Non-solvent Induced Phase Separation Research Articles

A novel, green, and environmentally friendly PBS/nano-CaCO3 hybrid membrane

Biodegradable membrane materials can be degraded into small molecules under natural conditions, which can effectively alleviate the environmental pollution caused by the waste of traditional organic membrane materials. In this work, biodegradable poly (butylene succinate) (PBS)/nano-CaCO3 hybrid membranes has been prepared via non-solvent induced phase separation method by blending environmentally friendly nano-CaCO3 particles with PBS. The incorporation of nano-CaCO3 particles into the membrane leads to a notable enhancement in mechanical strength, from 1.03±0.05 MPa to 1.42±0.13 MPa, resulting in a substantial increase of approximately 37 %. Additionally, the introduction of these particles also contributes to a reduction in contact angle, from 63° to 56°. Consequently, the issue of inadequate mechanical strength and limited hydrophilicity of PBS membrane is effectively addressed. Moreover, the pure water permeance of membrane increases from 8.5 L·m−2·h−1·bar−1 to 89.3 L·m−2·h−1·bar−1, and the permeability is greatly improved. The permeance recovery rate of the membrane increases from 78 % to 95 %, and the anti-fouling performance is improved. In addition, PBS can be degraded after the service of PBS/nano-CaCO3 hybrid membrane, and CaCO3 particles are environmentally friendly. Therefore, the PBS/nano-CaCO3 hybrid membrane hybrid membrane prepared in this study is a green and environmentally friendly membrane material.

Synergistic Interaction of Ionic Liquid Grafted Poly(vinylidene Fluoride) and Carbon Nanotubes to Construct Water Treatment Membranes with Multiple Separation Properties.

In this study, the dual strategy of 1-butyl-3-vinylimidazolium bromide ionic liquid (IL) grafting and carbon nanotubes (CNTs) nanocomposition was applied to modify poly(vinylidene fluoride) (PVDF)-based membranes. The highly hydrophilic/oleophobic and fouling-resistant PVDF-g-IL/CNTs membranes with excellent separation efficiency were obtained by the nonsolvent-induced phase separation method with ethanol-water mixed solution as the coagulation bath. The grafted IL not only generated hydrophilic groups on PVDF chains but also acted together with the CNTs to induce the formation of hydrophilic β-crystalline phase of PVDF, which significantly improved the hydrophilicity and pore structure of the modified PVDF membranes. As a result, the pure water flux of the optimal membrane increased up to 294.2 L m-2 h-1, which was 5.2 times greater than that of the pure PVDF membrane. Simultaneously, the electrostatic interaction of the positive IL and the integration of CNTs enhanced adsorption sites of the membranes, producing exceptional retention and adsorption of dye wastewater and oil-water emulsion. This study presents a straightforward and efficient approach for fabricating PVDF separation membranes, which have potential applications in the purification of various polluted wastewater.

Controlling the polymorphs of PVDF membranes: Effects of a salt additive on PVDF polarization during phase separation processes

Polyvinylidene fluoride (PVDF) membranes, acclaimed for their outstanding chemical resistance, thermal stability, and mechanical properties, play a crucial role in diverse industrial purification applications. While various methods have been employed for fabricating PVDF membranes such as thermally induced, evaporation-induced, vapor-induced, and nonsolvent-induced phase separation processes, controlling the polarity of PVDF chains using these techniques remains challenging. Recent studies have shown that the nonpolar α-phase PVDF is susceptible to organic acid fouling owing to hydrophobic interactions, whereas the β-phase PVDF has demonstrated polarity and offers antifouling properties. Herein, porous PVDF membranes predominantly composed of the β-phase were successfully fabricated by incorporating a small amount of LiCl salt into the PVDF dope solution. The addition of LiCl influences ion–dipole moments between ions and PVDF during phase separation, simultaneously affecting the PVDF chain arrangement and membrane morphology. Since the LiCl additive alters both the pore size and structure of PVDF membranes, both freestanding and non-woven supported membranes were prepared and characterized to assess the effects of polarity and pore size on fouling tendency. Characterizations of prepared PVDF membranes revealed considerable changes in the PVDF polymorph, membrane morphology, pore size, and antifouling properties upon introducing the salt additive. Our findings imply that β-phase–dominant PVDF membranes can be effectively utilized in water purification applications.

