Organic 14C Research Articles

Validating the application of the revised ICRP’s biokinetic models for organic 14C and organically bound tritium to members of the public

In 2016, the International Commission on Radiological Protection (ICRP) has revised the biokinetic models for carbon and tritium in Publication 134 to calculate the dose coefficients of these radionuclides for workers. The following publication for members of the public is now in the process of revising by the ICRP. According to the draft manuscript published for consultation in 2023, the same models will be adopted for members of the public, although the parameters in these models are not corroborated by the metabolic data of radionuclides in foods. Dose coefficients were estimated using the modified models developed in this study to validate the application of the revised models to members of the public. In the modified models, several parameters were replaced based on the metabolic data of these nuclides in foods and compartments of radio-insensitive tissues were introduced. For these estimations, we utilised the an inhouse program for internal-dose calculation developed by the Japan Atomic Energy Agency. The estimated dose coefficient values for ingestion of organic 14C and organically bound tritium ranged from 3.2×10-11 to 7.6×10-11 Sv Bq-1 and from 3.5×10-11 to 5.4×10-11 Sv Bq-1, respectively. We concluded that the dose coefficient value of 1.6×10-10 Sv Bq-1 obtained by the revised ICRP's carbon model was conservative, while the value of 5.1×10-11 Sv Bq-1 for organically bound tritium was appropriate.&#xD.

Flood events in the lower reaches of the Yellow River: OSL and radiocarbon dating on the Anshang site

The lower reaches of the Yellow River have witnessed numerous episodes of flooding and considerable shifts in its course. Examining flood records within the Yellow River basin offers invaluable insights into ancient human settlements, agricultural practices, trade routes, and technological advancements of ancient Chinese civilizations. However, dating these fluvial sediments poses a considerable challenge due to either the scarcity of organic material for radiocarbon (14C) dating or the potential incomplete bleaching of sediments for optically stimulated luminescence (OSL) techniques. This study focused on the Anshang site located in Henan Province, we obtained OSL ages from distinct grain size fractions of quartz and cross-verified them with independent acceleration mass spectrometry (AMS) 14C ages. The findings revealed that both coarse quartz grains (CG) and medium quartz grains (MG) underwent complete bleaching in silt-dominated flood deposits and shallow lacustrine deposits. Conversely, the OSL ages of CG and MG quartz were notably overestimated by approximately 3–6 ka in silty clay-dominated flood deposits. Upon comparing the OSL ages with AMS 14C ages, it was evident that bulk organic matter AMS 14C ages aligned with CG OSL ages in shallow lacustrine deposits, but they appeared older than CG OSL ages in flood deposits. However, the AMS 14C ages from plant demonstrated good consistency. Consequently, we successfully identified flood-lacustrine sediments dating back to approximately ∼13 ka, ∼8–3 ka, ∼2.6 ka, ∼1 ka, and the last few hundred years, aligning well with historical documentation and earlier research. The regional evidence presented herein enhances our understanding of the applicability of OSL dating and AMS 14C dating in fluvial-lacustrine sediments. Armed with these new ages, we constructed a reference chronology for archaeological localities situated in the fluvial sediments of the lower reaches of the Yellow River.

