Negative Eu Anomalies Research Articles

Evolution of Silurian to Devonian magmatism associated with the Acadian orogenic cycle in eastern and southern Newfoundland Appalachians: Evidence for a three-stage evolution characterized by episodic hinterland- and foreland-directed migration of granitoid magmatism

The migration and character of magmatism over time can provide important insights into the tectonic evolution of an orogen. We present evidence for three separate stages of compositionally distinct granitoid magmatism associated with the Acadian orogenic cycle in the eastern and southern Newfoundland Appalachians. The interpretations are based on new zircon U-Pb ages, geochemical data, and Sr-Nd-Hf-O isotopic data for 18 samples from 15 Silurian and Devonian granitoid plutons, combined with previously published data. The three stages outline hinterland- and foreland-directed migration trends and represent subduction (435−420 Ma), syncollision (415−405 Ma), and postcollision (395−370 Ma) settings in the Acadian orogenic cycle. The Silurian plutons (435−420 Ma) of the first stage consist mainly of quartz diorite, tonalite, granodiorite, monzogranite, and syenogranite, with high-K calc-alkaline and enriched Sr-Nd-Hf-O isotopic compositions (e.g., εNd[t] = −5 to −2; εHf[t] = −3 to −1; δ18O = +6‰ to +8‰). They are interpreted to record the subduction of oceanic lithosphere of the Acadian seaway that separated the leading edge of composite Laurentia, represented by the Gander margin, and Avalonia. Early Devonian plutons (415−405 Ma) of the second stage contain more voluminous monzogranite and syenogranite; they have calc-alkaline to high-K calc-alkaline features, adakite-like compositions, and more depleted Sr-Nd-Hf-O isotopic compositions (e.g., εNd[t] = −6 to 0; εHf[t] = +1 to +3; δ18O = +5‰ to +6‰). Plutons of this stage occur mostly to the northwest of the Silurian granitoids, indicating a regional-scale northwestward (hinterland-directed) migration of magmatism with a rate of >9 km/m.y. The migration is interpreted to have been related to the progressive shallow underthrusting of Avalonia beneath the Gander margin (composite Laurentia) at least as far as 90 km inboard. The Middle to Late Devonian plutons of the third stage (395−370 Ma) consist mainly of monzogranite, syenogranite, and alkali-feldspar granite, which are silica- and alkali-rich granites with large negative Eu anomalies. These rocks are concentrated along both sides of the Dover−Hermitage Bay fault zone, which represents the boundary between Avalonia and composite Laurentia, to the southeast of the Silurian and Early Devonian igneous rocks. This stage of magmatism represents a foreland-directed (retreating) migration. The Early Devonian and Middle to Late Devonian episodes of magmatism were separated by a gap between 405 Ma and 395 Ma and recorded an evolution from (high-K) calc-alkaline to alkaline compositions, ascribed to partial delamination of Avalonian lithospheric mantle in a postcollisional setting.

Petrogenesis of cassiterite-rich greisens from Guengue hill, Mayo Darlé, Northwestern Cameroon

The studied cassiterite-rich greisens of Mayo Darlé are hosted in granites located on the NE slope of the Guengue hill. They have three various structural forms including massive, vein, and stockwork. This study aims to describe all the different structural forms of greisen and also explains the main processes of greisen deposition related to the tin mineralization. The petrographic study shows that the massive form presents two facies: the massive greisens are rich and barren in cassiterite respectively; the stockworks and veins are all mineralized. The mineralogical composition recorded for each of the forms are Quartz + Muscovite + Cassiterite + Zinnwaldite + Plagioclase for the cassiterite-bearing greisen; Quartz + Muscovite + Tourmaline + Chlorite for the barren greisen and Quartz + Muscovite + Cassiterite + Tourmaline + Chlorite for the veins and stockworks. This mineralogy could indicate a varied chemical nature of the hydrothermal/magmatic fluids and the host granite. Also, the presence of minerals such as tourmaline, zinnwaldite and chlorite can equally indicate that there were three main stages in the granitic process: (i) tourmalinization, (ii) lepidolitization, and (iii) chloritization. The greisens have a chemical composition rich in SiO2 (over 71 %) and Al2O3 (5.23–43 %). The chondrite-normalized REE pattern shows a negative Eu anomaly (0.0005–0.15) resulting from the disappearance of feldspars and biotite from the geochemical system, which is gradually transformed to quartz and chlorite respectively during leaching. The ratios of Rb/Sr, Zr/Hf, and Nb/Ta indicates an M-type tetrad effect, which also characterizes the variable values of the Eu anomaly. From a mining point of view, the areas most suitable for further prospection would be those hosting the massive, cassiterite-rich greisens. The significant occurrence of tourmaline and zinnwaldite in the studied greisens could indicate a possible Sn–W–Li polymetallic deposit.