Highly Stretchable Polyurethane Porous Membranes with Adjustable Morphology for Advanced Lithium Metal Batteries.

A highly flexible, tunable morphology membrane with excellent thermal stability and ionic conductivity can endow lithium metal batteries with high power density and reduced dendrite growth. Herein, a porous Polyurethane (PU) membrane with an adjustable morphology was prepared by a simple nonsolvent-induced phase separation technique. The precise control of the final morphology of PU membranes can be achieved through appropriate selection of a nonsolvent, resulting a range of pore structures that vary from finger-like voids to sponge-like pores. The implementation of combinatorial DFT and experimental analysis has revealed that spongy PU porous membranes, especially PU-EtOH, show superior electrolyte wettability (472%), high porosity (75%), good mechanical flexibility, robust thermal dimensional stability (above 170 °C), and elevated ionic conductivity (1.38 mS cm-1) in comparison to the polypropylene (PP) separator. The use of PU-EtOH in Li//Li symmetric cell results in a prolonged lifespan of 800 h, surpasing the longevity of PU or PP cells. Moreover, when subjected to a high rate of 5 C, the LiFePO4/Li half-cell with a PU-EtOH porous membrane displayed better cycling performance (115.4 mAh g-1) compared to the PP separator (104.4 mAh g-1). Finally, the prepared PU porous membrane exhibits significant potential for improving the efficiency and safety of LMBs.

Investigating the impact of the sulfonation degree in sulfonated polyphenylsulfone (sPPSU) on PES/sPPSU polymer blend membranes

Polyethersulfone (PES) has widespread applications due to its excellent processability, mechanical strength, and chemical resistance. Nevertheless, its hydrophobic nature often leads to severe fouling and permeance decline. To improve the hydrophilicity of PES membranes, polymer blending is one of the most common methods. In this work, a series of sulfonated polyphenylene sulfones (sPPSU) with 1.9, 4.5, 8.2, 12.7, 19 degrees of sulfonation (DS) were synthesized and used to blend with PES. The PES/sPPSU blends were found to be compatible by calculating their theoretical enthalpy of mixing and measuring their glass transition temperatures (Tg's) at a blend weight ratio of 1:1. Ultrafiltration (UF) membranes were cast using the nonsolvent-induced phase separation (NIPS) method. It was found that 50/50 PES/sPPSU blend membranes with a DS equaling to or exceeding 8.2 eliminated finger-like macrovoids, resulting in a thinner and tight cross-sectional structure. A higher DS of sPPSU rendered the blend membranes with more hydrophilicity and oleophobicity as well as a more negatively charged surface. The unmodified PES membrane had rejections of 87.47 % and 91.5 % in ultrafiltration tests using feed solutions containing BSA and oil/water emulsion, respectively. The rejections could be further increased to 99.37 % and 97.17 % respectively by the blend membranes. The blend membranes consisting of a higher DS of sPPSU also exhibited a higher permeance, lower BSA absorption and better anti-fouling properties than the PES membrane.

Preparation and performance study of waste plastic blended ultrafiltration membrane

Waste plastic packaging bags (rPVC) and waste milk tea straws (rPLA) were used as membrane materials to prepare ultrafiltration (UF) membranes by the non-solvent induced phase separation (NIPS) method. The study aimed to investigate the influence of various factors, including different rPVC contents (10 wt%-20 wt%), membrane fractions (rPVC/rPLA), additive fractions (Pluronic F-127/PVP-K30), and different additive contents (0.5 wt%-3.0 wt%), on the performance of the membranes. The permeability, morphology, hydrophilicity, chemical composition, thermal stability, and antifouling properties of the blended UF membranes were thoroughly investigated. The experimental results revealed that the presence of rPLA and Pluronic F-127 increased the porosity, water absorption, pore size, and hydrophilicity of the blended UF membranes. Furthermore, the introduction of rPLA enhanced the thermal stability of the blended UF membranes. Additionally, the incorporation of Pluronic F-127 further improved the overall performance of the blended UF membranes. Specifically, it was found that the blended UF membranes achieved a pure water flux (PWF) of 192.50 L·m−2·h−1, while maintaining a bovine serum albumin (BSA) rejection rate of 95.20%. These results were obtained using a content ratio of rPVC/rPLA (90/10) at 14 wt% and an additive content of Pluronic F-127 at 2.5 wt%. By comparing with the blended UF membranes without introducing additives into the casting solution, the roughness (Ra) was reduced by 40.3%, the water contact angle (WCA) was reduced by 7.5%, the flux recovery rate (FRR) was increased by 80.5%, and the fouling resistance was enhanced.

