Non-biodegradable Materials Research Articles

Influence of Drying Temperature in the Oven on Physical, Morphology and Mechanical Properties of Mycelium Composite

Mycelium, a root-like fungi network, possesses distinctive characteristics that render it an appealing contender for replacing polystyrene (PS). Drying in the oven is one of the most commonly used methods for producing mycelium composites. However, achieving its desired properties requires proper control of the drying temperature. This research aims to develop a mycelium-based composite by utilising an edible mushroom, specifically Pleurotus ostreatus (oyster mushroom), as an alternative to non-biodegradable materials for packaging applications. The composite is developed by inoculating Pleurotus ostreatus fungi into the substrate, mainly consisting of kenaf, wheat bran and CaCO3. Afterwards, the composite was incubated for 20 days and then subjected to drying at different oven temperatures (e.g. 40°C, 60°C, and 80°C) for 24 hours. Our findings indicate that the desirable mechanical properties of mycelium composite were found at 60°C, where flexural strength, flexural modulus and impact strength were obtained at 0.11 MPa, 4.15 GPa and 635.8 N, respectively. The moisture content was 26.13%, and the shrinkage was 20.73%. The obtained density of 0.15 g/cm3 was compared to the density of PS, which is 1.04 g/cm3. This research indicates that a lightweight composite material, consisting of a network of interconnected hyphae that function as a natural adhesive, holds significant potential as a viable solution for achieving a more sustainable and environmentally friendly future, primarily due to its biodegradability.

Biopolymers Derived from Forest Biomass for the Sustainable Textile Industry

In line with environmental awareness movements and social concerns, the textile industry is prioritizing sustainability in its strategic planning, product decisions, and brand initiatives. The use of non-biodegradable materials, obtained from non-renewable sources, contributes heavily to environmental pollution throughout the textile production chain. As sustainable alternatives, considerable efforts are being made to incorporate biodegradable biopolymers derived from residual biomass, with reasonable production costs, to replace or reduce the use of synthetic petrochemical-based polymers. However, the commercial deployment of these biopolymers is dependent on high biomass availability and a cost-effective supply. Residual forest biomass, with lignocellulosic composition and seasonably available at low cost, constitutes an attractive renewable resource that might be used as raw material. Thus, this review aims at carrying out a comprehensive analysis of the existing literature on the use of residual forest biomass as a source of new biomaterials for the textile industry, identifying current gaps or problems. Three specific biopolymers are considered: lignin that is recovered from forest biomass, and the bacterial biopolymers poly(hydroxyalkanoates) (PHAs) and bacterial cellulose (BC), which can be produced from sugar-rich hydrolysates derived from the polysaccharide fractions of forest biomass. Lignin, PHA, and BC can find use in textile applications, for example, to develop fibers or technical textiles, thus replacing the currently used synthetic materials. This approach will considerably contribute to improving the sustainability of the textile industry by reducing the amount of non-biodegradable materials upon disposal of textiles, reducing their environmental impact. Moreover, the integration of residual forest biomass as renewable raw material to produce advanced biomaterials for the textile industry is consistent with the principles of the circular economy and the bioeconomy and offers potential for the development of innovative materials for this industry.

Factors Influencing Solid Waste Management Practices and Challenges in Awi Administrative Zone, Northwestern Ethiopia

