Near-infrared Regime Research Articles

Near-Infrared Light-Driven CO2 Reduction on Cup-Stacked Carbon Nanotubes.

Carbon nanotubes feature one-dimensional nature of collective excitations, wherein strong confinement of surface plasmons severely hinders the liberation of hot electrons (HEs), posing grand challenges for their utilization in photochemistry. In this study, we prototypically achieved directed HEs flow and extraction in hybrid plasmonic CNN based on cup-stacked carbon nanotubes (CSCNTs), taking advantage of their privileged edge-plane sites. The localized pz electronic states and accessible intersubband plasmon excitations in the near-infrared (NIR) regime stands in striking contrast to the conventional concentric carbon nanotubes, as evidenced by combined photo-induced force microscopy (PiFM) and transient photocurrent response. The hybrid comprising intimately integrated CSCNTs-C3N4 effectively sustains interfacial electronic states and underlies the energy extraction out of plasmonic components. The CNN demonstrates almost near-unity NIR light-driven CO2 reduction to CO with a rate of 1.35 µmol g-1 h-1. This work sheds light on the exploitation of metal-free carbon-based plasmonic nanostructures for photocatalytic applications.

Nonlinear Thermoplasmonics in Graphene Nanostructures.

The linear electronic dispersion relation of graphene endows the atomically thin carbon layer with a large intrinsic optical nonlinearity, with regard to both parametric and photothermal processes. While plasmons in graphene nanostructures can further enhance nonlinear optical phenomena, boosting resonances to the technologically relevant mid- and near-infrared (IR) spectral regimes necessitates patterning on ∼10 nm length scales, for which quantum finite-size effects play a crucial role. Here we show that thermoplasmons in narrow graphene nanoribbons can be activated at mid- and near-IR frequencies with moderate absorbed energy density, and furthermore can drive substantial third-harmonic generation and optical Kerr nonlinearities. Our findings suggest that photothermal excitation by ultrashort optical pulses offers a promising approach to enable nonlinear plasmonic phenomena in nanostructured graphene that avoids potentially invasive electrical gating schemes and excessive charge carrier doping levels.

Study of modulation in complex refractive indices induced by ultrafast relativistic electrons using infrared and THz probe pulses.

Objective 
Achieving ultra-precise temporal resolution in ionizing radiation detection is essential, particularly in positron emission tomography, where precise timing enhances signal-to-noise ratios and may enable reconstruction-less imaging. A promising approach involves utilizing ultrafast modulation of the complex refractive index, where sending probe pulses to the detection crystals will result in changes in picoseconds (ps), and thus a sub - 10 ps coincidence time resolution can be realized. Towards this goal, here, we aim to first measure the ps changes in probe pulses using an ionizing radiation source with high time resolution.
Approach 
We used relativistic, ultrafast electrons to induce complex refractive index and use probe pulses in the near-infrared (800 nm) and terahertz (THz, 300 µm) regimes to test the hypothesized wavelength-squared increase in absorption coefficient in the Drude free-carrier absorption model. We measured BGO, ZnSe, BaF2, ZnS, PBG, and PWO with 1 mm thickness to control the deposited energy of the 3 MeV electrons, simulating ionization energy of the 511 keV photons. 
Main results 
Both with the 800 nm and THz probe pulses, transmission decreased across most samples, indicating the free carrier absorption, with an induced signal change of 11% in BaF2, but without the predicted Drude modulation increase. To understand this discrepancy, we simulated ionization tracks and examined the geometry of the free carrier distribution, attributing the mismatch in THz modulations to the sub-wavelength diameter of trajectories, despite the lengths reaching 500 µm to 1 mm. Additionally, thin samples truncated the final segments of the ionization tracks, and the measured initial segments have larger inter-inelastic collision distances due to lower stopping power (dE/dx) for high-energy electrons, exacerbating diffraction-limited resolution. 
Significance
Our work offers insights into ultrafast radiation detection using complex refractive index modulation and highlights critical considerations in sample preparation, probe wavelength, and probe-charge carrier coupling scenarios.

