methods are for assessing per- and polyfluoroalkyl substances. MCDA and GreenScreen were analyzed in detail using two different data sets. The results of the assessments show that none of the investigated hazard assessment methods use the same criteria as described in Article 57 of REACH. It was also not possible to parametrize multi-attribute value theory (MAVT), a commonly used MCDA method, to align with Article 57 of REACH by using the relatively simple objective hierarchy that has been proposed in previous publications. There is therefore an urgent need for a modified/new method that can be used in the future to assess organic substances that are used within the European Economic Area.

MXene Electrodes for All Strain-Free Solid-State Batteries.

All-solid-state batteries with nonflammable inorganic solid electrolytes are the key to addressing the safety issues of lithium-ion batteries with flammable organic liquid electrolytes. However, conventional electrode materials suffer from substantial volume changes during Li+ (de)intercalation, leading to mechanical failure of interfaces between electrode materials and solid electrolytes and then severe performance degradation. In this study, we report strain-free charge storage via the interfaces between transition metal carbides (MXenes) and solid electrolytes, where MXene shows negligible structural changes during Li+ (de)intercalation. Operando scanning electron transmission microscopy with electron energy-loss spectroscopy reveals the pillar effect of trapped Li+ in the interlayer spaces of MXene to achieve the strain-free features. An all strain-free solid-state battery, which consists of a strain-free Ti3C2Tx negative electrode and a strain-free disordered rocksalt Li8/7Ti2/7V4/7O2 positive electrode, demonstrates long-term stable operation while preserving the interfacial contact between electrode materials and solid electrolytes.

Deoxyfluorination: A Detailed Overview of Recent Developments

AbstractFluorine organic compounds have been a predominant force of pharmaceutical chemistry for modern drug design, with an increasing amount of fluorine-containing compounds entering the market. Methodologies for fluorine atom incorporation into organic molecules are still challenging to date and thus represent an important research area. Deoxyfluorination serves as a useful tool for the construction of carbon–fluorine bonds in biologically active molecules by converting a common hydroxyl group into the corresponding fluoride. In this review, we have summarized and categorized deoxyfluorination reaction protocols developed over the last decade (2015–2024) by the structural type of C–O bond deoxyfluorination, including substrates like alcohols, phenols, ketones, aldehydes, and carboxylic acids.1 Introduction2 Deoxyfluorination of C(sp3)–O Bonds2.1 Alcohols2.2 Alcohol Derivatives3 Deoxyfluorination of C(sp2)–O Bonds3.1 Phenols3.2 Phenol Derivatives3.3 Aldehydes and Ketones3.4 Carboxylic Acids4 Conclusions

Utilizing a medicinal plant and soil assays for heavy metal pollution assessment and its impacts in a Turkish Industrial Zone

Due to the worldwide growth in population, agricultural and industrial activities are expanding quickly, which pollutes the air, water, and soil and leads to the buildup of potentially hazardous substances in medicinal plants. The current study sought to determine the concentrations of various metals in Silybum marianum plants and soils in order to highlight the level of pollution in a Turkish Organized Industrial Zone in Dilovasi District, Kocaeli, and to investigate the effects of these heavy metals on plants. In order to determine the concentrations of elements evaluated within the scope of this study inductively coupled plasma optical emission spectroscopy was employed, due to the benefits of ICP that provides few or no organic molecules, few ionization interferences, as well as the ability to analyze many elements sequentially. Furthermore, in order to evaluate elemental analysis in terms of nutritional values, risk assessments using RDA, EDI, THQ, and HI parameters were conducted. The value of heavy metals in co-located soil samples is relatively high. However, except for Co, Mn, and Ni, it has stayed within the World Health Organization’s permitted limits. The evaluation of the co-located soil samples found that the highest contents (mg kg−1) of Al, Ca, Cd, Cr, Cu, Fe, K, Mn, Na, Ni, Pb, and Zn, were recorded as 7825.10, 4365.86, 4768.59, 2.50, 30.45, 38.49, 8352.00, 17452.26, 1495.82, 1495.82, 163.53, 1452.23, 28.67, 136.55 and 125.45, respectively, belonging to Location 1. These findings are in accordance with the Industrial Status Report since the place specified as Location 1 in the current study is characterized by its pronounced industrial activity and the robust electrical plant station with an industrial facility for generating electric power. Furthermore, the hazard index, the estimated daily intake and target hazard quotient for potentially harmful components and recommended daily allowance values for mineral nutrients were computed. Therefore, even though mineral nutritional values in some areas were found to be higher than Buyukada control location, this should be ignored. Consequently, this study warns against using S. marianum plants as food or medicine collected from current regions. As a result, ongoing inspection is necessary to prevent an excessive buildup of metals in the area and other places with similar human life-related features.