Calcareous termite mounds in South Africa are ancient carbon reservoirs

Ecosystems that offer carbon sequestration by leaching bicarbonate to groundwater are valuable natural capital. One region that may offer this service is the west coast of South Africa. Over 20 % is covered by soil mounds (“heuweltjies”) up to 40 m diameter, 2 m high, inhabited by the southern harvester termite Microhodotermes viator and enriched in soil organic and inorganic carbon and soluble minerals. We aimed to generate radiogenic and stable isotope data for soils and groundwater in a region where these data are absent, to 1) verify the atmosphere-soil-groundwater link, and 2) resolve the timing and pattern of calcite dissolution and water infiltration in the landscape. Results show that soil and groundwater sulfate have the same marine aerosol source. Episodic calcite dissolution in mound centers, which increased during periods of global cooling, has been set against background input of marine aerosols since before the Last Glacial according to radiocarbon (14C) ages. Our data push back soil organic carbon 14C ages of inhabited termite mounds to 13-19 ka (kiloannum, thousand years before present), nest carbonate 14C ages to 33 ka, and mound soil carbonate 14C ages to 34 ka, making these the oldest active termite features ever dated. These ages are consistent with soil organic carbon and carbonate 14C ages of regional, non-mound, coastal petrocalcic horizons formed by accumulation of carbonate leached from their overlying aeolian dune fields. Harvesting activities of termites inject younger organic material around nests >1 m deep, leading to continuous renewal of important soil carbon reservoirs at depth. Termite bioturbation increases the system's ability to dissolve carbonate. The central, bioturbated part of the mounds have greater infiltration depths and greater calcite dissolution, whereas surrounding soils experienced more surface runoff. Calcareous termite mounds offer a mechanism to sequester CO2 through dissolution and leaching of soil carbonate-bicarbonate to groundwater.

Technical note: Studying lithium metaborate fluxes and extraction protocols with a new, fully automated in situ cosmogenic 14C processing system at PRIME Lab

Abstract. Extraction procedures for in situ cosmogenic 14C (in situ 14C) from quartz require quantitative isotopic yields while maintaining scrupulous isolation from atmospheric and organic 14C. These time- and labor-intensive procedures are ripe for automation; unfortunately, our original automated in situ 14C extraction and purification systems, reconfigured and retrofitted from our original systems at the University of Arizona, proved less reliable than hoped. We therefore installed a fully automated stainless-steel system (except for specific borosilicate glass or fused-silica components) incorporating more reliable valves and improved actuator designs, along with a more robust liquid nitrogen distribution system. As with earlier versions, the new system uses a degassed lithium metaborate (LiBO2) flux to dissolve the quartz sample in an ultra-high-purity oxygen atmosphere, after a lower-temperature combustion step to remove atmospheric and organic 14C. We compared single-use high-purity Al2O3 against reusable 90 %Pt / 10 %Rh (Pt/Rh) sample combustion boats. The Pt/Rh boats heat more evenly than the Al2O3, reducing procedural blank levels and variability for a given LiBO2 flux. This lower blank variability also allowed us to trace progressively increasing blanks to specific batches of fluxes from our original manufacturer. Switching to a new manufacturer returned our blanks to consistently low levels on the order of (3.4 ± 0.9) × 104 14C atoms. We also analyzed the CRONUS-A intercomparison material to investigate sensitivity of extracted 14C concentrations to the temperature and duration of the combustion and extraction steps. Results indicate that 1 h combustion steps at either 500 or 600 ∘C yield results consistent with the consensus value of Jull et al. (2015), while 2 h at 600 ∘C results in loss of ca. 9 % of the high-temperature 14C inventory. Results for 3 h extractions at temperatures ranging from 1050 to 1120 ∘C and 4.5 h at 1000 ∘C yielded similar results that agreed with the nominal value and published results from most laboratories. On the other hand, an extraction for 3 h at 1000 ∘C was judged to be incomplete due to a significantly lower measured concentration. Based on these results, our preferred technique is now combustion for 1 h at 500 ∘C followed by a 3 h extraction at 1050 ∘C. Initial analyses of the CoQtz-N intercomparison material at our lab yielded concentrations ca. 60 % lower than those of CRONUS-A, but more analyses of this material from this and other labs are clearly needed to establish a consensus value.

