The recent commitment towards a net-zero target by 2050 will require considerable improvement to the UK’s building stock. Accounting for over 10% of the services energy consumption of the United Kingdom, the education sector will play an important role. This study aims to improve the understanding of English primary and secondary schools, using national on-site survey data with several large-scale disaggregate data sources. Property Data Survey Programme (PDSP) data on 18,970 schools collected between 2012 and 2014, Display Energy Certificate (DEC) and school census data from the same period were linked and processed to form a unified schools dataset. Statistical analyses were undertaken on 10,392 schools, with a focus on energy performance, and the relationship to several building and system characteristics. The analyses may point to the possibility of assessing operational energy use of schools in a more disaggregate manner. New datasets with detailed and accurate disaggregate information on characteristics of buildings, such as those used in this study, provide opportunities to develop more robust models of the building stock. Such data would provide an opportunity to identify pathways for reducing carbon emissions effectively and provide lessons for other organisations seeking to achieve significant reductions for achieving climate change goals. Practical Application: Outputs from this study are expected to benefit researchers in various organisations to establish a basis for typical buildings and their performance, facilities managers to assess the operational energy efficiency of school buildings, and relevant public bodies to make informed decisions on improving energy efficiency of the school stock.