Tandem Solid‐Solution Phase Post‐Synthetic Modification of Porous Molecular Crystals for In‐Situ Generation of Fluorophores

AbstractConventional synthetic methods of organic luminescent molecules often involve labor‐intensive solution‐phase organic synthesis, which violate the principles of atom‐economic transformation. Post‐synthetic modification (PSM) offers a promising alternative, allowing direct transformation from one fluorophore to another. Although PSM is commonly implemented in extended frameworks, its application in porous molecular crystals remains challenging. Herein, we focus on utilizing porous molecular crystals, specifically tetraphenylethylene‐cored frameworks, as versatile platforms for tandem PSM reactions to customize organic fluorophores. The tailored skeleton design ensures both the formation of porous structures and the occurrence of tandem solid‐solution phase reactions while maintaining the solid state of reactants and products in each step. The inherent non‐covalent bonding nature of the frameworks facilitates processing and characterization, offering unparalleled advantages for porous networks. The accompanying solid‐state fluorescence transition from green to blue and then to green (or yellow) enables real‐time monitoring of tandem reactions and provides intuitive mechanistic insights. This phenomenon is exploited for the facile construction of a dynamic information encryption system using fluorescent quick response codes.

No more gap-shifting: Stochastic many-body-theory based TDHF for accurate theory of polymethine cyanine dyes.

We introduce an individually fitted screened-exchange interaction for the time-dependent Hartree-Fock (TDHF) method and show that it resolves the missing binding energies in polymethine organic dye molecules compared to time-dependent density functional theory (TDDFT). The interaction kernel, which can be thought of as a dielectric function, is generated by stochastic fitting to the screened-Coulomb interaction of many-body perturbation theory (MBPT), specific to each system. We test our method on the flavylium and indocyanine green dye families with a modifiable length of the polymethine bridge, leading to excitations ranging from visible to short-wave infrared. Our approach validates earlier observations on the importance of inclusion of medium range exchange for the exciton binding energy. Our resulting method, TDHF@vW, also achieves a mean absolute error on a par with MBPT at a computational cost on a par with local-functional TDDFT.

The role of flow field dynamics in enhancing volatile organic compound conversion in a surface dielectric barrier discharge system

Abstract This study investigates the correlation between flow fields induced by a surface dielectric barrier discharge (SDBD) system and its application for the volatile organic compound (VOC) gas conversion process. As a benchmark molecule, the conversion of n-butane is monitored using flame ionization detectors, while the flow field is analysed using planar particle image velocimetry. Two individual setups are developed to facilitate both conversion measurement and investigation of induced fluid dynamics. Varying the gap distance between two SDBD electrode plates for three different n-butane mole fractions reveals local peaks in relative conversion around gap distances of 16 mm to 22 mm, indicating additional spatially dependent effects. The lowest n-butane mole fractions exhibit the highest relative conversion, while the highest n-butane mole fraction conversion yields the greatest number of converted molecules per unit time. Despite maintaining constant energy density, the relative conversion exhibits a gradual decrease with increasing distances. The results of the induced flow fields reveal distinct vortex structures at the top and bottom electrodes, which evolve in size and shape as the gap distances increase. These vortices exhibit gas velocity magnitudes approximately seven times higher than the applied external gas flow velocity. Vorticity and turbulent kinetic energy analyses provide insights into these structures' characteristics and their impact on gas mixing. A comparison of line profiles through the centre of the vortices shows peaks in the middle gap region for the same gap distances, correlating with the observed peaks in conversion. These findings demonstrate a correlation between induced flow dynamics and the gas conversion process, bridging plasma actuator studies with the domain of chemical plasma gas conversion.

