Optical Orientation Research Articles

Magnetic coherence effects in the spectroscopy of transitions between energy levels with total angular momenta J = 1/2 and J = 1 using unidirectional waves

The physical processes that form the spectra of saturated absorption resonances at atomic transitions between energy levels with angular momenta J = 1/2 and J = 1 in the field of two unidirectional linearly polarised laser waves are studied analytically and numerically. It is shown that the specific features of the resonance spectra are formed in the Λ-schemes of transitions and manifest themselves in the form of narrow coherent structures – dips due to the magnetic coherence (optical orientation) of the transition levels induced by the optical fields. In this case, the energy levels of the lower state make the main contribution, and the contribution of the transfer of magnetic coherence from the sublevels of the upper state to the lower ones in the resonance amplitude manifests itself as an additive. Conditions are found under which the nonlinear resonance is exclusively coherent. The effect of the saturating wave field on the shape of coherent resonance structures is studied.

Submillisecond Spin Relaxation in CsPb(Cl,Br)3 Perovskite Nanocrystals in a Glass Matrix.

Lead halide perovskite nanocrystals in a glass matrix are a promising platform for optoelectronic applications due to their excellent optical properties combined with outstanding stability against the environment. We reveal the potential of this system for spintronics by studying the electron spin properties of CsPb(Cl,Br)3 nanocrystals in a fluorophosphate glass matrix. Using optical spin orientation and spin depolarization with a radio frequency field, we measure longitudinal spin relaxation time, T1, reaching several hundreds of microseconds at low temperatures. This time T1 corresponds to a spin state with a small g factor, which we attribute to a weakly exchange-coupled electron-hole pair with antiparallel spins.

Intraoperative navigation system with a multi-modality fusion of 3D virtual model and laparoscopic real-time images in laparoscopic pancreatic surgery: a preclinical study

BackgroundLaparoscopy is widely used in pancreatic surgeries nowadays. The efficient and correct judgment of the location of the anatomical structures is crucial for a safe laparoscopic pancreatic surgery. The technologies of 3-dimensional(3D) virtual model and image fusion are widely used for preoperative planning and intraoperative navigation in the medical field, but not in laparoscopic pancreatic surgery up to now. We aimed to develop an intraoperative navigation system with an accurate multi-modality fusion of 3D virtual model and laparoscopic real-time images for laparoscopic pancreatic surgery.MethodsThe software for the navigation system was developed ad hoc. The preclinical study included tests with the laparoscopic simulator and pilot cases. The 3D virtual models were built using preoperative Computed Tomography (CT) Digital Imaging and Communications in Medicine (DICOM) data. Manual and automatic real-time image fusions were tested. The practicality of the navigation system was evaluated by the operators using the National Aeronautics and Space Administration-Task Load Index (NASA-TLX) method.ResultsThe 3D virtual models were successfully built using the navigation system. The 3D model was correctly fused with the real-time laparoscopic images both manually and automatically optical orientation in the preclinical tests. The statistical comparative tests showed no statistically significant differences between the scores of the rigid model and those of the phantom model(P > 0.05). There was statistically significant difference between the total scores of automatic fusion function and those of manual fusion function (P = 0.026). In pilot cases, the 3D model was correctly fused with the real-time laparoscopic images manually. The Intraoperative navigation system was easy to use. The automatic fusion function brought more convenience to the user.ConclusionsThe intraoperative navigation system applied in laparoscopic pancreatic surgery clearly and correctly showed the covered anatomical structures. It has the potentiality of helping achieve a more safe and efficient laparoscopic pancreatic surgery.

Visualization of optical polarization transfer to photoelectron spin vector emitted from a spin-orbit coupled surface state

Similar to light polarization that is selected by a superposition of optical basis, electron spin direction can be controlled through a superposition of spin basis. We investigate such a spin interference occurring in photoemission of the spin-orbit coupled surface state in Bi2Se3 by using spin- and angle-resolved photoemission spectroscopy combined with laser light source (laser-SARPES). Our laser-SARPES with three-dimensional spin detection and tunable laser polarization including elliptical and circular polarization enables us to directly visualize how the direction of the fully-polarized photoelectron spin changes according to the optical phase and orientation of the incident laser polarization. By this advantage of our laser-SARPES, we demonstrate that such optical information can be projected to the three-dimensional spin vector of the photoelectrons. Our results, therefore, present a novel spin-polarized electron source permitting us to optically control the pure spin state pointing to the arbitrary direction.

