NH3-N Volatilization Research Articles

Ammonia volatilization and nitrogen status in second-season corn after lime and gypsum application in no-till

In no-till (NT), liming and urea fertilization are performed on the soil surface, which can increase nitrogen (N) losses via ammonia volatilization. On the basis of N fertilization management, gypsum application provides a promising alternative for improving N uptake by plants. Therefore, the objective of this study was to evaluate the N behavior loss by NH3-N volatilization, the soil pH at a depth of 0 – 0.05 m, leaf N content, and N uptake by second-season corn after lime and gypsum application in a Rhodic Ferralsol under NT. Overall, the treatments consisted of a 4 × 4 factorial arrangement with four lime rates (0, 2.6, 5.4, and 8.1 Mg ha-1) and four gypsum rates (0, 4, 8, and 12 Mg ha-1). During the study period, second-season corn was cultivated for two years and fertilized with urea, for which the N losses through ammonia volatilization, soil pH, leaf N content, and N uptake values were quantified. The losses through ammonia volatilization were subjected to nonlinear regression using a logistic model, and the other variables were subjected to linear regressions. The lime applied by broadcasting on the soil surface in the NT increased the pH of the topsoil and increased N losses via NH3-N volatilization in the second-season corn. Further, the N losses in the NT treated with lime accounted for 58% of the applied N, which increased by 2.3 to 2.5% for each Mg ha-1 of lime applied. Therefore, lime or gypsum application did not improve the status of N in second-season corn in soils with low acidity and no S deficiency.

Nitrogen Fertilizers Technologies for Corn in Two Yield Environments in South Brazil.

Improvements in nitrogen use efficiency (NUE) in corn production systems are necessary, to decrease the economic and environmental losses caused by loss of ammonia volatilization (NH3-N). The objective was to study different nitrogen (N) fertilizer technologies through characterization of N sources, NH3-N volatilization losses, and their effects on the nutrient concentration and yield of corn grown in clayey and sandy soils in south Brazil. The treatments consisted of a control without N application as a topdressing, three conventional N sources (urea, ammonium sulfate, and ammonium nitrate + calcium sulfate), and three enhanced-efficiency fertilizers [urea treated with NBPT + Duromide, urea formaldehyde, and polymer-coated urea (PCU) + urea treated with NBPT and nitrification inhibitor (NI)]. The losses by NH3-N volatilization were up to 46% of the N applied with urea. However, NI addition to urea increased the N losses by NH3-N volatilization by 8.8 and 23.3%, in relation to urea alone for clayey and sandy soils, respectively. Clayey soil was 38.4% more responsive than sandy soil to N fertilization. Ammonium sulfate and ammonium nitrate + calcium sulfate showed the best results, because it increased the corn yield in clayey soil and contributed to reductions in NH3-N emissions of 84 and 80% in relation to urea, respectively.

The Efficiency of Stabilized Fertilizers in Reducing Ammonia Loss Is Influenced by Liming Method

ABSTRACT Urea is the most used nitrogen (N) fertilizer worldwide, but its rapid hydrolysis on the soil surface results in N loss in the form of ammonia (NH3-N). Enzyme inhibitors have been investigated for their ability to reduce NH3-N volatilization, particularly from no-till and surface-limed soils. This study assessed the efficiency of stabilized fertilizers in reducing NH3-N volatilization under different lime rates and application methods. The experiment followed a 2 × 4 × 3 factorial design, with two liming methods (surface application and incorporation), four base saturation levels (50, 60, 70, and 90%), and three urea (45% N) sources: conventional urea, urea + N-(n-butyl)-Thiophosphoric triamide (NBPT), and urea + Boron (B) + Copper (Cu). NH3-N volatilization losses varied from 9.15 to 20.43 kg ha−1, accounting for 11.4 to 25.5% of the applied N rate. Base saturation did not influence NH3-N volatilization. Liming method, however, had a significant effect. Urea + B + Cu was effective in reducing volatilization loss only in soils ameliorated by lime incorporation (23% reduction compared with conventional urea). Urea + NBPT was effective in surface-limed and incorporated soils (up to 55.5% reduction). The results showed that soil management influences the efficiency of stabilized fertilizers and that urea + NBPT provides the best results.

