Optical Emission Spectroscopy Technique Research Articles

Influence of Applied Discharge Voltage and Gas Flow Rate on Nickel Plasma Jet Parameters Diagnosed by Optical Emission Spectroscopic Technique

Abstract: In this work, we measure the plasma parameters by using an AC high-voltage power supply that generates a non-thermal plasma jet system at atmospheric pressure. A nickel (Ni) metal strip, with dimensions of 1.5 × 10 cm2, was connected to the anode electrode of the AC power supply. This nickel strip was immersed in a flask with a small amount of distilled water positioned below the plasma plume nozzle. Optical emission spectroscopy (OES) was used to diagnose the plasma system at different argon gas flow rates (1-5 L/min) and varying applied voltage values (11-15 kV). It is significant to know the processes accompanying plasma generation to measure their parameters which include the electron temperature (Te), electron number density (ne) of the plasma, Debye length (λD), and plasma frequency (fp). Our results showed an increase in the intensity of spectral lines with the increase in applied discharge voltage (11-15 kV). The maximum peak for ArI was observed at a wavelength of 811.531 nm, and the maximum peaks for nickel (Ni) were observed at wavelengths of 285.21 and 519.70 nm. Also, the results indicated a gradual increase in electron temperature (Te) and electron density (ne) values at the applied voltage of 0.403-0.468 eV. Likewise, the electron density (ne) was in the range of (11.486-13.851) × 1017 cm-3. Keywords: Atmospheric plasma jet, Nickel (Ni) plasma parameters, Electron temperature, Spectroscopic optical emission (OES).

Elemental Profiling of Common Anti-diabetic Medicinal Plants of Swat and Peshawar Districts of Khyber Pakhtunkhwa (KPK) Province of Pakistan: An Investigation Using PIXE and ICP-OES.

The use of medicinal plants is integral to addressing liver, heart, lung, and other metabolic issues. These plants are rich in vitamins, minerals, flavonoids, and alkaloids, which collectively help in lowering intestinal glucose absorption and increasing insulin secretion by pancreatic tissues. Elemental analysis, encompassing major, minor, and trace elements, was performed on various parts (leaves, roots, and seeds) of 16 anti-diabetic medicinal plants collected from different regions of Swat and Peshawar in Khyber Pakhtunkhwa (KPK), Pakistan. This analysis utilized proton-induced X-ray emission (PIXE) and inductively coupled plasma optical emission spectroscopy (ICP-OES) techniques. Our PIXE and ICP-OES analysis revealed the presence of major (Ca, K, S, P), minor (Si, Cl), and trace (Al, Mn, Fe, Ni, Cu, Zn, Se, Cr, and Sc) elements in various parts (leaves, roots, and seeds) of the 16 anti-diabetic medicinal plants studied. Specifically, elements such as Ca, K, Cr, Cu, Mn, Zn, and Se were detected, all of which are known to contribute in maintaining normal glucose metabolism. Notably, Zn and Se are crucial trace elements for the synthesis, secretion, and action of insulin. Significant Zn concentrations were observed in ten anti-diabetic medicinal plants: Albizia lebbeck (AL), Atropa acuminata (AA), Avena fatua (AF), Citrus medica (CM), Commiphora wightii (CW), Cymbopogon citratus (CC), Daucus carota (DC), Ziziphus mauritiana (FM), Hyoscyamus niger (HN), and Martynia annua (MA), and significant Se concentrations were observed in twelve medicinal plants, i.e., Albizia lebbeck (AL), Allium sativum (AS), Atropa acuminata (AA), Avena fatua (AF), Cannabis sativa (CS), Capparis spinosa (CaS), Commiphora wightii (CW), Cymbopogon citratus (CC), Datura alba (DA), Daucus carota (DC), Ziziphus mauritiana (FM), and Hyoscyamus niger (HN). Our study's elemental analysis using PIXE and ICP-OES on various parts of 16 medicinal plants identified a significant number of useful elements. Elements such as Ca, K, S, P, Al, Si, Cl, Mn, Fe, Ni, Cu, Zn, Se, and Cr were identified and quantified. These findings support the potential use of these plants in managing diabetes and highlight the importance of elemental profiling in understanding their therapeutic properties.

