NiFe Layered Double Hydroxide Research Articles

Introducing carbon dots to NiFe LDH via a mild coprecipitation–aging method to construct a heterojunction for effective oxygen evolution

Modified NiFe-layered double hydroxide (NiFe LDH) materials with a high oxygen evolution reaction (OER) performance make it possible to replace noble metal catalysts for widespread applications.

Reinforcement of Electrocatalytic Oxygen Evolution Activity Enabled by Constructing Silver-Incorporated NiCo-PBA@NiFe-LDH Hierarchical Nanoboxes.

Complicated oxygen evolution reaction (OER) poses the bottleneck in improving the efficiency of hydrogen production through water electrolysis. Herein, an integrated strategy to modulate the electronic structure of NiFe layered double hydroxide (NiFe-LDH) is reported by constructing Ag-incorporated NiCo-PBA@NiFe-LDH heterojunction with a hierarchical hollow structure. This "double heterojunction" facilitates local charge polarization at the interface, thereby promoting electron transfer and reducing the adsorption energy of intermediates, ultimately enhancing the intrinsic activity of the catalyst. It is noteworthy that an exchange bias field is observed between NiCo-PBA and NiFe-LDH, which will be conducive to regulating the electron spin states of metals and facilitating the production of triplet oxygen. Additionally, the unique hierarchical nanoboxes provide a large specific surface area that ensures adequate exposure to adsorption sites and active sites. Profiting from the synergistic advantages, the overpotential is as low as 190mV at a current density of 10mAcm-2, with a low Tafel slope of 21mVdec-1. Moreover, density functional theory (DFT) calculation further substantiated that the incorporation of Ag in the heterojunction can effectively reduce the adsorption energy of reactant intermediates and enhance the conductivity.

Nanoporous Architecture of Mo Incorporated Nifeldh Oxygen Evolution Reaction (OER) Electrode for Efficient Water Electrolysis

Designing efficient catalysts with non-precious metals is of utmost significance for a sluggish anodic reaction (oxygen evolution reaction) in large-scale hydrogen production via electrochemical water splitting. Towards this endeavor, this work presents a simple and scalable methodology for binder free direct growth of Mo-doped NiFe-layered double hydroxides (NiFeLDH) on a nickel substrate by electrodeposition route at room temperature. A three-dimensional (3D) porous nanosheet architecture of electrocatalyst delivers immense electrochemical surface area as well as abundant catalytically active sites. In addition, Mo doping in the NiFeLDH plays a vital role in regulating the OER catalytic performance. Furthermore, the fabricated electrocatalyst exhibits low overpotential (230 mV) at 30 mAcm−2 for oxygen evolution reaction (OER) in an alkaline electrolyte with ultralow Tafel slope of ~28 mV dec−1 and retains exceptional stability for 100 h. Furthermore, the optimized Mo doped NiFeLDH electrode was used as an anode in single cell lab-scale system for alkaline water electrolysis at 80 °C with continuous flow of alkaline electrolyte. The single cell exhibits efficient electrochemical performance with a lower cell voltage of 1.80 V at a current density of 400 mA cm−2. Also, an admirable long-term cell durability is shown by the cell for 24 h. This work encourages new designs and further development of electrode materials for alkaline water electrolysis to the commercial scale.

Mechanism exploration in tetracycline degradation by Ni-Fe layered double hydroxide-biochar/peroxymonosulfate system: Nonradical-dominated oxidation process

Metal-based materials are widely regarded as promising catalysts for activating peroxymonosulfate (PMS) to remove refractory organic contaminants with high efficiency. In our study, Ni-Fe layered double hydroxide (LDH)-biochar (BC) composite-induced PMS-based advanced oxidation process (AOP) was utilized to elucidate the degradation of tetracycline hydrochloride (TCH). In Ni-Fe LDH-BC/PMS system, more than 99% TCH (45 μM) could be removed effectively at low doses of oxidant (PMS, 0.10 mM) and catalyst (Ni-Fe LDH-BC, 0.10 g/L) addition within 80 min. Besides, the Ni-Fe LDH-BC/PMS system showed high resistance to some inorganic anions, and the Ni-Fe LDH-BC composite possessed excellent reusability in the degradation of TCH (>99% in four cyclic experiments). The reaction mechanisms were investigated via electron paramagnetic resonance detection, chemical quenching tests, probe experiments, and electrochemical measurements. These results indicated that the electron-shuttle mechanism played the dominant role in the removal of TCH. It is worth noting that determination of PMS concentration can reflect the reliability of quenching experiments. In the Ni-Fe LDH-BC composite, BC could not only improve the dispersion of Ni-Fe LDH, but also increase the conductivity of Ni-Fe LDH. Overall, a successful modification strategy was proposed in our study to improve the catalytic property of Ni-Fe LDH, and reaction mechanisms of TCH degradation were discussed deeply and comprehensively.

