Northern Margin Research Articles

Detrital zircon U–Pb geochronology and geochemistry of sandstones in the Siziwang Banner, Central Inner Mongolia: Implication for tectonic evolution

The central Inner Mongolia, located at the intersection of the northern margin of the North China Craton (NCC) and the Central Asian Orogenic Belt, is crucial for deciphering the Late Palaeozoic tectonic evolution associated with the subduction and closure of the Palaeo‐Asian Ocean (PAO). Our study focused on petrology, detrital zircon LA–ICP–MS U–Pb geochronology and whole‐rock geochemistry for the Late Carboniferous to Permian sandstones within the Shuanmazhuang, Dahongshan, Naobaogou, and Laowopu formations in Siziwang Banner, central Inner Mongolia. This comprehensive analysis shed light on the dynamic interplay between the NCC and the South Mongolia Block. Detrital zircon U–Pb ages in investigated samples mainly cluster between 250 and 2650 Ma, with significant peaks at 2.4–2.5 Ga, 1.8–2.0 Ga, 400–430 Ma, and 250–320 Ma, respectively. The geochemistry data are characterized by SiO2 contents (56.29–77.95 wt. %), Na2O / K2O ratios (0.45–1.58) and SiO2/Al2O3 ratios between 4.33 and 7.44. Moreover, they exhibit the slight enrichment in large ion lithophile elements (Rb and Ba) and the depletion in high field strength elements (Nb, Ta, Th, and U). These facts indicate that the sedimentary detritus predominantly originates from felsic sources, probably deriving from the Late Carboniferous–Permian continental island arc‐related intermediate‐acid igneous rocks, the Late Ordovician‐Silurian magmatic rocks in the Bainaimiao arc and the basements of the NCC. Furthermore, our present results also suggest that during the Early–Middle Permian, accelerating oceanic crust subduction triggered significant magmatic events in Siziwang Banner, leading to rapid uplift and the erosion of arc magmatic rocks, as well as the abundant corresponding sediments. Subsequently, the gradual convergence and eventual collision between the NCC and the Southern Mongolian Block took place at the end of the Permian, representing final closure of the PAO.

Using detrital zircons to constrain the late Paleozoic tectonic evolution of the adjacent tectonic domains of the Tarim Craton, NW China

Late Paleozoic tectonic evolution of adjacent tectonic domains of the Tarim Craton is vital for understanding the basin-mountain coupling and dynamical mechanisms of the Paleo-Asian and Tethys tectonic systems as well as hydrocarbon exploration and development. U−Pb dating and Lu-Hf isotope analyses of detrital zircons of the Late Paleozoic sedimentary successions from three sections across the Tarim basin enable comprehensive identification of provenance changes and reconstruction of the tectonic evolutionary history of the Tarim Basin in the late Paleozoic. A total of 248, 499, and 470 valid ages were obtained for detrital zircon samples from the Kuqa Section in the northern margin of the Tarim Basin; the Xiaohaizi Section in the platform area; and the Aitegou Section in the southwestern margin of the Tarim Basin, respectively. Each age interval corresponds to the geotectonic thermal events of the opening–subduction–closing of the surrounding oceans and the collage/collision of terranes/island arcs. Based on detailed age spectral analysis and other evidence, we propose a tectonic evolutionary model that encompasses the northern and southwestern margins of the Tarim Basin. The South Tianshan Ocean closed completely in the late Carboniferous, resulting in the collision of the Tarim Basin with the Yili–Middle Tianshan Terranes no later than 315 Ma. In the southwestern part of the Tarim Basin, the Tianshuihai Terrane began to approach in the late Carboniferous, gradually amalgamated with the southwestern margin of the Tarim Basin, and finally wholly collided with the Tarim Basin at the end of the Permian, making the Tarim Basin an entirely terrestrial basin. The southwestern Tarim Basin was not an open passive continental margin in the Carboniferous–Permian but a retro-arc basin.