Fast and Greener Ultrasound-Assisted Acid Extraction for the Determination of Potentially Toxic Elements in Fluorescent Lamp Waste Using ICP OES.

Understanding the chemical composition of fluorescent lamp residue, particularly potentially toxic elements is crucial for reducing environmental impacts and human health risks after disposal. However, the challenge lies in effectively analyzing these heterogeneous solid samples. Techniques involving quantitative dissolution become imperative, playing a fundamental role in quantifying trace elements. The aim of this work is to develop and present a new, faster, and more efficient and environmentally friendly method using ultrasound-assisted acid extraction to quantify potentially toxic elements (Cu, Mn, Ni, Sr, and Zn) present in fluorescent lamp waste using the inductively coupled plasma optical emission spectrometry technique. An ultrasound-assisted acid extraction method for the quantification of potentially toxic elements in fluorescent lamp waste was developed and applied as a greener alternative to conventional digestion methods. For variables optimization a full factorial design with two levels and two variables (time and temperature) was used to found which factors significantly affect the observed response. The results obtained for the developed extraction method were compared with a reference method employing a heating acid digestion (mixture of HCl, HClO4 and HF) using statistical tools. The best results were obtained using extraction time of 10 min and temperature of 25 °C. Inductively coupled plasma optical emission spectrometry was applied for element quantification. The proposed extraction method showed good results for Cu, Mn, Ni, Sr and Zn. Furthermore, the proposed method based on ultrasound radiation presents additional criteria that align with the concepts of the green analytical chemistry. A greener alternative method for determination of Cu, Mn, Ni, Sr and Zn in fluorescent lamp waste was developed. Optimal conditions for ultrasound extraction of potentially toxic elements were achieved in 10 min at temperature of 25 °C. Environmentally friendly aspects of ultrasound align with the requirements of green analytical chemistry.

Spatial confinement offered by a blocker on the laser-induced breakdown spectroscopy of Ti plasma

Spatial confinement effects offered by a blocker on the laser-induced plasma parameters of titanium (Ti) are evaluated using the Optical Emission Spectroscopy technique. Nd:YAG (1064 nm, 10 ns) laser is used as an irradiation source. To observe the spatial confinement effects, an Al blocker at different distances of 4, 6, and 8 mm from the target is placed along the plume path. All the measurements are performed under the Ar environment at different pressures. It is observed that with increasing laser irradiance plasma parameters such as excitation temperature (Te) and electron number density (ne) increase, whereas it is vice versa true for increasing blocker distances. Without the blocker, the maximum values of Te and ne are about 7000 K and 1.4 × 1018 cm−3, respectively, at an Ar pressure of 50 Torr. A significant increase in emission intensity along with Te ≈ 9810 K and ne ≈ 2.2 × 1018 cm−3 is achieved in the presence of blocker. The results show that spatial confinement is responsible for the enhancement of Te and ne, which is attributed to the increased collisional frequency of plasma species after compression by shockwaves. The ablation pressure and shock pressure are also analytically evaluated and vary from 0.15 to 0.25 GPa and from 0.1 to 0.2 GPa, respectively, with increasing laser irradiance. With increasing blocker distances from 4 to 8 mm, the work done by reflected shockwaves to compress the plume varies from 0.02 to 0.002 mJ.

Influence of pulse laser energy on the Nickel plasma characteristics that produced in laser-induced plasma system

تُستخدم تقنية قياس طيف الانبعاث البصري ( OES) لتحليل البلازما المتولدة من هدف (النيكل) المضاء باستخدام ليزر Q- Switched (Nd: YAG) بطاقات مختلفة في الهواء. تم استخدام طريقة التوسيع Boltzmann-Plot و Stark لحساب معاملات البلازما بما في ذلك كثافة الإلكترون (ne) ودرجة حرارة الإلكترون (Te) وتردد البلازما (fp) وطول ديباي (λD). يتضح أن قيم (ne) و (Te) و (λD) و (fp) تزداد بزيادة طاقة الليزر مع قيم درجة حرارة الإلكترون المحسوبة التي تتراوح بين (0.934 - 1.479) الكترون - فولت.