Chemical and boron isotopic compositions of tourmaline from the pegmatite in Ke'eryin rare metal orefield, Eastern Tibet: Implications for pegmatitic evolution

Pegmatites occur widely in the Ke'eryin rare metal orefield. The genesis and evolution of the Ke'eryin pegmatites are still in dispute, and morphological and geochemical studies on tourmalines from the Ke'eryin pegmatites are limited. In this study, in-situ analyses of major and trace elements and B isotope were conducted to uncover the origin of tourmaline and the evolution of related pegmatites. Three types of tourmaline from the Ke'eryin barren pegmatite were identified: elongated columnar or needle-columnar tourmaline (Tur-1 type), isolated, disseminated, irregular, and massive tourmaline (Tur-2 type), and long columnar tourmaline (Tur-3 type). Petrographically, the Tur-1 type crystallized at the early stage of pegmatitic crystallization sequence, the Tur-2 type possibly formed at the early- and/or syn-pegmatitic crystallization sequence, whereas the Tur-3 type likely formed at the relatively late crystallization sequence. Compositionally, most tourmalines belong to the alkali group with a few falling in the vacancy group. All the tourmalines show a schorl composition and are of magmatic origin. Chemical variations from the Tur-1 to Tur-3 tourmalines are controlled by magma fractionation and melt compositions rather than crystal chemical effects. Most tourmalines follow the (Na, Mg)(Xvac, Al)−1, (Mg, OH)(Al, O)−1, and (Ca, Mg2)(Xvac, Al2)−1 exchange vectors. The higher contents of Zn, Sn, Li, Be, Nb, and Ta and negative Eu anomalies in the Tur-3 type indicate that it was likely crystallized at a more evolved stage. In combination with textural evidence and tourmaline chemistry, we suggest that the Tur-1 and Tur-2 types were formed at the relatively earlier stage of pegmatite-forming magma and the Tur-3 type was likely formed closer to the end-stage of barren pegmatite crystallization. The B isotopic compositions are relatively homogeneous and display slightly higher in the Tur-3 type, which were likely caused by fractional crystallization during B-rich magma evolution. It can be inferred that the tourmaline in more evolved and/or Li-mineralized pegmatite with magma evolution should have higher Li, Be, Nb, Ta, and Sn contents, implying that tourmaline chemistry may be used as a potential exploration indicator for rare metal mineralization.

Detrital mode and geochemical constraints on the provenance, paleoweathering and tectonic setting of the Surma sediments of Chittagong-Tripura fold belt, Tripura, India

The Chittagong Tripura Fold Belt (CTFB), the folded eastern part of the Bengal Basin is critical for understanding sediments origin and tectonic evolution linked to interactions among the Indian, Eurasian, and Burma plates. The upper Bhuban and Bokabil sediments (Surma Group) from Atharamura anticline, Tripura, India were analyzed using whole-rock geochemistry and petrography to assess their provenance, tectonics, weathering, and depositional milieu in this least explored area. Petrographic study indicates sub-lithic arenite to sub-arkosic composition, with moderate-high quartz, feldspar poor containing metamorphic and sedimentary lithic fragments (Bh Q88.3F3.0L8.6; Bk Q83.5F7.6L8.8), indicating significant recycled orogen source. Geochemical characteristics such as Eu/Eu* (0.6, 0.7), La/Sc (3.2, 2.4), Th/Sc (1.7, 1.4), Th/Co (1.9, 1.8), CIA/WIP (∼1–2), high Hf, Zr/Sc, low K2O/Al2O3 and enriched LREEs, depleted HREEs, and negative Eu anomalies, indicate a recycled provenance of felsic origin that underwent moderate to intense chemical weathering in active continental margin settings. Radiolarian chert, volcanic lithic fragments with Barail-like recycled sediments strongly suggests an additional detritus from uplifted Indo-Burman Ranges from the east. Elevated Th/U and Th/Rb ratios, sediment immaturity and poor sorting suggest first-cycled detritus. This study indicate that Tripura Neogene sediments are chiefly Himalayan-derived, with minor inputs from IBR and Meghalaya Plateau. Sediments were deposited under brackish near shore to shallow marine oxic basins to the west of the uplifted IBR during the Miocene. The study offers insights into regional geological processes, facilitating correlation of foreland Neogene basins and enhances understanding of the geological evolution of the CTFB.

Petrography and Geochemistry of Hydrothermal Alteration in the Low-Sulfidation Epithermal Kestanelik Au Deposit, Biga Peninsula, NW Turkey

In this study, the facies and degrees of hydrothermal alteration related to the low-sulfidation epithermal Kestanelik Au deposit in the Biga Peninsula metallogenic province are identified through petrographic studies and analysis of geochemical characteristics, such as mass changes, molar element ratios, and alteration indices. The gold mineralization is located in silicified zones containing veins and stockwork veinlets of silica. In the Kestanelik Au deposit, common hydrothermal alteration is mainly found in the Permian-Upper Cretaceous Çamlıca basement metamorphics and the Eocene granodiorite, and less often in the Eocene Şahinli volcanic rocks of the Karabiga Massif on the Peninsula. Based on mineralogical and geochemical studies conducted on altered samples, four different alteration facies are defined as silicic, sericitic, argillic, and propylitic, which show remarkable differences in the behavior of REEs, Si, K, Al, Na, and Ca elements. The hydrothermal fluids that caused alteration in the Kestanelik Au mineralization and host rocks had low REE contents because of REE mobilization. In addition, the kaolinization of feldspars and micas, and the chloritization of biotite and feldspars, may have caused negative Eu anomalies. The characterization of rocks subjected to hydrothermal alteration that are most influenced by diverse K-metasomatism with the largest K gains and losses in Na–Ca is illustrated by molar element ratio plots. Depending on the intensity of K-metasomatism, gold mineralization increases with increasing K trends toward gold ore veins. In the Kestanelik Au field, the argillic, sericitic, and propylitic alteration types from the zones enclosing the Au ore veins are revealed using the Ishikawa alteration index and chlorite–carbonate–pyrite index. Mass changes in the altered rocks indicate that there are gains in Si, K, and Al, and losses in Na and Ca with the increasing intensity of alteration toward the ore veins. The results confirm the presence of silicic and K–metasomatic (sericite and argillic) and propylitic (Fe-rich chloride) alteration zoning extending from the inner regions to the outer regions, which characterize the epithermal ore systems.