Neoproterozoic sedimentary rocks in the Liantuo Formation in South China and their implication based on geochronological and Sr–Nd–Hf–Pb isotope insights

Deposition of the Liantuo Formation is closely associated with the evolutionary history of the Rodinia supercontinent, as indicated by the breakup of the Yangtze Craton in South China. In this paper, we also carried out a detailed UPb zircon examination of the Liantuo Formation. Radiometric dating of sandstone within the Liantuo Formation suggested that it was deposited ca. 790 Ma, which coordinated with the age-paleopole contradictions in the Liantuo Formation for exploring the evolutionary history of the Yangtze Block during the breakup of the Rodinia supercontinent. All the Liantuo sandstones and shales have variable Sr isotopic compositions, with initial Sr isotope ratios ranging from 0.6920 to 0.7217, which support significant fluvial contributions during the deposition of the Liantuo Formation. Samples of the Liantuo Formation show distinct variations in NdHf isotopic compositions, suggesting that the Nantuo Formation received relatively juvenile materials (e.g., the newly formed Neoproterozoic rocks from the northern margin of the Yangtze Block), whereas the Liantuo Formation received relatively mature inputs (e.g., the Huangling granitoids and/or Kongling complex). The samples from the Liantuo Formation also contain various Pb isotopes (206Pb/204Pb = 17.56–17.76, 207Pb/204Pb = 15.05–15.43 and 208Pb/204Pb = 35.51–36.79). These values are also close to the Pb isotopic compositions of the Kongling complex, which suggest that the sedimentary rocks were enriched (the Kongling complex) and are consistent with the NdHf isotope data. That is, the major provenance of the Liantuo Formation is from the South China Block basement, which is the local Kongling complex. In contrast, the Luoquan diamictite can represent the well-mixed composition of the upper continental crust (UCC) in the North China Block during the Neoproterozoic.

Druse Calcite Crystals Formed by Mesoproterozoic Paleo-Earthquake Activity in the Northern Margin of the North China Craton

Druse Calcite Crystals Formed by Mesoproterozoic Paleo-Earthquake Activity in the Northern Margin of the North China Craton

Consequences of Continental Core Complexes on Rifting Patterns: Insights From Multichannel Seismic Data From the Northern Margin of the South China Sea

AbstractCore complex type structures are common in continental margins. Recent studies have proposed exhumation of deeper crustal and mantle levels during extension of the continental margin along the Northern South China Sea (NSCS) in a core complex mode. Here, we present high‐resolution seismic profiles across different sections of the NSCS that allow us to observe two types of core complex systems. The Kaiping Rift and eastern Baiyun Rift are characterized by a sub‐horizontal Moho and exhumation of ductile deeper crust beneath an extremely thinned brittle upper crust. The central Baiyun Rift in contrast is marked by homogeneous thinning of the entire crust that is floored by mantle unroofing with a concave‐down Moho geometry. While the former type, referred to as crustal core complexes, coincides with relatively intense syn‐rift magmatism, the latter, referred to as mantle core complexes, is marked by limited magmatism. Consistently, basin subsidence rates are lower over crustal core complexes than mantle core complexes. Compared to mantle core complexes at the magma‐poor Iberian margin, the widely distributed crustal core complexes in the NSCS indicate higher geotherms and more intense magmatism during extension of the continental lithosphere. We propose that the continental core complexes observed at the NSCS represent a typical outcome of extension of a gravitationally unstable lithosphere.

The role of intra-oceanic arc in the growth of continental crust: Evidence from the Early Paleozoic Bainaimiao arc

The Early Palaeozoic arc-related formations in the northern margin of the North China Craton (NCC) belonging to the Bainaimiao arc belt is an important part of the eastern Central Asian Orogenic Belt (CAOB). The tectonic evolution of this belt remains controversial. Here we present detailed data on the geochronology and geochemistry on a newly identified Early Palaeozoic igneous suite from the Faku area in northern Liaoning. Zircon U–Pb dating of the Faku volcanic and intrusive rocks yielded weighted mean 206Pb/238U ages of ca. 458 Ma and 433–405 Ma, respectively, which represent their crystallization (eruption) times. Zircon Hf isotopic analyses show a low negative to positive εHf (t) values of − 0.33 to + 12.4, implying depleted characteristics of the source. The geochemical features of Laolingshan basaltic andesites display higher TiO2 and lower P2O5 contents, similar to that of mid-ocean ridge basalts, and relatively high Zr/Y and low Ta/Yb ratios, suggesting oceanic island arc basalt affinity. Therefore, we suggest that the Laolingshan basaltic andesites were formed in an intra-oceanic environment. The Bachagou granodiorites, with adakitic geochemical signatures, belong to the calc-alkaline and high-K calc-alkaline series, implying formation in an active continental margin tectonic setting. The Baerhushan granodiorites, which geochemically belong to S-type granites, were probably formed in a syn-collisional environment influenced by arc–continent collision. The Donggou granitoids, which have higher SiO2 and alkali and lower MgO and P2O5, show A-type granite features. Geochemical characteristics of the Donggou A-type granite suggest formation in an extensional setting caused by orogenic intermittent extension. The Baerhushan gabbro diorites, which display properties of both mid-ocean ridge and continental rift basalts, were produced under post-orogenic extensional tectonic setting after the arc–continent collision. Our study traces the Early Palaeozoic tectonic evolution of the south-eastern segment of the CAOB and the related accretionary tectonics.