Enhanced broadband perfect absorption in visible and near-infrared regimes

ABSTRACT It is still a challenge to achieve perfect ((near-unity)) absorption across a wide wavelength range with a three-layer structure. This paper presents a metamaterial absorber (MA) based on MXene that can achieve broadband and perfect absorption in the near-infrared and visible regions. The MA with a simple three-layer structure consists of a top Ti3C2T x layer, an intermediate dielectric layer and a bottom gold layer. It can achieve perfect absorption (the absorptivity over 99%) in the wavelength range of 730–900 nm. The electric field distribution reveals that the localized surface plasmon resonance occurring at the interface of Ti3C2T x and SiO2 leads to strong absorption over the wide wavelength range. Furthermore, the MA exhibits excellent angular stability. This work provides a method to construct MAs with broadband perfect absorption in the near-infrared and visible band.

Enhanced high-harmonic generation in a polarization-insensitive all-dielectric metasurface exploiting dual-Fano resonance

Nonlinear optics demands efficacious techniques for nonlinear properties engineering. Metasurfaces, as a flat technology with easy fabrication in various arrangements and without the need for phase-matching conditions, are suitable platforms for nonlinear optics. This study proposes a silicon metasurface with special geometry that provides high conversion efficiency by exploiting Fano resonances and the excitation of magnetic and toroidal dipoles. The results indicate the high efficiencies of third harmonic generation of 5.17×10−3 W−2 and fifth harmonic generation of 7.92×10−9 W−4 under 1 GW/cm2 pump intensity in the near-infrared regime. More specifically, linear and nonlinear optical responses of the structure are completely polarization-independent.

A Tamm-Fano resonance glucose sensor based on Cu and distributed bragg reflector plasmonic coupling interface in the near-infrared regime

A Tamm-Fano resonance glucose sensor based on Cu and distributed bragg reflector plasmonic coupling interface in the near-infrared regime

Simple and hybrid metalens with high polarization conversion efficiency for near-infrared spectrum

Thanks to their ability to control light, research on metalenses is developing rapidly. However, it is still quite difficult to design broadband metalenses with high polarization conversion efficiency. In this study, an alternative plasmonic material, aluminum-doped zinc oxide, is presented for metalens operating in near-infrared regime. We propose simple and hybrid metalenses with high polarization conversion efficiency and high transmission values that can focus efficiently in a wide near-infrared bandwidth (700–1000 nm). We design metalens consisting of subwavelength aluminum-doped zinc oxide nanoblocks based the Pancharatnam-Berry phase method and utilizing the finite-difference time-domain method. The polarization conversion efficiency (minimum 87 %) and transmission values (minimum 85 %) calculated for the metalens unit cell are higher than those previously obtained over the entire 300 nm bandwidth. In addition, we propose hybrid metalens to focus the incident beam in right and left handed circular polarized states in the studied frequency range. The presented aluminum-doped zinc oxide metalens with high polarization conversion efficiency and transmission values can find a place in the applications of near-infrared nanophotonic systems.

Boosting external quantum efficiency of a WSe2 photodetector across visible and NIR spectra through harnessing plasmonic hot electrons

The layered two-dimensional material tungsten diselenide ( WSe2 ) has triggered tremendous interests in the field of optoelectronic devices due to its exceptional carrier transport property. Nevertheless, the limited absorption of WSe2 in the near infrared (NIR) band poses a challenge for the application of WSe2 photodetectors in night vision, telecommunication, etc. Herein, the enhanced performance of the WSe2 photodetector is demonstrated through the incorporation of titanium nitride nanoparticles (TiN NPs), complemented by an atomically-thick Al2O3 layer that aids in suppressing the dark current. It is demonstrated that TiN NPs can dramatically enhance the absorption of light in the proposed WSe2 photodetector in the NIR regime. This enhancement boosts photocurrent responses through the generation of plasmonic hot electrons, leading to external quantum efficiency (EQE) enhancement factors of 379.66% at 850 nm and 178.47% at 1550 nm. This work presents, for the first time, to our knowledge, that the WSe2 photodetector is capable of detecting broadband light spanning from ultraviolet to the telecommunication range, all achieved without the reliance on additional semiconductor materials. This achievement opens avenues for the advancement of cost-effective NIR photodetectors.