A critical re‐analysis of constraints on the timing and rate of Laurentide Ice Sheet recession in the northeastern United States

AbstractWe review geochronological data relating to the timing and rate of Laurentide Ice Sheet recession in the northeastern United States and model ice margin movements in a Bayesian framework using compilations of previously published organic 14C (n = 133) and in situ cosmogenic 10Be (n = 95) ages. We compare the resulting method‐specific chronologies with glacial varve records that serve as independent constraints on the pace of ice recession to: (1) construct a synthesis of deglacial chronology throughout the region; and (2) assess the accuracy of each chronometer for constraining the timing of deglaciation. Near the Last Glacial Maximum terminal moraine zone, 10Be and organic 14C ages disagree by thousands of years and limit determination of the initial recession to a date range of 24–20 ka. We infer that 10Be inherited from pre‐glacial exposure adds 2–6 kyr to many exposure ages near the terminal moraines, whereas macrofossil 14C ages are typically 4–8 kyr too young due to a substantial lag between ice recession and sufficient organic material accumulation for dating in some basins. Age discrepancies between these chronometers decrease with distance from the terminal moraine, due to less 10Be inherited from prior exposure and a reduced lag between ice recession and organic material deposition. 14C and 10Be ages generally agree at locations more than 200 km distal from the terminal moraines and suggest a mostly continuous history of ice recession throughout the region from 18 to 13 ka with a variable pace best documented by varves.

Organic and inorganic carbon-14 in discharges of JSC Institute of Nuclear Materials

The aim of the study is the activity concentration measurements of organic and inorganic 14C in the discharges of JSC “Institute of Nuclear Materials” (INM). In INM the research water-water reactor “IVV-2M” is operating. Collecting of 14C species was performed using a 14C sampler with a chromium oxide and platinum catalysts at different temperatures: 400, 550 and 700 °C. The measurements of 14C activity were performed using a liquid scintillation counter. The share of organic 14C in emissions ranged from 0.30 to 0.84 and depends on the temperature of the catalyst, core structure and reactor operating mode.

A Eurasian Basin sedimentary record of glacial impact on the central Arctic Ocean during MIS 1–4

Pronounced Quaternary circulation and depositional changes in the Arctic Ocean basins remain poorly understood. We investigate sediment core ARC5-ICE4 (ICE4) in the Eurasian (Amundsen) Basin off the Lomonosov Ridge to reconstruct glacial-interglacial variability in sediment sources and circulation. The ICE4 record features variable lithologies including distinct glacigenic deposits with Ice Rafted Debris (IRD). The sediment age is constrained by a combination of the organic carbon 14C with paleomagnetic data and correlation to earlier developed stratigraphies. The derived sedimentation rates constitute several cm/kyr (6.5 cm/kyr average) consistent with estimates from regional geophysical data. The developed age model covers the time interval from ca. 10 to 75 ka including Late and Middle Weichselian/Wisconsinian glaciations. Respective glacigenic sediments were primarily deposited by pulsed iceberg discharge. The Last Glacial Maximum and deglaciation is expressed in sharp IRD peaks including mineral proxies of the Laurentide Ice Sheet with an apparent millennial-scale variability. The older glacigenic sedimentary unit with abundant IRD of predominantly Siberian provenance was deposited during deglaciation of the Middle Weichselian (MIS 4/3) Eurasian Ice Sheet. These sedimentary differences indicate diverging impacts of the two glaciations on the Arctic Ocean, including ice-sheet sizes/geometries and oceanic circulation.

A Dramatic Marine Environment Change in the Beibu Gulf of the South China Sea around 3.2 kyr BP

Abstract The profile geochemical characteristics of a seafloor sediment core, collected from the Beibu Gulf of the South China Sea, have been investigated in terms of the sediment grain size, the content of major and trace elements, the total organic carbon (TOC) and organic nitrogen (TN), and the carbon isotopic composition of organic matter (δ13Corg) and AMS 14C dating. These results show that the core sediments were deposited since 11.3 kyr BP and the profile could be clearly divided into the lower and upper sediment section based on geochemical characteristics. The lower section covers the depth of 86 cm to 200 cm and was deposited from 3.2 to 11.3 kyr BP, while the upper section is at the depth of 4 to 86 cm and represents sediments from 0.2 to 3.2 kyr BP. The upper section sediments are charcteristized by a much finer grain size and a clearly positive deviation of the δ13Corg value. Obviously, the overall profile geochemical characteristics indicate that the upper section was deposited under a significantly deeper seawater depth associated with a relatively weaker hydrodynamic and a better preservation condition for organic matter, while the low section was deposited under a relatively shallow seawater depth with the relatively stronger hydrodynamic condition and a relatively poor preservation condition for organic matter. Finally, it is suggested that the transition between the lower section and the upper section occurring around 3.2 kyr BP was mostly likely due to a dramatic marine environmental change caused by the rapid seafloor subsidence associated with the further expansion of the Qiongzhou Strait. And further multidisciplinary studies are needed to better reveal and understand different aspects of the significance of this marine environment change in the Beibu Gulf of the South China Sea.