Carboniferous–Early Permian volcano-sedimentary units from the northern margin of the North China Craton recorded subduction initiation in the Paleo-Asian Ocean

The precise timing of subduction initiation of the Paleo-Asian Ocean (PAO) in the northern margin of the North China Craton (NCC) remains controversial. In this study, we have conducted zircon UPb dating, whole-rock major and trace elements, and zircon Hf isotope analyses on metadacites and metamorphic greywackes from the Changde volcano-sedimentary rocks, feldspar quartz sandstones and argillaceous siltstones from the Luquantun Formation and the Sidao sedimentary rocks in central-eastern Jilin Province (NE China), to constrain the initial closure of the PAO. We obtained Early Carboniferous zircon UPb ages (345 ± 2 Ma and 351 ± 7 Ma) from the Changde volcano-sedimentary rocks. The metadacites are characterized by the enrichment in light rare earth elements and large ion lithophile elements, depletion in heavy rare earth elements and high field strength elements, and rare earth element ratios similar to those of the continental crust, indicating that these rocks originated from crustal melting. The metadacites exhibit affinity with the peraluminous A-type granite, with high zircon εHf(t) values (+3.46 − +12.21) and TDM2 of 1132–571 Ma, suggesting that they formed in a post-collisional extensional setting. Detrital zircon UPb ages from the Luquantun Formation and Sidao sedimentary rocks constrain their maximum depositional ages to the Late Carboniferous (319 ± 5 Ma) and Early Permian (284 ± 4 Ma), respectively. Most detrital zircons have age peaks at 1800 Ma with negative zircon εHf(t) values, and 2500 Ma with positive zircon εHf(t) values, suggesting that the Carboniferous–Early Permian sediments from these two formations were mainly sourced from the NCC. Moreover, the chemical index of alteration, index of compositional variability, and plagioclase index of alteration values suggest that the sediments of the Changde volcano-sedimentary rocks originated from a mafic igneous source with a low degree of weathering and a sedimentary recycling history, while the samples from the Luquantun Formation and Sidao sedimentary rocks were sourced from an intermediate-felsic igneous rock with a moderate to intense degree of weathering and mainly influenced by source composition. The crystallization age curves and summary plots of detrital zircons indicate that the Early Carboniferous metamorphic greywackes from the Changde Formation were mainly deposited in a passive margin, while the Carboniferous–Early Permian sediments of the Luquantun Formation and Sidao sedimentary rocks were mainly deposited in an active margin. We suggest that the tectonic transition from passive to active margin occurred at ∼333 Ma, marking subduction initiation in the PAO close to the northern margin of the NCC.

Early Miocene sand wedge deposits in Southwestern Tarim Basin and Implications for the Uplift of the Northern Tibetan Plateau

The uplift of the Tibet Plateau and its climatic effects have long been a hot topic in academic research. However, there is still significant controversy regarding the uplift history and related climate changes along the northern margin of the plateau. In this paper, we present sand wedge deposits from the base of the Wuqia Group (∼20 Ma) on the southwestern Tarim Basin, representing the oldest reported sand wedges in the Tibetan Plateau. A comprehensive study was conducted on lithostratigraphy, sedimentary environment, and macroscopic–microscopic features of the sand wedge deposits. The results indicate that the lithostratigraphic succession preserving the sand wedge deposits consists mainly of lenticular conglomerates and cross-bedded gravelly sandstone interbedded with medium–thin-bedded mudstone, consistent with the braided fluvial environment. The sand wedge deposits commonly exhibit a V-shape geometry and are filled with gravelly sandstone, with the gravels arranged parallel to the walls of the wedge. The clasts of the wedge-filled sandstone are well-rounded and show a unimodal grain size distribution. The quartz surfaces commonly display dish-shaped and crescent-shaped impact features, indicating an eolian origin and an arid climate. Based on the relationship between the formation temperature of modern sand wedges, the atmospheric temperature gradient, and altitude, the reconstructed paleo-elevation of the sand wedge deposits at the base of the Wuqia Group in the southwestern Tarim Basin is approximately ∼ 1000 m. These results indicate that the northern margin of the Tibet Plateau had already reached an elevation of ∼ 1000 m during the Early Miocene, forming a seasonal arid and cold climate.