Background: Effective management of solid waste, generated as a result of human activities, is crucial. However, improper solid waste management seriously threatens the environment and public health in developing countries including Ethiopia.Objective: This study is aimed at assessing the status of solid waste management practices and identifying key factors in Awi Administrative Zone, Ethiopia.Methods: A community‐based cross‐sectional study design was used to collect the data and then analyze using descriptive statistics and logistic regression modeling. The survey was conducted in select kebeles (wards) (administrative subdivisions) of Injibara, Dangila, and Chagni towns, using two‐stage sampling techniques. Primary and secondary data sources were utilized. The per capita waste generation rate was calculated based on the total solid waste generated in kilograms per total family size of households per year.Results: The per capita per day solid waste generation rates for Injibara, Dangila, and Chagni were 0.443, 0.456, and 0.487 kg/capita/day, respectively. The composition of household solid waste mainly consisted of biodegradable and nonbiodegradable materials. It was concluded that a significant proportion of household solid waste comprised biodegradable organic matter, which could be efficiently recycled or decomposed through microbial activity. Of the households, 40.6% had access to door‐to‐door solid waste collection service, and 35.9% and 26.2% of the households disposed their solid waste on riverside bridge/drainage lines and roadside/open land, respectively. The regression analysis showed that the head of the household’s age, family size, monthly income, solid waste selling practice, solid waste reduction practice, awareness of solid waste disposal rules, frequency of household cleanup campaign participation, and awareness of the impacts of improper solid waste management on the environment and human health were significantly associated with improper solid waste management practices.Conclusion: The study revealed poor performance in solid waste management in the study area, attributed to factors such as inadequate collection system design and schedule, open burning of refuse, substandard condition of the final dumpsite, and lack of community awareness leading to illegal dumping.Recommendations: Based on the findings of the study, we recommend that the town municipality strengthen its door‐to‐door solid waste collection service and distribution of communal bin containers, conduct environmental assessments for better dumpsite selection, and implement a community‐based waste management system to ensure sustainable solutions and continuous education on proper solid waste management practices.

Biocomposites and Poly(lactic acid) in Active Packaging: A Review of Current Research and Future Directions

The alarming rise in environmental pollution, depletion of global resources, and increasing health consciousness have placed significant pressure on the development of eco-friendly, sustainable materials. Consequently, green, environmentally friendly materials made from biobased and/or biodegradable sources are gaining recognition and political support as sustainable alternatives to petroleum-based, non-biodegradable materials. Bio-based packaging materials, in particular, are widely used across all industrial sectors, with a growing demand for solutions that preserve food quality and extend shelf life. Within this context, the concept of “active packaging” (AP) is attracting considerable interest. While the traditional view of packaging materials is that they should be basically inert, active packaging involves intentional interactions with the packaged product or surrounding atmosphere, providing enhanced protection against degradation caused by human actions and environmental factors. This work aims to highlight the significant impact of biocomposites in the active packaging sector, driven by the synergistic integration of nanofillers and active agents, while providing an in-depth analysis of the key mechanisms and strategies underlying their functionality. Particular emphasis is placed on poly(lactic acid)(PLA), presenting a comprehensive review of innovative approaches to enhance the performance of PLA-based packaging, with a focus on improving antioxidant and antimicrobial properties to meet the demands of sustainable and efficient packaging solutions.

Sustainable Biopolymer-Based Electrochemical Sensors for Trace Heavy Metal Determination in Water: A Comprehensive Review

The growing concern over heavy metal contamination in environmental and industrial settings has intensified the need for sensitive, selective, and cost-effective detection technologies. Electrochemical sensors, due to their high sensitivity, rapid response, and portability, have emerged as promising tools for detecting heavy metals. Recent years have seen significant progress in utilizing biopolymer-based materials to enhance the performance of these sensors. Biopolymers, derived from renewable raw materials, have garnered considerable interest in both science and industry. These biopolymer-based composites are increasingly recognized as superior alternatives to conventional non-biodegradable materials because of their ability to degrade through environmental exposure. This review provides a comprehensive overview of recent advancements in biopolymer-based electrochemical sensors for heavy metal detection. It discusses various types of biopolymers and bio-sourced polymers, their extraction methods, and chemical properties. Additionally, it highlights the state of the art in applying biopolymers to electrochemical sensor development for heavy metal detection, synthesizing recent advances and offering insights into design principles, fabrication strategies, and analytical performance. This review underscores the potential of biopolymer-based sensors as cost-effective, eco-friendly, and efficient tools for addressing the pressing issue of heavy metal contamination in water and discusses their advantages and limitations. It also outlines future research directions to further enhance the performance and applicability of these sensors.

