Olivine Melilitite Research Articles

Two Distinct Metasomatized Mantle Sources Produced Two Groups of Alkaline SiO2-Undersaturated Rocks in the Southern Central European Volcanic Province

Abstract Upper Cretaceous–Miocene alkaline SiO2-undersaturated volcanic rocks in the southern Central European Volcanic Province (CEVP) comprise two distinct rock series: (i) Upper Cretaceous–Eocene (~73–47 Ma) olivine nephelinites, basanitic nephelinites, and nepheline basanites have moderate to high MgO (8–16 wt. %), CaO, Ni, Co, Cr, Nb, and Ba, coupled with low F and SiO2 concentrations. These rocks contain abundant clinopyroxene and variable amounts of olivine macrocrysts as well as nepheline, K-dominated F-poor mica, and hydroxyapatite. Evolved and less common apatite-rich (phonolitic) haüynites/noseanites and haüyne nephelinites (~68–62 Ma) represent differentiated counterparts within this older group, showing higher alkali, Al2O3, P2O5, Nb, Zn, REE, and SO3 concentrations at low MgO (4–6 wt. %), CaO, Ni, Co, and Cr contents. (ii) Oligocene–Miocene (~27–9 Ma) olivine melilitites and melilite-bearing olivine nephelinites are characterized by even higher MgO (10–22 wt. %), CaO, Ni, Co, Cr, Nb, Ba, and high F contents at lower SiO2 concentrations, as reflected by the presence of abundant olivine macrocrysts, melilite, perovskite, Cr-rich spinel, F- and Ba-rich mica, and fluorapatite in addition to clinopyroxene and nepheline. Distinct mineral assemblages, crystallization trends, and various xenocrysts indicate different melt sources, a varying extent of enrichment, retention, and loss of volatiles (including timing of H2O and CO2 saturation), and limited wall rock interaction for the two rock groups. Partly resorbed, Fo-depleted olivine cores in the younger rocks and green-core pyroxenes in the older ones suggest early magma mixing. The nephelinitic–basanitic magmas derived from up to 6% partial melting of amphibole-bearing garnet/spinel lherzolite at or just above the lithosphere–asthenosphere boundary. This source was metasomatized involving hydrous melts or fluids. On the other hand, the melilite-bearing rocks probably originated in the upper asthenosphere by less than 3.5% partial melting of amphibole ± phlogopite-bearing garnet wehrlite, previously generated by subduction-related metasomatism with high CaO/MgO and CO2/(CO2 + H2O) ratios. Infiltration and storage of the metasomatic agents occurred in the former lower lithosphere, following continuous recycling of oceanic crust, comprising the release of Ca, CO2, H2O, further volatiles, and incompatible elements. Both volcanic episodes coincide with topographic uplift, erosion, rifting, and reactivation of lithosphere-scale faults, probably related to phases of strong mechanical coupling between Alpine orogen and European foreland. The first period overlapped with an era of prolonged N-directed intraplate compressional stress due to the Adriatic-Eurasian collision, provoking large-scale deformation, isostatic compensation, erosion, and consequent lithosphere thinning in the future CEVP. The second period is associated with the Oligocene–Miocene main stage of the European Cenozoic Rift System. Onset of volcanism was accompanied by a change in deformation in the Upper Rhine Graben from (W)NW extension to (E)NE extension and transtension by a complex interplay of evasive movements responding to shortening in Alps and Jura. Magma compositions, barely magmatic graben structures, volcanic activity outside rifts, and extensive exhumation suggest that in response to rifting, passive asthenospheric doming also contributed to magmatism by causing strong lithosphere–asthenosphere interaction and providing heat.

Bimodal volcanism in the Hegau region (SW Germany): Differentiation of primitive melilititic to nephelinitic rocks produces evolved nosean phonolites