The Lanseria palaeosol: Implications for palaeoweathering and terrestrial life at ∼2.6 Ga on the Kaapvaal Craton

Archaean palaeosols are a rare record of surface processes on the early Earth. We report on the discovery of a palaeoweathering profile developed at the contact between Mesoarchaean basement and the Neoarchaean to Palaeoproterozoic Transvaal Supergroup along the northern margin of the Johannesburg Dome, Kaapvaal Craton. Granodiorite ∼3.1 Ga old was subjected to weathering just prior to the deposition of the ∼2.6 Ga Black Reef Formation. The ∼25 m-thick profile is dominated by a palaeosaprolite and organic matter-rich palaeosol remnant at the top that experienced erosion upon marine transgression on the Kaapvaal Craton. The Al concentration of the profile, sericite content and chemical index of alteration (CIA) values progressively increase from the parent granodiorite towards the nonconformity as Fe, Mg, Na and Ca concentrations decrease. The decrease of Co and Zn together with Fe and the retention of U, V and Cr collectively suggest a reducing and acidic environment at the time of weathering. Carbonaceous matter with negative δ13C isotopic values (−27 to −23 ‰V-PDB) in the palaeosol is compatible with the former presence of photoautotrophic microbes. Copper depletion and mobility of P may indicate the presence of organic acids that enhanced chemical weathering of the bedrock. The palaeoweathering profile was subjected to diagenetic-hydrothermal K-metasomatism, regional metamorphism and deformation, which collectively transformed the regolith into a quartz-sericite schist, as it presently occurs. Despite these modifications, the original record of palaeoweathering and microbial colonisation is well preserved. Colonisation of a large swath of the Kaapvaal Craton by terrestrial soil-dwelling microbiota at 2.60 Ga is recorded in abundant soil-derived carbonaceous matter in transgressive marine conglomerates that erosively overlie the palaeosol.

Metallogeny and Genesis of Fault-Filling Barite-Sulfide Veins (Ougnat, Morocco): Petrography, Fluid Inclusion, and Sr-S Isotopic Constraints

The Ougnat Massif of the eastern Anti-Atlas (Morocco) hosts barite and sulfide vein-type deposits of vital economic importance. With over 150 mineralized structures reported in the Ougnat Massif, the ore-bearing ones are predominantly composed of barite, quartz, calcite, and minor portions of sulfides. The mineralized veins are driven by NW-SE and NE-SW to E-W oblique-slip opening faults that cross both the Precambrian basement and its Paleozoic cover. The mineralized structures occur as lenses and sigmoidal veins that follow stepped tension fracture sets oblique to the fault planes. These geometries and kinematic indicators of these structures point to a predominantly normal-sinistral opening in a brittle-ductile tectonic setting. The S isotopic compositions of barite from the Ougnat Massif (+10.8 to +19.5‰) fall mostly within the range of δ34S values of Late Triassic to Jurassic seawater, thus suggesting that some of the SO2− in barite comes from seawater sulfate. This range of δ34S values also corresponds approximately to the hydrothermal barite context. The 87Sr/86Sr ratios of barite, which range from 0.710772 to 0.710816, lie between the radiogenic strontium isotopic compositions of deposition by hydrothermal solutions, and also coincide with the non-radiogenic isotopic signature of Triassic to Jurassic seawater. Based on a fluid inclusions study, the ore-forming fluids were a mixture of two or more fluids. A deep hot fluid with an average temperature of 368 °C leached the granodiorites and volcanic-sedimentary complex of the Ouarzazate Group. This fluid provided the hydrothermal system with most of the Ba, radiogenic Sr, and some of the dissolved S. A second, shallow fluid with an average temperature of 242 °C was derived from Late Triassic to Jurassic seawater. The barite mineralization of the Ougnat Massif constitutes a typical example of vein-type mineralization that occurred along the northern margin of the West African Craton and regionally tied to the central Atlantic opening.