Phosphorylated Co(OH)2@NiFe-LDH core–shell heterostructure for highly efficient alkaline water splitting

The development of transition metal bifunctional electrocatalysts with high activity, stability and cost-effectiveness is necessary for the overall water decomposition. In this work, a phosphorylated core–shell heterostructure bifunctional catalytic material with a nickel foam carrier, a Co(OH)2 nanowire array core and an ultrathin NiFe layered double hydroxide (NiFe-LDH) shell is synthesized. The solid contact between the NiFe-LDH shell and the highly conductive Co(OH)2 core brings about excellent electrical connectivity and an integrated hierarchical nanostructure that greatly improves the active specific surface area. Meanwhile, the phosphorylated hierarchical core–shell nanostructure enables the presence of a large amount of amorphous material at the edges, which leads to excellent activity and stability for oxygen evolution reactions (OER) and hydrogen evolution reactions (HER).

NiFe layered double hydroxides synthesized based on solvent properties as anode catalysts for enhanced oxygen evolution reaction

NiFe layered double hydroxides (LDH) with their high specific surface areas have been used as alternatives to noble metal catalysts for the oxygen evolution reaction (OER) in anion exchange membrane water electrolysis. However, for bulk LDH structures, relatively narrow interplanar distances can lead to the slow diffusion of OH− and the induction a local acidic atmosphere, resulting in catalyst corrosion. In this study, we synthesize solvent (water and ethanol) ratio-adjusted NiFe LDH anode catalysts to enhanced the OER. Results show that the catalyst prepared at a 5:5 ratio of water and ethanol (WE 55) delivers a low overpotential of 310 mV at 50 mA cm−2, Tafel slope of 40.5 mV dec−1, and 100 h-stability in a half-cell test, and a high current density of 744.2 mA cm−2 at 1.8 V and 70 °C in a single-cell test. WE 55 exhibits a manipulated oxygen vacancy and a substantially high specific surface area of ∼ 164.5 m2 g−1, leading to improved charge transfer and mass transport rates.

Enhancing Electrocatalytic Water Oxidation of NiFe-LDH Nanosheets via Bismuth-Induced Electronic Structure Engineering.

The design and synthesis of high-efficiency electrocatalysts are of great practical significance in electrocatalytic water splitting, specifically in accelerating the slow oxygen evolution reaction (OER). Herein, a self-supported bismuth-doped NiFe layered double hydroxide (LDH) nanosheet array for water splitting was successfully constructed on nickel foam by a one-step hydrothermal strategy. Benefiting from the abundant active sites of two-dimensional nanosheets and electronic effect of Bi-doped NiFe LDH, the optimal Bi0.2NiFe LDH electrocatalyst exhibits excellent OER performance in basic media. It only requires an overpotential of 255 mV to drive 50 mA cm-2 and a low Tafel slope of 57.49 mV dec-1. The calculation of density functional theory (DFT) further shows that the incorporation of Bi into NiFe LDH could obviously overcome the step of H2O adsorption during OER progress. This work provides a simple and effective strategy for improving the electrocatalytic performance of NiFe LDHs, which is of great practical significance.

Incorporation of Bimetallic Sulfide with Carbon Nitride for Advanced Na-Ion Batteries.

