Guided by the principles of visual perception and basic design, this research was conducted to examine users’ preferences on how they perceive natural unique wood phenomena of Pedunculate Slavonian Oak veneers (Quercus robur L.) such as color changes, wood rays, sapwood, and knots, which in the production and technical sense represent defects and wood residue, but could be used in the design of sustainable and ecological wall decorations. The goal was to detect samples with the most positive attributes and to observe their connection with activities and functional space if they are viewed as wall coverings in the interior. The results confirm that discoloration and wood rays are considered the most harmonious (“prettiest”) decors. Discoloration is associated with quiet cognitive or medium-intensity activity that can be used in libraries, hotel rooms, and classrooms. Wood rays are connected with very quiet activity in ambulance waiting rooms or religious buildings and museums. Knot decors are considered the most natural and are recommended for interiors with very or medium-intensive activities such as restaurants, cafes, and hotel receptions, but attention should be paid to the way the wall decors are arranged on the walls. Sapwood–hardwood decors are the subject of further research and improvement concerning the relationship between the dark and light parts of the veneer. In conclusion, the results provide useful guidelines for manufacturers with a large veneer residue in production and who want to design decorative wall panels, as well as for designers and architects designing interiors for a specific purpose and function where certain user behavior and psychological stimulation are desired.