Influence of PEG-PPG-PEG Block Copolymer Concentration and Coagulation Bath Temperature on the Structure Formation of Polyphenylsulfone Membranes.

The effect of amphiphilic block copolymer polyethylene glycol (PEG)-polypropylene glycol (PPG)-PEG concentration in the polyphenylsulfone (PPSU) casting solution and coagulation bath temperature (CBT) on the structure, separation, and antifouling performance of PPSU ultrafiltration membranes was studied for the first time. According to the phase diagram obtained, PPSU/PEG-PPG-PEG/N-methyl-2-pyrrolidone (NMP) systems are characterized by a narrow miscibility gap. It was found that 20 wt.% PPSU solutions in NMP with the addition of 5-15 wt.% of PEG-PPG-PEG block copolymer feature upper critical solution temperature, gel point, and lower critical solution temperature. Membrane composition and structure were studied by Fourier-transform infrared spectroscopy, scanning electron and atomic force microscopies, and water contact angle measurements. The addition of PEG-PPG-PPG to the PPSU casting solution was found to increase the hydrophilicity of the membrane surface (water contact angle decreased from 78° for the reference PPSU membrane down to 50° for 20 wt.%PPSU/15 wt.% PEG-PPG-PEG membrane). It was revealed that the pure water flux increased with the rise of CBT from 18-20 L·m-2·h-1 for the reference PPSU membrane up to 38-140 L·m-2·h-1 for 20 wt.% PPSU/10-15 wt.% PEG-PPG-PEG membranes. However, the opposite trend was observed for 20 wt.% PPSU/5-7 wt.% PEG-PPG-PEG membranes: pure water flux decreased with an increase in CBT. This is due to the differences in the mechanism of phase separation (non-solvent-induced phase separation (NIPS) or a combination of NIPS and temperature-induced phase separation (TIPS)). It was shown that 20 wt.% PPSU/10 wt.% PEG-PPG-PEG membranes were characterized by significantly higher antifouling performance (FRR-81-89%, DRr-26-32%, DRir-10-20%, DT-33-45%) during the ultrafiltration of bovine serum albumin solutions compared to the reference PPSU membrane prepared at different CBTs (FRR-29-38%, DRr-6-14%, DRir-74-89%, DT-88-94%).

A Radiative-Cooling Hierarchical Aligned Porous Poly(vinylidene fluoride) Film by Freeze-Thaw-Promoted Nonsolvent-Induced Phase Separation

A Radiative-Cooling Hierarchical Aligned Porous Poly(vinylidene fluoride) Film by Freeze-Thaw-Promoted Nonsolvent-Induced Phase Separation

Highly stable, antibacterial and antiviral composites films via improved non-solvent induced phase separation for textile application

Textile composites are ubiquitous in daily life and are one of the main ways in which bacteria and viruses spread. Highly effective antibacterial and antiviral flexible composites are effective for reducing microbe transmission. Herein, we reported an improved nonsolvent-induced phase separation method for the fabrication of flexible textile composites. Cu2O/polyurethane (Cu2OPU) composite films containing antibacterial and antiviral coatings were constructed using a Cu2O-polyvinyl butyral coagulation bath and binary solvent mixtures, yielding a composite that had excellent mechanical properties and stability and the components did not leach out. The as-prepared Cu2OPU composite films exhibited strong antibacterial and antiviral activity against Staphylococcus aureus and the H1N1 virus (above 99.99 % inactivation ratio). What’s more, Cu2OPU has excellent mechanical and environmental stability owing to the strong interfacial adhesion of Cu2O with the polymer matrix. Furthermore, it can withstand multiple washes and be suitable for daily use. Cu2OPU may be sustainably produced with great scalability, which may meet public, home, and textile applications.

