Portugal exhibits a large deficit in cereals with an import/export ratio of about 18%. Alentejo is a southern vast plain region, which is the largest cereal producer in the country, with about 80% of the total cereal area. The region also shows a huge local energy deficit with a ratio of about 17% between spent and produced energy. In this context, this work used GIS modeling based on available digital geographical information on soil and topographic conditions in Alentejo for estimating optimal production areas of four main classes of cereal and legume classes, which were wheat, barley, oat/lupin, and triticale/broad bean. The estimated areas were validated by 199 sample points in the field and allowed to quantify a potential of bioenergy production from straw biomasses based on yields of biomass net calorific values of 18 MJkg−1 and yields of 6, 9, 6, and 9 tons/ha for the four classes in the order indicated. The estimated areas allocated to the cereal and legume classes covered approximately four municipalities in the region. The total modeled area in Alentejo for the four cultivation classes was 44,980 ha. The results showed that even if 50% of the estimated total straw biomass produced was used for animal feed, the estimated bioenergy production of the remaining half biomass would be of about 2940 TJy−1, or about 12.5% of the actual regional energy production, which is an energy amount able to supply 35 organic Rankine cycle (ORC) 2.5 MW cogeneration units and 347 boilers with 125 kW thermal power, delivering renewable electricity to the grid, and heating facilities as diverse as buildings, nursing homes, or horticultural greenhouses. More than 160 kton of CO2 fossil emissions would also be avoided, delivering a contribution to mitigating effects of climate change. By contributing to the reduction of the large cereal dependence and the carbon emissions of the country, the proposed strategy would contribute to increasing the decentralized bioenergy production for applications in buildings and local facilities, significantly boosting the socio-economic dynamics of rural areas involved.
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