Controlled nitrogen transformation in chemo-amended urea improves nitrogen use efficiency and productivity of wheat grown on alkaline calcareous soil.

Low wheat production is linked to soil degradation, low organic matter, temperature variation, and nutrient depletion in soils of semiarid regions. Nitrogen is mostly applied as urea to meet crop requirements; however, excessive N application may pollute the environment and contaminate groundwater. The current studies explored possible ways for decreasing N losses (NH3 volatilization and NO3 leaching) and improving N availability for wheat production in alkaline soil. The ZnO was coated on urea (1% Zn coating) to get zinc-coated urea (ZnU), and both urea and ZnU were incubated in laboratory at recommended rate (RR), i.e., 150kgNha-1 and 80% (N of RR), after further coating with inhibitors [N-(n-butyl) thiophosphoric triamide (NBPT) at 1% of urea and 4-amino-1,2,4-triazole (ATC) at 2% of urea], thus creating six treatments. The results showed higher NH3-N loss at day 4 and thereafter a decreasing trend reaching to minimum at day 14. The cumulative NH3-N volatilization from urea alone was found higher (28.99%), except ATC treatments producing statistically similar losses due to restriction in nitrification process. In greenhouse, the treatments were tested in wheat cultivars (Faisalabad 2008 and Lasani) for crop growth, nutrient (N, P, K, and Zn) uptake, and yield parameters, where 80% of RR treatment, i.e., NBPT + ZnU80, was found at par with full RR as commercial products, especially comparable to ZnU (at RR) that produced the highest chlorophyll (53.65unit value), net leaf photosynthetic rate (19.64μmol CO2 m-2s-1), plant biomass (208.13g/pot), grain yield (63.65g/pot), and nutrient (NPK and Zn) accumulation in grain of Fsd-2008 cultivar. In field trial, NBPT + ZnU80 also outperformed and produced the highest physiological efficiency (PE), agronomic efficiency (AE), and nitrogen recovery efficiency (REN); the treatment also found statistically similar with ZnU (at RR) that produced the maximum plant height (95.4cm), plant biomass (11.58 t/ha), grain yield (4.69 t/ha), and 1000-grain weight (42.55g). The relative NO3 leaching was found lower in 80% N treatments, yet leaching was not significant from either treatment at the three stages of crop growth. Overall, current studies revealed the effectiveness of NBPT-amended urea (followed by ZnU) with 20% saving of N inputs through higher N availability for plant uptake that could benefit growers as well as conserve environment.

Gaseous Nitrogen Emission from Soil After Application of NH4+-N Loaded Biochar

To safely and effectively transfer NH4+-N from eutrophic water to soil, biochar was applied to adsorb NH4+-N from wastewater, and this NH4+-N loaded biochar (N-BC) was subsequently used as a soil amendment. Understanding the influence of N-BC on N2O-N emission and NH3-N volatilization is important for both decreasing the application of chemical fertilizers and reducing gaseous nitrogen loss from soil. In this study, experiments were conducted in soil columns with four treatments, namely CK (no fertilizer), NPK (chemical fertilizer), N-BC+PK (NH4+-N loaded biochar+chemical fertilizer), and BC+NPK (biochar+chemical fertilizer). Compared to both the NPK and BC+NPK treatments, N-BC+PK significantly reduced the cumulative N2O-N emissions and NH3-N volatilization, as well as the total gaseous nitrogen loss from the soil (P<0.05). Relative to NPK and BC+NPK, cumulative N2O-N emissions decreased by 33.62% and 24.64%, cumulative NH3-N volatilization decreased 70.64% and 79.29%, and the cumulative total gaseous nitrogen loss decreased by 64.97% and 73.75%. In particular, BC+NPK significantly enhanced the cumulative NH3-N volatilization. Furthermore, the N2O-N emission flux and NH3-N volatilization rate were significantly positively correlated with the NH4+-N concentration, NO3--N concentration, and pH of soil (P<0.01). Overall, using NH4+-N loaded biochar can significantly decrease N2O-N emissions and NH3-N volatilization, relative to the traditional application combining biochar and chemical fertilizer. This research provides solid theoretical support and data for the application of NH4+-N loaded biochar in soil, to reduce gaseous nitrogen loss.

