Open Surface Research Articles

City-Level Solar Photovoltaic Potential Using Integrated Surface Models and Himawari Satellite in Jakarta and Bandung Indonesia

This research focuses on the detailed modeling of solar PV (Photovoltaic) in urban areas by integrating a detailed reconstructed digital surface model (DSM) and high-temporal-resolution satellite data. This study introduces enhancing method for open digital surface model from medium to high resolution to capture building height details, and integrating the new DSM with high-temporal satellite data to get detail spatial and temporal resolution of solar PV. The DSM reconstruction, building heights are determined using a combination of multi-data and multi-machine learning regression approaches to achieve building height results closely aligned with actual height. In Jakarta, building heights ranged from 5 to 223 m, while in Bandung, they ranged from around 3.58 to 254 m. The combination scenarios had a mean absolute error of 1.584 m, and the coefficient of determination (R2) was 0.754. The integration of new DSM detail data and high-temporal data employs an approach to integrate surface solar irradiance by shadow, sky view factor, and reflectance irradiance from surrounding object. The annual average energy potential in Jakarta and Bandung ranges from 260 to 420 W/Wp. Areas near tall buildings exhibit lower potential because of the shadow effect and sky view factor. This research hopefully can contribute to urban planning for carbon neutrality by providing a more detailed understanding of solar PV potential in urban areas in the absence of detailed data limitations.

Study on bubble behaviors and heat transfer at shallow liquid boiling over open rectangular microchannels

The heat transfer performance of shallow liquid boiling differs from that of deep liquid boiling owing to distinct bubble venting mechanisms. Since the liquid level is of the same order of magnitude as the bubble departure diameter, bubble detachment is restricted by the surface tension of the free interface, which causes an untimely liquid reflux toward the nucleate site. Consequently, shallow liquid boiling has a high heat transfer coefficient (HTC) at a liquid height below the critical liquid level but at the expense of limited critical heat flux (CHF). This study aims to improve the CHF of shallow liquid boiling by utilizing open rectangular microchannels surface (ORMS), which can provide separated vapor–liquid pathways to facilitate the liquid return. The boiling heat transfer curves and bubble behavior of distilled water at shallow liquid levels are investigated using the ORMS. A critical liquid level of 5 mm was achieved with heat fluxes of approximately 15 W/cm2, 25 W/cm2, and 35 W/cm2 over ORMS. Compared to a plain copper surface (PCS), ORMS improves the upper limit of the heat flux for the critical liquid level. A simplified and efficient analytical model with two-sphere bubble is established to predict the critical liquid level for the ORMS by considering the dynamic and static force balance. The critical liquid level is approximately twice the bubble departure diameter, which may aid in designing the liquid filling rates for phase-change heat sinks for HTC improvement.

Microplastic pollution in the North-east Atlantic Ocean surface water: How the sampling approach influences the extent of the issue

A lack of standardization in monitoring protocols has hindered the accurate evaluation of microplastic (MP) pollution in the open sea and its potential impacts. As sampling techniques significantly influence the amounts of MPs contained in the sample, the aim of this study was to compare two sampling methods: Manta trawl (size selective approach) and grab sampling (volume selective approach). Both approaches were applied in the open sea surface waters of the North-east Atlantic Ocean. Onshore sample processing was carried out using the innovative tape lifting technique, which affords a series of advantages, including prevention of airborne contamination during analysis, without compromising integrity of the results. The results obtained indicated an MP concentration over four orders of magnitude higher using grab sampling compared to the Manta net approach (mean values equal to 0.24 and 4050 items/m3, respectively). Consequently, the sole quantification of MPs using results obtained with the Manta trawl resulted in a marked underestimation of abundance. Nevertheless, the grab sampling technique is intricately linked to a risk of collecting non-representative water volumes, consequently leading to an overestimation of MPs abundance and a significant inter-sample variability. Moreover, the latter method is unsuitable for use in sampling larger MPs or in areas with low concentrations of MP pollution. The optimal sampling method therefore is dependent on the specific objectives of the study, often resulting in a combination of size and volume selective methods. The results of this study have the potential to contribute to the standardization of monitoring protocols for microplastics, both during the sampling phase and sample processing.