Peculiar bimodal volcanism in the Hegau region (SW Germany) comprises two contrasting SiO2-undersaturated rock suites.(I)Primitive olivine melilitites and melilite-bearing olivine nephelinites (12–9 Ma) are characterized by high MgO, CaO, Fe2O3, TiO2, Ni, V, F, moderate alkalis, Al2O3, P2O5, Ba, Nb, Zr, and low SiO2, Rb, Pb, and U concentrations. The rocks are composed of forsteritic olivine, diopsidic clinopyroxene, melilite, perovskite, Cr-bearing oxyspinel, F- and Ba-rich mica, and fluorapatite. In rare cases, they contain coeval coarse-grained ijolite patches generated by rapid in-situ fractionation in small melt pockets.(II)Evolved nosean phonolites (14–11 Ma) comprise high alkalis, Al2O3, SiO2, Rb, Nb, Zr, U, Pb, S, and low MgO, CaO, Fe2O3, TiO2, P2O5, Ba, Ni, and V concentrations, and contain abundant Ba-bearing alkali feldspar and nosean-haüyne-sodalitess macrocrysts, aegirine-augitic clinopyroxene, as well as accessory apatite, titanite, zircon, and pyrochlore.The melilititic–nephelinitic rocks formed by low degrees of partial melting of a carbonated amphibole ± phlogopite-bearing garnet wehrlite in the uppermost asthenosphere or in the thermal boundary layer and occur also in neighbouring regions. However, their coexistence with evolved nosean phonolites is a unique and so far, unexplained feature in the southern Central European Volcanic Province.Thermodynamic modelling implies that removal of 11–19% oxyspinel, 4–10% olivine, 42–57% clinopyroxene, <3% mica, <9% feldspathoids, <8% feldspar from melilititic–nephelinitic parental melts at upper crustal conditions (∼200 MPa) results in significant amounts of phonolitic residues that are compositionally similar to the exposed nosean phonolites. Strongly negative P and Ti anomalies and a trough of MREE in primitive mantle-normalized trace element patterns of phonolites indicate additional fractionation of titanite and apatite, consistent with the mineralogy of coarse-grained (nepheline) syenitic cumulates, which are present as enclaves in both rock suites. The modelling results suggest crystallization of the (nepheline) syenite cumulates between 1050 and 800 °C and ascent and eruption of the phonolite residues at no less than ∼900 °C with complete solidification of the observed assemblage at >750 °C. Significant crustal assimilation during fractionation appears unnecessary to explain the mineralogical, mineral chemical, and geochemical characteristics of the phonolites. Prolonged upper crustal differentiation of the magmas in one case (nosean phonolites) and fast ascent of primitive melts in the other (olivine melilitites and melilite-bearing olivine nephelinites) can be explained by stress field changes from an extensional to a more compressive regime, the magma ascent becoming thereby increasingly structurally controlled and supported by brittle deformation.

Desempenho de remineralizadores inoculados com microrganismos como fonte de potássio e outros nutrientes

ABSTRACT The consumption of potassium (K) fertilizers in Brazilian agriculture exceeds the national production of this input by more than ten times, indicating the need for alternatives to reduce imports of these products. The objective of this study was to evaluate the performance of the remineralizing rocks phonolite and olivine melilitite as sources of K and other nutrients, as well as the effects of inoculation with Bacillus subtilis and Bacillus megaterium on the solubilization of these rocks in the soil. A greenhouse experiment was conducted using a randomized block design, with four replications, in a factorial arrangement consisting of three K sources (potassium chloride, phonolite, and olivine melilitite), three rates (150, 300, and 600 kg ha-1 K2O), with and without inoculant, and two controls without K (one with and one without inoculant). The experimental units consisted of pots containing 3 kg of soil and a strawberry plant grown for eight months. The treatment with olivine melilitite inoculated with rhizobacteria favored phosphate solubilization when applied the highest rate. Olivine melilitite remineralizer, alone or inoculated with rhizobacteria, increased K+ and Ca2+ contents in the soil when applied at the intermediate and highest rates (300 and 600 kg ha-1 K2O), highlighting this remineralizer as an alternative potassium source for plants.

Pliocene-to-Holocene volcano-tectonic activity on Mohéli Island (Comoros archipelago) constrained by new K[sbnd]Ar ages

The volcanism of the Comoros archipelago (from west to east: Grande Comore, Mohéli, Anjouan, and Mayotte islands) has been under renewed scientific scrutiny since the eruption of a new submarine volcanic edifice (Fani Maoré) which begun in May 2018 east of Mayotte. West of Mayotte, Mohéli island has received little attention from the geoscience community, despite its largely uneroded volcanic landscapes suggesting a recent activity that has not been dated. Here we address this gap in knowledge by applying KAr geochronology on groundmass and major-trace element analyses to subaerial and submarine rocks, in an attempt to reconstruct the volcano-tectonic and geochemical evolution of Mohéli. Our results show that Mohéli's volcano-tectonic evolution proceeded in two constructional stages, including a primary edification along a N070°E axis from before ca. 3.8 Ma to ca. 3 Ma (Stage 1), and a second construction along a N110°E ridge shaping the present-day island since ca. 2 Ma (Stage 2). The two stages were separated by an increased subsidence (≥0.2 mm/yr) that drowned a large part of the N070°E primary edifice. The two identified volcano-tectonic stages are reflected also in the geochemical evolution of emitted magmas, which were moderately silica-undersaturated in Stage 1 and moderately to highly silica-undersaturated in Stage 2. Silica undersaturation increases with time up to the olivine melilitite field, together with enrichments in Ca, P, and incompatible trace elements, suggesting the increasing contribution of a metasomatized mantle in melts. The coeval changes of construction orientations and magmas compositions of Mohéli suggest a modification in the tectonics of the Comoros related to magmatism at about 2 Ma. The most recent volcanic morphology investigated is an olivine nephelinite lava flow on the north coast of the island dated at 8 ± 2 ka. This finding of Holocene volcanism on Mohéli implies that the entire Comoros archipelago should be considered as an active zone in any volcanic hazard assessment. The melilite-bearing rocks of Mohéli share geochemical similarities with those of Mayotte and of the Cenozoic volcanic provinces of Madagascar, further pointing to similar melting sources and magmatic processes over the Mozambique channel.