DETERMINATION OF THE TOTAL 14C CONCENTRATION OF WATER SAMPLES USING THE COD METHOD AND AMS

ABSTRACTRadiocarbon (14C) is the one of the most important radionuclides released from the nuclear facilities to the environment. Currently, inorganic 14C is checked during regular environmental monitoring as part of the groundwater monitoring program of the Paks Nuclear Power Plant. Several studies have shown that organic 14C can be also an important and sensitive tool for detection of possible leakage of nuclear technological systems. For this reason, a wet oxidation method was developed for the accelerator mass spectrometry (AMS) 14C measurement technique to determine the 14C activity concentration of the total dissolved carbon content of water samples, coming from environmental monitoring wells. The overall efficiency of the oxidation was around 94 ± 5% for different types of tested organic compounds. The typical 14C background (1–2 pMC) is obtained by preparation of blank samples, which allows a detection level of around 5·10–5 Bq L–1. The activity of the organic fraction can be calculated using the formula presented in the study. The method was applied for water samples deriving from environmental monitoring wells of a pressurized-water reactor (PWR) type of NPP. The results of our investigations over the 14 different water samples around the Paks NPP show that DO14C contribution to the total 14C activity concentration was between 5–25%.

Carbon-14 release and speciation during corrosion of irradiated steel under radioactive waste disposal conditions

Carbon-14 is a key radionuclide in the safety assessment of deep geological repositories (DGR) for low- and intermediate-level radioactive waste (L/ILW). Irradiated metallic wastes generated during the decommissioning of nuclear power plants are an important source of 14C after their disposal in a DGR. The chemical form of 14C released from the irradiated metallic wastes determines the pathway of migration from the DGR into the environment. In a long-term corrosion experiment with irradiated steel simulating the hyper-alkaline, anoxic conditions of a cement-based DGR, total inorganic (TI14C22TI14C: Total inorganic 14C; TO14C: total organic 14C; TG14C: total gaseous 14C) and organic 14C contents (TO14C) in the liquid and gas phases (TG14C), as well as individual 14C-bearing carbon compounds by compound-specific radiocarbon analysis (CSRA), were quantified using accelerator mass spectrometry (AMS). The AMS-based quantification allows the determination of 14C in the pico- to femtomolar concentration range. An initial increase in TO14C was observed, which could be attributed partially to the release of 14C-bearing oxygenated carbon compounds. In the long term, TO14C and the TI14C remain constant, while TG14C increases over time according to a corrosion rate of steel of 1 nm/yr. In solution, 14C-bearing carboxylic acids (CAs) contribute ~40% to TO14C, and they are the main 14C carriers along with 14C-bearing carbonate (14CO32−). The remaining fraction of TO14C (~ 60%) is likely due to the presence of as yet non-identified polymeric or colloidal organic material. In the gas phase, 14CH4 accounts for more than 80% of the TG14C, while only trace amounts of 14CO, and other small 14C-bearing hydrocarbons have been detected. In a DGR, the release of 14C will be mainly in gaseous form and migrate via the gas pathway from the repository near field to the surrounding host rock and eventually to the environment.