Sodium-ion batteries (SIBs) have received tremendous attention owing to their low cost, high working voltages, and energy density. However, the design and development of highly efficient SIBs represent a great challenge. Here, a unique and reliable approach is reported to prepare carbon nitride (CN) hybridized with nickel iron sulfide (NFCN) using simple reaction between Ni-Fe layered double hydroxide and dithiooxamide. The characterization results demonstrate that the hybridization with optimal amount of CN induces local distortion in the crystal structure of the hybrid, which would benefit SIB performance. Systematic electrochemical studies with a half-cell configuration show that the present hybrid structure exhibits a promising reversible specific capacity of 348 mAh g-1 at 0.1 A g-1 after 100 cycles with good rate capability. Simulation result reveals that the iron atoms in nickel iron sulfide act as a primary active site to accommodate Na+ ions. At last, with a full cell configuration using NFCN and Na3V2(PO4)2O2F as the anode and cathode, respectively, the specific capacity appears to be ≈95 mAh g-1 after 50 cycles at 0.1 A g-1 condition. This excellent performance of these hybrids can be attributed to the synergistic effect of the incorporated CN species and the high conductivity of nickel-iron sulfide.

Rapid and facile preparation of NiFe-layered double hydroxide nanosheets as self-supported electrode for glucose detection in drink sample

Layered double hydroxides have been widely used for electrochemical glucose detection due to their layered structure with more active sites, but they suffer from lower electrical conductivity and long-time hydrothermal preparation. In this paper, NiFe-layered double hydroxide nanosheets supported on nickel foam (NiFe-LDH NSs/NF) was prepared using an ultrafast and facile method via in-situ corroding foam nickel in FeCl3 solution under room temperature, and the whole synthetic process can be accomplished within several minutes. The as-fabricated NiFe-LDH NSs/NF shows significant catalytic activity in the glucose oxidation, showing its great promise in glucose detection. As a self-supported electrode, NiFe-LDH NSs/NF is favorable for glucose detection, with a sensitivity of 9.79 and 3.29 mA mM−1 cm−2 within the linear range of 0.001 to 1.16 mM and 1.16 to 4.67 mM, respectively. Moreover, NiFe-LDH NSs/NF is also selective and reliable towards glucose detection in drink sample.

Amine-Functionalized Graphene-Rich NiFe Layered Double Hydroxide Nanostructure for Enhanced Electrocatalytic Water and Urea Oxidation

Amine-Functionalized Graphene-Rich NiFe Layered Double Hydroxide Nanostructure for Enhanced Electrocatalytic Water and Urea Oxidation

Self-polarization-enhanced oxygen evolution reaction by flower-like core–shell BaTiO3@NiFe-layered double hydroxide heterojunctions

A flower-like core–shell heterostructured oxygen evolution reaction (OER) electrocatalyst based on tetragonal BaTiO3 nanoparticles (t-BTO NPs) and NiFe-layered double hydroxide (NiFe-LDH) nanoarrays was prepared in this study. The influence from the self-polarization effect of t-BTO on the OER performance of NiFe-LDH is reported. Intriguingly, the OER activity of the t-BTO@NiFe-LDH heterojunctions in an alkaline media (1.0 M KOH) exhibited a low overpotential of 186 mV at 10 mA/cm2 and a low Tafel slope of 38.3 mV dec-1, which were far superior to those of the component materials: NiFe-LDH (267 mV and 94.8 mV dec-1) and t-BTO NPs (517 mV and 132.4 mV dec-1). Density functional theory (DFT) calculations revealed that the effective electronic modulation between t-BTO NPs and NiFe-LDH nanoplatelets narrowed the bandgap, promoted the electric conductivity, moderately raised Ed (i.e., energy level of the d-band center), optimized the adsorption ability of the oxygen-containing intermediates (*O, *OH, and *OOH), and induced an apparent reduction in the free energy barrier for the transformation from O* to OOH* in the t-BTO@NiFe-LDH heterojunctions. The PDOS result confirmed that t-BTO in the heterojunctions was easier to polarize, which can cause the rapid electron transfer in the OER process. In these heterostructures, the interface tension between BTO NPs and NiFe-LDH endowed BTO with easier self-polarization, thus leading to greater band tilting and faster electron transfer. Multiple synergistic effects of the flower-like core–shell t-BTO@NiFe-LDH heterojunctions enabled them with higher electrocatalytic activity. This work provides an in-depth understanding of the rational design of a high-efficiency, noble metal-free ferroelectric OER electrocatalyst based on the self-polarization of t-BTO NPs.