Influence of the argon admixture on the reactive oxide species formation inside an atmospheric pressure oxygen plasma jet

In this work, a new atmospheric pressure plasma generated in a wire-to-multiwire dielectric barrier discharge on pure oxygen is introduced. This special geometry of 13 wires (one central wire and 12 ones on the external tube) is feeding by a radio frequency (RF) power (13.56 MHz, 1 kW) and produces a stable discharge. The capacity of this device to produce oxygen reactive species and the influence of Ar gas mixture (1–3%) on this production are investigated. The main characteristics of this DBD plasma are measured using optical emission spectroscopy techniques. The rotational, vibrational, and excitation temperatures along with the electron density are determined from OH (A2Σ → X2Π) band and the Stark broadening of the hydrogen atomic line at 486.1 nm, respectively. The temporal evolution and spatial distribution of charged and reactive species in this plasma are also numerically studied by a Global scheme and a two-dimension fluid model based on drift–diffusion approximation. A kinetic dominated by electron collisions is obtained for this plasma. The generation and movement of electrons, positive and negative ions in the wire-to-multiwire configuration are analyzed and discussed according to changes the electric field and plasma frequency. It is shown that the density of both charged and reactive species increases by adding a small amount of argon to the oxygen plasma while the electron temperature reduces in this configuration. A high level of agreement is observed between the experimental and simulation results for the electron density and temperature in this DBD plasma.

Direct Determination of Ca, K, and Mg in Soy Leaf Samples Using Laser-Induced Breakdown Spectroscopy.

This study was dedicated to developing analytical methods for determining macronutrients (Ca, K, and Mg) in soy leaf samples with and without petioles. The study's primary purpose was to present Laser-induced breakdown spectroscopy (LIBS) as a viable alternative for directly analyzing leaf samples using chemometric tools to interpret the data obtained. The instrumental condition chosen for LIBS was 70 mJ of laser pulse energy, 1.0 µs of delay time, and 100 µm of spot size, which was applied to 896 samples: 305 of soy without petioles and 591 of soy with petioles. The reference values of the analytes for the proposition of calibration models were obtained using inductively coupled plasma optical emission spectroscopy (ICP-OES) technique. Twelve normalization modes and two calibration strategies were tested to minimize signal variations and sample matrix microheterogeneity. The following were studied: multivariate calibration using partial least squares and univariate calibration using the area and height of several selected emission lines. The notable normalization mode for most models was the Euclidean norm. No analyte showed promising results for univariate calibrations. Micronutrients, P and S, were also tested, and no multivariate models presented satisfactory results. The models obtained for Ca, K, and Mg showed good results. The standard error of calibration ranged from 2.3 g/kg for Ca in soy leaves without petioles with two latent variables to 5.0 g/kg for K in soy leaves with petioles with two latent variables.

Influence of an oxygen-enriched layer on the tensile properties of an alpha titanium alloy

The manuscript focuses on establishing the role of an oxygen-enriched layer (OEL) on the tensile properties of an alpha titanium alloy, Ti-Al-Zr. The samples were heat-treated in the inert and air atmosphere for different durations up to 700 h. The air oxidation led to the formation of the OEL near the surface of the specimen. The specimens were characterized by different metallurgical techniques like a stereo microscope, optical microscopy, micro-hardness measurement and grain size measurement. The oxygen profiling was done by the glow discharge optical emission spectroscopy technique. The tensile testing was done at room temperature at a strain rate of 2.5 × 10−4 s−1. The fracture surface was examined under scanning electron microscopy. The tensile properties-yield strength and ultimate tensile strength were in the same range for the specimens oxidized in the inert and air atmosphere. However, the specimens oxidized in the air atmosphere showed a drastic decrease in ductility with increasing oxidation duration. The entire specimens oxidized in the inert atmosphere showed dimples features, typical of a ductile failure. The specimens oxidized in the air atmosphere showed fracture features like intercrystalline fracture, slip bands and cleavage facets in addition to dimples features. The OEL showed brittle failure and the regions other than OEL showed ductile failure. The role of oxygen on the tensile properties and the development of different fracture features during air oxidation are discussed.

Determination of trace elements and electrolyte levels in kidney tissue of simvastatin-treated septic rats.