Petrogenesis of the eudialyte-bearing syenite and indication for Nb-Zr-REE mineralization in Bashisuogong, Northwest China

The Bashisuogong alkaline igneous intrusion is located between the South Tianshan Orogenic Belt and the Kepingtage foreland thrust belt at the northern margin of the Tarim Craton and hosts economically significant Nb–Ta–Zr–rare earth element mineralization. Eudialyte has recently been discovered in the syenite unit of this intrusion, which is the primary host mineral for high-field-strength and rare earth elements. Based on detailed petrographic investigations, this study investigated the behavior of trace elements during magma evolution and the enrichment of ore-forming elements using whole-rock geochemical analyses of eudialyte-bearing syenite and compositional analyses of aegirine–augite and different types of eudialyte. We also undertook in situ titanite U-Pb dating. The Bashisuogong syenite comprises aegirine–augite and aegirine–augite–eudialyte syenite, the latter of which have higher total rare earth element contents. Both types of syenite exhibit slight enrichments in light rare earth elements, significant enrichments in high-field-strength elements (Nb, Ta, Zr, Hf, and Th), depletions in large-ion lithophile elements (Ba and Sr), and large negative Eu anomalies. There are two types (I and II) of eudialyte. Eudialyte I has higher Mn/Fe, Zr/Hf, and Nb/Ta ratios but lower Th/U ratios compared with eudialyte II but similar Y/Ho ratios. Eudialyte II crystallized earlier than eudialyte I, and aegirine–augite, titanite, and apatite crystallized earlier than eudialyte I. Both aegirine–augite and eudialyte have similar trace element characteristics to the host rocks, exhibiting enrichments in highly incompatible high-field-strength and rare earth elements, as well as marked negative Eu anomalies and depletions in Sr. These characteristics suggest that the Bashisuogong alkaline rocks formed by low-degree partial melting of geochemically enriched, metasomatized lithospheric mantle, which formed an alkaline basaltic parental melt that then underwent protracted magma evolution and fractionation in the shallow crust. The eudialyte syenite yield a titanite U-Pb age of 277.3 ± 1.2 Ma, which is consistent with the ages of different types of alkaline igneous rocks in the study area, indicating they were the products of the same magmatic event. Temporally and spatially, the Bashisuogong ore-bearing alkaline rocks were associated with the Tarim mantle plume, and the mantle plume provided the heat for their formation.

Eocene rhyolites in the Shanglaxiu-Xialaxiu area of north-eastern Qiangtang Block, Tibet: Partial melting of juvenile crust?

Many granitoids and their eruptive equivalents are substantially derived from the uppermost proportion of continental crust, and so their petrogenesis and source are significant in understanding the evolution and characteristics of continental crust. The Eocene felsic rocks in the Qiangtang block (central Tibet) commonly have enriched Nd isotope compositions and have been considered to be related to the recycling of ancient continental crustal material. In this paper we report new data on early Eocene felsic rocks with positive εNd(t) values in the northeastern Qiangtang block, which can be used to help understand Cenozoic evolution and characteristics of continental crust in the Qiangtang block. These rocks consist of rhyolites and occur in the Shanglaxiu and Xialaxiu areas in the north−eastern Qiangtang block. Zircon U−Pb dating yields ages of 47.8 ± 0.6 and 44.2 ± 0.7 Ma for the Shanglaxiu and Xialaxiu rhyolites, respectively, and so they represent the earliest record of Eocene magmatism in the Qiangtang block. The Shanglaxiu−Xialaxiu rhyolites have relatively low calculated zircon saturation temperatures (719–819 °C), along with high SiO2 (74.8–83.3 wt%) and K2O (5.1–7.8 wt%) contents, and low MgO (0.2–0.3 wt%), Cr and Ni contents. They are enriched in light rare earth elements (LREEs), Rb, K, Th, Zr, and Hf, and are depleted in Nb, Ta, Ti, Sr, and P, with moderately negative Eu anomalies. The Shanglaxiu rhyolites have positive whole−rock εNd(t) (0.3–0.4) and zircon εHf(t) (1.8–10.4), and variable zircon δ18O (6.3–7.3‰). The Xialaxiu rhyolites have slightly different whole−rock εNd(t) (−1.5 to −1.6), but similar zircon εHf(t) (2.2–7.7) and δ18O (6.7–7.2‰). We propose that the Shanglaxiu−Xialaxiu rhyolites were most probably generated by partial melting of the pre−existing juvenile crust with the addition of minor sedimentary material. This partial melting was possibly triggered by the south−dipping continental subduction of the Songpan−Ganzi block. The pre−existing juvenile crust was probably formed during the subduction of Paleo−Tethyan oceanic slab in Paleozoic−Early Mesozoic.