Annual Nitrogen Balance from Dairy Barns, Comparison between Cubicle and Compost-Bedded Pack Housing Systems in the Northeast of Spain.

Simple SummaryEnvironmental concerns related to livestock production have driven the importance of developing manure-management alternatives to mitigate N emissions. Hence, we carried out measurements of N loss in two different dairy housing systems (compost-bedded pack vs. cubicles), each system with a very distinct manure-management procedure. Since each system performs different manure-management practices, it may be important to compare their efficiency in terms of N recovery from manure in both systems. In contemplation of annual temperature variation, measurements of N recovery after manure management were carried out during warm and cold seasons of the year. Significantly higher volatilization rates were found in compost-bedded pack system with respect to cubicles system, therefore, N left in manure was lower in compost-bedded pack barns.The aim of this study was to determine N recovery and irreversible losses (i.e., through NH3-N volatilization) from manure in two different housing systems throughout a year using an N mass balance approach. Dietary, milk, and manure N were monitored together with outside temperatures in six dairy barns during six months, comprising two different seasons. Three barns were designed as conventional free stalls (cubicle, CUB) and the other three barns as compost-bedded packs (CB). All the barns were located in the Ebro’s valley, in the northeast of Spain. Mass N balance was performed simultaneously in the six barns, during two three-month periods (Season I and II) and sampling at a 15-day interval. Results of ANOVA analysis showed that annual N retained in manure (kg/head per year) from cows housed in CUB barns was significantly higher than in manure from cows housed in CB (133.5 vs. 70.9, p < 0.001), while the opposite was observed for N losses (26.9 vs. 84.8, for CUB and CB barn, respectively; p < 0.005). The annual mean proportion of irreversible N loss from manure in relation to N intake was much lower in barns using conventional free-stall cubicles than the mean ratio registered in bedded pack systems barns.

Effect of Reducing Ammonia Volatilization from the Arable Soil with Iron Sulfate

Ammonia (NH3) reacts with nitric acid or sulfuric acid in the atmosphere and contributes to the formation of fine particulate matter. It is mainly produced by application of nitrogen fertilizer and livestock manure to the arable soil. Volatilization of NH3 could decrease with application of acidic amendments such as iron sulfate (FeSO4) through decreasing soil pH. This study was conducted to determine an optimum application rate of FeSO4 to reduce NH3 volatilization and maintain crop productivity in arable soil. Iron sulfate was applied at the rates of 0, 50, 100, and 200 kg Fe ha-1. Cabbage (Brassica rapa L.) was planted on April 8th 2020 and harvested on June 10th 2020. The NH3 gas was collected using static chamber (300 mm in length and 120 mm diameter) method. Cumulative NH3-N volatilization decreased significantly with increasing application rate of FeSO4. It decreased by ca. 21% at 200 kg Fe ha-1 of FeSO4. Soil pH decreased significantly with increasing application rate of FeSO4. A decrease in cumulative NH3-N volatilization with FeSO4 was mainly attributed to decrease in soil pH. Cabbage yield did not decreased with increasing application rate of FeSO4. The maximum cabbage yield was 7.10 Mg ha-1 and cumulative NH3-N volatilization decreased by 10.2% from 28.4 kg ha-1 63 days-1 to 25.8 kg ha-1 63 days-1 with 110 kg Fe ha-1 of FeSO4 application. Cumulative NH3-N volatilization from soils amended with different rates of FeSO4

Effects of three types of soil amendments on yield and soil nitrogen balance of maize-wheat rotation system in the Hetao Irrigation Area, China

