Nitrogen-vacancy Center Spin Research Articles

Fluorescence thermometry enhanced by the quantum coherence of single spins in diamond

We demonstrate fluorescence thermometry techniques with sensitivities approaching 10 mK · Hz(-1/2) based on the spin-dependent photoluminescence of nitrogen vacancy (NV) centers in diamond. These techniques use dynamical decoupling protocols to convert thermally induced shifts in the NV center's spin resonance frequencies into large changes in its fluorescence. By mitigating interactions with nearby nuclear spins and facilitating selective thermal measurements, these protocols enhance the spin coherence times accessible for thermometry by 45-fold, corresponding to a 7-fold improvement in the NV center's temperature sensitivity. Moreover, we demonstrate these techniques can be applied over a broad temperature range and in both finite and near-zero magnetic field environments. This versatility suggests that the quantum coherence of single spins could be practically leveraged for sensitive thermometry in a wide variety of biological and microscale systems.

All-optical control of a solid-state spin using coherent dark states

The study of individual quantum systems in solids, for use as quantum bits (qubits) and probes of decoherence, requires protocols for their initialization, unitary manipulation, and readout. In many solid-state quantum systems, these operations rely on disparate techniques that can vary widely depending on the particular qubit structure. One such qubit, the nitrogen-vacancy (NV) center spin in diamond, can be initialized and read out through its special spin-selective intersystem crossing, while microwave electron spin resonance techniques provide unitary spin rotations. Instead, we demonstrate an alternative, fully optical approach to these control protocols in an NV center that does not rely on its intersystem crossing. By tuning an NV center to an excited-state spin anticrossing at cryogenic temperatures, we use coherent population trapping and stimulated Raman techniques to realize initialization, readout, and unitary manipulation of a single spin. Each of these techniques can be performed directly along any arbitrarily chosen quantum basis, removing the need for extra control steps to map the spin to and from a preferred basis. Combining these protocols, we perform measurements of the NV center's spin coherence, a demonstration of this full optical control. Consisting solely of optical pulses, these techniques enable control within a smaller footprint and within photonic networks. Likewise, this unified approach obviates the need for both electron spin resonance manipulation and spin addressability through the intersystem crossing. This method could therefore be applied to a wide range of potential solid-state qubits, including those which currently lack a means to be addressed.

Robust dynamical decoupling with concatenated continuous driving

The loss of coherence is one of the main obstacles for the implementation of quantum information processing. The efficiency of dynamical decoupling schemes, which have been introduced to address this problem, is limited itself by the fluctuations in the driving fields which will themselves introduce noise. We address this challenge by introducing the concept of concatenated continuous dynamical decoupling, which can overcome not only external magnetic noise but also noise due to fluctuations in driving fields. We show theoretically that this approach can achieve relaxation limited coherence times, and demonstrate experimentally that already the most basic implementation of this concept yields an order of magnitude improvement to the decoherence time for the electron spin of nitrogen vacancy centers in diamond. The proposed scheme can be applied to a wide variety of other physical systems, including trapped atoms and ions and quantum dots, and may be combined with other quantum technologies challenges such as quantum sensing and quantum information processing.

Measurement and Control of Single Nitrogen-Vacancy Center Spins above 600 K

We study the spin and orbital dynamics of single nitrogen-vacancy (NV) centers in diamond between room temperature and 700 K. We find that the ability to optically address and coherently control single spins above room temperature is limited by nonradiative processes that quench the NV center's fluorescence-based spin readout between 550 and 700 K. Combined with electronic structure calculations, our measurements indicate that the energy difference between the 3E and 1A1 electronic states is approximately 0.8 eV. We also demonstrate that the inhomogeneous spin lifetime (T2*) is temperature independent up to at least 625 K, suggesting that single NV centers could be applied as nanoscale thermometers over a broad temperature range.

Nitrogen-Vacancy-Assisted Magnetometry of Paramagnetic Centers in an Individual Diamond Nanocrystal

Semiconductor nanoparticles host a number of paramagnetic point defects and impurities, many of them adjacent to the surface, whose response to external stimuli could help probe the complex dynamics of the particle and its local, nanoscale environment. Here, we use optically detected magnetic resonance in a nitrogen-vacancy (NV) center within an individual diamond nanocrystal to investigate the composition and spin dynamics of the particle-hosted spin bath. For the present sample, a ∼45 nm diamond crystal, NV-assisted dark-spin spectroscopy reveals the presence of nitrogen donors and a second, yet-unidentified class of paramagnetic centers. Both groups share a common spin lifetime considerably shorter than that observed for the NV spin, suggesting some form of spatial clustering, possibly on the nanoparticle surface. Using double spin resonance and dynamical decoupling, we also demonstrate control of the combined NV center-spin bath dynamics and attain NV coherence lifetimes comparable to those reported for bulk, Type Ib samples. Extensions based on the experiments presented herein hold promise for applications in nanoscale magnetic sensing, biomedical labeling, and imaging.