Stocks and Sources of Soil Carbon and Nitrogen in Non-Native Kandelia obovata Afforestation and Spartina alterniflora Invasion: A Case Study on Northern Margin Mangroves in the Subtropical Coastal Wetlands of China

For decades in China, carbon neutrality policies have spurred the establishment of northern margin mangroves as artificial blue carbon ecosystems. However, there has been limited research on the impact of plantation and invasion on the stocks and sources of soil carbon and nitrogen in rehabilitated coastal wetlands. Non-native Kandelia obovata afforestation began on Ximen Island, Zhejiang, China, where Spartina alterniflora invasion had also occurred decades ago. Soil cores were collected from both mangrove and salt marsh habitats with depths from 0 to 50 cm and were analyzed for total carbon (TC), soil organic carbon (SOC), total nitrogen (TN), and the isotope of carbon and nitrogen in sediments. The results indicated that there were no significant differences in the TC, SOC, and C/N ratio between the K. obovata and the S. alterniflora, but there were significant differences in TN, isotope δ13C, and δ15N. The SOC content of both ecosystems in the 0–20 cm layer was significantly higher than that in the 30–50 cm layer. Our study has shown that the main sources of carbon and nitrogen for mangroves and salt marshes are different, especially under the impact of external factors, such as tidal waves and aquaculture. These findings provide insight into the ecological functioning of subtropical coastal wetlands and an understanding of the biogeochemical cycles of northern margin mangrove ecosystems.

Mineralogical and magnetic variations of periglacial loess in SE Tibet reveal mid-Pleistocene expansion of Tibetan glacial activity

The formation and evolution of the cryosphere on the Tibetan Plateau is of great significance in understanding the Earth's carbon and climatic system. Periglacial loess deposits in southeastern Tibet offer a means to constrain this history as they contain critical information on glacial grinding and frost shattering processes in high-altitude mountain regions through time, which yield lithogenic fractions of largely loess silts and sands. Based on combined analyses of lithogenic magnetic properties and mineralogical composition, here we find that increasing high mountain production and supply of fresh detrital components since the mid-Pleistocene climate transition (MPT, 1.2–0.7 Ma) led to a substantial increase of the lithogenic susceptibility and decrease in chemical weathering intensity of periglacial loess in southeastern Tibet. The agreement of these findings with similar results from eolian loess on the northern margins of the Tibetan Plateau suggests a plateau-wide glacier expansion during the MPT. Enhanced glacial erosion and freeze-thaw activities occurred in the high-altitude mountain regions of the plateau during the MPT, thereby providing vast amounts of fresh detritus for the formation of loess deposits. High and constant values of lithogenic magnetic parameters in the loess deposits after 0.7–0.6 Ma further indicate that the Middle Pleistocene is a critical period for the establishment of modern-like glacial and periglacial landforms on the Tibetan Plateau. Our results further suggest that enhanced Quaternary glaciation in SE Tibet occurred earlier than in the north, which we attribute to climate cooling combined with regional seasonal snowline lowering. As such, a close relationship exists between global climate changes, development of pan-Tibetan glaciations, and large-scale dust emission.

Deformation characteristics and reactivated failure modes of the massive Baimu ancient landslide deposit on the northern margin of the East Himalayan syntaxis

AbstractIn the Eastern Himalayan syntaxis, massive Quaternary loose deposits represent a typical product of abrupt topographic changes. Influenced by the Qinghai‐Tibet Plateau uplift and rapid river incision, the partial or complete failure of these deposits is a recurrent phenomenon in alpine‐gorge regions, posing substantial threats to major infrastructure development. Through topographic interpretation and field investigation, this study clarifies the geological features and genetic mechanisms of the Baimu ancient landslide deposit (BALD), located on the northern margin of the East Himalayan syntaxis. The surface deformation time series spanning October 2017 to December 2019 was estimated using employing multitemporal synthetic aperture radar interferometry. Then, the spatiotemporal deformation characteristics of the BALD was analysed by superposing terrain factors, and hazard division was implemented. The results indicate that high‐hazard zones are mainly distributed on high and steep free faces of the BALD. Deformation evolution and rainfall time series showed obvious correlation. Lastly, a generalized failure model is established for the BALD, which will serve as a valuable reference for disaster prevention and is applicable to the study of similar deposits in the Qinghai‐Tibet Plateau.