Excessive fertilization combined with unreasonable irrigation in farmland of the Hetao Irrigation Area (HIR), China, has resulted in a large amount of nitrogen (N) losses and agricultural non-point source pollution. Application of soil amendments has become one of the important strategies for reducing N losses of farmland. However, there is still no systematic study on the effects of various soil amendments on N losses in the HIR. In this study, three types of soil amendments (biochar, bentonite and polyacrylamide) were applied in a maize-wheat rotation system in the HIR during 2015–2017. Yields of maize and wheat, soil NH3 volatilization, N2O emission and NO3- leaching were determined and soil N balance was estimated. The results showed that applications of biochar, bentonite and polyacrylamide significantly increased yields of maize by 9.2%, 14.3% and 13.3%, respectively, and wheat by 9.2%, 16.6% and 12.3%, respectively, compared with the control (fertilization alone). Applications of biochar, bentonite and polyacrylamide significantly reduced soil N leaching by 23.1%, 35.5% and 27.1%, soil NH3-N volatilization by 34.8%, 52.7% and 37.8%, and soil N surplus by 23.9%, 37.4% and 30.6%, respectively. Applications of bentonite and polyacrylamide significantly reduced N2O-N emissions from soil by 37.3% and 35.8%, respectively, compared with the control. Compared with application of biochar, applications of bentonite and polyacrylamide increased yields of maize and wheat by 5.1% and 3.5%, respectively. Our results suggest that soil amendments (bentonite and polyacrylamide) can play important roles in reducing N losses and increasing yield for the maize-wheat rotation system in the HIR, China.

A short-term effect of date palm biochars on NH3 volatilization and N transformation in calcareous sandy loam soil

A short-term incubation experiment (30-day) was conducted using a calcareous sandy loam soil (having pH of 7.65 and CaCO3 of 16.8) amended with urea (U) at application rate of 360 kg N ha−1 in the presence and absence of biochars (BCs) produced from date palm waste at two pyrolysis temperatures of 300 (BC300) and 500 °C (BC500) with application rate of (0 and 45 Mg ha−1) at different incubation temperatures of 15, 25, and 35 °C to investigate their short-term effects on soil ammonia (NH3-N) volatilization and different forms of nitrogen (N) transformation. The results showed that applying BC300 had 23.1% and 12.5% and 10.2% significant (P = 0.05) lower cumulative NH3-N volatilization than U treatment at incubation temperatures of 15, 25, and 35 °C, respectively. Meanwhile, applying high pyrolysis temperature BC (BC500) showed significant (P = 0.05) lower cumulative NH3-N volatilization only at 15 °C, which accounted for 21.9% lower than U treatment. The concentrations of ammonium (NH4-N) in the soil increased with the progress of incubation time and reached the maximum peak at days 3–15 of incubation. With the progress of incubation time, BC300-treated soil showed a higher concentration of NH4-N and ammonification rate than those of other treatments (U and U + BC500); however, BCs did not show significant effects on NO3-N concentration and nitrification rate. Hence, integrated use of urea and biochar pyrolyzed at 300 °C having acidic functional groups and high content of total acidity may serve as an efficient fertilization strategy for minimizing NH3-N volatilization and enhancing the available form of N in calcareous soils from an arid environment.

Enhancing Nutrient Use Efficiency Using Zeolites Minerals—A Review

On tropical soils, liming and balanced nutrient supply are essential to ensure high crop yield and quality. An adequate agronomic nutrient management should be a balanced nutrition and fertilizers are the key factor on supplying nutrients. Urea is the most commonly used fertilizer-N source, despite potential losses by NH3 volatilization. Thus, new fertilizers technologies are needed to support the increasing demand and avoid the low N use efficiency (NUE). The reduction of NH3-N volatilization can be achieved by the use of natural aluminosilicates with nitrogenous fertilizer materials. This review consolidates the current status on the subject and the experience with the application of aluminosilicates as a slow release plant-nutrient fertilizer. Volatilization losses of nitrogenous fertilizers on the soil surface could be reduced with addition of natural aluminosilicates. Clay minerals (zeolites) are widely used in many countries to reduce NH3 volatilization from amide N fertilizers, such as urea, besides several organic forms of nitrogenous sources. The reduction in ammonia losses by volatilization and the increased efficiency of N utilization and slow release nature of urea-zeolite mixtures when urea is used together with aluminosilicates was demonstrated in laboratory, greenhouse and field experiments with different crops and environments. These results indicate that aluminosilicates minerals used with urea mineral fertilizer can enhance the efficiency of this source by improving the nitrogen use through the control of retention of ammonium ion, contributing to increasd N uptake and crop yields.

