A systematic TEM investigation of interstratified chlorite-biotite crystals showed that the crystals are composed of domains of periodically interstratified chlorite-biotite, non-periodically interstratified chlorite-biotite, biotite, and chlorite. The interstratified chlorite-biotite occurs as a vein filling and was apparently crystallized from a hydrothermal solution. The complex structure of the interstratified chlorite-biotite presumably results from a nonlinear growth phenomenon occurring under a nonequilibrium state. A simple nonlinear dynamics model derived from Duffing`s equation was constructed with an additional chemical potential that accounts for the variation of structural configuration of tetrahedral sheets or 2:1 layers in chlorite and biotite, a simple periodic fluctuation of hydrothermal fluid composition, and a simple damping force for two-dimensional lattice misfit on (001) resulting from the intergrowth of different types of layers with different structural configurations and other dissipation effects. Solutions to the equations of the model show that periodic interstratification, nonperiodic interstratification, and domains of the two end-member components (biotite, chlorite) can be formed during crystallization under various conditions. The nonperiodic sequences of biotite and chlorite layers along the c axis in the interstratified crystals produced by this model are chaotic rather than random. The calculations suggest that both periodic and nonperiodic interstratifications can result from periodic externalmore » force, e.g., compositional fluctuation of the fluid.« less
Read full abstract