Polypropylene membranes prepared via non-solvent/thermally induced phase separation: Effect of non-solvent nature

The goal of this work was to investigate the effect of non-solvent nature on the formation of porous membranes via non-solvent/thermally induced phase separation (N-TIPS). The hot solution of polypropylene (PP) in a mixture of dioctyl phthalate (DOP) and dibutyl phthalate (DBP) at 210 °C was placed as a thin film on a polyethylene terephthalate (PET) substrate, and then precipitated by immersion in the non-solvent (water, iso-propanol, 1-hexanol, or 1-decanol) at room temperature. It was found that the non-solvent nature greatly affected the morphology of the thin skin layer of the membrane facing the precipitation bath, which can be attributed to non-solvent induced phase separation (NIPS). The affinity between the polymeric solution and corresponding non-solvent was evaluated by using Hansen solubility parameters of components taken at room temperature and extrapolated to the temperature of 210 °C. An increase in the affinity between the non-solvent and the polymer transformed the surface layer structure from almost monolithic to cellular (with different pore sizes and porosity) and to spherulitic types. The non-solvent nature played a less pronounced role in the formation of the porous structure of the membrane bulk and the back side of the membrane (facing the PET substrate). Since the morphology of the rest of the membrane was correlated with thermophysical properties of non-solvents, it was concluded that the membrane formation took place due to temperature induced phase separation (TIPS). In the case of water, which has the highest cooling rate, the polypropylene crystallized by forming a “smectic” structure, while the standard α-lamellar structure was observed for other non-solvents. To gain insight into the TIPS process, a model of unsteady one-dimensional heat transfer was applied to simulate the change in the temperature profile of the hot, thin film of polymeric solution placed in the corresponding non-solvent. The resulting membranes were mainly in the microfiltration range with a mean through pore size of 0.05–0.61 μm, and iso-propanol permeance of 2.1–8.4 m3 m−2∙h−1∙bar−1. The rejection of 500 nm polystyrene microspheres was in the range of 45–98 %. The tensile strength was in the range of 2.9–3.2 MPa, and elongation at break was 30–190 % with respect to the non-solvent used.

Electrospun polycaprolactone/graphene oxide scaffolds with secondary surface porosity and gelatin-coating

Polycaprolactone (PCL) is a versatile and biodegradable synthetic polymer widely used in tissue regeneration applications owing to its versatility and mechanical properties. In this study, we employed a three-level strategy to develop innovative PCL-based scaffold biomaterials using electrospinning. First, we incorporated graphene oxide (GO); second, we introduced secondary surface porosity (SSP) through non-solvent induced phase separation (NIPS) with a diameter of approximately 2 μm; and third, we applied a gelatin coating (Gt). The inclusion of GO resulted in both a reduction in fiber size and a decrease in the size of the secondary surface pores formed on the fibers. Additionally, the incorporation of GO led to a noteworthy 20-fold increase in gelatin adhesion compared to pure SSP-PCL scaffolds. However, the mechanical properties of the gelatin-coated scaffolds exhibited a decrease compared to the uncoated scaffolds. This reduction is primarily attributed to the decrease in crystallinity in coating gelatin scaffold. Furthermore, GO and gelatin played critical roles in enhancing biodegradation and bioactivity, promoting hydroxyapatite formation on the surface of SSP-PCL scaffolds. In vitro cell viability tests demonstrated the cytocompatibility of PCL, PCL/Gt, and PCL/Gt/GO electrospun SSP scaffolds, facilitating the adhesion of human mesenchymal stem cells. Our study introduces an innovative strategy for fabricating PCL scaffolds through electrospinning, incorporating SSP for improved gelatin adsorption, and holds great promise for tissue engineering applications.

