Network Transistors Research Articles

Inkjet-printed p-type tellurene and n-type MoS2 transistors for CMOS electronics

Abstract Two-dimensional semiconductor materials combine exceptional electronic transport properties with mechanical flexibility and hence can be an ideal choice for large-area flexible and wearable electronics. While inkjet printing may be a suitable approach to fabricate high throughput electronic components on polymer substrates, solution-processed 2D semiconductor network transistors suffer from two major hindrances: extremely high inter-flake resistance and the lack of high-performance p-type semiconductors. This study shows that inkjet-printed tellurium nanowires or tellurene nanoflakes can offer high-performance p-type TFTs with current density up to 100 μA/μm and an On-Off ratio >105. In order to circumvent the high inter-flake junction resistance, a narrow-channel, near-vertical device architecture has been used that ensures predominantly intra-flake/ intra-nanowire transport, which resulted in three orders of magnitude increase in the current density compared to conventional devices without compromising on the On-Off ratio. Moreover, we show the whole device operation within ± 2 V, with a threshold voltage close to 0 V. The complete device fabrication is carried out at room temperature, thereby making it compatible with inexpensive polymer substrates. Next, outstanding device performance has also been realized with electrochemically-exfoliated and inkjet-printed n-type MoS2 TFTs, demonstrating a current density of 60 μA/μm and an On-Off ratio of 106. Furthermore, we show tellurene-based p-type depletion-load unipolar inverters and CMOS inverters alongside n-type MoS2 TFTs, demonstrating a signal gain of 12 and 11, respectively. The CMOS inverters are found to operate at a frequency of 1 kHz.

Gate Capacitance Coupling of Double-Gate Carbon Nanotube Network Transistors.

Carbon nanotube (CNT) network channels constructed using a high-purity CNT solution for use in CNT thin-film transistors have the advantages of the possibility of requiring a low-temperature process and needing no special equipment. However, there are empty spaces between individual CNTs, resulting in unexpected effects. In this study, double-gate (DG) CNT network transistors were fabricated and measured in four different configurations to observe the capacitive coupling effects between the top gate (TG) and bottom gate (BG) in the DG structure. As a result, the electrical characteristics measured with the BG with a thicker gate oxide while floating the TG were similar to those measured with the TG with a thinner gate oxide. A comparison of the measured transfer curves showed that TG and BG were strongly coupled through the empty spaces in the channels. In addition, we evaluated the capacitance coupling effect due to changes in the CNT density, which is closely related to the empty space of the network channel. Finally, we proposed a method to determine the effective gate capacitance by considering the empty spaces between CNTs, which enabled the accurate evaluation of mobility. The effects of these materials were demonstrated by fabricating transistors using Al2O3, HfO2, and ZrO2 as TG oxide materials. By focusing on considerations based on the properties of CNT materials, our study provides valuable insights into accurate electrical modeling and potential advancements in CNT-based devices.

Wafer-scale striped network transistors based on purified semiconducting carbon nanotubes for commercialization

Highly purified and solution-processed semiconducting carbon nanotubes (s-CNTs) have developed rapidly over the past several decades and are near-commercially available materials that can replace silicon due to its large-area substrate deposition and room-temperature processing compatibility. However, the more s-CNTs are purified, the better their electrical performance, but considerable effort and long centrifugation time are required, which can limit commercialization due to high manufacturing costs. In this work, we therefore fabricated ‘striped’ CNT network transistor across industry-standard 8 inch wafers. The stripe-structured channel is effective in lowering the manufacturing cost because it can maintain good device performance without requiring high-purity s-CNTs. We evaluated the electrical performances and their uniformity by demonstrating striped CNT network transistors fabricating from various s-CNT solutions (e.g. 99%, 95%, and 90%) in 8 inch wafers. From our results, we concluded that by optimizing the CNT network configurations, CNTs can be sufficiently utilized for commercialization technology even at low semiconducting purity. Our approach can serve as a critical foundation for future low-cost commercial CNT electronics.