REVIEW PEMANFAATAN SAMPAH PLASTIK UNTUK ENERGI DAN BAHAN KONSTRUKSI

The problem of plastic waste has become a global concern due to its negative impact on the environment. Plastic, as a non-biodegradable material, results in significant pollution of soil and water. As plastic production increases, efforts to find innovative solutions in reducing environmental impact are important. This article discusses the use of plastic waste as an alternative energy source and construction material. Using a liter-tour review method from various sources that explores the potential of plastics to be converted into energy as well as their use in building materials and as aggregates in concrete. The results of the analysis show that the use of plastic waste can not only reduce pollution, but also provide economic and social benefits, especially as fuel oil and building materials such as paving plastic, plastic aggregate, asphalt plastic mixture.

Enhanced Thermal and Mechanical Properties of Sapodilla/PLA Biocomposites Using Filament Extrusion 3D Printing

Abstract The large-scale use of non-biodegradable materials, mainly comprising plastics, has raised serious environmental concerns for their viable alternatives. However, most of the biocomposites, including PLA-based matrix material, exhibit shortcomings in mechanical and thermal properties, thus posing serious barriers to their applications. Dealing with such challenges, the present work is related to the additive manufacture of biocomposites using Poly (lactic) acid (PLA) reinforced with sapodilla seed shell particulates through an FDM technique. PLA was mixed with different concentrations of SSS fillers such as 5, 10, 15, 20, and 25 wt.%. PLA and SSS were extruded into filaments used for 3D printing. The experimental results reported an improvement in tensile and flexural strength; in particular, the composites showed tensile and flexural strengths around 25.5 MPa and 49.46 MPa, respectively, which is an increase of about 51.25% and 27.6% as compared to the PLA matrix. However, the addition of SSS fillers did not have any significant influence on impact energy absorption. Thermal stability was checked using TGA, while its char residue increased from 1.15% to 2.59% in the composites, compared to pure PLA at 0.64%. These results clearly indicate that sapodilla seed shell fillers can overcome the inherent weaknesses of PLA, offering a promising solution toward lightweight and environmentally sustainable applications in additive manufacturing, such as biodegradable packaging materials and lightweight automotive interior components.

Review on need for designing sustainable and biodegradable face masks: Opportunities for nanofibrous cellulosic filters.

The surge in microbial illnesses, notably seen during the COVID-19 pandemic, has led to the global use of face masks-cloth, surgical, medical, and respirator types-to curb respiratory pathogen spread. Widely used by the public, patients, and healthcare workers, masks play a key role in reducing airborne transmission. However, synthetic, non-biodegradable materials in these masks have sparked environmental concerns due to disposal issues. Moreover, challenges like limited microbial filtration, poor fit, breathing resistance, and low reusability raise further issues, as does the failure to neutralize trapped microbes. Addressing these issues calls for high-performance, biodegradable masks crafted from renewable nanofibrous materials using advanced technology. Antimicrobial nanomaterial coatings can further reduce contamination risks for users and the environment. Nanofibrous materials, with their high surface area, enhance filtration, allow customization, and improve capture efficiency. Research is progressing on sustainable, biodegradable filters, particularly with cellulose materials. This review outlines mask types and limitations, spotlighting nanofibrous filters for their filtration efficiency, breathability, and sustainability. It also delves into nanofiber manufacturing and assesses bacterial cellulose-a promising renewable nanofibrous material suited for air filtration.

Exploitation of extruded polystyrene (XPS) waste for lightweight, thermal insulation and rehabilitation building applications

The present article investigates the possibility of Extruded Polystyrene (XPS) waste to be used as a lightweight aggregate in cement-based materials for structural applications. The developed material offers a promising solution for rehabilitation and energy efficiency upgrades of existing civil infrastructures, providing thermal insulation without adding excessive weight to reinforced concrete structures. Through a comprehensive experimental approach, this contribution evaluates the mechanical and thermal performance of cement-based composites with varying XPS content (up to 100 %) as sand replacement. Results demonstrate a balance between enhanced thermal insulation and maintained mechanical robustness, with optimal XPS content ranges identified for specific application needs. The incorporation of XPS waste into construction materials supports sustainability by repurposing non-biodegradable materials, while meeting the dual requirements of structural performance and energy efficiency. This research supports the exploitation of XPS-modified cement-based materials in structural rehabilitation of existing structures and innovative construction applications, promoting greener and more efficient building materials that could be utilized in ground structures, such as buildings.

