The UCL 3-dimensional time-dependent thermospheric model, with atomic and molecular components, is used to study composition changes in the neutral gas at F-layer heights produced by a severe magnetic storm. The computations give the mean molecular weight ( MW), temperature and winds as functions of latitude, longitude, height and time for a period of 30 h. Starting from quiet-day conditions, the simulation starts with a 6-h “substorm” period in which strong electric fields are imposed in the auroral ovals, accompanied by particle input. Weaker electric fields are imposed for the remaining 24 h of the simulation. The energy input causes upwelling of air in the northern and southern auroral ovals, accompanied by localized composition changes (increases of MW), which spread no more than a few hundred kilometres from the energy sources. There is a corresponding downward settling of air at winter midlatitudes and low latitudes, producing widespread decreases of MW at a fixed pressure-level. These storm effects are superimposed on the quiet-day summer-to-winter circulation, in which upwelling occurs in the summer hemisphere and down welling in the winter hemisphere. The composition changes seen at a fixed height differ somewhat from those at a fixed pressure-level, because of the expansion resulting from the storm heating. The results can be related to the well-known prevalence of “negative” F-layer storms (with decreases of F2-layer electron density) in summer, and “positive” F-layer storms in winter and at low latitudes. However, the modelled composition changes are not propagated far enough to account for the observed occurrence of negative storms at some distance from the auroral ovals. This difficulty might be overcome if particle heating occurs well equatorward of the auroral ovals during magnetic storms, producing composition changes and negative storm effects at midlatitudes. Winds do not seem a likely cause of negative storm effects, but other factors (such as increases of vibrationally-excited N 2) are possibly important.
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