Staggered band alignment of n-Er2O3/p-Si heterostructure for the fabrication of a high-performance broadband photodetector

The low responsivity of conventional Silicon photodiodes in ultraviolet and near-infrared regimes restricts their utility as broadband photodetectors (BBPDs). Despite ongoing investigations into various p-n heterostructures for Silicon-based BBPDs, challenges such as high dark current (Idark), low collection efficiency, low detectivity, and compatibility issues with large-scale Silicon-based devices persist. In this context, we have fabricated relatively unexplored n-Er2O3/p-Si heterojunction-based BBPDs. Polycrystalline Er2O3 thin films (∼110 nm) were deposited on p-Si 〈100〉 substrates by radio frequency magnetron sputtering. Although this process induces a microstrain of approximately 0.022 and a dislocation density of about 0.00303/nm2, the presence of optically active defects is minimal, indicated by a low Urbach energy (∼0.35 eV). X-ray photoelectron spectroscopy (XPS) analysis confirms staggered band alignment at the heterointerface, facilitating efficient charge carrier separation and transport. Consequently, the In/p-Si/n-Er2O3/In device demonstrated significant BBPD properties– low Idark ∼0.15 μA (at +5 V), photo-to-dark current ratio (PDCR) ∼6.5 (at +5 V, 700 nm) with a maximum photoresponsivity ∼22.3 A W−1, and impressive detectivity (∼1013 Jones) even in UV-C region where traditional silicon-based photodetectors respond feebly. The device also demonstrates transient photo-response across an ultrawide spectrum (254 nm–1200 nm) with a fast rise time/fall time ∼79 ms/∼86 ms (at −5 V for 600 nm illumination). This work establishes a straightforward and reliable method for proper material engineering, surface texturing, staggered heterojunction formation, and high-performance BBPD fabrication with prominent broad-spectrum responsivity, sizeable detectivity, and fast response. The integration of these BBPDs with Silicon opens possibilities for their use in electronic devices containing optical switches for communications and broadband image sensors, enhancing their utility in various applications.

Multishot laser damage of multilayer dielectric mirrors in the near-infrared subpicosecond regime

The laser damage resistance of dielectric components of high-power laser facilities to laser irradiation depends significantly on the irradiation sequence. In the short pulse (fs) regime, it is known that continuous irradiation of these components leads to a reduction in the damage threshold, reflecting a laser fatigue effect. Conversely, in the long pulse (ns) regime, progressive irradiation of these components leads to an increase in the damage threshold, reflecting a laser conditioning effect. In this article, we experimentally evaluate the competition between the effects of laser fatigue and laser conditioning for multilayer dielectric components irradiated in the subpicosecond pulse regime in the infrared (∼1µm) through different test sequences. For this purpose, we implemented an original test sequence derived from an S-on-1 type protocol, which consists of irradiating the component until damage. By repeating this sequence at different set points, it was possible to estimate the progressive reduction in damage threshold with the number of laser irradiations and to compare it with that observed during the fluence ramps. Particular attention was also paid to the precise knowledge of the test beam irradiating the component, as a dependence of the beam surface on the test set point was highlighted.

Simultaneous Circular Dichroism and Wavefront Manipulation with Generalized Pancharatnam-Berry Phase Metasurfaces.

Simultaneous circular dichroism and wavefront manipulation have gained considerable attention in various applications, such as chiroptical spectroscopy, chiral imaging, sorting and detection of enantiomers, and quantum optics, which can improve the miniaturization and integration of the optical system. Typically, structures with n-fold rotational symmetry (n ≥ 3) are used to improve circular dichroism, as they induce stronger interactions between the electric and magnetic fields. However, manipulating the wavefront with these structures remains challenging because they are commonly considered isotropic and lack a geometric phase response in linear optics. Here, we propose and experimentally demonstrate an approach to achieve simultaneous circular dichroism (with a maximum value of ∼0.62) and wavefront manipulation using a plasmonic metasurface made up of C3 Archimedes spiral nanostructures. The circular dichroism arises from the magnetic dipole-dipole resonance and strong interactions between adjacent meta-atoms. As a proof of concept, two metadevices are fabricated and characterized in the near-infrared regime. This configuration possesses the potential for future applications in photodetection, chiroptical spectroscopy, and the customization of linear and nonlinear optical responses.