Dynamic elastic modulus of modified cotton fibres

The dynamic elastic modulus of three cultivated varieties of G. hirsutum Linn, namely Samaru 26J Nigeria, Samaru 26J Glasgow and an unspecified American upland has been studied at different stages of fibre maturity using visco-elastomer. The dynamic modulus is found to be strongly dependent on both the maturity and the optical orientation angle. To eliminate the effect of convolutions on both the dynamic modulus and the helix angle, fibres are treated in liquid ammonia to get Cellulose III lattice structure and revert back to Cellulose I lattice structure using distilled water. Both the X- ray diffractograms and the scanning electron micrographs also confirm this finding. Maturity ratio is shown to have a very strong effect on the dynamic elastic modulus and not the age of the fibre. Fibres of similar maturity ratio show similar dynamic modulus, irrespective of the environmental conditions. Cellulose III and Cellulose I regenerated fibres have about the same dynamic modulus values. This shows that treatment does produce profound changes in the gross structure and calls for a fresh look at the swelling mechanism in both structures, a possible disruption of the H- bonding systems of cellulose by both treatments.

Engineering Photon Statistics in a Spinor Polariton Condensate.

We implement full polarization tomography on photon correlations in a spinor exciton-polariton condensate. Our measurements reveal condensate pseudospin mean-field dynamics spanning from stochastic switching between linear polarization components, limit cycles, and stable fixed points, and their intrinsic relation to the condensate photon statistics. We optically harness the cavity birefringence, polariton interactions, and the optical orientation of an incoherent exciton reservoir to engineer photon statistics with precise control. Our results demonstrate a smooth transition from a highly coherent to a super-thermal state of the condensate polarization components.

Optimization for maximum modulation of a double-pass twisted nematic liquid crystal display.

Spatial light modulators are widely used to perform modulations of different properties of the electromagnetic field. In this work, a simple optimization method for general double-pass setups was developed. It takes into account the involved polarizing elements and displays, and a numerical simulation based on an exhaustive search routine finds the optimal optical axis orientations of the polarizing elements for the desired modulation. By simultaneously considering both impingements, we are able to take full advantage of the modulation capabilities of the chosen spatial light modulators. In particular, different polarization modulations and complex amplitude modulations were studied for twisted nematic liquid crystal displays and passive linear optical elements. Examples of different optimization criteria are shown and compared with experimental results, supporting the feasibility of this approach. This method offers the possibility of independent modulation of two properties of the input light state, outperforming the use of a single screen.

A machine learning approach to map crystal orientation by optical microscopy

Mapping grain orientation in crystalline solids is essential to investigate the relationships between local microstructure and crystallography and interpret materials properties. One of the main techniques used to perform these studies is electron backscatter diffraction (EBSD). Due to the limited measurement throughput, however, EBSD is not suitable for characterizing samples with long-range microstructure heterogeneity, nor for building large material libraries that include numerous specimens. We present a machine learning approach for high-throughput crystal orientation mapping, which relies on the optical technique called directional reflectance microscopy. We successfully apply our method on Inconel 718 specimens produced by additive manufacturing, which exhibit complex, spatially-varying microstructures. These results demonstrate that optical orientation mapping on a metal alloy is achievable. Since our method is data-driven, it can be easily extended to different alloy systems produced using different manufacturing processes.