Comparing the performance of a femoral shaft fracture fixation using implants with biodegradable and non-biodegradable materials.

Orthopedic injuries, such as femur shaft fractures, often require surgical intervention to promote healing and functional recovery. Metal plate implants are widely used due to their mechanical strength and biocompatibility. Biodegradable metal plate implants, including those made from magnesium, zinc, and iron alloys, offer distinct advantages over non-biodegradable materials like stainless steel, titanium, and cobalt alloys. Biodegradable implants gradually replace native bone tissue, reducing the need for additional surgeries and improving patient recovery. However, non-biodegradable implants remain popular due to their stability, corrosion resistance, and biocompatibility. This study focuses on designing an implant plate for treating transverse femoral shaft fractures during the walking cycle. The primary objective is to conduct a comprehensive finite element analysis (FEA) of a fractured femur's stabilization using various biodegradable and non-biodegradable materials. The study assesses the efficacy of different implant materials, discusses implant design, and identifies the optimal materials for femoral stabilization. Results indicate that magnesium alloy is superior among biodegradable materials, while titanium alloy is preferred among non-biodegradable options. The findings suggest that magnesium alloy is the recommended material for bone implants due to its advantages over non-degradable alternatives.

Synthesis and characterization of Borassus flabellifer flower waste-generated cellulose fillers reinforced PMC composites for lightweight applications

The development of eco-friendly materials is a challenging one in the research field. Natural fibers are more accessible, biodegradable, inexpensive, and less dense. They offer fewer health risks and are eco-friendly compared to synthetic fibers. Natural fiber-reinforced polymer composites are new, eco-friendly materials with excellent mechanical and practical applications. Adding biofillers to composites improves strength and will replace synthetic materials. Utilizing cellulose as a filler for a natural starch matrix is an effective way to reduce the environmental impact of non-biodegradable materials. This study covers the influence of natural Borassus flabellifer flower microcrystalline cellulose (BFF MCC) fillers on banana fiber-reinforced polymer matrix composites. Fourier-transform infrared spectroscopic peaks at 2357, 1730, and 1245 cm-1 were absent. This indicates that the amorphous proportion of banana fiber mat/BFF MCC-reinforced hybrid composites decreased. At 1% BFF MCC, thermogravimetric examination revealed an increase in the peak temperature of maximum degradation (389.6 °C). The hybrid banana composite’s tensile strength (31.36 ± 4.39 to 39.83 ± 3.07 MPa) and flexural strength (71.05 ± 2.66 to 82.4 ± 1.66 MPa) were also improved after adding 3% BFF MCC as filler material. The primary objective is to evaluate the suitability of fiber-reinforced hybrid polymers with natural fillers for future engineering applications such as automotive parts, construction materials, 3D printing, etc. In addition, this study investigated how the reinforcement of microcrystalline cellulose can result in a material with enhanced performance as well as its mechanical characteristics (XRD, FTIR, TGA, and SEM characterization).

Biodegradable Poly (L-Lactic acid) Fibrous Membrane with Ribbon-Structured Fibers and Ultrafine Nanofibers Enhances Air Filtration Performance.

Here, the poly (l-lactic acid) (PLLA) membrane with multi-structured networks (MSN) is successfully prepared by electrospinning technology for the first time. It is composed of micron-sized ribbon-structured fibers and ultrafine nanofibers with a diameter of tens of nanometers, and they are connected to form the new network structure. Thanks to the special fiber morphology and structure, the interception and electrostatic adsorption ability for against atmospheric particulate matter (PM) are significantly enhanced, and the resistance to airflow is reduced due to the "slip effect" caused by ultrafine nanofibers. The PLLA MSN membrane shows excellent filtration performance with ultra-high filtration efficiency (>99.9% for PM2.5 and >99.5% for PM0.3) and ultra-low pressure drop (≈20Pa). It has demonstrated filtration performance that even exceeds current non-biodegradable polymer materials, laying the foundation for future applications of biodegradable PLLA in the field of air filtration. In addition, this new structure also provides a new idea for optimizing the performance of other polymer materials.