Reconstructing the near- to mid-infrared environment in the stellar merger remnant V838 Monocerotis

Context. V838 Mon is a stellar merger remnant that erupted in a luminous red nova event in 2002. Although it has been well studied in the optical, near-infrared, and submillimeter regimes, its structure in the mid-infrared wavelengths remains elusive. Over the past two decades, only a handful of infrared interferometric studies have been performed, suggesting the presence of an elongated structure at multiple wavelengths. However, given the limited nature of these observations, the true morphology of the source has not yet been conclusively determined. Aims. By performing image reconstruction using observations taken at the VLTI and CHARA, we aim to map out the circumstellar environment in V838 Mon. Methods. We observed V838 Mon with the MATISSE (LMN bands) and GRAVITY (K band) instruments at the VLTI as well as the MIRCX/MYSTIC (HK bands) instruments at the CHARA array. We geometrically modelled the squared visibilities and the closure phases in each of the bands to obtain the constraints on the physical parameters. Furthermore, we constructed high-resolution images of V838 Mon in the HK bands using the MIRA and SQUEEZE algorithms to study the immediate surroundings of the star. Lastly, we also modelled the spectral features seen in the K and M bands at various temperatures. Results. The image reconstructions show a bipolar structure that surrounds the central star in the post-merger remnant. In the K band, the super-resolved images show an extended structure (uniform disk diameter ~1.94 mas) with a clumpy morphology that is aligned along a north-west position angle (PA) of −40°. On the other hand, in the H band, the extended structure (uniform disk diameter ~1.18 mas) lies roughly along the same PA. Yet the northern lobe is slightly misaligned with respect to the southern lobe, which results in the closure phase deviations. Conclusions. The VLTI and CHARA imaging results show that V838 Mon is surrounded by features resembling jets that are intrinsically asymmetric. This is further confirmed by the closure phase modelling. Further observations with VLTI can help to determine whether this structure shows any variations over time and also if such bi-polar structures are commonly formed in other stellar merger remnants.

Ultra-narrow dual-band perfect absorber based on double-slotted silicon nanodisk arrays

Due to its unique advantage of optical properties, nanophotonic metamaterials have gained extensive applications in perfect absorbers. However, achieving both dual-band and ultra-narrow linewidth in absorbers simultaneously remains a challenge for typical metal-dielectric based metamaterials. In this work, a dual-band ultra-narrow perfect absorber consisting of a double slotted silicon nanodisk array that located on a silver film with a silica spacer layer is proposed theoretically. By combining the hybrid mode excited by the coupling of diffraction wave mode and magnetic dipole mode with the anapole–anapole interaction, two absorption peaks can be induced in the near-infrared regime, achieving nearly perfect absorbance of 99.31% and 99.61%, with ultra-narrow linewidths of 1.92 nm and 1.25 nm respectively. In addition, the dual-band absorption characteristics can be regulated by changing the structural parameters of the as-proposed metamaterials. The as-designed metamaterials can be employed as efficient two-channel refractive index sensors, with sensitivity and figure of merit (FOM) of 288 nm RIU−1 and 150 RIU−1 for the first band, and sensitivity and FOM of up to 204 nm RIU−1 and 163.2 RIU−1 for the second band. This work not only opens up a new design idea for the realization of dual-band perfect absorber synchronously with ultra-narrow linewidth, but also provides potential attractive candidates for developing dual-frequency channel sensors.

Reconfigurable image processing metasurfaces with phase-change materials.

Optical metasurfaces have enabled analog computing and image processing within sub-wavelength footprints, and with reduced power consumption and faster speeds. While various image processing metasurfaces have been demonstrated, most of the considered devices are static and lack reconfigurability. Yet, the ability to dynamically reconfigure processing operations is key for metasurfaces to be used within practical computing systems. Here, we demonstrate a passive edge-detection metasurface operating in the near-infrared regime whose response can be drastically modified by temperature variations smaller than 10 °C around a CMOS-compatible temperature of 65 °C. Such reconfigurability is achieved by leveraging the insulator-to-metal phase transition of a thin layer of vanadium dioxide, which strongly alters the metasurface nonlocal response. Importantly, this reconfigurability is accompanied by performance metrics-such as numerical aperture, efficiency, isotropy, and polarization-independence - close to optimal, and it is combined with a simple geometry compatible with large-scale manufacturing. Our work paves the way to a new generation of ultra-compact, tunableand passive devices for all-optical computation, with potential applications in augmented reality, remote sensing and bio-medical imaging.