Paratobermorite, Ca4(Al0.5Si0.5)2Si4O16(OH)·2H2O·(Ca·3H2O), a new tobermorite-supergroup mineral with a novel topological type of the microporous crystal structure

Abstract A new mineral paratobermorite with the ideal crystal-chemical formula Ca4(Al0.5Si0.5)2Si4O16 (OH)·2H2O·(Ca·3H2O) is a member of the tobermorite group within the tobermorite supergroup. It was found at the Bazhenovskoe chrysotile asbestos deposit, Central Urals, Russia, in cavities of grossular rodingite in association with prehnite, pectolite, thomsonite-Ca, and calcite. Paratobermorite occurs as well-shaped prismatic to acicular crystals up to 1 × 1.5 × 8 mm3 typically assembled in spray- or bush-like radial clusters or open-work aggregates up to 1.5 cm across, which form interrupted crusts up to 3 × 5 cm2. Paratobermorite is transparent, colorless, pale yellowish, pale beige, or pinkish, with a vitreous luster. The mineral is brittle, with the (001) perfect cleavage. The Mohs hardness is ca. 3½. Dmeas = 2.51 (2) and Dcalc = 2.533 g/cm3. Paratobermorite is optically biaxial (+), α = 1.565 (2), β = 1.566 (2), γ = 1.578 (2), 2 Vmeas = 25 (10)° and 2 Vcalc = 32° (589 nm). Optical orientation is: X = c, Y = b, Z = a. The chemical composition of paratobermorite (electron microprobe, H2O by selective sorption from gaseous products of heating) is Na2O 0.40, K2O 0.28, CaO 36.60, MnO 0.04, BaO 0.07, Al2O3 6.46, SiO2 42.32, H2O 14.10, total 100.27 wt%. The empirical formula calculated on the basis of 22 O atoms per formula unit and (O,OH)17·5H2O is Na0.09K0.04Ca4.72Al0.92Si5.09O15.69(OH)1.31·5H2O. Like other members of the tobermorite supergroup, paratobermorite displays OD character, with two MDO (maximum degree of order) structures: one (MDO1), with non-standard space group F2/d11 and the second (MDO2), just corresponding to the structure-type of the new mineral, with non-standard space group C1121/m; its unit-cell parameters obtained from single-crystal X-ray diffraction data are: a = 11.2220(4), b = 7.3777(2), c = 22.9425(8) Å, γ = 89.990(3)°, V = 1899.46(10) Å3, and Z = 4; polytype 2M. The structure of paratobermorite is solved on a single crystal, R = 8.36%. Like structures of other “tobermorites 11 Å,” it is based on the complex layer built of a sheet of sevenfold Ca-centered polyhedra with wollastonite-type chains of T tetrahedra attached to the Ca-sheet from both sides. The tetrahedral (T) sites T1 and T2 are fully occupied by Si, while alternating T3 and T4 sites are filled by Al and Si in the ratio 1:1. The chains of tetrahedra belonging to neighboring complex layers share common oxygen vertices of the bridging T3,4 tetrahedra to form xonotlite-type ribbons [Si6O17]∞. The heteropolyhedral Ca-T-O scaffolding appears as a microporous quasi-framework with wide channels, which contain additional Ca atoms and H2O molecules. The complex Ca-T-O layers in paratobermorite (so-called “complex modules of type A”) significantly differ in topology (mutual arrangement of T tetrahedra and Ca polyhedra) from the complex Ca-T-O layers in tobermorite (“complex modules of type B”). IR spectrum confirms the presence of nonequivalent H2O molecules and nonequivalent T-O-T angles involving T atoms of two neighboring wollastonite-type chains. Due to the original topological type of the structure and the presence of significant amount of Al, which substitutes Si, paratobermorite can be considered as a novel microporous material, a perspective cation-exchanger.

Polarization modulation with optical lock-in detection reveals universal fluorescence anisotropy of subcellular structures in live cells

The orientation of fluorophores can reveal crucial information about the structure and dynamics of their associated subcellular organelles. Despite significant progress in super-resolution, fluorescence polarization microscopy remains limited to unique samples with relatively strong polarization modulation and not applicable to the weak polarization signals in samples due to the excessive background noise. Here we apply optical lock-in detection to amplify the weak polarization modulation with super-resolution. This novel technique, termed optical lock-in detection super-resolution dipole orientation mapping (OLID-SDOM), could achieve a maximum of 100 frames per second and rapid extraction of 2D orientation, and distinguish distance up to 50 nm, making it suitable for monitoring structural dynamics concerning orientation changes in vivo. OLID-SDOM was employed to explore the universal anisotropy of a large variety of GFP-tagged subcellular organelles, including mitochondria, lysosome, Golgi, endosome, etc. We found that OUF (Orientation Uniformity Factor) of OLID-SDOM can be specific for different subcellular organelles, indicating that the anisotropy was related to the function of the organelles, and OUF can potentially be an indicator to distinguish normal and abnormal cells (even cancer cells). Furthermore, dual-color super-resolution OLID-SDOM imaging of lysosomes and actins demonstrates its potential in studying dynamic molecular interactions. The subtle anisotropy changes of expanding and shrinking dendritic spines in live neurons were observed with real-time OLID-SDOM. Revealing previously unobservable fluorescence anisotropy in various samples and indicating their underlying dynamic molecular structural changes, OLID-SDOM expands the toolkit for live cell research.