Theoretical study of the effects of surface Cu coordination environment on CO2 hydrogenation to CH3OH

The coordination environment of Cu (the coordination number and arrangement of surface atoms) plays an important role in CO2 hydrogenation to CH3OH. Compared with the extensive studies of the effects of coordination number, the comprehensive effects of coordination number and arrangement of surface atoms were seldom explored in literature. To unravel the effects of surface Cu coordination environment on CO2 hydrogenation to CH3OH, the adsorption and reaction behaviors of H2 and CO2 on Cu(111), (100), (110) and (211) with different coordination numbers and arrangement of surface Cu were systematically calculated by density functional theory (DFT) and kinetic Monte Carlo (kMC) simulation. It was found that the adsorption energies of intermediates in CO2 hydrogenation on Cu surfaces increase with the decrease of coordination number. When the Cu coordination numbers are similar, the charge density on the open surface derived from the different atom arrangement becomes larger and leads to stronger interaction with intermediates than that on the compact one. DFT calculation and kMC simulation indicate that methanol formation pathway follows CO2*→HCOO*→HCOOH*→H2COOH*→H2CO*→CH3O*→CH3OH* on four Cu facets; CO formation is via CO2 direct dissociation on Cu(111), (100) and (110) but COOH* dissociation on (211). The low-coordinated surface Cu with more openness on Cu(211) is the highly active site for CO2 hydrogenation to CH3OH with high turnover of frequency (3.71 × 10−4 s−1) and high selectivity (87.17 %) at 600 K, PCO2 = 7.5 atm and PH2 = 22.5 atm, which is much higher than those on Cu(111), (100) and (110). This work unravels the effects of coordination environment on CO2 hydrogenation at the molecular level and provides an important insight into the design and development of catalysts with high performance in CO2 hydrogenation to CH3OH.

Flexible liquid-diode microtubes from multimodal microfluidics

Directional transport of liquids is of great importance in energy saving, chemical/biomedical engineering, and microfluidics applications. Despite considerable progress in engineering different open surfaces to achieve liquid manipulation, the realization of diode-like liquid transport in enclosed spaces is still challenging. Here, a flexible diode microtube is presented for directional liquid transport within confined spaces using pulsed microfluidics. The microtubes exhibit sophisticated microstructures on the inner wall, replicated from a precisely controlled flow configuration in the microfluidic channel. Under the effect of asymmetric pinning and unbalanced Laplace pressure, such microtubes enable directional liquid transport in closed channels. More importantly, by integrating in situ flow lithography with the microfluidic system, segmented liquid diodes are fabricated as assembly units for the construction of fluidic-electronic circuits that perform logic operations. These results demonstrate the capacity of the present liquid-diode microtubes for flexible, directional, and programmable liquid transport. We believe that it can open an avenue for designing advanced fluidic circuit-based devices toward versatile practical applications.

A PRIORI ASSESSMENT OF THE EFFECTIVENESS OF OCCUPATIONAL SAFETY MANAGEMENT SOLUTIONS

The article analyzes the problems of effective management of labor safety at enterprises. It is noted that the search for methods of justifying management decisions in this area remains relevant from the point of view of theoretical consideration of existing developments and the development of practical recommendations for their implementation at enterprises. Despite the presence of a large number of different approaches to improving management efficiency, based on the theory of decision-making and expert methods, taking into account the cost of implementing this or that variant of the decision, in the vast majority of cases, remains overlooked. A method of conducting an a priori assessment of the effectiveness of decisions is proposed, which involves the formation of a set of alternatives of management decisions, their subsequent expert assessment, as well as the assessment of the cost of their implementation. For a reasoned choice of alternatives, it is suggested to use the indicator of their effectiveness, which is calculated as the ratio of expert assessment to the conditional cost of implementing the alternatives. An example of the application of the developed methodology for one of the enterprises of the mining and metallurgical complex for the justification of measures to reduce the risk of a traumatic event "Contact with an open flame, hot substance or surface" is considered. An alternative is recommended for implementation, which involves increasing the level of technical control of dangerous production factors. For the rational implementation of the proposed methodology at the enterprise, it is necessary to ensure the functioning of the system of accounting and analysis of production factors for the possibility of using these data in the formation of problems that need to be solved. In addition, the implementation of the methodology involves the possibility of involving qualified experts for an objective a priori evaluation of alternatives