Geometry, slip rate, and the latest earthquake of the Jinta Nanshan Fault: Interactions of the Altyn Tagh Fault and the Qilian Shan at the northern margin of the Tibetan Plateau

This work presents a study of late Quaternary activity on the Jinta Nanshan Fault (JTF), to constrain its properties including seismic hazard, and to understand the tectonic evolution of the northern edge of the Tibetan Plateau. The JTF has developed during northeastward growth of the Qilian fold-and-thrust belt and eastward growth of the Altyn Tagh Fault. Based on remotely-sensed image interpretation and field investigation, trench studies, high-resolution terrain construction and Optical Stimulated Luminescence dating, we study the fault geometry and slip motion, and constrain the slip rate and the latest earthquake for the JTF. The JTF continues as far southeast as the Heihe River and shows predominantly left-lateral strike-slip displacement. The left-lateral slip rate is 0.27–0.48 mm/yr since late Pleistocene, much larger than the vertical slip rate of 0.05 ± 0.01 mm/yr. The latest rupture event of the JTF is slightly before 1 ka, which could be related to the poorly-recorded 756 CE earthquake in Hexi Corridor, and is also associated with fresh offset during this earthquake in the geomorphology of the east segment of the JTF. Strike-slip offset in this earthquake is estimated as 3.2 ± 0.4 m, with a rupture length of at least ∼13 km, indicating a moment magnitude of 6.4–7.2. We estimate the recurrence interval as 8–13 ka, based on the size of the latest offset and the slip rate of 0.27–0.48 mm/yr. These results indicate that the strike-slip continuation of the Altyn Tagh Fault dominates the slip behaviour of the JTF. The small strike-slip rate, and the match between the strike-slip of the JTF and the vertical slip of the North-South Normal Faults (NSF) at its eastern end, permit the interpretation that the slip of Altyn Tagh Fault is completely accommodated by crustal extension at the NSF, and dies out at the eastern end of the Jinta Nanshan region.

Co enrichment and Au–Cu–Co association in the Yundukala deposit in East Junggar, NW China: An in situ LA-ICP-MS study

The Yundukala deposit is a newly discovered Au–Cu–Co deposit located in the northern margin of Junggar in the Central Asian Orogenic Belt. The Au–Cu–Co mineralization is associated with the contact zone between a dioritic intrusion and basalt. The formation of the vein mineralization can be divided into three mineralization stages: chlorite + pyrite, quartz + polymetallic sulfide, and quartz + calcite. Ore microscopy and in-situ laser ablation inductively coupled plasma mass spectrometry were used to investigate textural and compositional relationship between pyrite, chalcopyrite, arsenopyrite, and cobaltite. The gold in the deposit is present in two main mineralogical forms: native gold (micron inclusions of the gold) and invisible gold (solid solution of gold). Cobalt in the vein mineralization is primarily associated with cobaltite, whereas pyrite, chalcopyrite, arsenopyrite, and pyrrhotite contain small amounts of cobalt. There is a positive correlation between As and Au in Py-Ⅱ (R2Au-As = 0.9211; R2Au-As = 0.4306) and cobaltite and a positive correlation between Co and Au in cobaltite (R2Au-Co = 0.8168). This relationship supports a model in which arsenic plays a role in the occurrence of gold. The correlation of trace elements in minerals and the formation sequence and interpenetration relationship between minerals indicate the progressive geochemical evolution of a single ore-forming fluid arising from a single vein mineralizing event. Hydrothermal processes led to alteration of the surrounding rocks while simultaneously extracting Au, Cu, and Co, forming ore-forming fluids. As physical conditions changed, minerals began to precipitate, ultimately resulting in the formation of ore deposits during the Carboniferous period (354–353 Ma).

Geochemical fingerprinting of continental crust trapped in Cadomian volcanic arcs along northern Gondwana

During the Ediacaran to Cambrian periods, the extensive Avalonian–Cadomian accretionary orogen formed along the northern margin of the Gondwana (Pannotia) supercontinent. One of the best-preserved magmatic arcs within this orogenic system is the Davle volcanic complex (DVC) in the Teplá–Barrandian unit of the Bohemian Massif. Using detailed field observations, petrography, major/trace element concentrations, Nd–Hf isotopic compositions as well as U–Pb zircon dating, we interpret a complex evolutionary history of the DVC as comprising three main stages. The first stage (∼610–570 Ma) is represented by a volcano-plutonic association of andesite, dacite, rhyolite and tonalite–trondhjemite–granodiorite (metamorphosed to orthogneiss). A wide range of major/trace element contents together with highly variable εNd values (+3.6 to –5.1) suggest derivation from a juvenile (mantle-derived) source with subsequent assimilation of cratonic crust during magma emplacement, also supported by the modelling of the assimilation–fractional crystallization (AFC) process. The second stage (∼580–560 Ma) is characterized by a gradual termination of the volcanic arc activity, followed by a deposition of marine siliciclastic succession comprising, from the bottom to the top, laminated tuffs, silicified black shales (Lečice Member), and a thick turbidite greywacke–shale–conglomerate sequence (Štěchovice Group). The third stage of poorly constrained age (∼570–500 Ma) is represented by an intra-arc extension and intrusion of juvenile trondhjemite and related rhyolite dykes (εNd +4.8 to +8.4). Finally, we compare these findings with zircon U–Pb ages and whole-rock Nd isotopic data from other Cadomian terranes and propose that the cratonic crust played an important role in recycling along the whole orogenic belt. Thus, we conclude that the Cadomian Orogen formed as a collage of fringing (such as modern Japan, Taiwan, or Philippines) and continental (as modern Andes) arcs of variable evolutionary stages rather than as a belt dominated by intra-oceanic island arcs.

