A series of zirconium phosphate fluorides were synthesized and structurally characterized using different amines as templates. The compounds have the general formulas [amHn]1/n[Zr2(HPO4)(PO4)2F]·H2O (1,am=ethylenediamine,n=2; 2.am=N-methylethylenediamine,n=2; 3,am=1,3-diaminopropane,n=2; 4,am=diethylenetriamine,n=3) and [amH2]0.5[Zr2(HPO4)2(PO4)F2]·0.5H2O (5,am=N,N,N′,N′-tetramethylethylenediamine). In the structures of 2–4 with a Zr:F ratio of 2:1, there exists a three-dimensional arrangement of zirconium octahedra (one ZrO6and one ZrO5F) and phosphate tetrahedra (two PO4and one HPO4) connected via common oxygen atoms, whereas fluorine atoms and OH groups are terminal. These compounds crystallize in the “ZrPO-1” structure type, which contains channels along thebaxis formed by eight-membered rings of alternating PO4tetrahedra and ZrO6or ZrO5F octahedra, respectively. The protonated disordered templates occupy the channels. Half the water molecules are situated in the positions alternatively left free by the disordered templates and the other half are bonded via hydrogen bridges to the terminal OH groups of the HPO4tetrahedra. In contrast, the structure of 5 reveals a Zr:F ratio of 1:1, consequently forming a layer structure. The layers formed by ZrO5F octahedra and PO4or HPO4tetrahedra, respectively, are linked by hydrogen bridges of type O–H···F and by weak H bonds over the protonated template. The similarities in connectivity pattern between Zr octahedra and P tetrahedra in all known zirconium phosphate fluorides and some zirconium phosphates are discussed.