Controllable effects of quantum fluctuations on spin free-induction decay at room temperature

Fluctuations of local fields cause decoherence of quantum objects. Usually at high temperatures, thermal noises are much stronger than quantum fluctuations unless the thermal effects are suppressed by certain techniques such as spin echo. Here we report the discovery of strong quantum-fluctuation effects of nuclear spin baths on free-induction decay of single electron spins in solids at room temperature. We find that the competition between the quantum and thermal fluctuations is controllable by an external magnetic field. These findings are based on Ramsey interference measurement of single nitrogen-vacancy center spins in diamond and numerical simulation of the decoherence, which are in excellent agreement.

Quantum measurements between a single spin and a torsional nanomechanical resonator

While the motions of macroscopic objects must ultimately be governed by quantum mechanics, the distinctive features of quantum mechanics can be hidden or washed out by thermal excitations and coupling to the environment. We propose a system consisting of a graphene nanomechanical oscillator (NMO) coupled with a single spin through a uniform external magnetic field, which could become the building block for a wide range of quantum nanomechanical devices. The choice of graphene as the NMO material is critical for minimizing the moment of inertia of the oscillator. The spin originates from a nitrogen-vacancy (NV) center in a diamond nanocrystal that is positioned on the NMO. This coupling results in quantum non-demolition (QND) measurements of the oscillator and spin states, enabling a bridge between the quantum and classical worlds for a simple readout of the NV center spin and observation of the discrete states of the NMO.

Detection and manipulation of single spin of nitrogen vacancy center in diamond toward application of weak measurement

A nitrogen vacancy (NV) center in diamond is studied as a solid state spin system realizing quantum information processing. In order to make such a system work as a qubit or a quantum memory, it is essential to have a full knowledge of interactions between the spins. Focusing on the properties of the NV center, of which the electron spin is experimentally accessible and can be transferred to a single nuclear spin, dynamics and interactions between the single spins can be known to the full extent. We aim at measuring a change of state of the single nuclear spin upon interaction with single NV electron spin in a short time interval. It corresponds to the weak measurement initiated by Aharonov et al., and through such a measurement the hyperfine interaction between the NV electron spin and the nuclear spin can be determined. As a first step toward such an experimental application of the weak measurement scheme, we carried out the detection of single NV centers with confocal laser microscopy and the measurement of the second-order autocorrelation function. We undertook an optically detected magnetic resonance (ODMR) to manipulate and read out the electron spin state and evaluated the static magnetic field applied at the single NV center from obtained ODMR spectra.

Instantaneous coherent destruction of tunneling and fast quantum state preparation for strongly pulsed spin qubits in diamond

Qubits driven by resonant strong pulses are studied and a parameter regime is explored in which the dynamics can be solved in closed form. Instantaneous coherent destruction of tunneling can be seen for longer pulses, whereas shorter pulses allow a fast preparation of the qubit state. Results are compared with recent experiments of pulsed nitrogen-vacancy center spin qubits in diamond.

Cavity enhanced spin measurement of the ground state spin of an NV center in diamond

A key step in the use of diamond nitrogen vacancy (NV) centers for quantum computational tasks is a single shot quantum non-demolition measurement of the electronic spin state. Here, we propose a high fidelity measurement of the ground state spin of a single NV center, using the effects of cavity quantum electrodynamics. The scheme we propose is based in the one-dimensional atom or Purcell regime, removing the need for high Q cavities that are challenging to fabricate. The ground state spin of the NV center has a splitting of ≈6–10 μeV, which can be resolved in a high-resolution absorption measurement. By incorporating the center in a low-Q and low volume cavity we show that it is possible to perform single shot readout of the ground state spin using a weak laser with an error rate of ≈7×10−3, when realistic experimental parameters are considered. Since very low levels of light are used to probe the state of the spin we limit the number of florescence cycles, which dramatically reduces the measurement induced decoherence approximating a non-demolition measurement of ground state spin.

Room-temperature manipulation and decoherence of a single spin in diamond

We report on room-temperature coherent manipulation of the spin of a single nitrogen-vacancy center in diamond and a study of its coherence as a function of magnetic field. We use magnetic resonance to induce Rabi nutations and apply a Hahn spin echo to remove the effect of low-frequency dephasing. A sharp rise in the decoherence rate is observed at magnetic fields where the nitrogen-vacancy center spin couples resonantly to substitutional nitrogen spins via the magnetic dipolar coupling. Finally, we find evidence that away from these energy resonances spin flips of nitrogen electrons are the main source of decoherence.

Long coherence times at 300 K for nitrogen-vacancy center spins in diamond grown by chemical vapor deposition

Electron-spin-echo experiments reveal phase-memory times as long as 58 μs at 300 K for nitrogen-vacancy centers in chemical vapor deposition (CVD) single crystals. The spins were optically polarized and optically detected. Two high-quality CVD samples were studied. From the current results, it is not clear whether these phase-memory times represent a fundamental limit or are limited by an external source of decoherence.