Economic analysis of olivine melilitite powder as an alternative source of nutrients in maize cultivation

Agriculture is characterized by the high use of fertilizers to promote higher income expectations and, due to the representativeness of this input, the cost of agricultural production is strongly affected. The present study aims to evaluate the economic efficiency of the association of olivine melilitite powder with beneficial microorganisms and the reduction of 25% chemical fertilization in maize cultivation. Five treatments were tested under a randomized block design with four replicates, represented by the application of the remineralizer associated with inoculation of bacteria of the genera Bacillus spp. and Azospirillum spp. with a 25% reduction in the recommended basal fertilization, plus fertilization with only formulated fertilizer as control treatment. The economic technical coefficients were evaluated: Gross Revenue (GR), Operating Profit (OP), Total Operating Cost (TOC), Leveling Point (LP), Profitability Index (PI) and Yield (YLD). Application of remineralizer associated with inoculation of bacterial strains of the genera Bacillus spp. and Azospirillum spp. showed the best economic indicators, promoting increments of up to 7% in PI and 15% in OP, and grain yield remained at high levels. However, application of remineralizer without inoculation of microorganisms negatively impacted grain yield, reducing PI, OP and GR. Pearson’s coefficients indicate a strong relationship of the YLD variable with PI and OP, enabling the application of olivine melilitite powder as an alternative source of nutrients in the cultivation of off-season maize. It is concluded that the application of olivine melilitite powder is economically viable and increases the profitability index, while keeping maize yield at high levels when associated with inoculation of bacteria of the genera Bacillus spp. and Azospirillum spp.

La Queglia carbonatitic melnöite: a notable example of an ultra-alkaline rock variant in Italy

Very primitive ultramafic igneous rocks occur at Mt. La Queglia (Abruzzo, Italy). They form a strongly deformed sill–dyke system now tilted vertically. These rocks were initially classified as alnöite and, subsequently, have been suggested to be a carbonatitic olivine melilitite. However, further investigation and interpretation of these rocks is needed due to the presence of hand-specimen-scale textural variation suggesting a complex petrogenesis. We study the texture, mineral chemistry, and whole-rock geochemistry to define three main rock-types. (1) A brecciated rock with an ocellar texture composed of calcite pseudomorphs after olivine and melilite, plus fresh diopside in a groundmass of mica, aegirine, garnet, calcite, apatite, perovskite, titanate and chlorite. Zoned ocelli in this rock show an amoeboid shape, agglutination, and menisci typical of a plastic state. (2) A quenched rock showing a spinifex texture containing long feathery phenocrysts of cpx and mica suspended in a groundmass of nepheline, aegirine, apatite, Ti–rich magnetite, plus abundant calcite and some K-feldspar and zeolites. (3) A coarse-grained rock is composed of calcite plus intergranular glauconite, a mixture of spinel mineral group and Ti–rich magnetite, accessory barite, pyrite, and chabazite-K. The igneous rocks at Mt. La Queglia show extreme SiO2-undersaturation (33.5–37.3 wt% SiO2), high MgO contents and TiO2/Al2O3 ratios. Rock-type 1 has a lower Mg number Mg# = 100 × [Mg/(Mg + Fe2+)], higher Ca number Ca# = 100 × [Ca/(Ca + Mg)], high Cr (up to 720 ppm) Ni (up to 379 ppm), higher rare earth elements (REE) contents as well as La/Lu ratio, compared to rock-type 2. Perovskite and chromite accumulation seems an important agent during rock differentiation. Rock-type 3 shows REE cross-over with rock-type 2 suggesting light (L)REE concentration in a carbothermal residuum. Mt. La Queglia rocks are an end-member compared to other Upper Cretaceous and Paleogene Italian lamprophyres, suggesting a low degree of melting of a HIMU (a colloquialism for “high-μ”; referring to mantle domains with high 238U/ 204Pb) garnet-bearing mantle source.