Controls on the formation of Mn carbonates in mudrocks of the Datangpo Formation, Northern Margin Rift Basin, Yangtze Block

Deglaciation following the Sturtian Ice Age led to widespread manganese carbonate precipitates within marine mudrocks, reflecting unique climatic and oceanographic changes. The Mn carbonates hold economic importance in the Datangpo Formation, Yangtze Block, South China. Although their genesis in the Nanhua Rift Basin is well understood, little is known regarding their formation mechanism in the North Margin Rift Basin (NMRB). With growing interest in Mn ore exploration in this region, this study examines the weathering trend, climate patterns and watermass conditions using a variety of geochemical proxies. The results reveal two phases of climate variation during the deglaciation. Climate during the early phase (Phase I) was unstable, characterized by fluctuating values of Chemical Index of Alteration (CIA = 65 ± 4) and elevated Li isotope (8.8 ± 3.0‰) patterns. The degree of chemical weathering during the later stage (Phase II) was relatively stable (CIA = 65 ± 1, δ7Li = 5.4 ± 2.7‰), but the weathering intensity increased due to the reduced denudation rate, possibly related to a shift in the basin development. Fe speciation data indicate euxinia prevailing much of the section. However, Mo and U enrichment (> 1) and fluctuating ratios of Mo versus total organic content (0–40) suggest that pulses of freshwater influx associated with climate variation during Phase I caused the fluctuation of the chemocline along the continental shelf, facilitating the formation of Mn carbonates through the particulate Fe-Mn-hydroxide shuttle. With the establishment of stabilized climate, basin tectonics, and watermass circulation during Phase II, the accumulation of Mn carbonates in the sediments became less significant. The accumulation of Mn carbonates in the NMRB conforms to the “bathtub ring model”, distinct from the metallogenic model in the NRB, providing valuable guidance for Mn ore prospecting within this area and elsewhere with similar settings.

Nitrogen isotope gradient on continental margins during the late Paleoproterozoic

The late Paleoproterozoic was a key period in the evolution of Earth’s surface environments and life. It is generally accepted that during the 2.43–2.06 Ga Great Oxidation Episode, the atmospheric oxygen level rose to an intermediate state (0.1% to 10% of the present atmospheric level) and the chemical composition of the oceans changed significantly. The paleontological record indicates that eukaryotes appeared during the late Paleoproterozoic. Nitrogen, an essential nutrient for life, is thought to have been one of the key factors in eukaryote evolution. However, nitrogen bioavailability and spatial heterogeneity in nitrogen cycle in the late Paleoproterozoic oceans remain controversial. Here, we examine carbon and nitrogen cycling in the late Paleoproterozoic ocean, via analysis of redox-sensitive element contents and organic carbon and nitrogen isotope compositions of black shales of the ca. 1.9 Ga Nuvilic Formation of the Povungnituk Group, Cape Smith Belt, Canada. Two diamond drill-holes (DDHs) 718–3333 (∼50 m-long) and 4G8069 (∼90 m-long) investigated in this study contain turbiditic greywackes and black shales deposited on the northern margin of the Archean Superior craton below the storm wave-base. Sedimentary rocks of DDH 4G8069 might have been deposited closer to the continental source area, as indicated by sandstone abundance, than those of DDH 718–3333. Redox-sensitive element (V, U, and Mo) contents in black shales of DDH 4G8069 are low and show positive correlation with Al contents, whereas those of DDH 718–3333 are irregularly elevated. Fe/Al ratios of DDH 718–3333 are low, which likely reflect Fe loss from sediments under anoxic water-column conditions. Depositional environment is inferred to be above and below the redoxcline for DDHs 4G8069 and 718–3333, respectively. Organic carbon isotope values of DDH 718–3333 are approximately 1.7‰ lighter than those of DDH 4G8069, which might reflect methane cycling at the redoxcline. Nitrogen isotope values are positive (> +3‰) for all the black shale samples, corresponding to aerobic nitrogen cycling and presence of bioavailable nitrate on the northern margin of the Superior craton during the late Paleoproterozoic. Furthermore, nitrogen isotope values for DDH 718–3333 are approximately 2‰ heavier than those for DDH 4G8069. The observed isotopic heterogeneity is similar to that in modern oxygen-minimum zones and could represent intense denitrification at the redoxcline. Although no ca. 1.9 Ga microfossils reported to date are considered unambiguously eukaryotic, the aerobic nitrogen cycling inferred for the Nuvilic Formation, as well as for the previously studied Rove, Virginia, and Menihek formations, suggests that nitrogen limitation was unlikely to have inhibited biological evolution during the late Paleoproterozoic, a finding that is consistent with molecular clock studies suggesting that the emergence of eukaryotes occurred during the Paleoproterozoic.