Investigating the role of 3D hierarchical Ni-CAT/NiFe-LDH/CNFs in enhancing the oxygen evolution reaction and Zn-air battery performance

NiFe layered double hydroxide (NiFe-LDH) is an efficient and widely available catalyst for the oxygen evolution reaction (OER), but further improvement of its OER property remains a challenge. Therefore, a conductive Ni-organic framework is triumphantly synthesized in-situ on NiFe-LDH/carbon nanofibers (Ni-CAT/NiFe-LDH/CNFs) through a hydrothermal treatment. This configuration utilizes the exposed surface area and the electron transfer pathways of Ni-CAT and CNFs, resulting in exceptional OER kinetics in alkaline conditions. A low overpotential of 370 mV at 10 mA cm−2 and a small Tafel slope of 79 mV dec−1 are achieved. The liquid-state Zn-air batteries, featuring Ni-CAT/NiFe-LDH/CNFs catalyst as an air cathode, indicate a significant peak power density of 292.1 mW cm−2 and an extended cycle durability of over 66 h. Solid-state Zn-air batteries demonstrate stable cycling at various flat/bent/flat states, showing great potential for flexible electronic device applications. According to experimental measurements and computational analysis, the in-situ growth of Ni-CAT on the NiFe-LDH matrix can optimize intermediate adsorption and alter hydrophilicity, resulting in improved performance of Zn-air batteries.

Heterostructured MoO3 Anchored Defect-Rich NiFe-LDH/NF as a Robust Self-Supporting Electrocatalyst for Overall Water Splitting.

The rational design of inexpensive metal electrocatalysts with exciting catalytic activity for overall water splitting (OWS) remains a significant challenge. Heterostructures of NiFe layered double hydroxides (NiFe-LDHs) with abundant oxygen defects and tunable electronic properties have garnered considerable attention. Here, a self-supporting heterostructured catalyst (named MoO3/NiFe-NF) is synthesized via a hydrothermal method to grow NiFe-LDH with oxygen vacancies (OV) in situ on inexpensive nickel foam (NF). Subsequently, MoO3 is anchored and grown on the surface of NiFe-LDH by electrodeposition. The obtained catalysts achieved outstanding oxygen/hydrogen evolution reaction (OER/HER, 212mV/85mV@10mAcm-2) performance in 1mKOH. Additionally, when MoO3/NiFe-NF is utilized as the cathode and anode in OWS, a current density of 10mAcm-2 can be obtained as an ultralow battery voltage of 1.43V, a significantly lower value compared to the commercial electrolyzer incorporating Pt/C and IrO2 electrode materials. Finally, density functional theory (DFT) calculations and advanced spectroscopy technology are conducted to reveal the effects of heterojunctions and OV on the internal electronic structure of the electrical catalysts. Mainly, the present study provides a novel tactic for the rational design of remarkable, low-cost NiFe-LDH electrocatalysts with heterostructures for OWS.

Achieving long-term stable BiVO4 photoanodes for solar water splitting via carbon-layer protecting combined with active centers dynamic repairing

Although great interest is focused on highly active photoanodes for efficient photoelectrochemical (PEC) water splitting, the issue on improving stability during oxygen evolution reaction (OER) is seldom discussed by far. Herein, a simple chemical way to construct carbon functional interlayer between bismuth vanadate (BiVO4) and NiFe layered double hydroxide (NiFe-LDH) co-catalyst, combined with hydroxylation, can significantly improve the activity and stability. The enhanced electronic conductivity by carbon layer and formed strong polarization electronic field via surface hydroxylation, promote the interfacial charge transfer and bulk charge separation. More importantly, the carbon layer combined with more efficient redeposition of Fe active centers in NiFe-LDH catalysts caused by enhanced adsorption of Fe(III) onto Ni sites via hydroxylation, can greatly improve the OH-BiVO4@C@NiFe-LDH photoanode stability. With the synergistic effects of carbon functional interlayer and self-healing mechanism, OH-BiVO4@C@NiFe-LDH photoanode achieves extremely high photocurrent density (5.31 mA cm−2 at 1.23 versus the RHE), even maintaining more than 87.5 % of the initial photocurrent density within 20 h irradiation in KBi electrolyte with Fe(III) ions. This work provides a new strategy to enhance the performance of BiVO4–based photoanodes, especially for achieving long-term stability during OER.