The potential role of iron-carbon micro-electrolysis materials in curtailing lag-phase stimulates kitchen waste anaerobic digestion at different solid contents: Performance, synergistic effect and microbial response

High-solid anaerobic digestion (HSAD) of kitchen waste was generally faced to the common problems such as systemic acidification, prolonged lag-phase time and low methane production. Iron-carbon micro-electrolysis (ICME) materials exhibited advantages that porous structure, large specific surface area and excellent conductivity. It was beneficial for organic compounds to hydrolysis. Moreover, ICME materials could establish direct interspecies electron transfer (DIET) pathway between bacteria and methanogens. ICME materials were commonly used to enhance the AD of wastewater, but they were rarely applied to HSAD of kitchen waste. In this study, ICME materials were utilized to enhance HSAD of kitchen waste at different solid content conditions. The results showed that the highest cumulative biogas yield (705.23 mL/g VS) was obtained in the experimental group (TS = 10%), which was 94.15% higher than that of the control group. At the same time, the addiction of ICME could shorten lag-phase time. Electrochemical characteristics and XPS analysis showed that ICME materials promoted the release of Fe2+ in the AD system and acceleration of direct interspecies electron transfer between microorganisms. Microbial community analysis showed that ICME materials enriched electroactive bacteria (Proteiniphilum), Methanosarcina, Methanobrevibacter and Methanofollis. Functional gene prediction revealed that ICME materials increased the relative abundance of carbohydrate transport and metabolism and coenzyme transport and metabolism. It provided a potential measure to treat kitchen waste.

Impact of Adsorption on the Vapor Availability of Contained Explosives and Drugs

AbstractDetection canines are used to locate explosives, drugs, and other contraband based on the presence of volatile organic compounds (VOCs) associated with the target items, even when attempts have been made to contain them in layers of packaging. It is important to understand the extent to which different materials impact vapor availability through adsorption or absorption and therefore the ability of canines to detect target materials. This study considered how the attenuation of vapor components associated with explosives and drugs (hexamethylene triperoxide diamine (HMTD), trinitrotoluene (TNT), triacetone triperoxide (TATP), and cocaine) by commonly used concealment and storage materials (metal, glass, plastic, and cardboard). Adsorption/desorption affinity was measured using a quartz crystal microbalance which can measure nanogram level mass changes as vapor from an analyte is flowed over and interacts with a sensor coated in a material of interest. Headspace analysis using solid phase microextraction (SPME) with gas chromatography/mass spectrometry or electron capture detector (GC/MS or ECD) measured the VOCs over time as each analyte of interest was exposed to either 50 cm2 or 100 cm2 of each material. Overall, the results demonstrated that the amount of sorption and vapor suppression varies based on the material, with the greatest attenuation of analyte vapor by cardboard, followed by polystyrene, and then glass. Furthermore, it also depends on the analyte, as demonstrated by minimal sorption of TATP, particularly to polystyrene, and the compounds in HMTD having different affinities resulting in an altered vapor profile.

Hydrocarbonoclastic Biofilm-Based Microbial Fuel Cells: Exploiting Biofilms at Water-Oil Interface for Renewable Energy and Wastewater Remediation

Microbial fuel cells (MFCs) represent a promising technology for sustainable energy generation, which leverages the metabolic activities of microorganisms to convert organic substrates into electrical energy. In oil spill scenarios, hydrocarbonoclastic biofilms naturally form at the water–oil interface, creating a distinct environment for microbial activity. In this work, we engineered a novel MFC that harnesses these biofilms by strategically positioning the positive electrode at this critical junction, integrating the biofilm’s natural properties into the MFC design. These biofilms, composed of specialized hydrocarbon-degrading bacteria, are vital in supporting electron transfer, significantly enhancing the system’s power generation. Next-generation sequencing and scanning electron microscopy were used to characterize the microbial community, revealing a significant enrichment of hydrocarbonoclastic Gammaproteobacteria within the biofilm. Notably, key genera such as Paenalcaligenes, Providencia, and Pseudomonas were identified as dominant members, each contributing to the degradation of complex hydrocarbons and supporting the electrogenic activity of the MFCs. An electrochemical analysis demonstrated that the MFC achieved a stable power output of 51.5 μW under static conditions, with an internal resistance of about 1.05 kΩ. The system showed remarkable long-term stability, which maintained consistent performance over a 5-day testing period, with an average daily energy storage of approximately 216 mJ. Additionally, the MFC effectively recovered after deep discharge cycles, sustaining power output for up to 7.5 h before requiring a recovery period. Overall, the study indicates that MFCs based on hydrocarbonoclastic biofilms provide a dual-functionality system, combining renewable energy generation with environmental remediation, particularly in wastewater treatment. Despite lower power output compared to other hydrocarbon-degrading MFCs, the results highlight the potential of this technology for autonomous sensor networks and other low-power applications, which required sustainable energy sources. Moreover, the hydrocarbonoclastic biofilm-based MFC presented here offer significant potential as a biosensor for real-time monitoring of hydrocarbons and other contaminants in water. The biofilm’s electrogenic properties enable the detection of organic compound degradation, positioning this system as ideal for environmental biosensing applications.