Geochemical characteristics of rare earth elements in late Palaeozoic coals from North China

Introduction: China is a large country of REE resources and production, supplying more than 90% of the world’s rare earth consumption market, China’s traditional REE resources, although rich, but reserves are also declining, in recent years, scholars have shown that the REEs in the specific geological conditions in the coals can be enriched, and even reach the industrial grade, the search for more REE mineral resources will be of great strategic significance.Methods: The article has selected the Zibo, Taozao, Huainan, Datong, Huozhou, Jungar, and Weibei coalfields in North China as the research objects. Based on inductively coupled plasma mass spectrometry (ICP-MS) analyses, the study provides a detailed analysis of the enrichment rules and distribution patterns of rare earth elements (REEs) in coal under different geological conditions.Results: The REE distribution patterns in Late Palaeozoic coals in North China are characterized by enrichment of LREEs, deficit of HREEs with gentle changes, and obvious negative anomalies of Eu, the enrichment of REE in coal is controlled by provenance and volcanism, and is related to distance of transport terrigenous material and the sedimentary environment. The REEs concentrations in North China indicates that Late Palaeozoic coals in the mining areas of the north, northwest, and western parts of North China are significantly enriched in REEs. In addition, REEs in Late Palaeozoic coals in the southeastern mining areas are relatively enriched, and the central and eastern regions are significantly depleted.Discussion: Large coal-type rare earth deposits are expected to be developed in North China, particularly the Datong coalfield, Jungar coal mine and the Weibei coal mine in the eastern margin of the Ordos Basin, and the Zibo coalfield.

Early Devonian Post‐collisional Granitic Magmatism in the North Qilian Orogenic Belt, Western China: Insights into Lithospheric Delamination and Orogenic Collapse

AbstractPost‐collisional magmatism contains important clues for understanding the reworking and growth of continental crust, as well as lithospheric delamination and orogenic collapse. Early Devonian magmatism has been identified in the North Qilian Orogenic Belt (NQOB). This paper reports an integrated study of petrology, whole‐rock geochemistry, Sm‐Nd isotope and zircon U‐Pb dating, as well as Lu‐Hf isotopic data, for two Early Devonian intrusive plutons. The Yongchang and Chijin granites yield zircon U‐Pb ages of 394–407 Ma and 414 Ma, respectively. Both of them are characterized by weakly peraluminous to metaluminous without typical aluminium‐rich minerals, LREE‐enriched patterns with negative Eu anomalies and a negative correlation between P2O5 and SiO2 contents, consistent with geochemical features of I‐type granitoids. Zircons from the studied granites display negative to weak positive εHf(t) values (–5.7 to 2.1), which agree well with those of negative εNd(t) values (−6.4 to −2.9) for the whole‐rock samples, indicating that they were derived from the partial melting of Mesoproterozoic crust. Furthermore, low Sr/Y ratios (1.13–21.28) and high zircon saturation temperatures (745°C to 839°C, with the majority being >800°C) demonstrated a relatively shallow depth level below the garnet stability field and an additional heat source. Taken together, the Early Devonian granitic magmatism could have been produced by the partial melting of ancient crustal materials heated by mantle‐derived magmas at high‐temperature and low‐pressure conditions during post‐collisional extensional collapse. The data obtained in this study, when viewed in conjunction with previous studies, provides more information about the tectonic processes that followed the closure of the North Qilian Ocean. The tectonic transition from continental collision to post‐collisional delamination could be constrained to ∼430 Ma, which is provided by the sudden decrease of Sr/Y and La/Yb ratios and an increase in zircon εHf(t) values for granitoids. A two‐stage tectonic evolution model from continental collision to post‐collisional extensional collapse for the NQOB includes (a) continental collision and crustal thickening during ca. 455–430 Ma, characterized by granulite‐facies metamorphism and widespread low‐Mg adakitic magmatism; (b) post‐collisional delamination of thickened continental crust and extensional collapse of orogen during ca. 430–390 Ma, provided by coeval high‐Mg adakitic magmatism, A‐type granites and I‐type granitoids with low Sr‐Y ratios.

Geochronology and Geochemistry of the Xingxingxia Triassic A‐type Granites in Central Tianshan, NW China: Petrogenesis and Tectonic Implications

AbstractThe Triassic granitoids in Central Tianshan play a key role in determining the petrogenesis and tectonic evolution on the southern margin of the Central Asian orogenic belt. In this study, we present SHRIMP zircon U‐Pb ages, Hf isotopic and geochemical data on the Xingxingxia biotite granite, amazonite granite and granitic pegmatite in Central Tianshan, NW China. Zircon U‐Pb dating yielded formation ages of 242 Ma for the biotite granite and 240 Ma for the amazonite granite. These granitoid rocks have high K2O with low MgO and CaO contents. They are enriched in Nb, Ta, Hf and Y, while being depleted in Ba and Sr, showing flat HREE patterns and negative Eu anomalies. They have typical A‐type granite geochemical signatures with high Ga/Al (8–13) and TFeO/(TFeO + MgO) ratios, showing an A2 affinity for biotite granite and an A1 affinity for amazonite granite and granitic pegmatite. Zircon εHf(t) values of the granitoids are 0.45–2.66, with Hf model ages of 0.99–1.17 Ga. This suggests that these A‐type granites originated from partial melting of the lower crust. We propose that Xingxingxia Triassic A‐type granites formed under lithospheric extension from post‐orogenic to anorogenic intraplate settings and NE‐trending regional strike‐slip fault‐controlled magma emplacement in the upper crust.