Optical axis-driven modulation of near-field radiative heat transfer between two calcite parallel structures.

Recently, the increasing research on the anisotropic optical axis (OA) has provided a novel way to control light. However, this method is rarely applied to modulate the near-field radiative heat transfer (NFRHT). In this work, we investigate the influences of the OA orientation of calcite on the NFRHT between two calcite parallel structures. The numerical results demonstrate that the near-field radiative heat flux is larger when the OA is along the z-axis than that when the OA is along the x-axis. This is because when the OA is along the z-axis, the excited hyperbolic polaritons exhibit a full range of angles in the type I hyperbolic band. In contrast, the excited hyperbolic polaritons exhibit a finite angle when the OA is along the x-axis. Moreover, it is further investigated that the thickness has a significant impact on the NFRHT between calcite slabs. Our findings may highlight the promising role of calcite in manipulating NFRHT.

Magnetic resonance frequency shifts of alkali atoms in a K-Li mixture

The calculation of the frequency shifts of the magnetic resonance of K and Li atoms in a K-Li mixture has been carried out. A significant difference in the behavior of the temperature dependences of the frequency shifts for the optical orientation of K or Li atoms is established. Keywords: spin exchange, cross sections, frequency shifts.

Сдвиги частоты магнитного резонанса щелочных атомов в смеси K-Li

The calculation of the frequency shifts of the magnetic resonance of K and Li atoms in a K-Li mixture has been carried out. A significant difference in the behavior of the temperature dependences of the frequency shifts for the optical orientation of K or Li atoms is established.

