Abstract Copper-doped zinc sulfide nanocrystals (Cu-ZnS NCs) exhibit durable, temperature-stable photochromic properties with cost-effective synthesis. However, existing photochromic Cu-ZnS NCs are water-soluble, limiting industrial applications. To address this, we synthesized hydrophobic Cu-ZnS NCs using ligands compatible with organic solvents. These NCs display reversible photochromism in several organic solvents, changing from pale yellow to brown under 365-nm light and reverting within tens of minutes. We systematically examined the effects of zinc precursors, particle size, Cu doping concentration, and solvents to optimize the performance and elucidate an optimal coloration condition. This study demonstrates the promise of Cu-ZnS NCs as versatile, next-generation photochromic materials.
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