Carbonatite, aillikite and olivine melilitite from Zandkopsdrift, Namaqualand, South Africa: Constraints on the origin of an unusual lamprophyre-dominated carbonatite complex and the nature of its mantle source

We present a chemical and stable and radiogenic isotope data set for carbonatite, aillikite (ultramafic lamprophyre) and olivine melilitite from the Zandkopsdrift carbonatite complex in Namaqualand, South Africa. This carbonatite complex is associated with the ≈500-km-long, NE-SW oriented, age-progressive (40–80 Ma) Namaqualand-Bushmanland-Warmbad ultramafic alkaline magmatic lineation that consists mainly of olivine melilitite and kimberlite. Zandkopsdrift has a radiometric age of 55 ± 4 Ma and is unusual among southern African carbonatites because the dominant rock type exposed is aillikite (a variety of carbonated ultramafic lamprophyre), with carbonatite occurring mainly as a network of subvertical dykes in the southwest of the complex and olivine melilitite occurring as meter-sized blocks of float derived from the subsurface. Calcite and ferroan dolomite carbonatites are present but Mg-rich dolomitic carbonatite varieties are lacking. All rock types appear to have experienced at least moderate differentiation and all show elevated δ18OSMOW values for carbonate minerals, whereas phlogopite and clinopyroxene from these rock types fall near mantle values (with ranges of +13.3 to +21.8‰ and + 4.9 to +5.4‰ for carbonates and silicates, respectively), indicative of interaction with hydrous fluids at low-temperature. Sr-Nd-Pb isotope compositions indicate moderate to strong HIMU signatures (e.g., 206Pb/204Pbi = 19.4 to 21.0) with limited SrNd isotope variation and subvertical NdHf isotope arrays extending well below the ocean island basalt field and terrestrial array. Uncertainty regarding the differentiation history of the three rock types complicates estimation of primary magma compositions but strong chemical similarities between the carbonatites and aillikites, plus their close physical intermingling, strongly suggests that they are related by fractional crystallization to a common parental magma, whereas their relationship to the melilitites is less straightforward. The aillikites and melilitites have compositions of the REE and other elements similar to near-primary versions of these rock types from other alkaline igneous provinces globally, which have been explained as the products of low degrees of partial melting at 4–7 GPa (for aillikites) and slightly higher degrees of melting at 3–3.5 GPa (for melilitites). Lower pressures of generation and distinct trace element characteristics of the Zandkopsdrift melilitites could be explained by these originating as melts of a garnet wehrlite halo around the magmatic conduit formed by metasomatic reaction between carbonated melts and lithospheric peridotite. Most Zandkopsdrift carbonatites have high Lu/Hf ratios which, combined with their relatively low 176Hf/177Hf values, suggests that their mantle sources could not have formed more than 30–50 Myr prior to emplacement of the complex. This implies that a mantle plume had a role in their formation, either as a direct source of melts or as a source of heat with which to melt pre-existing metasomatic heterogeneities.

Potencial do pó da rocha olivina melilitito como remineralizador de solos de acordo com tamanho de partículas e doses

Abstract The objective of this work was to evaluate the potential of olivine melilitite rock powder, in two particle sizes and in increasing rates, to improve the chemical properties of the soil and the growth and nutrient accumulation of soybean (Glycine max) and sorghum (Sorghum bicolor) plants. The treatments consisted of three rates of the rock powder, equivalent to 2.5, 5.0, and 10 Mg ha-1, in the powder and filler particle sizes of the commercial product. Physicochemical and mineralogical analyses were carried out using, as a basis, the Brazilian normative ruling on rock powder as a soil remineralizer. The soybean and sorghum plants were cultivated for 60 and 45 days, respectively, in a greenhouse on a Humic Dystrudept and a Typic Hapludult. The olivine melilitite rock powder applied in the tested increasing rates and two particle sizes improved soil chemical properties and promoted plant growth. However, the filler particle size is more efficient than that of the powder to improve soil chemical properties and plant growth and nutrient accumulation.

Chemical composition of soybean seeds subjected to fertilization with rock dusts

. Rock dusts in association with organic sources have been used in agriculture to improve soil chemical characteristics and food composition. In this context, this study aimed to evaluate the effect of the rock dusts siltstone, tephrite, and olivine melilitite pure or combined and associated or not with cattle manure on the chemical composition of soybean seeds of the cultivar BRS 232 grown on a Cambisol and Nitisol subjected to these treatments and conventional fertilization. For this, an experiment was carried out with pots in a greenhouse using a Cambisol and Nitisol to cultivate the soybean from January to May 2019 until seed production. The seeds were harvested, ground, and sieved through a 1 mm mesh sieve to determine the nutrient, phytate, and crude protein contents. The effects of the rock dusts on the chemical composition of seeds were directly related to the chemical characteristics of the evaluated soils. The tested rock dusts had a more pronounced response in the Cambisol (poorer soil) than in the Nitisol (more fertile). The contents and accumulation of nutrients in the seeds, as well as the total dry matter production in both soils subjected to the treatments with the rock dusts olivine melilitite and siltstone + olivine melilitite, pure and combined with manure, were similar and, in some cases, higher than the treatments subjected to conventional fertilization. The combination of manure and rock dusts provided an increase in the concentration of nutrients in both soils, resulting in their higher availability for plants and directly reflecting on the chemical composition of seeds.