Humus formation in soils of the Lena River Delta

The aim of the study. Nowadays close attention is paid to polar soils due to the expected landscape transformation rate under the predicted climate crisis. Intensive degradation of permafrost and the release of nutrients from their frozen state can lead to an increase in the emission of greenhouse gases into the atmosphere, as well as the loss of landscapes. The aim of the study was to investigate the peculiarities of organic residues formation and humification degree as well as humus structure and functioning in soil the Lena River Delta. 
 Location and time of the study. The study was conducted on the Samoylov and Sardach Islands in the Lena River Delta (Yakutia, Russia). Field studies were performed during the summer of 2019. 
 Objects and methodology. Soils of the Lena River Delta from the Samoylov Island (flooded area) and Sardakh (non-flooded zone), i.e. Subaquatic Fluvisol (Arenic) and Histic Cryosol (Siltic) were the objects of the study, respectively. To examine the features of humification chemical-analytical, sedimentation, micromorphological methods were used, as well as CP/MAS 13C-NMR spectroscopy. 
 Main results. The data obtained indicate a high diversity of soils and soil formation conditions in the Lena River Delta. Under non-flooded conditions Histic Cryosol (Siltic) were formed in the flooded parts of the Samoylov Island, Subaquatic Fluvisol (Arenic) were formed. These soils play an important role in the global carbon cycle, accumulation, transformation and deposition of condensed high- and low molecular mass organic compounds in the composition of soils and permafrost. The main soil micromorphology features were identified. In the young landscapes the soil microstructure was represented by poorly sorted sand with a circular type of optical orientation of the soil plasma (which indicated the influence of the river), as well as vertically oriented micas (muscovite/biotite). Soils influenced by the floodplain process were characterized by the presence of coarse amorphous humus. Due to the long-term effect of the freezing/thawing processes on the permafrost-affected soils the biogenic aggregates were formed. In such organo-mineral microaggregates humus is fixed in the composition of mineral components consisting of particles of quartz, micas and Mn-Fe nodules and is in a stable state (physical stabilization of humus). To analyze the molecular composition the 13C NMR spectroscopy method was used. According to 13C NMR spectroscopy data, up to 37% of aromatic structural fragments accumulated in soils, which indicates the process of condensation of molecules in humic acids, thus showing a relatively high level of humus stabilization in the soils of the Lena River delta. From the data obtained, three main groups of chemical structural fragments that accumulate in the delta soils can be distinguished, such as C,H - alkyls ((CH2)n/CH/C and CH3), aromatic compounds (C–C/C–H, C–O) and the OCH group (OCH/OCq). In the studied humic preparations aliphatic structural fragments of HAs (63–64%) predominated, which indicated a deficiency of lignin and lignin-like compounds in the composition of humification precursors. The predominance of aliphatic structures is typical of humic substances formed under reduction conditions, including the aqueous humic substances, as well as in soils, the precursors of humification of which are typical tundra vegetation (mosses and lichens) with a predominance of carbohydrates (up to 80%). A significant amount of aromatic fragments accumulated in the delta in the alluvial soils of the first terrace of the river (flooded zone). This is apparently due to the formation of vascular plants in the flooded areas of the Lena River Delta. The chemical composition of vascular plants includes components such as tannins, flavonoids and lignin (arenas). Thus in the samples formed under vascular plants with a lignin content of about 30%, an increase in signals in the range of 110-160 ppm were observed. Aromatic and carboxyl fragments in the structure of HA were formed during the transformation of lignin, which leads to the resistance of HAs to biodegradation.
 Conclusion. Under the floodplain condition humus is represented by coarse amorphous forms, whereas without the influence of flooding humus is fixed in mineral microaggregates. Specific humic acids composition in the studied regions is determined by bioclimatic conditions, cryogenic processes and the composition of humification precursors. High abundance of aromatic structures in humus substances suggests relatively stable humus status (most likely due to the putative condensation of humic acids) in the Lena River Delta during the study period.

Analogous Optical Activity in Free Space Using a Single Pancharatnam–Berry Phase Element

AbstractIt is commonly believed that optical activity (OA) is manifested mainly in chiral media, but rare in non‐chiral structures. Here, an analog of OA in free space is experimentally demonstrated by using a single liquid‐crystal Pancharatnam–Berry phase element (PBPE), for which the mechanism is highly consistent with that of the traditional OA. The specifically designed PBPE supports the direction‐dependent polarization rotation of a Bessel beam with controllable “rotatory power.” Such a polarization rotation can be revoked by another PBPE with the same structure. Unlike in a chiral medium, this scheme shows simultaneous realization of equivalent leverotation and dextorotation merely by switching the optical element orientation, promising for applications non‐magnetic optical devices such as optical isolators.

Highly Polarized Upconversion Emissions from Lanthanide-Doped LiYF4 Crystals as Spatial Orientation Indicators.

Polarized emission, an inherent characteristic that correlated with structure and morphology, is very sensitive to orientation. For the upconversion (UC) emission of lanthanides, the mechanism of polarization is rarely discussed, and the highly polarized UC emissions are poorly developed. Herein, with the benefit of the strong anisotropic crystal field, well-resolved emissions from lanthanide-doped LiYF4 crystals were studied, and highly polarized UC emissions from Er3+ and Ho3+ were investigated. With multiple sub-energy level transitions, the UC emissions are classified into two sets, with transition dipoles being either parallel or perpendicular to the c-axis of the LiYF4 crystal. An optical three-dimensional orientation sensor was further investigated, in which the in-plane angle is referenced from the orientation of the transition dipoles. In contrast, the out-of-plane angle can be deduced from the change in the degree of polarization. This research deepens our understanding of the polarized photoluminescence, and it opens up an avenue toward unique UC orientation sensors.