Biomimetic and soft lab-on-a-chip platform based on enzymatic-crosslinked silk fibroin hydrogel for 3D cell co-culture

Integrating biological material within soft microfluidic systems made of hydrogels offers countless possibilities in biomedical research to overcome the intrinsic limitations of traditional microfluidics based on solid, non-biodegradable, and non-biocompatible materials. Hydrogel-based microfluidic technologies have the potential to transformin vitrocell/tissue culture and modeling. However, most hydrogel-based microfluidic platforms are associated with device deformation, poor structural definition, reduced stability/reproducibility due to swelling, and a limited range in rigidity, which threatens their applicability. Herein, we describe a new methodological approach for developing a soft cell-laden microfluidic device based on enzymatically-crosslinked silk fibroin (SF) hydrogels. Its unique mechano-chemical properties and high structural fidelity, make this platform especially suited forin vitrodisease modelling, as demonstrated by reproducing the native dynamic 3D microenvironment of colorectal cancer and its response to chemotherapeutics in a simplistic way. Results show that from all the tested concentrations, 14 wt% enzymatically-crosslinked SF microfluidic platform has outstanding structural stability and the ability to perfuse fluid while displayingin vivo-like biological responses. Overall, this work shows a novel technique to obtain an enzymatically-crosslinked SF microfluidic platform that can be employed for developing soft lab-on-a-chipin vitromodels.

Biodegradable, stretchable, and high-performance triboelectric nanogenerators through interfacial polarization in bilayer structure

The increasing demand for wearable electronics has led to the development of triboelectric nanogenerators (TENGs) as a promising energy harvesting and sensing technology. However, conventional TENGs often utilize non-biodegradable materials, contributing to environmental pollution. In this work, we present a stretchable and biodegradable TENG based on hydroxyethyl cellulose (HEC) and gelatin (HG-TENG). The HG-TENG features a bilayered structure, where the large difference in their relative permittivity between HEC and gelatin induces interfacial polarization, effectively mitigating charge recombination and enhancing triboelectric performance. The optimized HG-TENG achieves an open-circuit voltage (Voc) of 93 V, a maximum power density of 57.8 µW/cm2, and can power 38 blue light-emitting diodes. The device exhibits a stretchability of 150 % and biodegrades within 3 hours in phosphate-buffered saline. Furthermore, we demonstrate the application of the HG-TENG as a wearable sensor by modifying it with trichloro(1H, 1H, 2H, 2H-perfluorooctyl)silane (FOTS) (FHG-TENG). The FHG-TENG-based smart glove, integrated with machine learning algorithms, enables real-time monitoring of blood pressure waveforms and finger motions, showcasing its potential for human-machine interfaces. The smart glove, equipped with five FHG-TENGs on the proximal interphalangeal joints of each finger, detects diverse finger gestures and generates voltage signals that control a robotic hand in real-time, demonstrating effective human-machine interaction through synchronized motion. Moreover, the smart glove achieves a high recognition accuracy of 96.15 % for 10 different hand sign languages.

Synthesis of a Quaternary Ammonium-Halamine and Preparation on the Modified Nanofibrous Filter with Superior Sterilization, Air Filtration, and Biodegradability.