Agronomic potential of four rock powders, pure or mixed, as soil remineralizers

Detailed knowledge of chemical, petrographic and mineralogical compositions as well as the effects of applying rock powder on soil chemical properties and plant production are required for classifying these materials as soil remineralizers (SR), as according to Brazilian legislation in force. This study aimed to evaluate the potential of rock powders siltstone, tephrite and olivine melilitite, pure or mixed, on improving the fertility of a Cambisol and a Nitisol as well as the yield of soybean and barley crops grown in succession inside a greenhouse. For that purpose, these products were characterized as their granulometry, chemical, mineralogical and petrographic compositions. Based on the results, it was verified which products met the requirements for registration as SR established by the Normative Instruction Number 5 (NI5) from MAPA. Elemental chemical and grain size analyses indicated that all tested products met the NI5 requirements for their registration as SR. The mineral composition identified through petrographic analyses was confirmed by analyses performed via X-ray diffractometry techniques. Olivine melilitite rock, pure or mixed with siltstone, had the highest agronomic potential when compared to other powders, thus acknowledged as a SR. Although tephrite had little agronomic response on evaluated soils and crops, it also meets the SR requirements. Siltstone fulfilled most of NI5 criteria, except for exceeding the maximum content of free silica (quartz); therefore, it likely does not meet the requirements for its admittance as a SR.

The geology of the late-Cretaceous Salpeterkop volcano near Sutherland: A geomorphologic benchmark

The Salpeterkop volcano is spatially part of the Sutherland Suite of alkaline rocks in the Northern Cape. It is one of the best preserved volcanoes in South Africa with part of the tuff ring still intact, remnants of the ejecta mantle outside the crater still preserved, and is host to epiclastic rocks, including ash and lapillistone and water lain sediments, inside the crater. New dates from apatites and phlogopites from Salpeterkop suggest an age close to 70 Ma. This Upper Cretaceous age is supported by the silicified wood found within the epiclastic sediments. Its relationship to the alkaline rocks in this cluster is not entirely clear but field evidence suggests that initial olivine melilitites and ultramafic bodies were followed by the main eruption that produced Salpeterkop. Clear igneous components in the associated breccias and pyroclastics are rare but indicate that this volcano was linked to an alkaline (trachytic) intrusion driven by phreatic magmatism. This is further highlighted by the presence of (nepheline?) syenite xenoliths in some carbonatite breccias and dykes that are part of the later carbonatites with its associated hydrothermal alteration products. Although the carbonatites are largely late-stage, there is evidence of earlier carbonatite activity from a precursor carbonatite dyke that has off-set an olivine melilitite dyke. Relatively unaltered pyroclastics, associated with two vents, northeast and northwest of the crater respectively, represent the final phase of this volcanic centre. Finally, the preservation of the Salpeterkop crater and its associated volcaniclastics highlights the change of intense landscape denudation, that ensued from Gondwana break-up to the end of the Cretaceous, to a period of drastically reduced erosion rates during the Cenozoic Era.

Productivity of soybean and barley plants cultivated in succession and subjected to different rock powders

The use of rock powders, pure our combined, associated or not with organic sources can be an interesting strategy to improve soil fertility and increase plant productivity. This study aimed to evaluate the productivity of soybean and barley plants subjected to treatments with rock powders siltstone, tephrite, and olivine melilitite, pure or combined, associated or not with cattle manure compared with the conventional treatment. Two experiments with pots were carried out in a greenhouse in Cambisol and Nitisol, where soybeans and barley were cultivated, in succession, in 2019, until seed production. Plant productivity of soybean in conventional treatment was higher than the obtained in most treatments. For this same treatment, barley had greater productivity than that obtained in the other treatments. Among the tested rock powders, the best response of plants, in terms of productivity, was verified in treatments with olivine melilitite and siltstone + olivine melilitite, and poor response in those submitted to pure siltstone and tephrite. The combination of manure with these powders provided an increase in plant productivity, especially in the treatment with manure + siltstone + olivine melilitite, in which plant productivity was close to and, in some cases, higher than the obtained in the conventional treatment.