Trace elements are cofactors in various enzymes in the antioxidant defense and cell homeostasis required in the tissue during inflammation. In acute kidney injury induced by lipopolysaccharide (LPS), renal cells are affected by cytotoxicity. Renal evacuation and gastrointestinal absorption rates are important in regulating plasma levels of trace elements. Simvastatin is a widely used anti-lipidemic drug with known anti-inflammatory effects. This study aimed to examine the effect of simvastatin on trace elements and electrolyte levels in kidney tissue in rats with LPS-induced sepsis. Adult male Wistar albino rats were divided into four groups: control, LPS (20mg/kg, i.p., single dose), simvastatin (20mg/kg, o.p., 5days), and LPS + Simvastatin (LPS + Sim). Sodium, potassium, calcium, magnesium, selenium, zinc, copper, and histological structural changes were examined in kidney tissue samples 4h after LPS execution. The inductively coupled plasma optical emission spectroscopy technique (ICP-OES) was used to determine the tissue trace element levels. In rats with sepsis-induced LPS, selenium, calcium, sodium, and magnesium levels significantly decreased while copper, potassium, and zinc levels significantly increased compared to other experimental groups. In sepsis treated with the simvastatin (LPS + Simvastatin) group, trace elements and electrolyte levels are like the control groups, apart from selenium levels. Selenium levels were significantly decreased in the LPS + Simvastatin group compared to the controls. As a result of examining the kidney tissues under a light microscope, simvastatin improved tissue damage caused by LPS-induced acute kidney injury. LPS-induced renal injury and simvastatin caused significant changes in the oxidant/antioxidant system. In septic rats, simvastatin was shown to balance some trace element levels, and it may improve damage in the kidney tissue.

Plasma Parameters Diagnosis of Laboratory Ar/O2 Cold Atmospheric Plasma Jet using Different Potential Discharges

This paper offers a clear methodology for the characterization of cold atmospheric plasmas and their development. The optical emission spectra of an Ar/O2 plasma jet produced in a plasma jet system at constant flow rates and for various potential discharges between 14 kV and 18 kV revealed that variations in voltage caused a significant difference in the intensity of the Ar/O2 emission. The plasma characteristics of electron temperature (Te), electron density (ne), plasma frequency (fp), Debye length (λD), and the number of particles in the Debye sphere (ND), were estimated using the technique of optical emission spectroscopy (OES). The obtained data are subject to further analysis and discussion. It was determined that potential discharges increased, and an electron temperature increased from 1.34 eV to 1.54 eV. With rising potential discharges, the Debye length decreases while the electron density, plasma frequency, and number of particles in the Debye sphere increase.

Silver Natural Asphalt Sulfonate (NA-SO3Ag): Fabrication and Utilization as a New Heterogeneous, Carbonaceous, and Retrievable Nanocatalyst for C(sp2)-X (X = C, S, and Se) Bond Formation.

Silver-based catalysts are valuable catalysts in various areas of the chemical industry, organic syntheses, and transformations, and from a chemical and industrial point of view, their recycling is very important. Herein, silver natural asphalt sulfonate (NA-SO3Ag) was fabricated via the grafting of Ag(I) on the surface of the solid natural asphalt sulfonate as a novel and efficient recoverable sliver nanocatalyst. Natural asphalt is one of the hydrocarbons that are found in mineral veins. The structure of NA-SO3Ag was characterized by diverse microscopic and spectroscopic techniques including Fourier-transform infrared (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), thermogravimetric analysis (TGA), Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), and inductively coupled plasma optical emission spectroscopy (ICP-OES) techniques. The NA-SO3Ag nanocatalyst was utilized for C-Se and C-S bond formation via coupling reactions of aryl halides and organic disulfides/diselenides to afford a wide variety of diaryl sulfides/selenides in good to excellent yields. Additionally, the utilization of NA-SO3Ag in C-C bond formation was examined in Suzuki coupling reactions successfully. For at least 6 trials, this heterogeneous catalyst can be separated and reused without any activity reduction.

Plasma Properties of Electric Arc Discharge Burning Between Cu-W Composites Electrodes

Plasma of electric arc discharge burning between different types of composite Cu-W electrodes was investigated. Electrodes manufactured of Cu-W composite materials (30/70% by mass) by shock sintering technology at temperatures of 750, 850, 950, and 1050°C were used. Optical emission spectroscopy techniques were applied to determine the main plasma parameters. Specifically, the side-on spectra of plasma emission were registered using a space-resolved spectrograph with a CMOS camera as a sensor device. The plasma thermodynamics properties were calculated based on the equilibrium plasma composition, which was determined using experimentally obtained radial distributions of temperatures and atom concentrations of the metals.