The Role of (E)-β-Farnesene in Tritrophic Interactions: Biosynthesis, Chemoreception, and Evolution.

(E)-β-farnesene (EBF) stands out as a crucial volatile organic compound, exerting significant influence on the complex interactions between plants, aphids, and predator insects. Serving as an alarm signal within aphids, EBF is also emitted by plants as a defense mechanism to attract aphid predators. This review delves into EBF sources, functions, biosynthesis, detection mechanisms, and its coevolutionary impacts on aphids and insect predators. The exploration underscores the need to comprehend the biophysical and structural foundations of EBF receptors in aphids, emphasizing their role in unraveling the intricate patterns and mechanisms of interaction between EBF and target receptors. Furthermore, we advocate for adopting structure-based or machine-learning methodologies to anticipate receptor-ligand interactions. On the basis of this knowledge, we propose future research directions aiming at designing, optimizing, and screening more stable and efficient active odorants. A pivotal outcome of this comprehensive investigation aims to contribute to the development of more effective aphid-targeted control strategies.

Recent Progress on Perovskite Materials for VOC Gas Sensing.

Volatile organic compound (VOC) gases are highly hazardous to human health, and their presence in the human breath plays an indispensable role for the early diagnosis of various diseases (cancer, renal failure, etc.). In recent times, perovskite materials have shown notable performance in the detection of VOC gases with high accuracy, fast response, recovery time, selectivity, and sensitivity, owing to their unique crystallographic structures and excellent optoelectronic properties. In this Review, we look at recent reports on perovskite-based sensors and their sensing performance toward VOC gases. Here, we focus on the sensing mechanisms of two types of perovskite materials, metal halide and metal oxide perovskites, and explain the differences in their crystal structures. We also discuss the common preparation methods used by researchers for the synthesis of these perovskite materials. Further, we elucidate various important factors influencing the sensing performance of perovskite-based sensors, such as doping, defects, morphology, temperature, humidity, and light. We conclude with the future prospects and challenges related to these perovskite-based sensors toward the detection of VOC gases.

Breaking Barriers in Chalcogenide Perovskite Synthesis: A Generalized Framework for Fabrication of BaMS3 (M═Ti, Zr, Hf) Materials

AbstractChalcogenide perovskites have garnered increasing attention as stable, non‐toxic alternatives to lead halide perovskites. However, their conventional synthesis at high temperatures (>1000 °C) has hindered widespread adoption. Recent studies have developed low‐to‐moderate temperature synthesis methods (<600 °C) using reactive precursors, yet a comprehensive understanding of the pivotal factors affecting reproducibility and repeatability remains elusive. This study delineates the critical factors in the low‐temperature synthesis of BaMS3 (M═Zr, Hf, Ti) compounds and presents a generalized framework. Innovative approaches are developed for synthesizing BaMS3 compounds using this framework involving organometallics for solution deposition. The molecular precursor routes, employing metal acetylacetonates to generate soluble metal–sulfur bonded complexes and metal–organic compounds to produce soluble metal‐thiolate, metal‐isothiocyanate, and metal‐trithiocarbonate species, are demonstrated to yield carbon‐free BaMS3. These methods have achieved the most contiguous films of BaZrS3 and BaHfS3 using solution deposition to date. Furthermore, a hybrid solution processing method involving stacking sputter‐deposited Zr and solution‐deposited BaS layers is employed to synthesize a contiguous, oxygen‐free BaZrS3 film. The diffuse reflectance measurements indicate a direct bandgap of ≈ 1.85 eV for the BaZrS3 films and ≈ 2.1 eV for the BaHfS3 film under investigation.

