Abstract In the globe, there is a rise in water demand for agricultural, industrial, and domestic purposes. Single-basin solar stills (SBSS) have been a subject of research in various countries, particularly in regions with water scarcity or limited access to clean drinking water. In this work, SBSS for desalinating high-salinity water were developed, tested, and evaluated based on a developed numerical model using MATLAB R2021a program to predict the best productivity through the best selection of raw materials used to develop the SBSS. A four-inclined SBSS was fabricated and examined experimentally according to numerical model findings for best design parameters at Marsa Matrouh, 31° 21′ 10.44″N, 27°14′14.10″ E, Agricultural Station—Agricultural Research Center (ARC), Egypt. The hourly experimental results are compared with the numerical results. A good correlation between the numerical and the experimental results with variations in water, and glass temperatures of 9, and 18% respectively, and a variation in cumulative productivity by 11%. The results clearly showed that instantaneous productivity increases by decreasing water depth to 10 mm and using the SBSS unit partially insulated from the bottom of the basin. Adding insulation in front of the sides and back of tempered glass increases the shading area and decreases water temperature hence the cumulative productivity by 15%. The cumulative productivity reached 3 L for the SBSS unit partially insulated from the bottom of the basin with an area of 0.6 m2 for only 12 h working system at a water depth of 10 mm.
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