Fossil wood from the Upper Cretaceous crater sediments of the Salpeterkop volcano, North West Province, South Africa

AbstractThe Salpeterkop volcano forms part of what has been referred to as the Upper Cretaceous Sutherland Suite of alkaline rocks, an igneous province composed of olivine melilitites, carbonatites, trachytes and ultramafic lamprophyres. Salpeterkop is a remnant of the summit tuff ring structure that surrounds a crater which is almost 1 km in diameter and is filled with epiclastic strata.Five pieces of silicified wood were collected from the crater filled sediments, sectioned and identified as a new species of Cupressinoxylon, C. widdringtonioides. This is the first example of the fossil genus in South Africa. Only one member of the Cupressaceae s.l. occurs in southern Africa today. From the wide and indistinct growth rings in the fossil wood it can be deduced that the local climate was warm and humid with little or no seasonality, in support of global records of a warm Late Cretaceous. The preservation of the crater further signifies the low level of erosion the region has experienced since its emplacement.

Interaction between mafic dike rocks and salt deposits in the Rhine Graben, southwest Germany

ABSTRACT Dikes of primitive olivine melilitites and monchiquites intruded into an Oligocene (Rupelian) potash salt deposit near Buggingen (SW Germany). Ocelli and amygdules reveal distinct mineral assemblages depending on whether the dike rocks are in direct contact with the potash layer or with bituminous shales (Fish Shale). Samples in contact with the potash salt layer show roundish textures that contain smectite ± talc ± chlorite, calcite, and in cases anhydrite and halite, while those close to the bituminous shale mainly comprise smectite, calcite, zeolite group minerals, and analcime. No textural or mineralogical evidence for high-temperature (magmatic) interaction between the dike rocks and the evaporites was observed. This is presumably related to (1) a very low magmatic water activity in the magma, which prevented exsolution of aqueous fluids and appreciable dissolution of the salt, and (2) fast cooling of the magmas, inhibiting melting of the salt deposits and potential liquid mingling and/or assimilation processes. Halite formation in the dike rocks is, rather, related to later, post-magmatic hydrothermal fluids that previously interacted with the salt-rich host rocks. Alteration of the initially glassy groundmass to smectites and zeolites caused an enrichment of Na in the residual fluid, but halite saturation was not attained, as indicated by the absence of groundmass halite. Only fluid–rock interaction in millimeter-sized vugs caused halite precipitation via desiccation by swelling of previously formed clay minerals. Locally, the boron silicate datolite formed in pseudomorphs after olivine. Its precipitation was controlled by the Si and B supply provided by the breakdown of serpentine and smectite.

Radiometric ages and time–space distribution of volcanism in the Campo de Calatrava Volcanic Field (Iberian Peninsula)

The volcanic region of Campo de Calatrava, which is located in the centre of the Iberian Peninsula, is characterized by monogenetic, strombolian and hydromagmatic volcanic activity. It is made up of more than two hundred volcanoes distributed over an area of about 4000 km2. They are mainly comprised of sodic alkaline and ultra-alkaline rocks, few evolved rocks (basalts, basanites, olivine nephelinites and olivine melilitites) and occasionally ultrapotassic rocks (olivine leucitites) and carbonatites. New radiometric ages (K/Ar and 40Ar/39Ar) allow a better understanding of the distribution and temporal evolution of volcanic activity in this region. The oldest volcanism is ultrapotassic and restricted to a single vent. The new 40Ar/39Ar ages date this centre between 7.4 Ma and 7.1 Ma, so it was contemporary with other ultrapotassic activity in the Iberian Peninsula (the lamproites of the SE of Spain). After a break of about 3 million years, the main volcanic activity in the region took place, without apparent major pauses, from about 4 Ma to less than 0.7 Ma, with most radiometric ages concentrated between 3.5 and 1.5 Ma. Except in the case of olivine leucitites, there are no significant compositional differences related to the ages of the volcanoes, although there may be minor variations. The mildly alkaline volcanoes (basalts and basanites) tend to be concentrated in the central areas of the region, while on the peripheral areas, the volcanoes are essentially ultra-alkaline. The spatial age distribution of the volcanoes seems to show a shift of the volcanic activity over time towards the northeast. The spatial age distribution of the volcanoes seems to show a displacement of volcanic activity over time towards the northeast, accompanied by an increase in its intensity.