The Upper Limit of Denudation Rate Measurement From Cosmogenic 10Be(Meteoric)/9Be Ratios in Taiwan

AbstractThe tectonically active Taiwan orogen features numerous rivers that yield a high amount of sediment with fluxes exceeding 104 t/km2/yr. Amongst these, the landslide‐dominated Liwu River is well studied regarding its dynamic surface processes. However, the quantification of denudation in the Liwu Basin is still an ongoing task as rates obtained to date are subject to substantial differences depending on methods that differ in their spatio‐temporal scales. We constrain an upper limit of global denudation using the cosmogenic nuclide 10Be(meteoric) and its ratio to stable 9Be. Meteoric cosmogenic 10Be is delivered to Earth’s surface by precipitation, whereas stable 9Be is released from rock weathering. In contrast to in situ cosmogenic 10Be measured in quartz, the 10Be(meteoric)/9Be ratio can be analyzed in quartz‐poor settings. 10Be(meteoric)/9Be‐derived denudation rates (Dmet) vary from 8.1 to >30 mm/yr in the Liwu mainstem, and from 3.4 to 21.5 mm/yr in the tributaries. These new Dmet are among the highest cosmogenic nuclide‐derived rates ever measured. Most of these rates agree with rates from sediment gauging or channel incision. We propose that stochastic landsliding plays a major role in denudation processes here. Using a soil‐bedrock mixing model and published riverine organic 14C data as a soil tracer, we estimate the fractional contribution of bedrock landslide material to mainstem sediments to be 55%–97%, which explains the magnitude and large variability (4‐fold) in Dmet. We demonstrate the complexity associated with denudation rates determination in landslide‐dominated routing systems; but also the potential of 10Be(meteoric)/9Be for tracing stochastic landsliding processes.

Sedimentary facies and Holocene depositional evolution of the Maricá Lagoon, Rio de Janeiro, Brazil

This study aims to improve the knowledge on the geological evolution of the Maricá Lagoon (Rio de Janeiro) during the Holocene. One hundred and three samples from four boreholes and GPR data were acquired. Laboratory analyses included grain size and morphology, color, organic matter contents, fossils, mineral composition, and 14C dating. The results indicate that the 12.5 m thick sedimentary section studied here represents the last 8111 years of lagoonal deposition. Five sedimentary facies were identified: (1) subrounded sand facies (containing a gravel subfacies) which occur along the southern margin; (2) silty sand facies occurring at the transition from the margin to the lagoon center; (3) sandy silt facies and (4) silt/clayey silt facies which cover the calmer, central areas of the lagoon; and (5) angular sand facies which occur only at the surface of the northern margin. The organic matter content in the mud varied from 18% to 81%. Sedimentation rates up to 4277 cal years BP in the western margin were 0.27 cm/y and 0.15 cm/y in the deeper, central lagoon areas, and 0.20 cm/y since then. The sedimentary facies and organisms (molluscs and sponges) indicated that the Maricá Lagoon has changed little during the Holocene. At about 8111 cal years BP, the lagoon was an important freshwater basin with occasional saltwater influence. At about 5600–5000 years ago, during the maximum Holocene transgression, the lagoon attained its maximum dimensions and prevailing marine influences. Overwash processes and inlets enabled the formation of washover fans and flood-tidal delta deposits that have been recognized since the early formation stages of the Pleistocene barrier. From 4645 cal years BP to the present day, the connection between the lagoon and the sea has occurred sporadically at the southeast extreme of the lagoon (Barra Lagoon). Today's sedimentary dynamics are influenced by fluvial input (which is building up a lagoonal delta) and by winds, which transport sands from the barrier into the lagoon, in addition to generating waves capable of remobilizing the marginal and bottom lagoon sediments.