Stimuli-Responsive Ion Transport Regulation in Nanochannels by Adhesion-Induced Functionalization of Macroscopic Outer Surface.

Responsive regulation of ion transport through nanochannels is crucial in the design of smart nanofluidic devices for sequencing, sensing, and water-energy nexus. Functionalization of the inner wall of the nanochannel enhances interaction with ions and fluid but restricts versatile chemical approaches and accurate characterizations of fluidic interfaces. Herein, we reveal a responsive regulating mechanism of ion transport through nanochannels by polydopamine (PDA)-induced functionalization on the macroscopic outer surface of nanochannels. Responsive molecules were codeposited with PDA on the outer surface of nanochannels and formed a valve of nanometer thickness to manually manipulate ion transport by changing its gap spacing, surface charge, and wettability under external stimulus. The response ratio can be up to 100-fold by maximizing the proportion of responsive molecules on the outer surface. Laminating the codepositions of different responsive molecules with PDA on the channel's outer surface produces multiple responses. A nearly universal adhesion of PDA with responsive molecules on the open outer surface induces nanochannels responsive to different external stimuli with variable response ratios and arbitrary combinations. The results challenge the primary role of functionalization on the nanoconfined interface of nanofluidics and open opportunities for developing new-style nanofluidic devices through the functionalization of macroscopic interface.

Cathode|Electrolyte Interface Engineering by a Hydrogel Polymer Electrolyte for a 3D Porous High-Voltage Cathode Material in a Quasi-Solid-State Zinc Metal Battery by In Situ Polymerization.

This work highlights the development of a superior cathode|electrolyte interface for the quasi solid-state rechargeable zinc metal battery (QSS-RZMB) by a novel hydrogel polymer electrolyte using an ultraviolet (UV) light-assisted in situ polymerization strategy. By integrating the cathode with a thin layer of the hydrogel polymer electrolyte, this technique produces an integrated interface that ensures quick Zn2+ ion conduction. The coexistence of nanowires for direct electron routes and the enhanced electrolyte ion infiltration and diffusion by the 3D porous flower structure with a wide open surface of the Zn-MnO electrode complements the interface formation during the in situ polymerization process. The QSS-RZMB configured with an integrated cathode (i-Zn-MnO) and the hydrogel polymer electrolyte (PHPZ-30) as the separator yields a comparable specific energy density of 214.14Whkg-1 with that of its liquid counterpart (240.38Whkg-1, 0.5MZn(CF3SO3)2 aqueous electrolyte). Other noteworthy features of the presented QSS-RZMB system include its superior cycle life of over 1000 charge-discharge cycles and 85% capacity retention with 99% coulombic efficiency at the current density of 1.0Ag-1, compared to only 60% capacity retention over 500 charge-discharge cycles displayed by the liquid-state system under the same operating conditions.

Novel 3D textile structures and geometries for electrofluidics.