Evidence for Multistage and Polychronous Alkaline–Ultrabasic Mesozoic Magmatism in the Area of Diamondiferous Placers of the Ebelyakh River Basin (Eastern Slope of the Anabar Shield)

New mineralogical and isotope–geochemical data for zircon megacrysts (n = 48) from alluvium of Kholomolokh Creek (a tributary of the Ebelakh River) are reported. Using the geochemical classification schemes, the presence of zircons of kimberlitic and carbonatitic genesis was shown. The U–Pb dating of zircons revealed two major age populations: the Triassic (258–221 Ma, n = 18) and Jurassic (192–154 Ma, n = 30). Weighted mean 206Pb/238U ages allowed us to distinguish the following age stages: 155 ± 3, 161 ± 2, 177 ± 1.5, 183 ± 1.5, 190 ± 2, 233 ± 2.5, and 252 ± 4 Ma. It is suggested that the Ebelyakh diamonds could have been transported from the mantle depths by kimberlite, as well as by other related rocks, such as carbonatite, lamprophyre, lamproite, olivine melilitite, etc. Diamonds from the Ebelyakh placers most likely have polygenic native sources and may be associated with polychronous and multistage Middle Paleozoic and Mesozoic kimberlite and alkaline–ultrabasic magmatism in the eastern slope of the Anabar Shield (the Ebelyakh, Mayat, and Billyakh river basins).

Olivine melilitites, mantle xenoliths, and xenocrysts of the Takarindiona district: Petrogenesis, magmatic evolution, and the sub-continental lithospheric mantle of east-central Madagascar

The olivine melilitites from the southern part of the 6.8 Ma-old Takarindiona volcanic field (Eastern Madagascar) are olivine ± chromite -phyric lavas, with zoned titanaugite, perovskite, melilite, nepheline, monticellite, Ba–Ti-mica and Fe–Ti oxides as microphenocrysts and groundmass phases. The rocks are very primitive, rich in incompatible trace elements (e.g., Ba = 1049 ± 153 ppm, Sr = 1050 ± 167 ppm, Nb = 98 ± 13 ppm; La/Ybn = 41 ± 5; La/Nb = 0.88 ± 0.05), and have restricted ranges of initial 87Sr/86Sr (0.70391–0.70410) and 143Nd/144Nd (0.51272–0.51282). The rocks follow a differentiation trend controlled by ab. 20% removal/addition of phenocryst olivine ± chromite. The olivine melilititic magmas are the product of small degrees of partial melting (1–3%) of a peridotitic source, enriched in highly incompatible trace elements by CO2-, F-, and H2O-rich melts, located within the garnet stability field (3–3.5 GPa and ~100 km depth) of sub-continental lithospheric mantle, where carbonates (dolomite) and possibly phlogopite were stable phases. Mantle xenoliths within the volcanics are mostly spinel harzburgites having mineral modes and chemical compositions suggesting variable degrees of “basalt” melt extraction. Based on textural and chemical evidence, and quantitative thermobarometric estimates, the xenoliths were incorporated at a pressure of ~1.1 GPa (~35–40 km depth), far shallower than the source of the melilititic magmas, and along a predictably cool geotherm beneath Archean continental lithosphere. Highly resorbed orthopyroxene xenocrysts mantled by augite indicate that the melilitites may have also entrained lower crustal materials or underplated subalkaline rocks. The mantle sources of the lavas and mantle xenoliths of the Takarindiona district indicate stratification of the lithospheric mantle, and help constraining the lithospheric features and the magmatic history of the Eastern Madagascar craton.

Evidence for olivine deformation in kimberlites and other mantle-derived magmas during crustal emplacement

This paper highlights published and new field and petrographic observations for late-stage (crustal level) deformation associated with the emplacement of kimberlites and other mantle-derived magmas. Thus, radial and tangential joint sets in the competent 183 Ma Karoo basalt wall rocks to the 5 ha. Lemphane kimberlite blow in northern Lesotho have been ascribed to stresses linked to eruption of the kimberlite magma. Further examples of emplacement-related stresses in kimberlites are brittle fractures and close-spaced parallel shears which disrupt olivine macrocrysts. In each of these examples, there is no evidence of post-kimberlite regional tectonism which might explain these features, indicating that they reflect auto-deformation in the kimberlite during or immediately post-emplacement. On a microscopic scale, these inferred late-stage stresses are reflected by fractures and domains of undulose extinction which traverse core and margins of some euhedral and anhedral olivines in kimberlites and olivine melilitites. Undulose extinction and kink bands have also been documented in olivines in cumulates from layered igneous intrusions. Our observations thus indicate that these deformation features can form at shallow levels (crustal pressures), which is supported by experimental evidence. Undulose extinction and kink bands have previously been presented as conclusive evidence for a mantle provenance of the olivines—i.e. that they are xenocrysts. The observation that these deformation textures can form in both mantle and crustal environments implies that they do not provide reliable constraints on the provenance of the olivines. An understanding of the processes responsible for crustal deformation of kimberlites could potentially refine our understanding of kimberlite emplacement processes.