Plant-Associated Volatile Organic Compound (VOC) Database (PVD): A Resource Supporting Research on VOCs Produced by Plants and Plant-Associated Microbes

Diverse volatile organic compounds (VOCs) perform functions crucial for plant growth and health. However, studies on the nature and mechanisms of action of bioactive VOCs, except those mediating plant-insect interactions, lag considerably behind those on waterborne compounds. We built the Plant-Associated VOC Database (PVD) to facilitate research on VOCs released by plants and plant-associated microbes. This platform presents the physicochemical characteristics, biosynthetic pathways, and known or hypothesized functions of VOCs. We present the design, utility, and planned expansion of PVD. [Formula: see text] Copyright © 2024 The Author(s). This is an open access article distributed under the CC BY-NC-ND 4.0 International license .

Identifying effects of volatile organic compounds exposure on kidney stone prevalence in U.S. adults: a cross-sectional analysis of NHANES 2007-2020.

Our aim was to comprehensively investigate the relationship between blood volatile organic compounds (VOCs) and kidney stone prevalence for U.S. adults. In this cross-sectional study, 10,052 participants from the 2007-2020 National Health and Nutrition Examination Survey (NHANES) were included. Multivariate logistic regression model was employed to investigate the association between 9 blood VOCs and kidney stones. We explored the dose-response relationship between blood VOCs and kidney stones using restricted cubic spline (RCS) analysis. Additionally, weighted quantile sum (WQS) regression model was performed to assess the overall association of 9 blood VOCs with kidney stones. Finally, subgroup analyses were conducted to identify the findings in different populations at high prevalence. Logistic regression analysis and dose-response risk curves revealed that blood benzene (aOR = 1.308, 95% CI: 1.118-1.530, P = 0.001), blood ethylbenzene (aOR = 1.280, 95% CI: 1.054-1.554, P = 0.013), blood m-/p-xylene (aOR = 1.187, 95% CI: 1.008-1.398, P = 0.040), blood 2,5-dimethylfuran (aOR = 1.319, 95% CI: 1.135-1.533, P < 0.001) and blood furan (aOR = 1.698, 95% CI: 1.305-2.209, P < 0.001) were positively associated with the prevalence of kidney stones. WQS regression analysis revealed that exposure to mixed blood VOCs was positively correlated with kidney stone prevalence (OR = 1.34, 95% CI: 1.14-1.57), with furans carrying the greatest weight. Subgroup analyses suggested that kidney stones were more susceptible to the effects of blood VOCs in young and middle-aged, female, overweight and obese, non-hypertensive, and non-diabetic populations. In this study, the results indicated that high VOC exposure was positively and independently associated with kidney stones in U.S. adults. This finding highlighted the need for public health strategies to reduce VOC exposure and its role in kidney stone prevention and treatment.

Key Roles of Free Cations in Modulating the Reaction Rate in Imidazolium Ionic Liquid-Dimethyl Sulfoxide Mixtures.

Imidazolium ionic liquids (ILs) are widely utilized in various fields due to their distinctive properties. However, their high viscosity limits their application in specific reactions, and mixing ILs with organic components is a way to solve this problem. While previous studies mainly focused on the structural changes of ILs after adding organic molecules, no studies elucidated the influence of their existing species on chemical reactions. In this study, aerobic α-hydroxylation of 2-methylcyclohexanone was chosen as a model reaction, and the reaction rate was found to be adjusted by varying imidazolium concentration in its mixtures with dimethyl sulfoxide. To elucidate the mechanism, the distribution of species in an IL solution and its change with concentration were studied by molecular dynamics simulations, and the results revealed the significant impact of the concentration of free cations on the reaction rate. The interaction between the ionic species and reaction intermediate, as calculated by density functional theory, highlighted the crucial role of free cations in this reaction. This study demonstrates the feasibility of tuning the concentration of free cations by varying the concentration of the IL solution, establishing the relationship between its microstructure and chemical reaction efficiency, thus providing vital information for the design and application of ILs.

