Charging stations and electric vehicle (EV) charging networks signify a significant advancement in technology as a frontier application of the Social Internet of Things (SIoT), presenting both challenges and opportunities for current 6G wireless networks. One primary challenge in this integration is limited wireless network resources, particularly when serving a large number of users within distributed EV charging networks in the SIoT. Factors such as congestion during EV travel, varying EV user preferences, and uncertainties in decision-making regarding charging station resources significantly impact system operation and network resource allocation. To address these challenges, this paper develops a novel framework harnessing the potential of emerging technologies, specifically reconfigurable intelligent surfaces (RISs) and causal-structure-enhanced asynchronous advantage actor–critic (A3C) reinforcement learning techniques. This framework aims to optimize resource allocation, thereby enhancing communication support within EV charging networks. Through the integration of RIS technology, which enables control over electromagnetic waves, and the application of causal reinforcement learning algorithms, the framework dynamically adjusts resource allocation strategies to accommodate evolving conditions in EV charging networks. An essential aspect of this framework is its ability to simultaneously meet real-world social requirements, such as ensuring efficient utilization of network resources. Numerical simulation results validate the effectiveness and adaptability of this approach in improving wireless network efficiency and enhancing user experience within the SIoT context. Through these simulations, it becomes evident that the developed framework offers promising solutions to the challenges posed by integrating the SIoT with EV charging networks.