The outbreak of the 2019 coronavirus pandemic has raised worldwide attention about self-protection from airborne diseases. Air filtration and wearing mask have been proven to be effective measures in reducing the pathogenic aerosol's transmission. Those lead to an increasing demand of high-efficient filters. However, the nonbiodegradable polymeric materials used in filters can accumulate in landfills or ecosystems, potentially causing pollution after improper disposals. Sustainable and biodegradable alternatives to current filter materials are urgently needed. Yet, very few commercial filters meet these needs. In this paper, a novel quaternary ammonium-halamine compound containing Schiff base and a sandwich-structured preparation strategy were developed. The obtained multifunctional filter consists of a PLA fleece as a support layer, an antimicrobial coating for bactericidal function, and a nanofibrous membrane for the particle removal. The filter demonstrates strong bactericidal properties, killing 97% of Escherichia coli and Staphylococcus aureus at a biocide concentration of only 1 mg/mL. It can rapidly kill bacteria within 5 min contact without leaching antimicrobial substances. Furthermore, it boasts a filtration performance with a success rate over 99.99% and a pressure drop of 45 Pa, which surpasses that of commercial N95 filters for PM0.3. Even under humid conditions, it maintains excellent filtration performance. Our reusability testing result of the developed filters shows that a simple halogenation treatment can renew the halamines and restore the filter's antimicrobial activity. The filters can degrade in natural soil. The successful development of this sustainable and biodegradable filter material offers a new alternative for high-performance air quality control that protect public health.

Blast response and protection level of concrete composite wall panels made with recycled tyre fibres in a cement matrix

This paper investigates the blast response and protection level of a new blast-resistance wall panels made of Recycled Tyre Fibres Concrete (RTFC) as an exterior protective layer compositely connected to a concrete wall through experiments and numerical modelling. RTFC is a novel sustainable cement-based versatile composite, made with recycled non-biodegradable material (tyre rubber particles) in the form of composite fibres in a cement matrix, with applications in blast and ballistic protection that features high dynamic properties. Three composite wall panels were constructed and subjected to blast loads generated by Advanced Blast Simulator (ABS). Three different loading scenarios, each with an intensity capable of causing complete structural failure, were applied. The blast wave characteristics, such as the imposed overpressure and impulse, were measured alongside the deflection of the specimens. The wall specimens could withstand the blast loads with minimal damage. No cracks were observed in the RTFC layer, with only minor cracks appearing on the concrete side of the wall. The protection performance of the wall specimens was examined following UFC guidelines, revealing their outstanding resistance to blast loads. Moreover, in line with these guidelines, the composite wall panel is eligible for a High Level of Protection (HLoP) classification. Finally, a Single Degree of Freedom (SDOF) analytical model was developed for the wall panel to determine the Dynamic Increase Factor (DIF) of RTFC. The analysis resulted in a DIF value of 1.5, which was then incorporated into the numerical models of the walls. The accuracy of the DIF was validated by comparing the numerical results with experimental data, confirming its reliability.

Toward a green economy: Lignin-based hybrid materials as functional additives in flame-retardant polymer coatings

This study describes the combination of unique properties of lignin with TiO2 as an innovative and effective preparation method for high-performance flame-retardant additives that may be utilized as polymer coatings. The use of lignin resulted in numerous advantages including an increased number of functional groups, satisfactory biocompatibility, low toxicity, and high carbon content. The major benefit of lignin is associated with the reduced carbon footprint of the manufactured product. Lignin can be classified as a natural flame-retardant agent owing to the high amount of char formed during combustion. In turn, TiO2 exhibits high chemical stability and low operating costs and is considered a non-toxic and environmentally friendly material. During the experiments, commercial TiO2 in anatase crystallographic form, TiO2 synthesized from titanyl sulfate hydrate, and kraft lignin as well as organic–inorganic hybrid materials composed of these materials were evaluated as functional additives in epoxy-resin-based polymer coatings (Epidian 601) and their properties were investigated in detail. The cone colorimetry test confirmed that the obtained hybrids are effective flame-retardant additives for polymer coatings, with a notable fire hazard reduction observed for samples containing a synergistic system of titanium oxide and lignin. The coating with lignin was the most effective in fire suppression processes. The conducted thermal and mechanical investigations confirmed good performance properties of the coatings indicating thermal resistance up to 360 °C and Shore D hardness in a range of 80.36–86.28°Sh, accordingly. Optical profilometry investigations show that the lignin/TiO2 hybrids exhibit a stable topological surface shape as well as good dispersion and uniformity in the polymer matrix. All the conducted tests allowed confirmation that the presence of functional additives in polymer coatings in the form of lignin and TiO2 can be a promising alternative to non-biodegradable synthetic materials which improve flame-retardant properties.