(Invited) Functionalized Polymer-Sorted Carbon Nanotube Networks for Sensing Applications

Networks of polymer-sorted, purely semiconducting single-walled carbon nanotubes (SWNTs) exhibit very high charge carrier mobilities, chemical stability and mechanical flexibility. Due to their large surface area they also permit a wide variety of modifications for sensing of gases, ions and even biomolecules. Exchanging the conjugated polymer used for the selective SWNT dispersion with specifically functionalized new wrapping polymers enables targeted sensing of analytes and improved devices performance. For example, spiropyran-functionalized polymer-nanotube hybrids can be used for dynamic optical memory devices and UV sensors (Adv. Electron. Mater. 2020, 6, 2000717). Other functional groups of the wrapping polymer promote the selective binding of copper ions and hence also the detection of the herbicide glyphosate in water by competitive binding using electrochemical SWNT network transistors. We further demonstrate how the performance of water-gated electrochemical SWNT transistors for bioelectronics (ACS Appl. Electron. Mater. 2021, 3, 3106) can be improved by exchanging the hydrophobic alkyl sidechains of the wrapping polyfluorene copolymer with hydrophilic tetraethylene glycol (TEG) groups. Thick, aerosol jet printed SWNT films with TEG sidechains show significantly increased volumetric capacitances and thus higher transconductances.

Cost-effective method for fabricating carbon nanotube network transistors by reusing a 99% semiconducting carbon nanotube solution

Carbon nanotubes (CNTs) are one-dimensional materials that have been proposed to replace silicon semiconductors and have been actively studied due to their high carrier mobility, high current density, and high mechanical flexibility. Specifically, highly purified, pre-separated, and solution-processed semiconducting CNTs are suitable for mass production. These CNTs have advantages, such as room-temperature processing compatibility, while enabling a fast and straightforward manufacturing process. In this paper, CNT network transistors were fabricated on a total of five 8 inch wafers by reusing a highly purified and pre-separated 99% semiconductor-enriched CNT solution. The results confirmed that the density of semiconducting CNTs deposited on the five selected wafers was notably uniform, even though the CNT solution was reused up to four times after the initial CNT deposition. Moreover, there was no significant degradation in the key CNT network transistor metrics. Therefore, we believe that our findings regarding this CNT reuse method may provide additional guidance in the field of wafer-scale CNT electronics and may contribute strongly to the development of practical device applications at an ultralow cost.

Inkjet‐Printed MoS2 Transistors with Predominantly Intraflake Transport

Abstract2D semiconductors, such as transition metal dichalcogenides (TMDs) show a rare combination of physical properties that include a large‐enough bandgap to ensure sufficient current modulation in transistors, matching electron and hole mobility for complimentary logic operation, and sufficient mechanical flexibility of the nanosheets. Moreover, the solvent‐exfoliated TMD‐nanosheets may also be processed at low temperatures and onto a wide variety of substrates. However, the poor inter‐flake transport in solution‐cast 2D‐TMD network transistors hinders the realization of high device mobility and current modulations that the intraflake transistors can regularly demonstrate. In this regard, fully printed and electrolyte‐gated, narrow‐channel MoS2 field‐effect transistors (FETs) with simultaneous high current saturation (>310 µA µm−1) and on–off ratio (>106) are proposed here. The transport limitation is overcome by printing an additional metal layer onto the 2D‐TMD nanosheet channel, which substantially shortens the effective channel lengths and results in predominant intraflake transport. In addition, a channel‐capacitance‐modulation induced subthermionic transport is recorded, which leads to a subthreshold slope value as low as 7.5 mV dec−1. On the other hand, thermionic MOSFETs and fully printed depletion‐mode NMOS inverters are also presented. The demonstrated generic approach involving chemically exfoliated nanosheet inks and the absolute device yield indicates the feasibility of fully printed 2D‐TMD electronics.

Wafer-scale carbon nanotube network transistors

Highly purified, preseparated semiconducting carbon nanotubes (CNTs) hold great potential for high-performance CNT network transistors due to their high electrical conductivity, high mechanical strength, and room-temperature processing compatibility. In this paper, we report our recent progress on CNT network transistors integrated on an 8-inch wafer. We observe that the key device performance parameters of CNT network transistors at various locations on an 8-inch wafer are highly uniform and that the device yield is impressive. Therefore, this work validates a promising path toward mass production and will make a significant contribution to the future field of wafer-scale CNT electronics.

Probing Mobile Charge Carriers in Semiconducting Carbon Nanotube Networks by Charge Modulation Spectroscopy.