The integration of microfluidics with electric field control, commonly referred to as electrofluidics, has led to new opportunities for biomedical analysis. The requirement for closed microcapillary channels in microfluidics, typically formed via complex microlithographic fabrication approaches, limits the direct accessibility to the separation processes during conventional electrofluidic devices. Textile structures provide an alternative and low-cost approach to overcome these limitations via providing open and surface-accessible capillary channels. Herein, we investigate the potential of different 3D textile structures for electrofluidics. In this study, 12 polyester yarns were braided around nylon monofilament cores of different diameters to produce functional 3D core-shell textile structures. Capillary electrophoresis performances of these 3D core-shell textile structures both before and after removing the nylon core were evaluated in terms of mobility and bandwidth of a fluorescence marker compound. It was shown that the fibre arrangement and density govern the inherent capillary formation within these textile structures which also impacts upon the solute analyte mobility and separation bandwidth during electrophoretic studies. Core-shell textile structures with a 0.47mm nylon core exhibited the highest fluorescein mobility and presented a narrower separation bandwidth. This optimal textile structure was readily converted to different geometries via a simple heat-setting of the central nylon core. This approach can be used to fabricate an array of miniaturized devices that possess many of the basic functionalities required in electrofluidics while maintaining open surface access that is otherwise impractical in classical approaches.

Diffraction of light by a slit in anisotropic media with closed and open wave vector surface

Fraunhofer diffraction of an electromagnetic wave by a slit on an opaque screen located between vacuum and an anisotropic medium with closed and open wave vectors surface is considered. A formula for diffraction in a material medium is obtained, including the case of diffraction into a uniaxial anisotropic medium in the absence of absorption, and the formation of diffraction minima and maxima is studied.

Protective Properties of Calcareous Deposit Layer for Cathodically Polarized AH36 Steel in Natural Seawater

A calcareous deposit is a by-product of the cathodic polarization in seawater environments. This study presents the results of evaluating the anticorrosion and anti-macro-biofouling effectiveness of a calcareous deposit layer on the surface of the cathodically polarized AH36 structural steel in tropical seawater. The polarization is induced with initial current densities at which the calcareous deposit layer formed with both aragonite and brucite for 12 months continuously. The protective properties of the layer were compared with those of the passive layer from corrosion products under the same environmental conditions. The macro-biofouling in the tropical seawater is observed in the closed and open surfaces of the steel. The comparison of the anticorrosion property shows that, to some degree, the calcareous deposit layer contributes to surface passivation, as in the case of the corrosion product layer. In addition, the composition of the brucite and aragonite in the calcareous layer in the study plays a role as a macro-biofouling growth-limiting factor.

Global WaterPack - The development of global surface water over the past 20 years at daily temporal resolution

Open surface water across the globe is essential for many life forms and is an important source for human settlements, agriculture, and industry. The presence and variation in time and space is influenced by different natural conditions (e.g. climate, topography, geology) and human use (e.g. irrigation, flood protection). The information on the spatial and temporal distribution of open surface water is fundamental for many disciplines and is also required as an essential parameter for hydrological and climatological modelling. Here, we present a dataset derived from satellite earth observation, which is based on more than 6.3 million single MODIS products with a volume of approx. 300 TB. The resulting dataset reflects the situation of open surface water on a global scale for each day over the time period from 2003 to 2022 at a spatial resolution of 250 m. The dataset enables the analysis of the development of lake and reservoir surface areas, freezing cycles, and inundation areas.

WO3-x as an activation medium to prompt overall water splitting of NiFe-based electrocatalyst

The efficient oxygen evolution reaction (OER) is crucial for various electrochemical processes, especially for overall water splitting (OWS). In this study, we focus on the utilization of WO3-x as an activation medium to enhance the OER performance of NiFe-based electrocatalysts. Firstly, we synthesize WO3-x nanowires supported on nickel foam (NF) and then incorporate NiFe on WO3-x nanowires by a simple hydrothermal method. The WO3-x self-supported NiFe (Oxy)hydroxide (denoted as NiFe-W-O/NF) shows a three-dimensional stereostructure composed of ultrathin nanosheets (∼ 4.0 nm). This unique structure provides a large open surface for fuller diffusion of the electrolyte while exposing more active sites. The electronic interaction of tri-centers of NiFeW accelerates the surface reconstruction process of γ-NiOOH and FeOOH, which are converted into the main active species in a short time. The electrochemical measurements confirm that the NiFe-W-O/NF has low OER overpotentials (233 mV at 10 mA cm−2, 298 mV at 100 mA cm−2) and excellent stability (100 h in total) in 1 M KOH electrolyte. In addition, the NiFe-W-O/NF || NiFe-W-O/NF battery also exhibits a low cell voltage (1.52 V at 10 mA cm−2) with a stable lifetime (50 h) under alkaline conditions. These results highlight the great potential of NiFe-W-O/NF for practical applications.