Multimodal Imaging-Guided Stem Cell Ocular Treatment.

Stem cell therapies are gaining traction as promising treatments for a variety of degenerative conditions. Both clinical and preclinical studies of regenerative medicine are hampered by the lack of technologies that can evaluate the migration and behavior of stem cells post-transplantation. This study proposes an innovative method to longitudinally image in vivo human-induced pluripotent stem cells differentiated to retinal pigment epithelium (hiPSC-RPE) cells by multimodal photoacoustic microscopy, optical coherence tomography, and fluorescence imaging powered by ultraminiature chain-like gold nanoparticle cluster (GNC) nanosensors. The GNC exhibits an optical absorption peak in the near-infrared regime, and the 7-8 nm size in diameter after disassembly enables renal excretion and improved safety as well as biocompatibility. In a clinically relevant rabbit model, GNC-labeled hiPSC-RPE cells migrated to RPE degeneration areas and regenerated damaged tissues. The hiPSC-RPE cells' distribution and migration were noninvasively, longitudinally monitored for 6 months with exceptional sensitivity and spatial resolution. This advanced platform for cellular imaging has the potential to enhance regenerative cell-based therapies.

Sensing Characteristic Analysis of All-Dielectric Metasurfaces Based on Fano Resonance in Near-Infrared Regime

A novel, all-dielectric metasurface, featuring a missing wedge-shaped nanodisk, is proposed to investigate optical characteristics. By introducing symmetry-breaking to induce Fano resonance, the metasurface achieves an impressive Q-factor of 1202 in the near-infrared spectrum, with a remarkably narrow full width at half maximum (FWHM) of less than 1 nm. The ability to adjust the wavelength resonance by manipulating the structure of the wedge-shaped nanodisk offers a simple and efficient approach for metasurface design. This breakthrough holds great potential for various applications in sensing and optical filtering, marking a significant advancement in the field of nanophotonics.

Surface phonon resonance: A new mechanism for enhancing photonic spin Hall effect and refractive index sensor

Abstract Metal-based surface plasmon resonance (SPR) plays an important role in enhancing the photonic spin Hall effect (SHE) and developing sensitive optical sensors. However, the very large negative permittivities of metals limit their applications beyond the near-infrared regime. In this work, we theoretically present a new mechanism to enhance the photonic SHE by taking advantage of SiC-supported surface phonon resonance (SPhR) in the mid-infrared regime. The transverse displacement of photonic SHE is very sensitive to the wavelength of incident light and the thickness of SiC layer. Under the optimal parameter setup, the calculated largest transverse displacement of SiC-based SPhR structure reaches up to 163.8 μm, which is much larger than the condition of SPR. Moreover, an NO2 gas sensor based on the SPhR-enhanced photonic SHE is theoretically proposed with the superior sensing performance. Both the intensity and angle sensitivity of this sensor can be effectively manipulated by varying the damping rate of SiC. The results may provide a promising paradigm to enhance the photonic SHE in the mid-infrared region and open up new opportunity of highly sensitive refractive index sensors.

Detecting Visible to Near-Infrared II Light via CsPbBr3 Nanocrystals/Y6 Heterojunctions.

In the endeavor to develop advanced photodetectors (PDs) with superior performance, all-inorganic perovskites, recognized for their outstanding photoelectric properties, have emerged as highly promising materials. Due to their unique electronic structure and band characteristics, the majority of all-inorganic perovskite materials are not sensitive to near-infrared (NIR) light. Here, we demonstrate the fabrication of a high-performance broadband PD comprising CsPbBr3 perovskite NCs/Y6 planar heterojunctions. The incorporation of Y6 not only facilitates charge transfer from CsPbBr3 NCs to Y6 for enhancing photodetection performance under visible illumination but also broadens the absorption spectrum range of the whole device toward the NIR regime. As a result, the heterojunction PD exhibits a photo-to-dark-current ratio above 105, a dynamic range of 149.5 dB, and an impressive lowest detection limit of incident power density of 1.6 nW/cm2 under 505 nm illumination. In the NIR regime, where photon energy is below the bandgap of CsPbBr3, electron-hole pairs can still be produced in the Y6 layer even when illuminated at 1120 nm. Consequently, photodetection is uniquely possible in PDs that incorporate heterojunctions when the illumination wavelength is longer than 565 nm. At 850 nm, the heterojunction device is capable of detecting light with power densities as low as 1.3 μW/cm2 corresponding to a LDR of 99.8 dB. The exceptional performance is attributed to the creation of a heterojunction between CsPbBr3 NCs and Y6. These findings propose a novel approach for developing broadband PDs based on perovskite NC materials.