Mapping spatial and temporal variation of seafloor organic matter Δ14C and δ13C in the Northern Gulf of Mexico following the Deepwater Horizon Oil Spill

Following the Deepwater Horizon oil spill of 2010, large amounts of biodegraded oil (petrocarbon) sank to the seafloor. Our objectives were to 1) determine post-spill isotopic values as the sediments approached a new baseline and 2) track the recovery of affected sediments. Sediment organic carbon δ13C and Δ14C reached a post-spill baseline averaging −21.2 ± 0.9‰ (n = 129) and −220 ± 66‰ (n = 95). Spatial variations in seafloor organic carbon baseline isotopic values, 13C and 14C, were influenced by river discharge and hydrocarbon seepage, respectively. Inverse Distance Weighting of surface sediment Δ14C values away from seep sites showed a 50% decrease in the total mass of petrocarbon, from 2010 to 2014. We estimated a rate of loss of −2 × 109 g of petrocarbon-C/year, 2–11% of the degradation rates in surface slicks. Despite the observed recovery in sediments, lingering residual material in the surface sediments was evident seven years following the blowout.

Compound‐Specific Radiocarbon Analysis of (Sub‐)Antarctic Coastal Marine Sediments—Potential and Challenges for Chronologies

AbstractIn Antarctic and Subantarctic environments, 14C‐based age determination is often challenging due to unknown reservoir effects, low organic carbon contents of sediments, and high contributions of petrogenic (14C‐free) carbon in ice marginal settings. In this study, we evaluate possible benefits and challenges of compound‐specific radiocarbon analysis (CSRA) as a tool for age determination of marine Antarctic and Subantarctic sediment sequences. We present a comprehensive data set of 14C ages obtained on bulk organic carbon, carbonates, and on fatty acids (FA) from three coastal marine sediment cores from Subantarctic South Georgia and East Antarctica. Low molecular weight (LMW) FA represent the least 14C‐depleted fraction, indicating that the phytoplankton‐derived compounds can be a means of dating sediments. In contrast, vascular plant‐derived high molecular weight FA are systematically depleted in 14C relative to the low molecular weight homologues, reflecting processes such as soil formation/erosion in the catchment. Comparative age‐depth models show significant differences, depending on the material used for the respective models. While the land plant‐derived FA may lead to an overestimation of the actual sediment age, LMW FA reveal complex aquatic reservoir effects. Bulk sedimentary organic carbon 14C ages likely provide appropriate age estimates in settings with low petrogenic carbon input in the Antarctic, whereas CSRA has the potential to produce improved age control in settings with high contributions of petrogenic carbon.

Distribution of radiocarbon in sediments of the cooling pond of RBMK type Ignalina Nuclear Power Plant in Lithuania.

The vertical distribution of radiocarbon (14C) was examined in the bottom sediment core, taken from Lake Drūkšiai, which has served as a cooling pond since 1983 for the 26 years of the Ignalina Nuclear Power Plant (INPP) operation using two RBMK-1500 reactors (Russian acronym for”Channelized Large Power Reactor”). 14C specific activity was measured in alkali-soluble and -insoluble fractions of the sediment layers. Complementary measurements of the 210Pb and 137Cs activity of the samples provided the possibility to evaluate the date of every layer formation, covering the 1947–2013 period. In addition, 14C distribution was examined in the scales of pelagic fish caught between 1980 and 2012. Our measurements reveal that, during the period 1947–1999, the radiocarbon specific activity in both fractions exhibits a parallel course with a difference of 5 ± 1 pMC (percent of modern carbon) being higher in alkali-soluble fraction, although 14C specific activity in both fractions increased by 11.4–13.6 pMC during the first 15 years of plant operation. However, during the 2000–2009 period, other than previously seen, a dissolved inorganic carbon (DIC) → aquatic primary producers → sediments 14C incorporation pattern occurred, as the radiocarbon specific activity difference between alkali-soluble and -insoluble fractions reached 94, 25, and 20 pMC in 2000, 2006, and 2008, respectively. Measurements in different sediment fractions allowed us to identify the unexpected organic nature of 14C contained in liquid effluences from the INPP in 2000–2009. The discrepancy between 14C specific activity in fish scales samples and DIC after 2000 also confirmed the possibility of organic 14C contamination. Possible reasons for this phenomenon might be industrial processes introduced at the INPP, such as the start of operation of the cementation facility for spent ion exchange resins, decontamination procedures, and various maintenance activities of reactor aging systems and equipment.

