A basilar property and a useful tool in the theory of Sobolev spaces is the density of smooth compactly supported functions in the space $W^{k,p}(\R^n)$ (i.e. the functions with weak derivatives of orders $0$ to $k$ in $L^p$). On Riemannian manifolds, it is well known that the same property remains valid under suitable geometric assumptions. However, on a complete non-compact manifold it can fail to be true in general, as we prove in this paper. This settles an open problem raised for instance by E. Hebey [\textit{Nonlinear analysis on manifolds: Sobolev spaces and inequalities}, Courant Lecture Notes in Mathematics, vol. 5, 1999, pp. 48-49].
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