Morphology Evolution of NiFe Layered Double‐Hydroxide Nanoflower Clusters from Nanosheets: Controllable Structure–Performance Relation for Green Energy Storage

NiFe‐layered double hydroxide (NiFe‐LDH) as electrode materials for supercapacitors are successfully prepared by green and one‐step hydrothermal method without template. The controllable structure–performance relation of NiFe‐LDH nanoflower clusters (NCs) for green energy storage is realized by regulating reaction time. The morphology evolution of NiFe‐LDH is elucidated. NiFe‐LDH‐24 h offers a unique NC structure and has specific capacitance of 635.8 F g−1 at 1 A g−1, which is larger than one of the reported pure NiFe‐LDHs so far. The improved electrochemical performance of NiFe‐LDH‐24 h NCs is due to its unique structure and synergistic effect between components that cause the larger specific surface area and more electroactive sites for Faradic reaction. The reaction kinetics reveals the electrochemical energy storage mechanism of the NiFe‐LDH‐24 h NCs. The energy storage is contributed by diffusion and surface capacitance. The electrochemical performance of NiFe‐LDH‐24 h NCs is further modified for the first time by doping F, and the specific capacitance of F‐doped NiFe‐LDH‐24 h NCs (1942 F g−1) is increased by 3 times higher than that of NiFe‐LDH‐24 h NCs. This work provides a more solid theoretical basis for green energy storage through morphology control and doping modification strategies.

Robust CoP@NiFe LDH/Ni heterostructured electrodes for efficient overall water splitting with high current density

Alkaline water electrolysis techniques have enormous potential for industrial-scale hydrogen generation, but a lack of effective and low-cost bifunctional electrocatalysts capable of steady high-current density operation has hampered progress. Layered double hydroxides (LDHs) have been considered promising OER electrocatalysts, but their poor electrical conductivity impedes hydrogen evolution reaction (HER) activity. Integrating LDHs with transition metal phosphides (TMPs) can potentially achieve bifunctional capability by overcoming individual limitations. Herein, CoP@NiFe LDH/Ni heterostructured catalyst was rapidly synthesized by a scalable two-step electrodeposition method. The integration of NiFe LDH with CoP enhanced its electrical conductivity. Meanwhile, electron transfer occurred from the metal atoms to the more electronegative phosphorus, facilitating phosphorus to act as a proton acceptor and expedite the HER process. Benefiting from the synergistic integration and optimized electronic structure, CoP@NiFe LDH/Ni exhibited excellent alkaline water-splitting performances with low overpotentials of 260 mV for HER and 351 mV for OER at 400 mA/cm2. The CoP@NiFe LDH/Ni two-electrode-based alkaline electrolyzer displayed a cell voltage of 2.13 V and stable operation for 100 h at a high current density of 1000 mA/cm2. This work elucidates a strategy to tackle critical challenges impeding the design and preparation of high-current-density tolerant bifunctional electrocatalysts.

Zn-Leaching Induced Rapid Self-Reconstruction of NiFe-Layered Double Hydroxides for Boosted Oxygen Evolution Reaction.

Optimizing the active centers through reconstruction is recognized as the key to construct high-performance oxygen evolution reaction (OER) catalysts. Herein, a simple and rapid in situ leaching strategy to promote the self-reconstruction of NiFe-layered double hydroxides (LDHs) catalysts is reported. The trace Zn dopants are introduced in advance by a facile and one-step hydrothermal method, followed by leaching over the electrochemical activation process, which can remarkably reduce the formation potential of NiFeOOH active centers to enable the deeper self-reconstruction for the formation of abundant highly active centers. Moreover, the self-restructured NiFeOOH-VZn cannot only significantly lower the dehydrogenation energy barrier for the transformation from Ni(OH)2 to NiOOH, but also decrease the free energy barrier of rate determining step for the *OH converted to *O through a deprotonation process, thus significantly boosting the OER behaviors. As a proof of concept, the obtained NiFeOOH-VZn catalyst just requires a low overpotential of 240mV at 10mAcm-2, and delivers robust stability at 50mA cm-2 over 120h, which outperforms the benchmark of noble metal RuO2 and those of most non-noble metal catalysts ever reported.