Spectral statistics of a 1D photonic crystal containing an anisotropic graphene-based hyperbolic metamaterial defect layer

A simple photonic crystal is a periodic and regular nanostructure. Breaking the periodicity of a photonic crystal by a defect layer can be an interesting pattern. We study the spectral statistics of eigenfrequency spacings (the so-called level spacing statistics) for TM-polarized waves in the one-dimensional (1D) defective photonic crystal containing graphene-based hyperbolic metamaterial as a defect layer. The localization of light in the proposed structure has been investigated using the transfer matrix method. Moreover, the effects of different parameters, such as the number of graphene cells and the defect layer's optical axis orientation, are discussed. The performance of the ratios of nearest neighbor level spacings has become a Wigner distribution at the localized phases which are introduced by inserting a defect layer. The spectral statistics are found to approach the Wigner distribution for different repeat numbers of graphene layers. In contrast, in the absence of graphene layers, the level spacing statistics follow the Poisson distribution.

Experimental Approach for Complex Optical Fiber Angular Orientation and Twist Measurement

Applications associated with complex, structured optical fibers having no circular symmetry often require information about their specific angular orientation. Such cases include, for example, splicing, sophisticated mode coupling, selective fiber Bragg gratings inscription, or direction‐sensitive sensing. Besides the external angular orientation of the fiber, additionally an intrinsic twist of the internal fiber structure has been identified as a critical parameter for applications. Such an intrinsic fiber twist might occur as a side effect of the fiber drawing process, or it may have been introduced intentionally as a special fiber property. In all such cases, a measurement of the local orientation along the fiber is highly desirable. A method for such measurements based on the analysis of the refractive–diffractive scattering patterns is presented. By comparing such measured patterns with reference patterns from modeling or from reference measurements, the orientation of the fiber can be identified with high accuracy and without measuring or reconstructing the detailed cross section of a fiber. The method, therefore, provides an approach for quick identification of a local angular fiber orientation status.

Contribution of inter-valley scattering in governing the steady state optical spin orientation in Al x Ga1−x As

The impact of inter-valley scattering in modifying the density of optically injected spin polarized electrons in Al x Ga1−x As/GaAs heterostructure is investigated. Polarization resolved photoluminescence excitation measurements are performed for studying the spectral dependence of degree of circular polarization (DCP) of photoluminescence signal emanating from an adjacent quantum well layer. The experimental DCP spectra is found to deviate from the theoretically calculated curve at high excitation energy and the deviation is seen to widen with the Al-content of Al x Ga1−x As barrier layer. In the past, researchers had attributed similar deviations to the Dyakonov–Perel (DP) spin relaxation mechanism which dominates the electrons spin dynamics at high excitation energy. However, we find that the inter-valley scattering along with the DP mechanism decide the shape of optical spin orientation spectra at higher energy. In fact, at higher Al-content, the inter-valley scattering in Al x Ga1–x As layer becomes the most dominant mechanism to govern the steady state electron spin polarization at the band edge. A numerical model is also proposed for estimating the steady state electron spin polarization at zone centre by including the inter-valley scattering, energy relaxation and DP spin relaxation mechanisms.

Exploiting High Geopositioning Accuracy of SAR Data to Obtain Accurate Geometric Orientation of Optical Satellite Images

Accurate geopositioning of optical satellite imagery is a fundamental step for many photogrammetric applications. Considering the imaging principle and data processing manner, SAR satellites can achieve high geopositioning accuracy. Therefore, SAR data can be a reliable source for providing control information in the orientation of optical satellite images. This paper proposes a practical solution for an accurate orientation of optical satellite images using SAR reference images to take advantage of the merits of SAR data. Firstly, we propose an accurate and robust multimodal image matching method to match the SAR and optical satellite images. This approach includes the development of a new structural-based multimodal applicable feature descriptor that employs angle-weighted oriented gradients (AWOGs) and the utilization of a three-dimensional phase correlation similarity measure. Secondly, we put forward a general optical satellite imagery orientation framework based on multiple SAR reference images, which uses the matches of the SAR and optical satellite images as virtual control points. A large number of experiments not only demonstrate the superiority of the proposed matching method compared to the state-of-the-art methods but also prove the effectiveness of the proposed orientation framework. In particular, the matching performance is improved by about 17% compared with the latest multimodal image matching method, namely, CFOG, and the geopositioning accuracy of optical satellite images is improved, from more than 200 to around 8 m.