Hydrothermal carbonization (HTC) of dairy waste: effect of temperature and initial acidity on the composition and quality of solid and liquid products

Background: Hydrothermal carbonization (HTC) of dairy processing waste was performed to investigate the effect of temperature and initial pH on the yield and composition of the solid (hydrochar) and liquor produced. All hydrochars met the EU requirements of organo-mineral solid fertilizers defined in the Fertilizing Products Regulation in terms of phosphorus (P) and mineral content. Methods: Laboratory scale HTC was performed using pressurized reactors, and the products (solid and liquid) were collected, stored and analyzed for elemental composition and nutrient content using Inductively coupled plasma optical emission spectroscopy (ICP-OES), ultraviolet-visible spectrophotometry (UV-Vis) and other analytic techniques. Results: Maximum hydrochar yield (60.67%) was observed at T=180℃ and pH=2.25, whereas the maximum P-recovery was 80.38% at T=220℃ and pH=4.6. The heavy metal content of the hydrochars was mostly compliant with EU limitations, except for Ni at T=220℃ and pH=8.32. Meanwhile, further study of Chromium (Cr) species is essential to assess the fertilizer quality of the hydrochars. For the liquid product, the increase in temperature beyond 200℃, coupled with an increase in initial acidity (pH=2.25) drove P into the liquor. Simultaneously, increasing HTC temperature and acidity increased the concentration of NO 3 - and NH 4 + in the liquid products to a maximum of 278 and 148 mg/L, respectively, at T=180℃ and pH=4.6. Furthermore, no direct relation between final pH of liquor and NH 4 + concentration was observed. Conclusions: HTC allows for the production of hydrochar as a potential fertilizer material that requires further processing. Adjusting HTC conditions enhanced P-recovery in the hydrochar, while retrieving higher nitrate concentrations in the liquid product. Optimizing HTC for the production of qualified hydrochars requires further treatment of Cr content, studying the availability of P in the products and enhancing the hydrochar yield for economic feasibility.

Plasma emission monitored via optical emission spectroscopy during the Cs conditioning at SPIDER

The SPIDER test facility is the full-size ITER neutral beam injector (NBI) ion source, required to provide 355 A/m2 extracted negative ion current density in hydrogen (285 A/m2 in deuterium) with an electron-to-ion ratio lower than 0.5 (one in deuterium). The negative ion source is attached to a three-grids extraction and acceleration system. The operational conditions for the cases presented in this work involve short pulses (up to about 30 s length) repeated every five to six minutes. The duty cycle can be adjusted. In order to fulfil the requirement on the extracted negative ion current with reduced amount of co-extracted electrons, the evaporation of caesium into the ion source through Cs ovens (three in SPIDER) and the optimisation of Cs conditioning techniques are mandatory. At SPIDER, the plasma is monitored via optical emission spectroscopy techniques measuring the plasma emission in a line-of-sight (LOS) integrated manner in several positions inside the ion source. In particular, close to the extraction region, two sets (centred at 5 mm and at 35 mm distance from the plasma grid) of four horizontal LOSs are used to retrieve the vertical profile of the plasma emission. During the Cs conditioning campaign performed at SPIDER, although the extraction capabilities were reduced due to technical problems, the RF power coupled to the plasma reached 400 kW with all four RF generators working simultaneously. The negative ions produced by surface emission affects the plasma radiation, and the ion source performances in terms of extracted negative ions and co-extracted electrons. The aim of this work is to study the evolution of the plasma emission over the initial phase of the Cs conditioning campaign. The effect of Cs conditioning on the extracted negative ions and electrons is also presented and discussed.

Application of a hyperspectral camera for in situ plasma-material interaction studies at the linear plasma device PSI-2.