Integration of surficial oxygen vacancies and interfacial two-dimensional NiFe-layered double hydroxide nanosheets onto bismuth vanadate photoanode for boosted photoelectrochemical water splitting

Considering its outstanding cost-to-efficiency ratio, N-type bismuth vanadate (BiVO4) is an ideal photoanode for photoelectrochemical (PEC) water splitting. Nevertheless, the widespread application of BiVO4 is being hindered commercially by innate challenges such as its poor carrier mobility, short hole diffusion length, and sluggish oxidation chemistry. Herein, we report the unique integration of surficial oxygen vacancies (Ovac) in conjunction with two-dimensional (2D) nickel-iron (NiFe) layered double hydroxide (LDH) nanosheets onto pristine BiVO4 photoanode to tweak the charge transfer kinetics during water splitting. The introduction of oxygen vacancies efficiently modulates band energetics, amplifies light absorption, and augments the carrier density. Concurrently, the 2D NiFe-LDH nanosheets play a dual role by facilitating interfacial hole transfer, thereby reducing excessive defect states, and serving as a protective layer against photocorrosion, ultimately resulting in a notable improvement in solar-driven water oxidation efficiency. The results of PEC water-splitting experiments demonstrate that the BiVO4 photoanode enriched with surficial oxygen vacancies and NiFe-LDH (BiVO4:Ovac/NiFe-LDH) achieved a photocurrent density of 2.92 mA cm−2 with ∼3-fold enhancement compared with a pristine BiVO4 photoanode. The engineered BiVO4 system yielded an impressive photoconversion efficiency of 1.29 %, charge separation efficiency (ηsep) > 40 %, and charge transport efficiency (ηtrans) > 35 %, clearly evidencing a boost in the charge dynamics of pristine BiVO4. Furthermore, during long-term stability testing, BiVO4:Ovac/NiFe-LDH retained 91 % of its initial photocurrent density for ∼20 h without any significant deterioration. This work sheds light on the role of integrating surface and interface engineering tactics for enhancing photo-induced charge transport in BiVO4, thereby providing efficient and stable PEC water splitting.

Intrabasal Plane Defect Formation in NiFe Layered Double Hydroxides Enabling Efficient Electrochemical Water Oxidation.

Defect engineering has proven to be one of the most effective approaches for the design of high-performance electrocatalysts. Current methods to create defects typically follow a top-down strategy, cutting down the pristine materials into fragmented pieces with surface defects yet also heavily destroying the framework of materials that imposes restrictions on the further improvements in catalytic activity. Herein, we describe a bottom-up strategy to prepare free-standing NiFe layered double hydroxide (LDH) nanoplatelets with abundant internal defects by controlling their growth behavior in acidic conditions. Our best-performing nanoplatelets exhibited the lowest overpotential of 241 mV and the lowest Tafel slope of 43 mV/dec for the oxygen evolution reaction (OER) process, superior to the pristine LDHs and other reference cation-defective LDHs obtained by traditional etching methods. Using both material characterization and density functional theory (DFT) simulation has enabled us to develop relationships between the structure and electrochemical properties of these catalysts, suggesting that the enhanced electrocatalytic activity of nanoplatelets mainly results from their defect-abundant structure and stable layered framework with enhanced exposure of the (001) surface.

Cobalt Polyoxometalates Anchored on Nife‐LDH Nanoplates as Highly Active and Stable Bifunctional Catalysts for Overall Water Splitting

AbstractDesigning efficient and bifunctional electrocatalysts for water splitting conforms to the concept of energy conservation and emission reduction but remains challenging now. Herein, the fabrication of a heterostructure by anchoring cobalt‐polyoxometalates (Co‐POM) on NiFe layered double hydroxide (NiFe‐LDH) nanoplates in situ on nickel foam (NF) is first reported (Co‐POM@LDH/NF). The surface area, electron transfer ability, and stability of the heterostructure are increased due to the synergistic effect between Co‐POM and NiFe‐LDH. Particularly, Co‐POM@LDH/NF can deliver a current density of 100 mA cm−2 with an overpotential of only 220 mV for hydrogen evolution reaction (HER) and 226 mV for oxygen evolution reaction (OER) in 1.0 m KOH electrolytes. Impressively, the outstanding stability of Co‐POMs in heterostructures is verified by the experimental observations after electrolysis, indicating the successful construction of stable POMs‐based heterogeneous electrocatalysts. More attractively, the electrolyzer composed by Co‐POM@LDH/NF as anode and cathode shows a much lower operating voltage of 1.51 V at the current density of 10 mA cm−2 for overall water splitting. This study provides a feasible and extensible idea for the design of the POM‐based heterostructures.