Abstract Recent research on co-firing natural gas and hydrogen, a carbon-free clean fuel, aims to reduce greenhouse gas emissions from aging gas turbine power generation, a key energy issue. This approach can enhance old gas turbines and increase the proportion of combined cycle power plant utilization as coal-fired power plants in Korea gradually shut down. This study seeks optimal operating conditions for mixed fuels without modifying the F-class gas turbine combustor. Experiments were conducted using four different types of fuel nozzles (F-Class DLN combustors) under varying loads and co-firing rates. The test used actual machine operating conditions from 30% to 100% thermal load, with hydrogen co-fired with natural gas up to 70% at each load. OH high-speed imaging and an OH-PLIF technique analyzed flame structure and characteristics. Dynamic pressure was measured to check combustion instability, and exhaust gas emissions were evaluated for combustion characteristics. Key findings include critical co-firing rates for each nozzle based on NOx emission levels and combustion dynamics. As the hydrogen co-firing rate increased, flame length decreased, and NOx levels rose rapidly beyond 30%vol. Dynamic pressure oscillations showed no significant variations compared to natural gas combustion. This study successfully derived a characteristic operation map for a single nozzle based on the hydrogen co-firing rate.