Petrogenesis and Tectonic Significance of Shenxianshui Alkaline Granite in Gejiu, Yunnan Province, China

AbstractThe Shenxianshui granites in the western Gejiu area were formed in the Late Cretaceous. Laser ablation inductively coupled plasma mass spectrometry indicates zircon U‐Pb ages ranging from 90.67 ± 0.7 to 85.97 ± 0.6 Ma. The intrusive rocks are peraluminous (A/CNK = 1.03 to 1.33) and calc‐alkaline, showing an affinity towards I‐type granite. Large ion lithophilic elements are enriched in K and Rb, while high field strength elements are depleted. Moreover, light rare earth elements are significantly enriched, showing a slight negative Eu anomaly (Eu/Eu* = 0.39 to 0.58). Shenxianshui granite has a relatively high initial Sr isotope ratio (87Sr/86Sr)i (0.7098–0.7105), negative εNd(t) values (−7.99 to −7.44) and negative εHf(t) values (−8.37 to −2.58). Combined with previous studies, these characteristics suggest that the Shenxianshui alkaline granites were formed in a post‐collision extensional environment. The alkaline granitic magma possibly originated from the partial melting of the lower crust during the Mesoproterozoic era and may have contained mantle source materials. Shenxianshui alkaline granite was formed from mixed magma with a high degree of crystal differentiation. The abundance of ore‐forming elements indicates that Shenxianshui granite has the potential to mineralize key metals and rare earth elements.

Petrology and Geochemistry of Intrusive Rocks in the Tanjung Area, South Sulawesi, Indonesia: Implications for Magma Origin, Source Materials, and Geodynamic Setting

The origin of magma, source materials, and geodynamic setting of plutonic and volcanic rocks was elucidated by studying the characteristics of the rocks in the Tanjung area, South Sulawesi, Indonesia. The composition of plutonic rocks is dominated by granodiorite, granite, monzonite, and quartz monzonite, whereas volcanic rocks consist of porphyry basalt, amygdaloidal basalt, trachyte, and trachy-andesite. The main minerals in the rocks are quartz, K-feldspar plagioclase feldspars, Hornblende, biotite, pyroxene, and some opaque minerals. Plots of plutonic rock samples with calc-alkaline affinity indicated a typical I-type granitic rock. Meanwhile, plots of volcanic rock samples with calc-alkaline to shoshonitic affinity indicated S- and I-type basaltic rocks. Harker diagrams suggested that the rocks underwent crystallisation fractionation during magma evolution. Plutonic and Volcanic rocks showed enrichment of LILE and LREE and negative Eu anomalies, which resemble continental crust affinity. It is a product of partial melting in the upper continental crust. The geochemical characteristics demonstrate the relationship between the subduction environment and a continental arc.

Metallogenic Difference between the Late Aptian Nansu and Aishan Pluton in Jiaodong: Constraints from in Situ Apatite Elemental and Nd Isotopic Composition

A series of Mo-polymetallic deposits have been developed in the Jiaodong Peninsula. Notably, these Mo-dominant deposits formed essentially during the same period as the well-known world-class Au deposits in this area, hinting at a potentially unique geological correlation between them. Therefore, conducting thorough research on Mo deposits in Jiaodong holds significant importance in exploring the area’s controlling factors of Mesozoic metal endowments. To reveal the petrogenesis and metallogenic potentials of Mo-fertile and ore-barren granitoid, apatite grains from the Late Aptian Nansu granodiorite and Aishan monzogranite are investigated in this study. Detailed petrographical observations, combined with in situ analysis of electron probe micro-analyzer (EPMA) and Laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), have been conducted on apatite grains from the Nansu and Aishan plutons. This comprehensive analysis, encompassing both major and trace elements as well as isotopic characteristics of apatite, aims to elucidate the metallogenic differences within the late Early Cretaceous granitoids of Jiaodong. The results reveal that the apatite grains across all samples belong to fluorapatites, suggesting their magmatic origin. Additionally, chondrite-normalized rare earth element (REE) patterns of apatites in ore-fertile and ore-barren granitoids exhibit a “right-leaning” trend, characterized by relative enrichments in light REEs and depletions in heavy REEs. Both the Nansu and Aishan plutons exhibit moderately negative Eu anomalies (with averages δEu values of 0.44 and 0.51, respectively), along with slightly positive Ce anomalies (averaging δCe values of 1.08 and 1.11, respectively). A negative correlation is observed between their δEu and δCe values, indicating that the parental magmas of ore-fertile and ore-barren granitoids were formed in a relatively oxidizing environment. The calculated apatite OH contents for the Nansu pluton range from 0.26 to 1.38, while those for the Aishan pluton vary between 0.24 and 1.51, indicating comparable melt H2O abundances. Consequently, the results suggest that neither the oxygen fugacities nor the water contents of the parental magma can account for the metallogenic differences between Nansu and Aishan plutons. The apatite in the Nansu pluton exhibits a higher Ce/Pb ratio and a relatively lower Th/U ratio, indicating the involvement of a greater volume of fluids in the magmatic evolution process of this ore-bearing granitoid. Apatite grains sourced from the Nansu and Aishan plutons exhibit εNd(t) values ranging from −16.63 to −17.61 (t = 115.7 Ma) and −17.86 to −20.86 (t = 116.8 Ma), respectively. These results suggest that their parental magmas primarily originated from the partial melting of Precambrian metamorphic basement rocks within the North China Craton, with a minor contribution from mantle-derived materials. Additionally, the presence of mafic microgranular enclaves in both the Nansu and Aishan plutons indicates that both have undergone magma mixing processes. The binary diagrams plotting the ratios of Ba/Th, Sr/Th, and U/Th against La/Sm demonstrate that apatite grains of ore-fertile granitoid exhibit a distinct trend towards sediment melting. This suggests the potential incorporation of sedimentary materials, particularly those rich in molybdenum, into the magmatic source of the Nansu pluton, ultimately leading to the occurrence of molybdenum mineralization.