A hyperspectral camera (HSC-type Specim IQ) has been applied at the linear plasma device PSI-2 under steady-state conditions. The camera has the capacity of hyperspectral imaging (HSI) with the dimension of a data array 512 × 512 × 204 (x, y, λ) covering the spectral span from 400 to 1000nm with moderate average spectral resolution (FWHM ∼7nm). After radiometric calibration and background/continuum emission subtraction, two main applications of the camera, (i) plasma diagnostics in helium (He) plasmas and (ii) plasma-material interaction studies with tungsten (W) targets in neon (Ne) plasmas, have been carried out. The measurements were complemented by a movable Langmuir double probe system (LP) measuring electron temperature (Te) and electron density (ne) in radial direction r and a fiber-coupled cross-dispersion spectrometer with high spectral resolution (Spectrelle) recording neutral He, W, and Ne emission lines over the full plasma column. (i) Two-dimensional (2D) imaging of Te and ne radial profiles in axial direction z of the He plasma column were for the first time obtained by the regression analysis of Te and ne (from LP) and six He I line ratios (from HSC). The spatially resolved plasma parameters covered in these studies range between Te ∼ 0.8-13.4eV and ne ∼ 0.2 × 1018-3.9 × 1018m-3 and permit a reconstruction of the plasma conditions in PSI-2 in 2D without LP perturbation. (ii) W sputtering was studied in situ in Ne plasmas exposing W target samples (negatively biased at 100V) under perpendicular Ne plasma impact. Simultaneously, the 2D distributions of W (W I line at 429.5nm) in front of the target and the 2D Ne plasma distribution (Ne I line at 703.2nm) were recorded with complete spectral separation as confirmed by the Spectrelle spectrometer. This permits the simultaneous measurement of the neutral W penetration and its angular distribution induced in the sputtering process and of the impinging plasma distribution. The HSI technique offers, despite a few technical drawbacks, such as the moderate spectral resolution and poor time resolution, a new possibility to distinguish multiple emission lines from plasma and impurities and complements the portfolio of existing Optical Emission Spectroscopy techniques, providing a good compromise regarding spectral, spatial, and temporal resolution.

Changing pattern of N2 dissociation in N2–Ar RF plasma during E–H mode transition

The behaviour of nitrogen plasma mixed with varying proportions of argon (10%–80%) is investigated under different RF discharge conditions. It is observed that at a relatively low RF power of 200 W (E-mode) the dissociation fraction (DF) of nitrogen increases with the growing concentration of argon, whereas the opposite happens for a higher RF power of 1000 W (H-mode), when the DF rapidly falls from a high value as the argon percentage starts to increase. This rising trend of DF closely follows the argon metastable fraction (MF) in the E-mode, and for the H-mode it is not followed until the argon percentage crosses the 20% mark. The electron density, temperature and electron energy probability function (EEPF) are obtained using a RF compensated Langmuir probe and to evaluate the vibrational and rotational temperatures, DF, MF etc, a separate optical emission spectroscopy technique is incorporated. At 5 × 10−3 mbar of working pressure and 10% argon content the EEPF profile reveals that the plasma changes from non-Maxwellian to Maxwellian as the RF power jumps from 200 W to 1000 W, and for a fixed RF power the high energy tail tends to move upwards with the gradual increment of argon. These observations are reverified theoretically by considering electron–electron collision frequency and electron bounce frequency as a function of electron temperature. Overall, all the major experimental phenomena in this study are explained in terms of EEPF profile, electron–electron collision effect, electron and gas temperature, electron density and argon metastable population.

Physical properties of the swept arc channel in the context of lightning strikes to aircraft

During an in-flight lightning strike, the relative motion between the arc channel and the aircraft causes a sweeping of the attachment point on the aircraft skin. To predict the behaviour of the arc channel and therefore the potential locations for further restrikes, this study aims at investigating the phenomenon with an innovative method for producing sweeping arcs based on a stationary arc and an electromagnetic launcher propelling aeronautical samples. This article focuses on characterisation of the arc channel, aiming at establishing the evolution of its physical properties during swept-stroke for various experimental conditions. Firstly, the experimental coupling of the lightning generator with the electromagnetic launcher and with a wind tunnel is described with a discussion on the representativeness of the experiment. Then, high-speed cameras and voltage and current probes are used to measure the electrical and geometrical behaviour of the electric arc channel during a swept-stroke. The shape, the length, the voltage and the power evolution of the arc channel are evaluated for different input parameters such as speed, polarity, arc current and sample length. Furthermore, the influence of these parameters on the temperature of the arc channel is studied, resorting to an optical emission spectroscopy technique. The results are presented and discussed with the objective of providing a physical insight into arc elongation phenomenology during a swept-stroke.