Superhydrophobic finishing of cotton fabric via nonsolvent-induced phase separation of polystyrene–perfluoropolyether block copolymer

This paper reports synthesis of polystyrene–perfluoropolyether block copolymer@cotton fabric (PS–PFPE@CF) with a rough structure through nonsolvent-induced phase separation. The factors affecting the hydrophobicity of the coating, such as solvent quality, the molecular weight of the PS segments, and the volume ratio of tetrahydrofuran/1,3-di(trifluoromethyl)benzene (THF/DTFMB) and THF–MeOH, were all investigated, and the relation between the coating structure and hydrophobicity was also analyzed. In the THF–DTFMB system, PS–PFPE@CF (4 h, 80 mg/mL) appeared as a secondary structure with the superposition of small spheres on large spheres. For this structure, the water-contact angle reached 156.2° ± 0.5° and the sliding angle was 9.5° ± 1.5°. Furthermore, scanning electron microscopy, energy-dispersive X-ray spectroscopy, atomic force microscopy, and thermogravimetric analysis confirmed that PS–PFPE coated the cotton fabric. Finally, application tests were performed to assess the application prospects of PS–PFPE@CF. Oil-water separation, self-cleaning, and antifouling applications were studied, and the experimental results showed that the separation efficiency of the superhydrophobic fabric was nearly constant, from 99.4 % to 98.3 % after 10 oil-water separation tests. PS–PFPE@CF exhibited excellent self-cleaning properties and performed well in the sandpaper abrasion and tape peeling tests. This research thus used a degradable PFPE block copolymer to produce cotton fabrics with excellent hydrophobicity, self-cleaning, and wear resistance.

Facile fabrication of regenerated cellulose-based separators for high-performance lithium-ion batteries by regulating degrees of polymerization

Cellulose-based separators have great application prospects in the field of lithium-ion batteries (LIBs) due to their excellent wettability and thermal stability. However, most current cellulose-based separators come from high-cost nanocellulose and bacterial cellulose. Herein, regenerated cellulose (RC) separators were prepared from dissolving pulp with different degrees of polymerization (DPs) by using the NaOH/urea/thiourea dissolution system as well as a nonsolvent-induced phase separation method. The results showed that the DP of cellulose had a significant influence on the mechanical properties, pore structure, and electrochemical properties of the resultant RC separator. An appropriate increase in the DP could improve the mechanical strength, porosity, and ionic conductivity of the separator. The RC separator with a DP of 599 exhibited the best performance with a porosity of 56.1 %, an average pore size of 305 nm, an electrolyte uptake of 339 %, a tensile strength of 38.3 MPa, and an ionic conductivity of 1.88 mS·cm−1. The lithium-ion battery prepared with the optimal RC separator had a specific capacity of 156.55 mAh/g for 100 cycles at a current density of 0.5 C and a coulombic efficiency of more than 96 %, which was a clear advantage over the commercially available Celgard2400 and cellulose separators. This work makes contributions to the development of high-performance LIBs separators from cellulose.

Preparation of Antioxidant and Antifouling Ultrafiltration Membrane by Co-blending Eugenol with Polyethylene Glycol-Modified Polyvinylidene Fluoride

Polyvinylidene fluoride-graft-polyethylene glycol methyl acrylate (PVDF-g-PEGMA) was prepared by grafting PEGMA onto PVDF using a homogeneous irradiation grafting method. After incorporating various concentrations of eugenol, a natural antioxidant component of clove oil, the membranes were fabricated through non-solvent induced phase separation. The results indicated that the addition of eugenol did not alter the inherent properties of the membrane but slightly reduced the pore size and water flux. The cyclic flux test showed that eugenol did not compromise the anti-fouling performance of the membrane, with the flux recovery ratio exceeding 93%. The antioxidant performance test revealed that eugenol enhanced the membrane’s capacity to remove free radicals and imparted oxidation resistance in NaClO solution, making the modified membrane suitable for use in oxidizing environments. This study successfully demonstrated a simple method to prepare a bifunctional membrane with anti-fouling and antioxidant properties, potentially extending its service life and applicability in oxidative contexts.

Improved Protein Removal Performance of PES Hollow-Fiber Ultrafiltration Membrane with Sponge-like Structure.

