The utility of toroid resonators for NMR has been discussed in several reports (I, 2). Most recently, using “0 NMR, Glass and Dom (3) have shown an SINadvantage of 3-5 for toroids compared with Helmholtz detectors. However, realization of this advantage for narrow-line nuclides was limited by poor B0 field homogeneity, since typical linewidths achieved were 45-70 Hz, which could only be reduced to a best value of 11.7 Hz with use of a specially designed shim system (4). Were it not for the B. field homogeneity problem, we suspected that toroids, due to their greater coil efficiency and their confinement of the B, field to the internal regions of the coil, would be particularly useful in metal pressure vessels, since this confinement would also be expected to avoid losses due to magnetic coupling with the vessel. Here, we report 2H static linewidths near 1.0 Hz for several toroid detectors, even though mounted within a Be-Cu pressure vessel, with 13C sensitivities significantly better than that of a commercial 10 mm ambient pressure multinuclear probe. The spectra were recorded using a General Electric GN300/89 spectrometer with an Oxford 89 mm magnet and standard shim system. Magnetic coupling of a transmitter coil to a nearby conductor results in loss of energy to the conductor in the form of eddy currents. In addition, the coupling also allows pickup of thermal or other noise from the conductor when the coil is used to receive signals. Magnetic coupling decreases the coil’s inductance and quality factor. To alleviate these problems, Hoult (5) recommends that detector coils be located at least a distance equal to their largest dimension from nearby conductors. The recommendation applies to metal pressure vessels in that their walls are conductive. Significantly, it essentially triples the required inside diameter and wall thickness of the pressure vessel and one designed for 10 mm sample sizes for use in magnets of 7.05 T or above would be difficult to achieve. Jonas’ high-pressure NMR probes have their detectors far removed from the walls of the vessel (6, 7). To investigate the potential advantages of toroids for use in high-pressure NMR probes, the pressure vessel in Fig. 1 was fabricated from Berylco alloy 25 (tensile strength; 192,000 psi). The vessel is intended for homogeneous catalysis studies involving reactions of gases and liquids under pressure and is designed to receive effluent from a separate stirred reactor where gas and liquid mixing occur. It uses standard l/l 6 in. compression fittings (Parker or single ferrule Swagelok) in both the gas connections and in the RF feedthroughs; however, the feedthroughs used VespelSP 1 reducing ferrules (Alltech Associates, 1 / 16 in. to 1 .O mm) in place of the standard
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