The Origin of Mesozoic A‐type Granitoids, Fujian Province, Southeast China: Insights from Geochronology, Mineralogy and Geochemistry

AbstractThe magma sources, origins and precise forming ages of the miarolite from Qishan and Kuiqi intrusions are still uncertain. New results reveal that, miarolites from the Qishan and Kuiqi intrusions yield crystallization ages of ∼101 and ∼98 Ma, and they have a high formation temperature (∼910°C) and low oxygen fugacity value, indicating crystallization condition at low pressure in the upper crust with temperature of 678°C. The Qishan and Kuiqi miarolites are characterized by enrichment in SiO2 and high‐K alkali, depletion in Ca and Mg, and belong to the high‐K weak peraluminous rock series. The samples are enriched in HFSEs (i.e., Ta, Zr and Hf) and LILEs (i.e., Ba, P and Sr), depleted in Ba and Sr with the negative anomaly of Eu. In the primitive mantle normalized trace element spider diagram, the samples show a right‐inclined ‘seagull‐type’ pattern, combined the ratios of (La/Yb)N, 10000 × Al/Ga, Rb/Nb and Nb/Ta etc., they were proved to be alkaline A‐type granite. Combined the characterize of the trace elements, they were derived from clay‐rich source accompanied pelite melting, and subjected to K‐feldspar crystallization fractional. The values of εHf(t) and tDM2 are distributed in the range of –2.8 to 3.3 with ∼1.2 Ga, and –6.0 to 4.0 with ∼1.2 Ga, revealing that they were generated from the Mesoproterozoic Cathaysia basement rocks. The comprehensive research reveals the Kuiqi and Qishan intrusions derived from crust‐mantle mixing and partial melting of the crust, respectively, resulting from lithospheric extension generated by the Paleo‐Pacific Plate subducted into the European–Asian Plate.

Relationship between the genesis of Changlinggang alkaline rocks and uranium mineralization in the 414U-Th deposit, Jianshui County, Yunnan Province, China

Alkaline rocks identified in the 414 U-Th deposit in Jianshui County, Yunnan Province, exhibit intense spatial correlation with uranium mineralization. However, limited investigations into their genesis have had an adverse impact on our understanding of uranium mineralization. Analyses of major and trace elements, U-Pb chronology, and petrography were conducted on alkaline rocks. The results indicate that anorthosite, which is rich in alkalis, high in potassium, peraluminous, enriched in rare earth elements (U, Th, Rb, and Zr) and deficient in Sr, Ba, Ti, and P, predominates the lithology. The light and heavy rare earth fractionation of the material is readily apparent (LREE/HREE=7.89–46.72), and the presence of Eu negative anomalies (δEu=0.65–0.81) suggests that the region from which the magma originated is a metasomatism-enriched mantle where the source material originates from the transition zone between garnet-lherzolite and spinel-lherzolite in the EMII-enriched lithospheric mantle. This area underwent metasomatization by subduction material from the Paleo-Pacific Ocean and during the ascent process, magma experienced a certain degree of partial melting and a significant degree of crystallization differentiation. The diagenesis of the syenite (186.64 ± 3.76 Ma) occurred after the closure time of the Paleotethys Ocean (237 Ma) in a dynamical context of an intra-terrestrial rift environment following subduction of the oceanic plate. In summary, the U and Th present in the 414 U-Th deposits underwent isomorphism within biotite and feldspars during the hydrothermal mineralization stage of magma evolution, where they were enriched in minerals through the separation and crystallization of alkaline magma.