The research used polyethersulfone (PES) as a membrane material, polyvinylpyrrolidone (PVP) k30 and polyethylene glycol 400 (PEG 400) as water-soluble additives, and dimethylacetamide (DMAc) as a solvent to prepare hollow-fiber ultrafiltration membranes through a nonsolvent-induced phase separation (NIPS) process. The hydrophilic nature of PVP-k30 and PEG caused them to accumulate on the membrane surface during phase separation. The morphology, chemical composition, surface charge, and pore size of the PES membranes were evaluated by SEM, FTIR, zeta potential, and dextran filtration experiments. The paper also investigated how different spinning solution compositions affected membrane morphology and performance. The separation efficiency of membranes with four different morphologies was tested in single-protein and double-protein mixed solutions. The protein separation effectiveness of the membrane was studied through molecular weight cutoff, zeta potential, and static protein adsorption tests. In addition, the operating pressure and pH value were adjusted to improve ultrafiltration process conditions. The PES membrane with an intact sponge-like structure showed the highest separation factor of 11, making it a prime candidate membrane for the separation of bovine serum albumin (BSA) and lysozyme (LYS). The membrane had a minimal static protein adsorption capacity of 48 mg/cm2 and had excellent anti-fouling properties. When pH = 4, the BSA retention rate was 93% and the LYS retention rate was 23%. Furthermore, it exhibited excellent stability over a pH range of 1-13, confirming its suitability for protein separation applications.

A microfluid-on-microfluid phase separation strategy fabricates high-throughout porous polyimide separator for lithium-ion batteries

The microstructures and thermal stability of separators are critical for the safety and performance of lithium-ion batteries; however, it is still challenging to fabricate advanced separators simultaneously achieving uniform and high-throughput interconnected microporous structures with high thermal stability. Here, based on a soluble polyimide (PI) with high thermal stability, we report a microfluid-on-microfluid phase separation strategy (MF2-PS) to address the above challenge. Compared to the traditional non-solvent induced phase separation by immersion, the MF2-PS strategy can achieve more controlled porous structures with sponge-like open channels at submicron scale. The high surface polarity of the PI-separator also exhibited good wettability with liquid electrolytes, and a high electrolyte uptake (182 wt%) for achieving a high ion-conductivity. It also showed much superior thermal stability as compared to PP separator. Finally, due to the unique porous structures, the PI-separator by MF2-PS strategy successfully delivered a discharge capacity of 161.9 mA h g−1 for LiFePO4 electrode, and very stable cycling performance. All these results indicates that the PI-separator by MF2-PS may find significant applications in safe and high-performance batteries.

Ternary Phase-Field Simulation of Poly(vinylidene fluoride) Microporous Membrane Structures Prepared by Nonsolvent-Induced Phase Separation with Different Additives and Solvent Treatments.

In this study, an existing ternary membrane system based on nonsolvent-induced phase separation (NIPS) with a phase-field model was optimized. To study and analyze the effects of different additives on the formation of the skin layer and the effects of the three solvents on membrane characterization under the same conditions, two-dimensional simulations of the relevant parameters of a poly(vinylidene fluoride) (PVDF) membrane system were performed. The specific application of quaternary substances in ternary membrane systems was elaborated by determining the cohesive energy density between the additives and solvents, followed by the interaction parameters χ under the joint effect of the two. The results showed that the PVDF microporous membrane formed a dense surface layer at the mass transfer exchange interface, and with an increase in the poly(ethylene glycol) (PEG) concentration, the phase separation of the skin layer was predominantly transformed from liquid-solid partitioning to liquid-liquid partitioning; the number of membrane pores increased with increasing poly(vinylpyrrolidone) (PVP) concentration. The N,N-dimethylacetamide (DMAc) solvent system had the most stable thermodynamic properties; the dimethyl sulfoxide (DMSO) solvent system had mostly large pores running through the membrane and exhibited a porous structure. Related experiments also validated the model. Therefore, this model can be applied to other PVDF ternary membrane systems to better understand the structural development of microporous PVDF membranes under different conditions.