Solution-processed networks of semiconducting, single-walled carbon nanotubes (SWCNTs) have attracted considerable attention as materials for next-generation electronic devices and circuits. However, the impact of the SWCNT network composition on charge transport on a microscopic level remains an open and complex question. Here, we use charge-modulated absorption and photoluminescence spectroscopy to probe exclusively the mobile charge carriers in monochiral (6,5) and mixed SWCNT network field-effect transistors. Ground-state bleaching and charge-induced trion absorption features as well as exciton quenching are observed depending on applied voltage and modulation frequency. Through correlation of the modulated mobile carrier density and the optical response of the nanotubes, we find that charge transport in mixed SWCNT networks depends strongly on the diameter and thus bandgap of the individual species. Mobile charges are preferentially transported by small bandgap SWCNTs especially at low gate voltages, whereas large bandgap species only start to participate at higher carrier concentrations. Our results demonstrate the excellent suitability of modulation spectroscopy to investigate charge transport in nanotube network transistors and highlight the importance of SWCNT network composition for their performance.

Percolation Effects in Electrolytically Gated WS2/Graphene Nano:Nano Composites.

Mixed networks of conducting and nonconducting nanoparticles show promise in a range of applications where fast charge transport is important. While the dependence of network conductivity on the loading level of conductive additive is well understood, little is known about the loading dependence of mobility and carrier density. This is particularly important as the addition of graphene might lead to increases in the mobility of semiconducting nanosheet network transistors. Here, we use electrolytic gating to investigate the transport properties of spray-coated composite networks of graphene and WS2 nanosheets. As the graphene loading is increased, we find that both conductivity and carrier density increase in line with the percolation theory with percolation thresholds (∼8 vol %) and exponents (∼2.5) consistent with previous reporting. Perhaps surprisingly, we find the mobility increases modestly from ∼0.1 cm2/V s (for a WS2 network) to ∼0.3 cm2/V s (for a graphene network) which we attribute to the similarity between WS2-WS2 and graphene-graphene junction resistances. In addition, we find both the transistor on- and off-currents to scale with loading according to the percolation theory, changing sharply at the percolation threshold. Through fitting, we show that only the current in the WS2 network changes significantly upon gating. As a result, the on-off ratio falls sharply at the percolation threshold from ∼104 to ∼2 at higher loading. Reflecting on these results, we conclude that the addition of graphene to a semiconducting network is not a viable strategy to improve transistor performance as it reduces the on:off ratio far more than it improves the mobility.

Ferroelectric polarization effect on hysteresis behaviors of single-walled carbon nanotube network field-effect transistors with lead zirconate-titanate gating

We report the fabrication of single-walled carbon nanotube (SWCNT) network transistors by ferroelectric Pb(Zr0.4Ti0.6)O3 (PZT) bottom-gating and investigate the polarization effects of PZT on the transport properties of the transistor device. Our devices exhibit typical p-channel transistor characteristics and a large hysteresis loop with high ON/OFF current ratio and large ON current as well as memory window (MW) measured up to 5.2 V. The origin of clockwise hysteresis is attributed to ferroelectric polarization modulated charge trapping/de-trapping process in the interface states between SWCNT networks and PZT. The retention time about 104s with two high stable current states preliminarily demonstrates great potential for future non-volatile memory applications based on such SWCNT/PZT hybrid systems.

Solution-processed polymer-sorted semiconducting carbon nanotube network transistors with low-k /high-k bilayer polymer dielectrics

Solution-processed semiconducting carbon nanotube transistors with a high mobility and an ON/OFF ratio are the most promising for use in flexible electronics. In this paper, we report low-k/high-k bilayer polymer dielectrics for solution-processed semiconducting single-walled carbon nanotube (s-SWNT) field-effect transistors (s-SWNT-FETs) with efficient charge transport and operation at low voltage. Thin low-k polystyrene (10 nm) is used for the first contact insulator with a channel in order to passivate the dipolar disorder induced by high-k insulators. The second gate insulator for low voltage operation is cyanoethyl pullulan (CEP), which is an environmentally friendly high-k insulator based on cellulose. Moreover, poly[(vinylidenefluoride-co-trifluoroethylene) is chosen as a single layer dielectric for comparison. A reasonably low operational voltage (<10 V) and high operational stability are achieved by the s-SWNT-FETs with polystyrene/CEP bilayer gate dielectrics. In addition, this indicates that the interface between the s-SWNTs and the low-k insulator is of critical importance for efficient charge transport.