The Relationship between Granitic Magma and Mineralization in the Darongxi Skarn W Deposit, Xiangzhong District, South China: Constrained by Zircon and Apatite

The Xiangho Zng district is the largest low-temperature W-Au-Sb metallogenic area in the world. The Darongxi skarn W deposit in the north of the Xiangzhong district is closely related to biotite monzonite granite, muscovite monzonite granite, and felsophyre, but the nature of granitic magma and its relationship with mineralization is relatively weak. In this paper, U-Pb dating, Lu-Hf isotope, the in situ composition of zircon, and the apatite of biotite monzonite granite, muscovite monzonite granite, and felsophyre in the Darongxi mining area are systematically studied, and the formation age, magma property and source, and their relationship with mineralization are discussed. The values of zircon U-Pb age and the εHf(t) of biotite monzonite granite are 222.2 ± 0.54 Ma and −2.9~−6.4, respectively. The values of zircon U-Pb age and the εHf(t) of muscovite monzonite granite are 220.8 ± 0.58 Ma and −2.7 to −8.1, respectively. The values of zircon U-Pb age and the εHf(t) of felsophyre are 222.3 ± 2.20 Ma and −2.2~−5.4, respectively. Magmatic apatite grains from biotite monzonite granite and muscovite monzonite granite show distinctive core–rim and oscillatory zoning textures in CL images, and demonstrate a bright yellow in colorful CL images. The magmatic apatite has a total rare earth concentration (3766~4627 ppm), exhibiting right-inclined nomorlized rare earth element patterns and obvious negative Eu anomalies. The geochemical data of magmatic zircon and apatite indicate that magma sources are responsible for these intrusions in the Darongxi mining area, mainly derived from the partial melting of the Mesoproterozoic crust, which is rich in W; the magma is rich in F and poor in Cl (F = 2.4~3.3 wt%, Cl = 0.0024~0.0502 wt%). The oxygen fugacity of magmatic zircon (ΔFMQAVG = −4.02~−0.26), the high negative Eu anomaly (δEu = 0.06~0.12) and the low positive Ce anomaly (δCe = 1.09~1.13) of magmatic apatite, and the occurrence of ilmenite all indicate that the redox condition of magma from the Darongxi mining area is reduced. The reduced F-rich crust-source granitic rock and W-rich source provide favorable conditions for the mineralization of the Darongxi reduced skarn W deposit.

Revisiting the Petrogenesis of Pyroclastic Glass Bead Deposits at the Apollo 15 and 17 Sites

Abstract The Apollo 15 low-titanium and Apollo 17 high-titanium pyroclastic glass beads are among the most primitive magmatically derived samples obtained from the Moon. Two key samples, the low-Ti Apollo 15426 green glass clod and the high-Ti Apollo 74220 orange glass are morphologically distinct, where the Apollo 15 beads are larger (~107 μm along maximum axis) and more fractured, and the Apollo 17 are smaller (~42 μm) and less fractured. In this study, holohyaline beads as well as crystallized beads were examined from both samples using petrography, electron microprobe analysis, and laser-ablation inductively coupled plasma mass spectrometry. Crystallized beads show compositional variability in major, minor, and trace elements and enable examination of magmatic mineral fractionation processes during cooling of both deposits. The Apollo 15426 beads experienced variable olivine crystallization, whereas the Apollo 74220 beads experienced both olivine and ilmenite crystallization. Holohyaline beads from both deposits show more limited major, minor, and trace element variability than their crystallized counterparts. Trace element abundance data for individual holohyaline beads show that in Apollo 74220, they are tightly clustered at ~30× Carbonaceous Ivuna chondrite [CI] with negative Eu anomalies and subchondritic Nb/Ta, interpreted to reflect the presence of late-stage magma ocean cumulates overturned into an otherwise primitive mantle source. Incompatible trace element abundances for holohyaline beads in 15426 are supra-chondritic from ~8× CI, to >80× CI, with pronounced relative depletions in Sr and Eu for the most incompatible element enriched beads, which represent a distinct bead group within the deposit. Apollo 15426 beads have elevated Ni and Co abundances at the edges of the beads compared to their centers. These data are interpreted to reflect a more complex magmatic evolution of the 15426 deposit, beginning with (i) initial magma generation, storage, and assimilation within shallower low- and high-Ca pyroxene bearing magma ocean cumulates (15B,C); (ii) mobilization of the earlier magmas by more recently generated primitive magmas (15A); (iii) eruption and crystallization of some beads (15D,E); and (iv) later jumbling of the deposit, possible impact contamination and addition of exotic basaltic bead components (J Group). In contrast, the 74220 data show no discernable difference between Ni and Co abundances at the edges and centers supporting prior observations for limited melt fractionation and an absence of meteoritic components. Both deposits are likely to have been formed in the presence of a transient atmosphere. Using 74220 melt compositions from this study, post-entrapment crystallization abundances range from 266 to 1130 μg/g for H2O, 36 to 68 μg/g for F, 441 to 832 μg/g for S, and 0 to 2.31 μg/g for Cl, consistent with prior studies and suggesting up to ~0.1 wt % H2O in the melt, with considerably less in the source. The role that late-stage magma ocean cumulates rich in ilmenite and high-Ca pyroxene might play in modifying this volatile element estimate, however, casts remaining doubt on the volatile element abundance and evolution of the primitive Moon.