Experimental Study of Plastic Bricks Made from Waste Plastics

This study describes the use of municipal plastic waste (MPW) in the construction industry. Plastic is a nonbiodegradable material that takes thousands of years to decompose and causes soil and water pollution. The amount of plastic waste in municipal solid waste (MSW) is increasing rapidly. Usage is estimated to double every decade. Plastic consumption is high and one of the largest plastic wastes is polyethylene (PE). The use of earth-derived clay materials has caused resource depletion and one of these efforts is the efficient use of plastic waste and laterite quarry waste, along with small amounts of asphalt, to meet the growing demand for traditional building materials, which are less absorbent than laterite bricks. The challenge is to develop alternative building materials, such as brick, that have little but sufficient strength. The use of MPW as a building material, especially in brick production, is one of the promising steps towards sustainable resource and waste management. Plastic waste can partially or completely replace one or more raw materials in brick production. Further research based on recent research and a better understanding of the use of waste plastics in bricks is needed to produce high-quality and durable bricks and to achieve an optimal balance in all aspects, especially in terms of cost and functionality.

Towards sustainable electronics: High-performance biodegradable polymer-based dielectric composite utilizing hydroxyapatite from cattle bone waste

Polymer-based film capacitors find widespread use in electronics and electrical systems, but the utilization of non-biodegradable dielectric materials contributes to excessive electronic waste. To address this issue, a biodegradable composite of hydroxyapatite (HAp) and poly (butylene adipate-co-terephthalate) (PBAT) was prepared and extensively characterized. HAp, as a filler, was synthesized via biomass-derived bone waste pyrolysis. The analyses confirmed successful HAp synthesis with high crystallinity and well-defined grain boundaries, which promote interfacial polarization and charge storage capability. The composite exhibited remarkable dielectric properties, with high dielectric constant, low dielectric loss, and good breakdown strength at low filler content. The PBAT/HAp-3 % composite showed significant energy storage density improvement (3.56 J/cm3), 43.55 % higher than pure PBAT (2.48 J/cm3), alongside enhanced mechanical properties and thermal stability. This study presents a cost-effective, eco-friendly route for next-generation high-performance disposable electronics.

Biodegradable Alternatives to Plastic in Medical Equipment: Current State, Challenges, and the Future

The use of plastic products or components in medical equipment and supplies results in challenges in terms of environmental sustainability and waste management for disposable, non-recyclable, and non-biodegradable materials. Medical plastic waste includes items ranging from syringes, tubing, intravenous (IV) bags, packaging, and more. Developing biodegradable replacements to petroleum-based plastics in medical equipment has not yet become an urgent priority, but it is an important endeavor. Examining alternatives involves several key themes, including material selection, testing, validation, and regulatory approval. To date, research includes studies on biodegradable polymers, composite materials, surface modifications, bacterial cellulose, three-dimensional (3D) printing with biodegradable materials, clinical trials and testing, collaboration with industry, regulatory considerations, sustainable packaging for medical devices, and life cycle analysis. The incorporation of bio-based and biodegradable plastics in the healthcare industry holds immense potential for reducing the environmental impact of medical plastic waste. The literature suggests that researchers and industry professionals are actively working towards finding sustainable alternatives that meet the stringent requirements of the medical industry. This paper reviews the efforts made so far to develop biodegradable and sustainable alternatives to plastic in medical equipment using a meta-analysis of resources, which include relevant papers published in English until June 2024. A total of 116 documents were found and screened by three reviewers for relevance. The literature reviewed indicated that various medical uses require plastics due to their unique properties, such as having strength and flexibility; being lightweight; and being able to prevent bacterial contamination. Among the alternatives, polycaprolactone (PCL), polylactic-co-glycolic acid (PLGA), starch-based acid, and polybutyric acid (PBS) have demonstrated favourable outcomes in terms of biocompatibility, safety, and efficacy. Additionally, a set of approaches to overcome these barriers and strategies is discussed alongside potential future solutions. This review aims to catalyze discussions and actions toward a more environmentally sustainable future in the medical industry by providing a comprehensive analysis of the current state, challenges, and prospects of this domain.