Application effects of coated urea and urease and nitrification inhibitors on ammonia and greenhouse gas emissions from a subtropical cotton field of the Mississippi delta region

Nitrogen (N) fertilization affects both ammonia (NH3) and greenhouse gas (GHG) emissions that have implications in air quality and global warming potential. Different cropping systems practice varying N fertilizations. The aim of this study was to investigate the effects of applications of polymer-coated urea and urea treated with N process inhibitors: NBPT [N-(n-butyl)thiophosphoric triamide], urease inhibitor, and DCD [Dicyandiamide], nitrification inhibitor, on NH3 and GHG emissions from a cotton production system in the Mississippi delta region. A two-year field experiment consisting of five treatments including the Check (unfertilized), urea, polymer-coated urea (ESN), urea+NBPT, and urea+DCD was conducted over 2013 and 2014 in a Cancienne loam (Fine-silty, mixed, superactive, nonacid, hyperthermic Fluvaquentic Epiaquepts). Ammonia and GHG samples were collected using active and passive chamber methods, respectively, and characterized. The results showed that the N loss to the atmosphere following urea-N application was dominated by a significantly higher emission of N2O-N than NH3-N and the most N2O-N and NH3-N emissions were during the first 30–50days. Among different N treatments compared to regular urea, NBPT was the most effective in reducing NH3-N volatilization (by 58–63%), whereas DCD the most significant in mitigating N2O-N emissions (by 75%). Polymer-coated urea (ESN) and NBPT also significantly reduced N2O-N losses (both by 52%) over urea. The emission factors (EFs) for urea, ESN, urea-NBPT, urea+DCD were 1.9%, 1.0%, 0.2%, 0.8% for NH3-N, and 8.3%, 3.4%, 3.9%, 1.0% for N2O-N, respectively. There were no significant effects of different N treatments on CO2-C and CH4-C fluxes. Overall both of these N stabilizers and polymer-coated urea could be used as a mitigation strategy for reducing N2O emission while urease inhibitor NBPT for reducing NH3 emission in the subtropical cotton production system of the Mississippi delta region.

Assessing Tillage Systems for Reducing Ammonia Volatilization from Spring-Applied Slurry Manure

The effect of tillage management on NH3-N volatilization and its influence on succeeding corn (Zea mays L.) silage production were studied at the University of Massachusetts Agricultural Experiment Station (South Deerfield, MA) during 2010–2012 growing seasons. Tillage treatments consisted of disking before and after manure application, solid-tine aeration before and after manure application, and no-till management. The greatest NH3-N loss (61 percent) occurred within the first 8 h after slurry manure application regardless of tillage management. The greatest NH3-N emission occurred with surface application (no-till), which ranged between 5.2 and 10.3 kg NH3-N ha−1 (9–20 percent of NH3-N applied) over the 3 years of the study. Immediate incorporation of manure into soil through disking reduced NH3-N loss by 66 to 75 percent. Ammonia loss abatement with aeration before or after manure application ranged from 13 to 41 percent compared with surface manure application. Tillage management did not influence corn silage yield or quality.