Genesis and metallogenic potential of the ca.90 Ma Jiangcisha magmatic rocks in the western Shiquanhe suture zone, Xizang, China

Numerous mineral deposits related to the ca.90 Ma magmatic activity were found in the northern and central Lhasa terrane. Recently, many Late Cretaceous intermediate and felsic magmatic rocks were discovered in the Jiangcisha area in the western Shiquanhe-Nam Tso Mélange Zone, separating the Lhasa terrane into northern and central subterranes. In this study, zircon UPb dating, whole-rock major and trace element geochemistry, zircon Hf isotopes and trace element compositions are used to determine the petrogenesis and mineralization potential of the Jiangcisha intermediate and felsic magmatic rocks. The zircon UPb ages of the diorite porphyry, dacite porphyry, and diorite sample are 92.2 ± 1.6 Ma, 90.0 ± 1.3 Ma, and 85.8 ± 1.7 Ma, respectively. The diorite porphyry and diorite samples have A/CNK values ranging from 0.65 to 0.91 and show elevated Mg# (44.78–53.11), Cr (108–338 ppm) and Ni (53.2–119 ppm) concentrations. These rocks also have high Sr/Y values (30.37–58.03) and low Rb/Sr ratios (0.04–0.33), with weak negative Eu anomalies (δEu = 0.75–0.95). Based on these values, these samples are high-Mg# calc-alkaline and metaluminous adakitic rocks. The dacite porphyry has a high SiO2 content (73.54–74.07 wt%) and significant negative Eu (δEu = 0.69–0.73) and Sr anomalies. Their Sr contents are 10 times lower than those of the diorite porphyry and diorite samples. The zircon εHf(t) values of these three magmatic rocks are high (7.61–12.69), and the Hf isotope two-stage model ages are young (0.41–0.78 Ga). The geochemical characteristics mentioned above indicate that the diorite porphyry and diorite were derived from the partial melting of the delaminated juvenile lower crust. However, the dacite porphyry is the product of plagioclase and K-feldspar fractional crystallization from the diorite porphyry. The zircons in the diorite porphyry and diorite samples have low Ce/Nd (3.66–29.04), logfO2 (−16.022-–12.976), and ΔFMQ (0.08–1.99) values and moderate Dy/Yb (0.22–0.37), 10,000 × δEu/Y (1.48–9.66), and (Ce/Nd)/Y (0.0025–0.0224) ratios. Compared to typical large porphyry-skarn CuAu deposits with dioritic rocks developed in the Tibetan Plateau, the relatively low oxygen fugacity and magma water content of the Jiangcisha dioritic rocks indicate their limited potential to form large porphyry and skarn CuAu deposits.

Geochemical and isotopic evidence for early neoproterozoic (ca. 1000 Ma) subduction-related magmatism in the central Borborema Province, Brazil

Early Neoproterozoic (1000-920 Ma) rocks related to the Cariris Velhos event in the central Borborema Province have been linked to either continental rifting or accretionary-collisional orogenesis. The Serra do Jatobá Suite is located in the southwestern part of the Alto Pajeú Terrane along with coeval metasedimentary sequences and Ediacaran granites. This suite is composed of alkali-calcic, meta-to peraluminous granodiorites to monzogranites that share similarities with both ferroan- and magnesian granite series. Chondrite normalized REE (Rare Earth Elements) patterns are moderately fractionated with pronounced negative Eu anomalies. Incompatible element spidergrams show a negative Nb–Ta anomaly, similar to those observed in Cordilleran-type granites. U–Pb zircon data constrain the crystallization ages at around 1000 Ma, whereas calculated εNd(t) values range between −1.74 and −0.94. Obtained TDM model ages range from 1.76 to 1.54 Ga, which corresponds with source ages for the Cariris Velhos magmatic rocks. Our findings suggest that subduction took place in the early Neoproterozoic in the Borborema Province, pointing to an accretionary nature for the Cariris Velhos event.

Provenance, chemical weathering, and sedimentary environment of the aquifer sediments: Implication for arsenic enrichment in groundwater

High arsenic (As) groundwater has been widely observed in the world, but the provenance, chemical weathering, and sedimentary environment of aquifer sediments hosting high As groundwater remain poorly understood. The geochemical and isotopic characteristics of high-resolution aquifer sediments were investigated to unravel the roles of provenance, chemical weathering, and sedimentary environment of the aquifer sediments. The average values of rare earth elements (REEs) showed the enrichment of light REEs and flat heavy REEs in the aquifer and the Yellow River sediments. The chemical index of alteration reflected incipient and moderate weathering (41 to 71). The δ13CSOM (−27.4‰ ± 4.3‰) and C/N values (8.1 ± 5.8) indicated aquatic environment of sedimentation. Shallow aquifer sediments mostly had relatively high ΣREEs contents and negative Eu anomalies, demonstrating that the aquifer sediments were mainly derived from the Yellow River (up to 94.3% ± 5%). Deep aquifer sediments had relatively low ΣREEs contents and positive Eu anomalies, which originated from the Yinshan Mountains (up to 72.2% ± 20.4%) principally with igneous and metamorphic rocks. Moreover, recycling of the Yellow River sediments from Northeastern Tibetan Plateau enhanced the silicate weathering and increased contents of Fe/Mn oxides and As. The δ13CSOM and C/N values evidenced that organisms of paleo-lake or paleo-Yellow River were responsible for abundant sedimentary organic matter. Concentrations of Fe, Mn, and As were high in shallow groundwater from the plain. The As enrichment in the shallow groundwater was jointly controlled by the provenance and chemical weathering of the aquifer sediments (14%), sedimentary environment (10%), reductive dissolution (35%) of Fe/Mn oxides, As desorption under elevated pH (20%), and competitive adsorption of HCO3- (21%). This study systematically reveals the roles of provenance, chemical weathering, and sedimentary environment of the aquifer sediments and highlights joint contributions of geochemical processes and geochemical conditions to As enrichment in groundwater.