Effect of Cyclodextrins Formulated in Liposomes and Gold and Selenium Nanoparticles on siRNA Stability in Cell Culture Medium

Background: Encapsulation of siRNA fragments inside liposome vesicles has emerged as an effective method for delivering siRNAs in vitro and in vivo. However, the liposome’s fluid-phospholipid bilayer of liposomes allows siRNA fragments to diffuse out of the liposome, decreasing the dose concentration and therefore the effectiveness of the carrier. We have previously reported that β-cyclodextrins formulated in liposomes help increase the stability of siRNAs in cell culture medium. Here, we continued that study to include α, γ, methyl-β-cyclodextrins and β-cyclodextrin-modified gold and selenium nanoparticles. Methods: We used Isothermal Titration Calorimetry to study the binding thermodynamics of siRNAs to the cyclodextrin-modified nanoparticles and to screen for the best adamantane derivative to modify the siRNA fragments, and we used gel electrophoresis to study the stabilization effect of siRNA by cyclodextrins and the nanoparticles Results: We found that only β- and methyl-β-cyclodextrins increased siRNA serum stability. Cyclodextrin-modified selenium nanoparticles also stabilize siRNA fragments in serum, and siRNAs chemically modified with an adamantane moiety (which forms inclusion complexes with the cyclodextrin-modified-nanoparticles) show a strong stabilization effect. Conclusions: β-cyclodextrins are good additives to stabilize siRNA in cell culture medium, and the thermodynamic data we generated of the interaction between cyclodextrins and adamantane analogs (widely used in drug delivery studies), should serve as a guide for future studies where cyclodextrins are sought for the delivery and solvation of small organic molecules.

Molecular Simulation of Cyclohexane in Nanoporous Materials: Adsorption of Conformers and Coadsorption with Water and Carbon Dioxide.

Molecular simulation is used to investigate the adsorption of an organic molecule and its different conformers into various nanoporous adsorbents. In more detail, we perform grand canonical Monte Carlo simulations to determine the adsorption isotherms for cyclohexane with its three conformers (chair, boat, and twisted boat) at three different temperatures into a molecular model of active carbons and two metal-organic frameworks (MOFs) (Cu-BTC and Al-Fum). By considering the adsorption of each conformer separately, we show that the adsorption isotherms are weakly dependent on the molecular conformation. When considering the concomitant adsorption of the three conformers under realistic conditions (to verify the population of each conformer in bulk mixtures), we show that the chair conformer is predominantly adsorbed in each material. However, such favorable adsorption mostly reflects the fact that this conformer has the largest population in the bulk mixture under the same thermodynamic conditions. On the contrary, with an increase in the cyclohexane gas pressure, the adsorption of boat and twisted boat conformers increases, while that of the chair conformer decreases as packing (entropy) effects become predominant during confinement. The adsorption of cyclohexane in the active carbon and MOF materials is also considered in the presence of water and CO2 atmospheres. In the case of the Al-fumarate material, the material is found to be strongly organophilic so that water and CO2 adsorption are negligible, and cyclohexane adsorption is not affected by competitive adsorption under any considered thermodynamic condition. On the contrary, for the active carbon and Cu-BTC material, competitive adsorption between cyclohexane and water or CO2 is observed even if cyclohexane adsorption remains preferred. While the different molecules coexist in the adsorbed phase at low pressures, increasing the cyclohexane pressure beyond 103 Pa promotes cyclohexane adsorption concomitantly with water and/or CO2 desorption.

Visible Light Mediated CO2 Fixation Reactions to Produce Carbamates and Carbonates: A Comprehensive Review

ABSTRACTCO2 is a significant greenhouse gas, and is considered as a copious renewable carbon reagent. From a synthetic perspective, it can be used as a sustainable and substitute C1 building block because of its nontoxic, nonflammable, and abundant nature. The transformation of a wide range of organic molecules with CO2 into numerous efficient commodities is a defining feature of recent success in this sector. Because of its numerous applications, photocatalysts and visible light‐mediated synthesis of carbamates and cyclic carbonates using CO2 have drawn a lot of interest from researchers. This mini review mainly focusses on the different one‐pot reactions that are proven to be efficacious for chemical fixation of CO2 in producing industry‐based compounds of carbamates and carbonates with the creation of CO, CH, CC, and CN bonds.