Effects of Poultry Litter Injection on Ammonia Volatilization, Nitrogen Availability, and Nutrient Losses in Runoff

Poultry litter is a common organic amendment in agricultural production, but nutrient losses can reduce its effectiveness as a fertilizer. Three experiments were conducted to evaluate ammonia nitrogen (NH3-N) volatilization, N availability, and runoff losses of nutrients by conducting a closed chamber volatilization study, a soil incubation, and a rainfall simulation. In all studies, poultry litter was applied at a rate of 6.7 Mg · ha−1 either on the surface or injected and compared with an unamended control. In the volatilization and soil incubation studies, Braddock Loam and Bojac Sandy Loam surface soils were compared. Of the ammonium N added, cumulative loss of NH3-N by volatilization was 3% from injected and 121% from surface applied poultry litter after 7 days in the Loam. In the Sandy Loam, cumulative loss of NH3-N was 9% from injected and 153% from surface applied poultry litter after 7 days. After a 40-day soil incubation, injection increased total inorganic N by 52% and 99% for the Loam and Sandy Loam soils, respectively, when compared with surface application. Injection reduced total Kjeldahl N by 59%, total Kjeldahl P by 53%, dissolved reactive P, dissolved nitrate N by 73%, and dissolved NH3-N in runoff by 99%, compared with surface application. Injection reduced NH3-N volatilization and nutrients in runoff to levels of the control. These studies show that injection increases plant available N while decreasing losses through volatilization and runoff.

Nitrogen metabolism and route of excretion in beef feedlot cattle fed barley-based backgrounding diets varying in protein concentration and rumen degradability1,2

The objectives of the study were to characterize the effects of CP concentration and ruminal degradability of barley-based backgrounding diets on route and chemical form of N excretion, ruminal fermentation, microbial protein synthesis, and nutrient digestion in beef cattle. Four Angus heifers (479 ± 14.6 kg average BW) with ruminal and duodenal cannulas were used in an experiment designed as a 4 × 4 Latin square. The basal diet consisted of 54% barley silage and 46% barley grain-based concentrate (DM basis). Dietary treatments included the basal diet with no added protein (12% CP) or diets formulated to contain 14% CP by supplementation with urea (UREA), urea and canola meal (UREA+CM), or urea, corn gluten meal, and xylose-treated soybean meal (UREA+CGM+xSBM). The amount of feed offered was restricted to 95% of ad libitum intake. There was no effect of the diets on DMI (P = 0.38), and therefore, N intake was less (P < 0.05) in heifers fed the 12% CP diets than the 14% CP diets. Fecal N output was not affected by the diet (P = 0.15), but urine N (P < 0.10) and urea N output were greater (P < 0.05) in heifers fed the 14% CP than the 12% CP diets. There was no effect of CP degradability (P > 0.10) on the amount of urine N output. Urine N output was 38.9 and 45.1 ± 5.50% of N intake in heifers fed the 12% CP and 14% CP diets (P < 0.05), respectively. Urea N, the form of N most susceptible to NH3-N volatilization and loss, was the major form of N in urine (75.5% in heifers fed the 12% CP diet and 81.4 ± 1.7% in heifers fed the 14% CP diets; P < 0.05). Supplemental RDP (UREA+CM) and RUP combined with urea (UREA+CGM+xSBM) to provide 14% CP increased (P < 0.05) ruminal NH3-N but had no effect on ruminal peptide N (P = 0.62) and free AA N (P = 0.18) concentration, the flow of microbial (P = 0.34) and feed (P = 0.55) N, and ruminal (starch, P = 0.11; NDF, P = 0.78) and total tract nutrient digestibility (OM, P = 0.21; starch, P = 0.16). Supplementation of barley-based backgrounding diets containing 12% CP with NPN alone or combined with ruminally degradable and undegradable true protein to attain 14% CP had no effect on fecal N output, but urine N and urea N increased irrespective of protein source. In addition, the ruminal degradability of the protein sources did not influence the composition of protein flowing to the intestine and site and extent of nutrient digestibility.