Spectroscopic Diagnosis of Cobalt Plasma Produced by OES Technique and Influence of Applied Voltage on Plasma Parameters

In this work, plasma system that operates at vacuum was designed and built using a sheet of cobalt metal for the purpose of diagnosing plasma and measuring its parameters, as it is very important to know the processes that accompany plasma generation and are closely related to them, including the electron density in the plasma and its temperature. The spectroscopic diagnosis was done by optical emission spectroscopy (OES) which relies on the calculation of the optical radiation emitted by the plasma to describe plasma parameters in the chemical, molecular, and ionic radiator's near environment, and applied to cobalt metal at vacuum D.C high voltage power supply. The results showed the rise of spectral lines intensity with increasing the applied voltage. The maximum peak of argon gas (ArI) was at the wavelength (811.5311) nm and the maximum peak of cobalt metal (CoI) was at the wavelength of 242 nm, where argon gas was used at the fifth flow per minute with variable voltages (13-21) kV. The results also achieved that the values ​​of electron temperature rises from (0.2708-0.6649) eV with the increase in the applied voltage, as well as the electron density from (8.108-13.851)x1017cm-3 with the stability of the argon gas flow rate at 5 l/min. The length of the plasma was measured at different gas flow rates (1-5) l/min and different applied voltages (13-21) kV that were used in this diagnosis.

Spectral Analysis of the Effects of Variation in Electrodes' Area for Dielectric Barrier Discharge Actuator

In this work, one configuration was used to study the electrical discharge resulting from the dielectric barrier. This configuration consists of a sheet of epoxy/Al composite with dimensions of 75 mm in length, 25 mm in width, and 3 mm in thickness. This panel is located at the center of the electrodes, so that the distance between each of the electrodes and the plate is 2 mm and plasma is generated at these distances. The relationship between voltage and current with changing the frequency of the equipment as well as changing the area of ​​exposure to the upper electrode or changing its length has been studied. The length of the top electrode varies at 0, 10, 20, 30, and 40 mm from the center of the electrodes producing exposure areas of 1875, 1625, 1375, 1125, 875, and 625 mm2, respectively. Two frequencies of 8 and 9 kHz were applied in this work. The results showed that the discharge current increases linearly with the applied input voltage and with the decrease of the exposure of the upper electrode. Then, the current increases with the stability of the voltage in varying proportions depending on the exposure area and frequency. The plasma generated from this modulation was diagnosed with the exposure area and the fitted frequency. Electron temperature and electron density are calculated using the optical emission spectroscopy technique by Boltzmann and Lorenz, respectively. It can be seen that the temperature, electron density, and plasma frequency increase with the decrease of the exposure area, while the Debye length shows the opposite behavior and this is clear in this formation and high effectiveness at Diagnosis and Reason This formation will be adopted in the surface treatment of the aluminum epoxy compound.

A Spectroscopic Evaluation of the Generation Process of Semiconductor Nanoparticles (ZnO) by DC Arc Plasma

The fabrication of ZnO nanoparticles (NPs) was monitored and studied in situ by controlling the plasma parameters of the direct current (DC) arc plasma system, such as the current density and chamber pressure. The optical emission signature of nitrogen was spectroscopically studied using optical emission spectroscopy (OES) techniques, and it showed a dependency on the nitrogen concentration in the ZnO nanoparticles in relation to the output of the ZnO NPs-based homojunction light-emitting diodes (LEDs). The synthesized NPs had a good crystalline quality and hexagonal wurtzite structure, and they were characterized by X-ray diffraction (XRD) techniques and scanning electron microscope (SEM). The photoluminescence properties of the ZnO NPs and the optical and electrical parameters of the LEDs were also analyzed and correlated. The results indicate that the nitrogen dopants act as acceptors in the ZnO NPs and are favored in low plasma temperatures during fabrication. We anticipate that the results can provide an effective way to realize reliable nitrogen-doped p-type ZnO and tremendously encourage the development of low-dimensional ZnO homojunction LEDs.