Geochemistry of volcanic rocks from Oldoinyo Lengai, Tanzania: Implications for mantle source lithology

Oldoinyo Lengai is the only active carbonatite volcano within the East African Rift Valley in northern Tanzania. The volcano is dominated by peralkaline silicate rocks with natrocarbonatites. This study presents new mineralogical and geochemical data, including Sr–Nd–Pb–Hf–Mg isotopic compositions, for volcanic rocks at Oldoinyo Lengai and lavas from the nearby Gregory Rift Valley. The samples analyzed in this study include olivine melilitite, melanephelinite, wollastonite nephelinite, and phonolite. The olivine melilitites and melanephelinites have highly fractionated rare-earth-element (REE) patterns with (La/Yb)N values of 26.4–64.9, suggesting that they formed from magmas generated by low-degree (up to ∼7%) of partial melting within the garnet stability field. The wollastonite nephelinites have much higher (La/Sm)N values but lower (Sm/Yb)N values relative to typical oceanic island basalts (OIB), with flat heavy REE patterns [(La/Yb)N = ∼22]. The phonolites have elevated REE abundances but with patterns intermediate between the other two sample groups [(La/Yb)N = ∼41]. All samples have primitive-mantle-normalized incompatible element patterns that are characterized by negative K and Rb anomalies but no significant Eu anomalies. They also have elevated Yb contents relative to the compositions of modeled garnet peridotite-derived melts, suggesting that they were derived from a sublithospheric source containing enriched HIMU-like recycled oceanic crustal material. However, the wollastonite nephelinites have significantly positive Ba, U, Sr, and Pb anomalies similar to those found within the Oldoinyo Lengai natrocarbonatites. The wollastonite nephelinites might have been sourced from a region of sub-continental lithospheric mantle (SCLM) that was previously metasomatized by interaction with carbonatite melts. The phonolites in the study area have also weakly positive Pb and Sr anomalies indicative of some interaction with the SCLM. All samples have δ26Mg values (−0.39‰ ± 0.07‰) lighter than the composition of normal mantle material (−0.25‰ ± 0.04‰). In addition, a negative correlation between δ26Mg values and MgO concentrations suggests derivation from a source region containing recycled carbonate. The samples from the study area define a mixing array between HIMU- and EM1-type OIB in Sr–Nd and Pb–Pb isotopic correlation diagrams, and have pronounced Nd–Hf isotopic decoupling, plotting below the mantle regression line in Nd–Hf isotopic space. The negative deviation from the Nd–Hf isotopic mantle array and the presence of an EM1-type mantle component in the Sr–Nd isotopic compositions of the Oldoinyo Lengai volcanic rocks can be generated by recycling of E-MORB-type oceanic crustal material with an age of 1.5–1.0 Ga.

Geochemical constraints on Cenozoic intraplate magmatism and their relation to Jurassic dolerites in Tasmania, using Sr-Nd-Pb isotopes

Tasmania hosts two prominent Meso-Cenozoic mafic magmatic provinces: abundant Jurassic dolerites that belong to the Ferrar Magmatic Province that formed during Gondwana break-up; and Cenozoic, mainly basaltic volcanics, which represent intraplate magmatism, post-Gondwana break-up. The origin of the Cenozoic volcanics is still controversial, in that the detailed role of competing asthenospheric and lithospheric sources remains unclear. This study presents new geochemical and isotopic data which is used to identify and contrast the magmatic sources and their relationship to Jurassic and Cenozoic magmas. The compositions of the Cenozoic lavas span a wide range from highly silica-undersaturated olivine melilitites and nephelinites to basanites, ne-hawaiites, olivine basalts and quartz-tholeiites. New Sr-Nd-Pb isotopic data combined with major and trace element geochemistry show that the most silica-undersaturated rocks are most enriched in incompatible elements and also have the least radiogenic Sr and most radiogenic Nd. Sr-Nd-Pb isotope ratios for the most silica-rich lavas trend towards values for the Ferrar Jurassic dolerite source. More generally, Sr, Nd and Pb isotopes in the Cenozoic lavas can be modelled by a three component mixture of Pacific Mid-Ocean Ridge Basalts (MORB), HIMU-like (characterized by high time-integrated μ (238U/204Pb)) and Jurassic dolerite sources. Pb isotope values confirm the HIMU-like component in the array. Various degrees of melting during decompression melting has also contributed to the wide range of compositions observed, with most silica-undersaturated rocks originating at the highest pressures (>20 kbar) and by the smallest percentages of melting. We suggest that this process, combined with variable interaction of MORB and HIMU-like asthenospheric sources with lithospheric mantle containing remnant Jurassic signatures, resulted in the wide range of Cenozoic lava compositions observed today.