Black Sea Morphotectonic Nature

Abstract The presence of oceanic crust on the Black Sea bottom indicates that this sea basin was a section - a Pontic Ocean gulf at the northern margin of the Phanerozoic Tethys Ocean. The late Phanerozoic subduction of the Tethys oceanic crust under the European continental massif in this area took place in the subduction zone, whose modern traces are found today south of the Crimean Peninsula. On the surface of the subducted oceanic crust were numerous fragments of the destroyed continental crust on the northern margin of the Gondwana continent. These relatively lighter than oceanic crust crustal fragments (or a significant part of them) were not subducted. They accumulate in the immediate vicinity of the subduction zone on the unsub ducted remnants of oceanic crust. Such is the case with the Black Sea. It is not an imposed subcontinental basin, but a last modern relict of the northern margin of the Late Phanerozoic Tethys Ocean.

Segmented growth of reactivated major bounding faults and their control on basin structures: Insights from the Nanpu Sag, Bohai Bay Basin, eastern China

AbstractA thorough insight into the initiation, segmentation, propagation and interaction of multitrend basin‐bounding faults is crucial to restoring the growth history of the faults and clarifying the fault growth pattern and its influence on the structures developed along the margin due to the growth of the basin‐bounding faults, but systematic studies on the individual influence of the evolution of each fault segment on the present structure are lacking. Based on 3D seismic data, the timing and growth of multitrend basin‐bounding faults were analysed using T‐z plots and throw backstripping, allowing us to determine the individual effects that each fault segment evolution exerteds on the present‐day configuration of the northern margin of the Nanpu Sag. The basin‐bounding fault is composed of the Xinanzhuang and Baigezhuang faults, and the Xinanzhuang fault comprises three linked segments with varying orientations (i.e., NE–SW, E–W, and NNE–SSW). In comparison, the Baigezhuang fault comprises only two linked NW–SE‐oriented fault segments. The evolution process can be divided into three stages. (1) During the early synrift I stage, namely, the isolated fault stage, five isolated multitrend basin‐bounding segments were active. (2) During the late synrift I stage, namely, the hard‐linkage stage, the five segments propagated laterally and linked with each other, behaving as a single fault. Meanwhile, the NE‐trending No. 5 Fault bifurcated upward from the basin‐bounding fault to accommodate local stress, and the NW‐trending Gaobei Fault deviated from the basin‐bounding fault controlled by local stresses induced by differential activities of the multitrend fault segments under the same far‐field stress. (3) During the synrift II to postrift linkage development stage, the extension orientation changed from NW–SE‐ to N–S, and additional displacement accumulated along the basin‐bounding fault without further lateral propagation. Newly formed E–W‐trending faults developed orthogonal to the extension orientation and linked with preexisting NE‐ or NW‐trending faults, forming a complex fault zone. In addition, influenced by the geometry of the basin‐bounding fault, the Laoyemiao Anticline formed by gravitational collapse under the dual action of a rollover anticline and transverse anticline. Furthermore, the evolution of the basin‐bounding faults played an important role in controlling the source‐to‐sink system, and the transition zone was the main provenance channel formed by the segmented growth of the faults. This study provides new insight into multitrend large fault evolution, and their impact on basin development provides a comprehensive explanation of the later structures developed in polyphase rifts.