Aerosol‐Jet Printing of Polymer‐Sorted (6,5) Carbon Nanotubes for Field‐Effect Transistors with High Reproducibility

Single‐walled carbon nanotubes (SWNTs) are a promising material for flexible and printed electronics. Efficient dispersion and sorting methods facilitate the production of large quantities of high‐quality semiconducting SWNT inks for direct printing. Here, the suitability of aerosol‐jet printing of polymer‐sorted (6,5) SWNTs for top‐gate field‐effect transistors is investigated. Despite the sonication involved in the printing process, almost no impact on the quality of the SWNTs in terms of defects and length is found. Printed network transistors show reproducible device performance over extended printing periods and for different ink batches with constant printing parameters. Deposition of multiple SWNT layers to obtain thicker and optically dense films increases the effective mobility and on‐conductance, while also decreasing hysteresis. Aerosol‐jet printing of SWNTs is thus suitable for the fabrication of integrated circuits based on nanotube transistors.

Doping-dependent G-mode shifts of small diameter semiconducting single-walled carbon nanotubes

We investigate the impact of electrochemical doping on the frequency of the G+-mode of a selection of polymer-sorted, nearly monochiral and semiconducting single-walled carbon nanotubes (SWCNTs) via in-situ Raman spectroscopy of ambipolar electrolyte-gated SWCNT network transistors. The purified semiconducting nanotubes have small diameters from 0.76 nm to 1.39 nm. In contrast to previous experimental data on large diameter nanotubes and current electron-phonon coupling theories, we find a pronounced red-shift (phonon softening) of the G+-mode at low to medium hole concentrations before an upshift is observed for larger hole concentrations. The effect is largest for those nanotubes with the smallest diameters. The pronounced dependence of these frequency shifts on the diameter of the semiconducting SWCNTs suggests that curvature effects start to play a significant role and should not be neglected.

Effect of Polymer Gate Dielectrics on Charge Transport in Carbon Nanotube Network Transistors: Low-k Insulator for Favorable Active Interface.

Charge transport in carbon nanotube network transistors strongly depends on the properties of the gate dielectric that is in direct contact with the semiconducting carbon nanotubes. In this work, we investigate the dielectric effects on charge transport in polymer-sorted semiconducting single-walled carbon nanotube field-effect transistors (s-SWNT-FETs) by using three different polymer insulators: A low-permittivity (εr) fluoropolymer (CYTOP, εr = 1.8), poly(methyl methacrylate) (PMMA, εr = 3.3), and a high-εr ferroelectric relaxor [P(VDF-TrFE-CTFE), εr = 14.2]. The s-SWNT-FETs with polymer dielectrics show typical ambipolar charge transport with high ON/OFF ratios (up to ∼105) and mobilities (hole mobility up to 6.77 cm2 V-1 s-1 for CYTOP). The s-SWNT-FET with the lowest-k dielectric, CYTOP, exhibits the highest mobility owing to formation of a favorable interface for charge transport, which is confirmed by the lowest activation energies, evaluated by the fluctuation-induced tunneling model (FIT) and the traditional Arrhenius model (EaFIT = 60.2 meV and EaArr = 10 meV). The operational stability of the devices showed a good agreement with the activation energies trend (drain current decay ∼14%, threshold voltage shift ∼0.26 V in p-type regime of CYTOP devices). The poor performance in high-εr devices is accounted for by a large energetic disorder caused by the randomly oriented dipoles in high-k dielectrics. In conclusion, the low-k dielectric forms a favorable interface with s-SWNTs for efficient charge transport in s-SWNT-FETs.

Electrical properties of carbon-nanotube-network transistors in air after gamma irradiation

We experimentally evaluate the electrical properties of carbon nanotube (CNT)-network transistors before and after 60Co gamma-ray irradiation up to 50kGy in an air environment. When the total dose is increased, the degree of the threshold voltage (Vth) shift towards positive gate voltages in the drain current–gate voltage (ID–VGS) characteristics decreases for total irradiation doses above 30kGy, although it is constant below 30kGy. From our analysis of the ID–VGS characteristics along with micro-Raman spectroscopy, the gamma-ray irradiation does not change the structure of the CNT network channel for total doses up to 50kGy; it instead generates charge traps near the CNT/SiO2 gate insulator interfaces. These traps are located within the SiO2 layer and/or the adsorbate on the device surface. The positively charged traps near the CNT/SiO2 interface contribute less to the Vth shift than the interface dipoles at the CNT/metal electrode interfaces and the segment of the CNT network channel below doses of 30kGy, while the contribution of the charge traps increases for total doses above 30kGy. Our findings indicate the possibility of the application of CNT-network transistors as radiation detectors suitable for use in air for radiation doses above 30kGy.