Impacts of greenwaste biochar on ammonia volatilisation from bauxite processing residue sand

The objective of this study was to test the suitability of greenwaste biochar to aid nitrogen (N) retention in rehabilitated bauxite-processing residue sand (BRS). Bauxite residue sand was collected from the Alcoa of Australia Pinjarra refinery. The pH of BRS was adjusted to values of 5, 7, 8 and 9 and subsequently amended with different rates (1, 5, 10 and 20 %, w/w) of greenwaste biochar. The loss of N via NH3 volatilization following addition of di-ammonium phosphate (DAP) was determined using an acid trapping method. At low pH (5), increasing pH rather than adsorption capacity, resulting from biochar addition, caused greater losses of N through volatilization from BRS. In BRS with medium pH (7, 8), increasing adsorption capacity, induced by biochar addition, played the more dominant role in enhancing adsorption of NH 4 + -N /NH3-N and lowering NH3 volatilization. In the BRS with high pH (9), the majority of NH 4 + -N /NH3-N pools was lost via NH3 volatilization due to the strong acid-base reaction at this pH. It is concluded that the interaction of changes in pH and adsorption capacity induced by greenwaste biochar addition affects the availability and dynamics of NH 4 + -N/ NH3-N in BRS amended with DAP.

Volatilização de amônia proveniente de ureia com zeólita natural

O objetivo deste trabalho foi avaliar os efeitos da adição de zeólita a grânulos de ureia e dos diâmetros de grânulos nas perdas de NH3 por volatilização e na absorção de N pelo sorgo. Formulações de ureia com adição de zeólita e ligante orgânico, nos diâmetros menores que 2 mm, 2-4 mm e maiores que 4 mm e, sulfato de amônio e ureia-NBPT, foram aplicados à superfície do solo sobre bandejas, em casa de vegetação. A adição de zeólitas naturais à superfície dos grânulos de ureia ou à composição destes diminuiu as perdas por volatilização em 20% e aumentou a extração de N pelas plantas. A acumulação de N nas plantas de sorgo foi inversamente proporcional às perdas de N por volatilização.

USING THIOPAQ SULFUR FOR REDUCING NH3 VOLATILIZATION FROM CALCAREOUS SOILS AND INCREASING N USE

A laboratory and greenhouse studies were conducted to evaluate the effect of different rates (0.1, 0.5 and 1.0 ton ha-1) of THIOPAQ elemental sulfur (TES) application to the urea amended calcareous soils on NH3-N volatilization from soil surface and on N uptake efficiency by corn plants. In incubation experiment under laboratory conditions, daily ammonia loss was measured for up to 30 days after surface urea-N applied to soil (200 kg N ha-1) using closed dynamic airflow system. Results showed that daily NH3-N loss in tested soils were in the order: M. Ismail > Adam > Abu Bakr soils within the first 18 days of incubation then turned to Abu Bakr > Adam > M. Ismail soils until the end of experiment. Total NH3-N volatilization from urea-treated soils were 50.3, 49.8 and 66.6% of applied N in Abu Bakr, Adam and M. Ismail soils, respectively. Significant reductions in NH3-N volatilization were observed in urea amended with TES and this reduction increased by increasing applied TES rate. The percentage inhibition in NH3-N loss as a result of application of different TES to tested soils ranged between 14.60-37.52, 75.28 – 84.52 and 70.00 – 77.42 in Abu Bakr, Adam and M. Ismail soils, respectively. The reduction in NH3-N loss by TES was accompanied by a decrease in soil pH and increase in concentrations of water soluble SO42-. It is concluded that application of TES by rates 0.1 and 0.5 tons ha-1 had significant effect in reducing ammonia volatilization from surface applied urea. Results of greenhouse experiment showed that TES application and T. thiooxidans inoculation had significant effects on biomass production and N uptake by corn plant. Soil inoculation without addition of S increased N uptake in both shoots and roots by 22.25 and 19.5%, respectively, and reflects the promoting role for bacteria on N uptake. TES application significantly increased N uptake by plant shoots and roots and more uptake was obtained with applied TES and inoculation with T. thiooxidans.