Landscape evolution and hydrology at the Late Pleistocene archaeological site of Narabeb in the Namib Sand Sea, Namibia

The Namib Sand Sea (NSS) in Namibia is known to preserve a wide variety of Pleistocene-age archaeological sites. However, few Middle Stone Age (MSA) sites in this region have been systematically investigated and basic questions around chronology and technological organization remain open. Here we examine Narabeb, an open air MSA surface site exposed in an interdune pan, ∼30 km into the northern NSS. Narabeb was first documented in the 1970s, and then re-examined in 2021 and 2022 by members of this team. Lithic technological analysis combined with a geomorphological description of the site, palaeoenvironmental interpretation of fine-grain water-lain sediments, and luminescence ages from northern and southern locations on the Narabeb pan provide some of the first understanding of human-environmental interactions and estimates of chronology from the later-Middle and Late Pleistocene in the NSS. In addition, we apply a quantitative approach to aeolian linear dune accumulation and extension to explore possible scenarios for landscape development at this site, in order to better understand the former water course(s) affecting the area. The new chronology suggests this site contained standing water at, or just after, the MIS 7/6 transition, and again at, or just after, the end of MIS 6 into early MIS 5. The timing of greater phases of water availability have some overlap with the speleothem growth record at Rössing Cave, situated ∼90 km north of the NSS (and ∼135 km north of Narabeb). Our results provide the foundation for larger, regional-scale analyses of early human adaptive strategies in this unique environment within Southern Africa.

Healing Process Affected by Morphology of PCL/Epoxy Blends

In this study, a blend of epoxy and polycaprolactone (PCL) was prepared to investigate its ‎properties. Different weight percentages of thermoplastic PCL (0.25, 0.5, 1, 2 wt%) were ‎combined with epoxy coatings. The final morphology revealed PCL scattered as spherical ‎particles within the epoxy phase, which was functioning as a continuous matrix. The coating ‎showed toughness and rigidity when it had fully cured. The PCL phase had a special behavior ‎when heated, called "bleeding," in which it filled any open surfaces of its own volition. By ‎using molten PCL to fill in cracks, this property can be used for self-healing applications. The ‎self-healing efficacy of blends with different PCL contents was assessed. The self-healing ‎efficacy of the various mixes was determined by dividing the width of the self-healed crack by ‎the width of the original crack. The results showed that the highest thermal-mending efficiencies, ‎reaching 100%, were achieved with a PCL/epoxy blend containing co-continuous phases, ‎specifically at a 1 wt.% PCL content. Fourier-transform infrared (FTIR) analysis indicated that ‎there was physical interaction between the epoxy and PCL phases, but no chemical bonding ‎occurred between them.‎

Correlation of postural stability with pain, disability and quality of life among patients with sacroiliac joint dysfunction- A cross-sectional study

Context-Sacroiliac (SI) joint dysfunction accounts for altered postural stability which can cause a continuously intense pain level and range of disabilities. AimTo investigate the correlation of postural stability with pain, disability & QOL among sufferers of sacroiliac joint dysfunction. SettingThis cross-sectional research was undertaken at Rehabilitation Centre, Jamia Hamdard University. MethodA total of fifty participants were recruited using sample of convenience according to inclusion and exclusion criteria. After obtaining informed consent, three pain provocative tests and one motion palpation test were used to determine sacroiliac joint dysfunction. Humac balance master system (CSMi USB powered, Stoughton, USA), Visual analogue scale (VAS), modified Oswestry Disability Index (ODI) & WHO QOL-BREF (US version) were used to assess postural stability, pain, disability & Quality of life (QOL) respectively. Data analysis was done for correlation by SPSS version 24.0. ResultStrong positive correlations were found between reaction time, VAS (r = 0.791) and modified ODI score (r = 0.576) and weak positive correlations between eyes closed solid surface (ECSS) component of modified clinical test of sensory interaction & balance with VAS (r = 0.333) and with modified ODI score (r = 0.304) and eyes open foam surface (EOFS) component with environmental component of QOL (r = 0.287). There were negative correlations between reaction time, physical health (r = −0.413), psychological health (r = −0.375), social relations (r = −0.305), and environment (r = −0.379) parameters of QOL. ConclusionAccording to the findings of the study, there were positive correlations of reaction time with pain and disability and negative correlations with QOL. Awareness of clinicians regarding the altered postural stability can help in improvising the assessment and treatment protocols for patients of SI dysfunction.

