NNN Donor Ligands Research Articles

ChemInform Abstract: TERDENTATE NNN DONOR LIGANDS DERIVED FROM 2,6‐DIACETYLPYRIDINE

AbstractDas Diacetylpyridin (I) bildet mit den Aminen (II) die Schiffschen Basen (III), von denen (IIIa) mit Zink‐ und Nickel‐Salzen die Komplexe (IV) und (V) ergibt.

Terdentate NNN Donor Ligands Derived from 2,6-Diacetylpyridine

Abstract The Schiff base condensation of 2,6-diacetylpyridine with aniline, p-methoxyaniline and benzylamine gives high yields of 2,6-diacetylpyridine-bis (arylimines). Complexation of 2,6-diacetylpyridinebis (anil) with nickel (II) and zinc (II) to form five- and six-coordinate complexes of the types MCl2·L and [ML2] (C104)2 illustrates the versatility of these new terdentate NNN donor ligands.