Structurally stable copolymer ultrafiltration membranes prepared via vinyl chloride suspension copolymerization and tannic acid in-situ modification integration

Polyvinyl chloride ultrafiltration membranes, widely used in various industries, are hindered by their high susceptibility to contamination. To address this concern, researchers have investigated diverse modification methods, encompassing surface modification and physical blending. Although surface modification provides stability, but it is intricate, expensive, and may result in pore clogging. Physical blending is a simpler approach but lacks durability and stability. Tannic acid (TA), a natural compound, has attracted attention for its potential in membrane modification due to its diverse benefits. However, the existing methods, such as TA-metal networks, encounter challenges of weakened stability and reduced permeability of membrane. To solve these issues, this research presents a novel approach that integrates suspension copolymerization, polyaddition, and a sol–gel process to fabricate structurally stable copolymer ultrafiltration membranes. Active sites for sol–gel reactions were embedded into the copolymer through copolymerization. Subsequently, TA was added to the copolymer casting solution, and isocyanate propyltriethoxysilane was decorated onto TA through a polyaddition reaction. Following this, a non-solvent induced phase separation method was used for membrane fabrication. During the formation of the membrane, a sol–gel reaction occurred between the copolymer and the modified TA, ensuring both stable chemical cross-linking. The membrane demonstrates excellent permeability, fouling resistance, and long-term operational stability. This innovative approach not only addresses compatibility and leakage issues associated with traditional methods but also ensures the stable integration of hydrophilic functional monomers within the copolymer matrix. The proposed method holds promise for advancing applications of ultrafiltration membrane technology in various complex environments.

Effect of layered transition metal dichalcogenide hybrid nanomaterials on the piezoelectric performance of non‐solvent induced phase separated polyvinylidene fluoride

AbstractLayered transition metal dichalcogenides (TMDs) with high aspect ratios enhance the alignment of polymer chains and induce a preferred orientation of the polymeric crystallites when incorporated into polyvinylidene fluoride (PVDF). In addition to offering an effective charge‐transfer mechanism, TMDs give PVDF more rigidity and piezoelectric qualities. This work reports the non‐solvent induced phase separation (NIPS) introduced while developing the PVDF/MoS2 composites. During the NIPS, the PVDF chains become phase‐separated, which induces high polarization in the PVDF matrix. Phase‐separated PVDF/MoS2 composites show high porosity and charge distribution attributed to the enhanced piezoelectric output voltage. While the neat PVDF demonstrated very feeble output voltage generation, the hybrid composite containing 2 wt.% of MoS2/ZnO facilitated almost 20 times higher performance (peak‐to‐peak voltage of 2.4 V). This work yielded a phase‐separated composite that finds uses in energy harvesting, sensors, and actuators, among other fields.Highlights NIPS creates high‐porosity composites with improved charge distribution. Layered TMDs improve charge‐transfer mechanism and PVDF's electrical properties. 2 wt.% MoS2/ZnO exhibits nearly 20 times higher voltage generation than neat PVDF.

Facile Lithium Densification Kinetics by Hyperporous/Hybrid Conductor for High-Energy-Density Lithium Metal Batteries.

Lithium metal anode (LMA) emerges as a promising candidate for lithium (Li)-based battery chemistries with high-energy-density. However, inhomogeneous charge distribution from the unbalanced ion/electron transport causes dendritic Li deposition, leading to "dead Li" and parasitic reactions, particularly at high Li utilization ratios (low negative/positive ratios in full cells). Herein, an innovative LMA structural model deploying a hyperporous/hybrid conductive architecture is proposed on single-walled carbon nanotube film (HCA/C), fabricated through a nonsolvent induced phase separation process. This design integrates ionic polymers with conductive carbon, offering a substantial improvement over traditional metal current collectors by reducing the weight of LMA and enabling high-energy-density batteries. The HCA/C promotes uniform lithium deposition even under rapid charging (up to 5mA cm-2) owing to its efficient mixed ion/electron conduction pathways. Thus, the HCA/C demonstrates stable cycling for 200 cycles with a low negative/positive ratio of 1.0 when paired with a LiNi0.8Co0.1Mn0.1O2 cathode (areal capacity of 5.0mAhcm-2). Furthermore, a stacked pouch-type full cell using HCA/C realizes a high energy density of 344Whkg-1 cell/951WhL-1 cell based on the total mass of the cell, exceeding previously reported pouch-type full cells. This work paves the way for LMA development in high-energy-density Li metal batteries.