Organic Carbon Storage and 14C Apparent Age of Upland and Riparian Soils in a Montane Subtropical Moist Forest of Southwestern China

Upland and riparian soils usually differ in soil texture and moisture conditions, thus, likely varying in carbon storage and turnover time. However, few studies have differentiated their functions on the storage of soil organic carbon (SOC) in sub-tropical broad-leaved evergreen forests. In this study, we aim to uncover the SOC storage and 14C apparent age, in the upland and riparian soils of a primary evergreen broad-leaved montane subtropical moist forest in the Ailao Mountains of southwestern China. We sampled the upland and riparian soils along four soil profiles down to the parent material at regular intervals from two local representative watersheds, and determined SOC concentrations, δ13C values and 14C apparent ages. We found that SOC concentration decreased exponentially and 14C apparent age increased linearly with soil depth in the four soil profiles. Although, soil depth was deeper in the upland soil profiles than the riparian soil profiles, the weighted mean SOC concentration was significantly greater in the riparian soil (25.7 ± 3.9 g/kg) than the upland soil (19.7 ± 2.3 g/kg), but has an equal total SOC content per unit of ground area around 21 kg/m2 in the two different type soils. SOC δ13C values varied between −23.7 (±0.8)‰ and −33.2 (±0.2)‰ in the two upland soil profiles and between −25.5 (±0.4)‰ and −36.8 (±0.4)‰ along the two riparian soil profiles, with greater variation in the riparian soil profiles than the upland soil profiles. The slope of increase in SOC 14C apparent age along soil depth in the riparian soil profiles was greater than in the upland soil profiles. The oldest apparent age of SOC 14C was 23,260 (±230) years BP (before present, i.e., 1950) in the riparian soil profiles and 19,045 (±150) years BP in the upland soil profiles. Our data suggest that the decomposition of SOC is slower in the riparian soil than in the upland soil, and the increased SOC loss in the upland soil from deforestation may partially be compensated by the deposition of the eroded upland SOC in the riparian area, as an under-appreciated carbon sink.

Multivariate Statistical and Multiproxy Constraints on Earthquake-Triggered Sediment Remobilization Processes in the Central Japan Trench.

Understanding the impact of earthquakes on subaqueous environments is key for submarine paleoseismological investigations seeking to provide long‐term records of past earthquakes. For this purpose, event deposits (e.g., turbidites) are, among others, identified and stratigraphically correlated over broad areas to test for synchronous occurrence of gravity flows. Hence, detailed spatiotemporal petrographic and geochemical fingerprints of such deposits are required to advance the knowledge about sediment source and the underlying remobilization processes induced by past earthquakes. In this study, we develop for the first time in paleoseismology a multivariate statistical approach using X‐ray fluorescence core scanning, magnetic susceptibility, and wet bulk density data that allow to test, confirm, and enhance the previous visual and lithostratigraphic correlation across two isolated basins in the central Japan Trench. The statistical correlation is further confirmed by petrographic heavy grain analysis of the turbidites and additionally combined with our novel erosion model based on previously reported bulk organic carbon 14C dates. We find surficial sediment remobilization, a process whereby strong seismic shaking remobilizes the uppermost few centimeters of surficial slope sediment, to be a predominant remobilization process, which partly initiates deeper sediment remobilization downslope during strong earthquakes at the Japan Trench. These findings shed new light on source‐to‐sink transport processes in hadal trenches during earthquakes and help to assess the completeness of the turbidite paleoseismic record. Our results further suggest that shallow‐buried tephra on the slope might significantly influence sediment remobilization and the geochemical and petrographic fingerprints of the resulting event deposits.