Investigation of optimal hydrogen sensing performance in semiconducting carbon nanotube network transistors with palladium electrodes

The work function of palladium (Pd) is known to be sensitive to hydrogen (H2) via the formation of a surface dipole layer or Pd hydride. One approach to detect such a change in the work function is based on the formation of a Schottky barrier between Pd and a semiconductor. Here, we demonstrate a H2 sensor operable at room temperature by assembling solution-processed, pre-separated semiconducting single-walled carbon nanotube (SWNT) network bridged by Pd source/drain (S/D) electrodes in a configuration of field-effect transistors (FETs) with a local back-gate electrode. To begin with, we observed that the H2 response of the fabricated SWNT FETs can be enhanced in the linear operating regime, where the change in the work function of the Pd S/D electrodes by H2 can be effectively detected. We also explore the H2 responses in various SWNT FETs with different physical dimensions to optimize the sensing performance.

피드백 구조를 갖는 광대역 캐스코드 증폭기의 설계

본 연구에서는 초고주파 대역 소신호 트랜지스터를 이용하여 광대역 특성을 갖는 캐스코드 증폭기의 설계에 대하여 기술한다. 캐스코드 구조를 사용함으로써, 중간대역 이득의 감소를 피하면서 밀러 효과를 감소시켜 차단주파수를 확장시켰다. 또한 입력 매칭을 용이하게 하고 광대역에서 리플이 작은 이득 특성을 얻기 위해 피드백 회로를 이용하였다. 종래에 광대역 증폭기로 평형 증폭기나 분산형 증폭기가 자주 사용되지만, 본 연구에서는 기존보다 회로의 크기를 감소시키면서 광대역 이득특성을 얻을 수 있도록 캐스코드 구조의 증폭기를 설계하였다. 실제 측정에서 1000-2000MHz사이에서 <TEX>$8.5dB{\pm}1.5dB$</TEX>의 이득을 보였다. 제작된 캐스코드 증폭기는, 비록 약간의 주파수 이동이 있으나, 예측 결과와 유사하게 1000MHz 이상의 대역폭에서 8dB 이상의 평탄한 이득을 가졌다. This paper describes the design of a wideband cascode amplifier using a feedback network and microwave small-signal transistors. The adopted cascode structure enables the miller effect to be lessened, cutoff frequency to increase, and reduction of gain in the mid-band to be mitigated. In addition, a feedback network is added to the cascode structure to improve the input matching and ripple performances over the wide operating band. The designed cascode amplifier contains a feedback network for small size and broadband amplification, whereas balanced amplifiers and distributed amplifiers have been used widely. The measurement shows <TEX>$8.5dB{\pm}1.5dB$</TEX> of gain over 1000-2000MHz. The fabricated cascode amplifier has more than 8dB of gain over a 1000MHz bandwidth with a good flatness. The measured performances agree with the predicted ones even a minor shift in operating frequency is observed.

Highly uniform carbon nanotube nanomesh network transistors

A new type of single-walled carbon nanotube (SWNT) thin-film transistor (TFT) structure with a nanomesh network channel has been fabricated from a preseparated semiconducting nanotube solution and simultaneously achieved both high uniformity and a high on/off ratio for application in large-scale integrated circuits. The nanomesh structure is prepared on a high-density SWNT network channel and enables a high on/off ratio while maintaining the excellent uniformity of the electrical properties of the SWNT TFTs. These effects are attributed to the effective elimination of metallic paths across the source/drain electrodes by forming the nanomesh structure in the high-density SWNT network channel. Therefore, our approach can serve as a critical foundation for future nanotube-based thinfilm display electronics.