RESEARCH AND DEVELOPMENT OF HEAT TECHNOLOGY OF PREBIOTIC COMPLEX-FORMING POWDER PRODUCTION

The process of dehydration of the prebiotic squash-apple mixture is investigated, taking into account the properties of the material and drying modes. Prebiotic raw materials are maximally represented by dietary fibers, which include pectin substances, the content of which in raw materials is from 6 to 12%. Optimal modes of grinding and separation into different fractions of dry prebiotic materials for obtaining functional powders were determined. The complexing property of prebiotic mixtures is determined, which is 15-20% higher than pure pectin, due to an increase in the open surface of powders and the nativity of pectin substances.

Complete CMC-1 surfaces in hyperbolic space with arbitrary complex structure

We prove that every open Riemann surface [Formula: see text] is the complex structure of a complete surface of constant mean curvature [Formula: see text] ([Formula: see text]) in the three-dimensional hyperbolic space [Formula: see text]. We go further and establish a jet interpolation theorem for complete conformal [Formula: see text] immersions [Formula: see text]. As a consequence, we show the existence of complete densely immersed [Formula: see text] surfaces in [Formula: see text] with arbitrary complex structure. We obtain these results as application of a uniform approximation theorem with jet interpolation for holomorphic null curves in [Formula: see text] which is also established in this paper.

Rewritable printing of ionic liquid nanofilm utilizing focused ion beam induced film wetting

Manipulating liquid flow over open solid substrate at nanoscale is important for printing, sensing, and energy devices. The predominant methods of liquid maneuvering usually involve complicated surface fabrications, while recent attempts employing external stimuli face difficulties in attaining nanoscale flow control. Here we report a largely unexplored ion beam induced film wetting (IBFW) technology for open surface nanofluidics. Local electrostatic forces, which are generated by the unique charging effect of Helium focused ion beam (HFIB), induce precursor film of ionic liquid and the disjoining pressure propels and stabilizes the nanofilm with desired patterns. The IBFW technique eliminates the complicated surface fabrication procedures to achieve nanoscale flow in a controllable and rewritable manner. By combining with electrochemical deposition, various solid materials with desired patterns can be produced.

Urban heat island patterns in garden cities: Putrajaya as a case study

The garden-city model, characterised by sprawling urban expansion and extensive open spaces, features green and water surfaces alongside substantial road networks, large parking lots and unshaded lands. This diverse landscape contributes to uneven air temperature distribution within the city. Our study investigated urban heat island (UHI) patterns in various urban environments within Putrajaya, focusing on rural, business, residential and near-water areas. Atmospheric data were collected over a year. Putrajaya exhibits two distinct UHI patterns: cool-day-hot-night in residential zones and hot-noon-temperate-elsewhere in impermeable areas. Business areas display alternating patterns based on seasonal climatic conditions and anthropogenic factors. The efficacy of artificial water bodies as a UHI countermeasure in garden cities depends on the size of the water body and the nature of the surrounding land cover. Shaded and green areas exhibit UHI intensities limited to 3°C, while impermeable areas, regardless of proximity to water surfaces, experience UHI up to 6°C. Overall, the garden-city model tends to restrict UHI variations within −1 to 3°C compared to −2 to 4°C in nearby Kuala Lumpur.