Paleomagnetic observations from lake sediments on Samosir Island, Toba caldera, Indonesia, and its late Pleistocene resurgence

AbstractApproximately 74 ka, Toba caldera in Sumatra, Indonesia, erupted in one of the most catastrophic supereruptions in Earth's history. Resurgent uplift of the caldera floor raised Samosir Island 700 m above Lake Toba, exposing valuable lake sediments. To constrain sediment chronology, we collected 173 discrete paleomagnetic 8 cm3 cubes and 15 radiocarbon samples from six sections across the island. Bulk organic 14C ages provide an initial chronostratigraphic framework ranging from ~12 to 46 ka. Natural and laboratory magnetizations were studied using alternating field demagnetization. A generally well-defined primary magnetization is isolated using principal component analysis. Comparison of inclination, and to a lesser degree declination, across independently dated sections suggests paleomagnetic secular variation (PSV) is recorded. Average inclination of −6° is more negative than a geocentric axial dipole would predict, but consistent with an eastward extension of the negative inclination anomaly observed in the western equatorial Pacific. The 14C- and PSV-derived age model constrains resurgent uplift, confirming faster uplift rates to the east and slower rates to the west, while suggesting that fault blocks moved differentially from each other within a generally trapdoor-type configuration.

The deficiency of organic matter 14C dating in Chinese Loess-paleosol sample

Abstract In the absence of reliable charcoal, wood or plant macrofossils, organic matter in loess-paleosols is often used for 14C dating. However, organic matter can be contaminated by a variety of carbon sources within the sediments, and this may affect the radiocarbon dating results. Specific chemical pretreatments can be applied to minimize such effects, and comparisons with optically stimulated luminescence (OSL) dates from the same sediments allows us to assess potential open system effects on organic matter. Here we present comparisons of the two geochronometers from loess-paleosol deposits in the Chinese Loess Plateau. Our results show that loess -paleosol samples from the past 25 cal kyr BP generally yield reliable 14C dates, however, beyond this range, specifically ~25–59 cal kyr BP, we observe a steady increase in OSL ages with depth, but no consistent increase in corresponding AMS 14C ages. We suggest that relatively old samples from loess-paleosols should be studied using techniques such as compound-specific radiocarbon dating, ramped pyrolysis or stepped-temperature combustion.

Soil organic carbon fractions and 14C ages through 70 years of cropland cultivation

Understanding the biogeochemistry of soil organic carbon (SOC) and SOC components is essential to assess soil quality and management practices in reclaimed croplands. Here we study the radiocarbon (14C) ages in profiles to a depth of 500 cm for five cultivation timespans: 5, 15, 35, 60, and at least 70 years from the Gutun watershed on the Chinese Loess Plateau. We isolated an acid-extractable SOC component (F1), three temperature stepped-combustion SOC components: F2 (400 °C), F3 (600 °C), and F4 (900 °C), and measured their 14C ages. Our results show that SOC stocks in reclaimed soils declined from cultivation times of 5 years (R5) to 15 years (R15), then increased with longer cultivation times, until 70 years (R70). The SOC content of the F2 and F3 fractions was higher than F1 and F4 over the past 60 years, while the F4 fraction in R70 had the highest value. Since the newly reclaimed croplands were heavily fertilized, R5 had high SOC and carbon management index (CMI) values, and 14C ages close to the other SOC fractions in the surface soil. The 14C ages of SOC fractions in deep soils were older than others, indicating a weak capacity to fix fresh C that infiltrated the deeper soils in R5. R70 contained the highest SOC stocks, but with a large proportion of old, non-labile SOC that contributed to relatively low SOC quality and CMI. Therefore, we predict that the R70 site would be unable to sustain optimal maize productivity. The SOC stocks under R35 were significantly lower than those from R5 and R70, but contained a high proportion of labile SOC, with relatively young 14C ages (compared to R60), even to a depth of 500 cm. This observation suggests that planting forest nurseries can improve SOC quality and promote SOC sequestration even in relatively deep soils. This study demonstrates the efficacy of labile SOC content and 14C ages as measures of SOC quality, and our findings offer useful guidance for the management of reclaimed croplands.