Subsurface Application of Poultry Litter in Pasture and No‐Till Soils

Poultry litter provides a rich nutrient source for crops, but the usual practice of surface-applying litter can degrade water quality by allowing nutrients to be transported from fields in surface runoff while much of the ammonia (NH3)-N escapes into the atmosphere. Our goal was to improve on conventional titter application methods to decrease associated nutrient losses to air and water while increasing soil productivity. We developed and tested a knifing technique to directly apply dry poultry litter beneath the surface of pastures. Results showed that subsurface litter application decreased NH3-N volatilization and nutrient losses in runoff more than 90% (compared with surface-applied litter) to levels statistically as low as those from control (no litter) plots. Given this success, two advanced tractor-drawn prototypes were developed to subsurface apply poultry litter in field research. The two prototypes have been tested in pasture and no-till experiments and are both effective in improving nutrient-use efficiency compared with surface-applied litter, increasing crop yields (possibly by retaining more nitrogen in the soil), and decreasing nutrient losses, often to near background (control plot) levels. A paired-watershed study showed that cumulative phosphorus losses in runoff from continuously grazed perennial pastures were decreased by 55% over a 3-yr period if the annual poultry litter applications were subsurface applied rather than surface broadcast. Results highlight opportunities and challenges for commercial adoption of subsurface poultry litter application in pasture and no-till systems.

Effects of dicyandiamide, farmyard manure and irrigation on crop yields and ammonia volatilization from an alluvial soil under a rice ( Oryza sativa L.)-wheat ( Triticum aestivum L.) cropping system

Volatilization of NH3 from soil is a major N-loss mechanism that reduces the efficiency of applied N fertilizers, and causes environmental pollution. Strategies are needed to reduce the loss. The influences of dicyandiamide (DCD), farmyard manure (FYM) and irrigation on NH3 volatilization from an alluvial soil in rice (Oryza sativa L.)-wheat (Triticum aestivum L.) cropping system was studied using the acid trap method. The loss of NH3 in the rice-wheat system ranged from 38.6 kg N ha–1 from the unfertilized soil to 69.0 kg N ha–1 in the treatment with urea+DCD. Substitution of 50% N provided through urea by FYM reduced NH3-N volatilization by 10% in rice and wheat as compared to the urea treatment. Application of DCD increased NH3 volatilization in wheat by 7% but in rice it had no effect. The irrigation level had no effect on NH3 volatilization in rice but fewer irrigations with fewer splits of N in wheat resulted in higher NH3 volatilization. Application of DCD and FYM with urea had similar effects on grain yield and N uptake by rice and wheat as that of the urea treatment. The study showed that integrated use of organic manure and chemical fertilizer has the potential to reduce the loss of N due to volatilization and thereby minimize environmental pollution. Nitrification inhibitors, which are reported to be useful in increasing the N-use efficiency by reducing the leaching and denitrification losses of N, however, may increase N loss due to volatilization.

Influência da mistura de sulfato de amônio com uréia sobre a volatilização de nitrogênio amoniacal

Com o objetivo de avaliar a influência da mistura de sulfato de amônio com uréia sobre a volatilização de nitrogênio amoniacal (N-NH3), realizou-se um experimento em laboratório climatizado do Departamento de Solos e Nutrição de Plantas (ESALQ/USP). Em um delineamento inteiramente casualizado, foram utilizados cinco tratamentos com cinco repetições. Cada tratamento foi obtido pela mistura de uréia (330 mg) com sulfato de amônio (0, 75, 150, 225 e 300 mg). As misturas de fertilizantes foram aplicadas na superfície do solo (Latossolo Vermelho distrófico, textura média/arenosa) contido em recipientes plásticos de 400 cm³. O N-NH3, volatilizado aos 3, 8, 15 e 23 dias da incubação, foi coletado em recipiente com ácido sulfúrico e indicador alaranjado de metila. Variáveis que influenciam a qualidade da mistura de fertilizantes, como higroscopicidade, granulometria e ângulo de repouso, também foram avaliadas. A volatilização do N-NH3 depende do pH do solo. A mistura de uréia (330 mg) com sulfato de amônio (300 mg) reduziu significativamente as perdas de N-NH3 sem afetar a qualidade da mistura em relação aos atributos físico-químicos avaliados, apresentando eficiência técnica e agronômica para o fim proposto.