Accurate extraction of mobility in carbon nanotube network transistors using C-V and I-V measurements

The mobility of single-walled carbon nanotube (SWNT) network thin-film transistors (TFTs) is an essential parameter. Previous extraction methods for mobility encountered problems in extracting accurate intrinsic mobility due to the uncertainty of the SWNT density in the network channel and the existence of contact resistance at the source/drain electrodes. As a result, efficient and accurate extraction of the mobility in SWNT TFTs is challenging using previous methods. We propose a direct method of extracting accurate intrinsic mobility in SWNT TFTs by employing capacitance-voltage and current-voltage measurements. Consequently, we simply obtain accurate intrinsic mobility within the ink-jet printed SWNT TFTs without any complicated calculations.

Recent Advances on Electrically Induced Light Emission from Carbon Nanotubes

Light emission from individual (or small bundle) and network carbon transistors based on single-walled carbon nanotubes (SWNTs) and double-walled carbon nanotubes (DWNTs) is here reviewed in relation with the different mechanisms for light emission: electroluminescence [1,2,3] and incandescence or thermal radiation [4]. These studies guide our ongoing efforts towards making efficient light sources from nanotube emitters. The approach consists of operating the nanotubes transistors in different conditions of thermalisation and of exploring for each condition the different signatures in the emission, either thermal or electroluminescent, using an analysis of the resulting near-IR spectrum. The spectra were acquired in the energy range between 0.5 and 1.3 eV using the Spectrometer Infrared of Montreal (SIMON) mounted with a HgCdTe detector and on a probe station. Three different device configurations were measured. The first is a sub-monolayer network of nanotubes interconnected together to form a percolating semiconducting layer. [5] The numerous tube-tube junctions in the networks limit the current and prevent temperature raise by joule heating at higher bias. Electroluminescence from exciton recombination is found to dominate in all conditions, evidenced by well-defined emission peaks (~200meV in width) in the near-IR (Figure 1). The emission is ascribed to a radiative relaxation of the first excitonic transition. Even at very large biases, the main component of the emission from network transistors is electroluminescence, not incandescence. The second device geometry consists of a thick (~250 nm) and suspended carbon nanotube film having low resistance and reduced thermalization. This configuration favors joule heating when operating at large source-drain voltage and allows to significantly increase the nanotube temperature. The resulting incandescence was measured and used to calibrate SIMON for blackbody emission from a thermal source of pure nanotubes. A third set of devices was finally prepared with individual SWNT and DWNT transistors operating in vacuum, which conditions is used to prevent convection and for reducing the cooling capability of the substrate. The spectra were then compared with the different spectral signatures ascribed either to electroluminescence or thermal radiation depending on the biasing conditions. The experiments show a transition from electro-luminescence at low source-drain voltage to incandescence at higher voltage, with a regime of both in-between. These results will be discussed in terms of the dominant dissipation channels and carrier scatterings in nanotubes. Last, the best conditions to maximize light emission while avoiding heating and progress towards our effort to build electroluminescent transistors at 1,55 μm wavelength using sorted SWNTs will be discussed. Figure 1 Left: SEM and infrared micrographs of a large SWNT network transistor. Right: A carbon nanotube network transistor with the electroluminescence spectra at different biases. [Adapted from Ref. 5] REFERENCES [1] J. A. Misewich, R. Martel, Ph. Avouris, J. C. Tsang, S. Heinze, and J. Tersoff, Science, 300, 783 (2003). [2] J. Chen, V. Perebeinos, M. Freitag, J. Tsang, Q. Fu, J. Liu, and P. Avouris, Science, 310, 1171 (2005). [3] L. Marty, E. Adam, L. Albert, R. Doyon, D. Ménard and R. Martel, Phys. Rev. Lett. 96, 136803 (2006). [4] D. Mann, K. K., A. Kinkhabwala, E. Pop, J. Cao, X. Wang, L. Zhang, Q. Wang, J. Guo, and H. Dai, Nat. Nano, 2, 33 (2006). [5] E. Adam, C. M. Aguirre, L. Marty, B. C. St-Antoine, F. Meunier, P. Desjardins, D. Menard, and R. Martel, Nano Lett. 8, 2351 (2008).This work was done in collaboration with : Elyse Adam1, Pierre Lévesques2, Étienne Gaufrès2, Vincent Aymong2, David Ménard1 : RQMP and 1École Polytechnique de Montréal, Département de génie physique, Montréal, Québec H3C 3A7, Canada 2Université de Montréal, Département de chimie, Montréal, Québec H3T1J4, Canada.