The SPHERE view of the Chamaeleon I star-forming region

Context. The past few years have seen a revolution in the study of circumstellar disks. New instrumentation in the near-infrared and (sub)millimeter regimes have allowed us to routinely spatially resolve disks around young stars of nearby star-forming regions. As a result, we have found that substructures with scales of ~10 au in disks are common. We have also revealed a zoo of different morphologies, sizes, and luminosities that is as complex as the diversity of architectures found in evolved exoplanet systems. Aims. We study disk evolutionary trends as they appear in scattered light observations. Scattered light traces the micron-sized particles at the disk surface that are well coupled to the gas. This means that scattered light observations can be used to trace the distribution of the disk gas and its interaction with embedded perturbers. Methods. We used VLT/SPHERE to observe 20 systems in the Cha I cloud in polarized scattered light in the near-infrared. We combined the scattered light observations with existing literature data on stellar properties and with archival ALMA continuum data to study trends with system age and dust mass. We also connected resolved near-infrared observations with the spectral energy distributions of the systems. Results. In 13 of the 20 systems included in this study we detected resolved scattered light signals from circumstellar dust. For the CR Cha, CT Cha, CV Cha, SY Cha, SZ Cha, and VZ Cha systems we present the first detailed descriptions of the disks in scattered light. The observations found typically smooth or faint disks, often with little substructure, with the notable exceptions of SZ Cha, which shows an extended multiple-ringed disk, and WW Cha, which shows interaction with the cloud environment. New high S/N K-band observations of the HD 97048 system in our survey reveal a significant brightness asymmetry that may point to disk misalignment and subsequent shadowing of outer disk regions, possibly related to the suggested planet candidate in the disk. We resolve for the first time the stellar binary in the CS Cha system. Multiple wavelength observations of the disk around CS Cha have revealed that the system contains small, compact dust grains that may be strongly settled, consistent with numerical studies of circumbinary disks. We find in our sample that there is a strong anti-correlation between the presence of a (close) stellar companion and the detection of circumstellar material with five of our seven nondetections located in binary systems. We also find a correlation between disk mass, as inferred from millimeter observations, and the detection of scattered light signal. Finally, we find a tentative correlation between relative disk-to-star brightness in scattered light and the presence of a dust cavity in the inner (unresolved) disk, as traced by the system spectral energy distribution. At the same time, faint disks in our sample are generally younger than 2 Myr.

Extrapolation of Type Ia Supernova Spectra into the Near-infrared Using Principal Component Analysis

We present a method of extrapolating the spectroscopic behavior of Type Ia supernovae (SNe Ia) in the near-infrared (NIR) wavelength regime up to 2.30 μm using optical spectroscopy. Such a process is useful for accurately estimating K-corrections and other photometric quantities of SNe Ia in the NIR. A principal component analysis is performed on data consisting of Carnegie Supernova Project I & II optical and NIR FIRE spectra to produce models capable of making these extrapolations. This method differs from previous spectral template methods by not parameterizing models strictly by photometric light-curve properties of SNe Ia, allowing for more flexibility of the resulting extrapolated NIR flux. A difference of around −3.1% to −2.7% in the total integrated NIR flux between these extrapolations and the observations is seen here for most test cases including Branch core-normal and shallow-silicon subtypes. However, larger deviations from the observation are found for other tests, likely due to the limited high-velocity and broad-line SNe Ia in the training sample. Maximum-light principal components are shown to allow for spectroscopic predictions of the color-stretch light-curve parameter, s BV, within approximately ±0.1 units of the value measured with photometry. We also show these results compare well with NIR templates, although in most cases the templates are marginally more fitting to observations, illustrating a need for more concurrent optical+NIR spectroscopic observations to truly understand the diversity of SNe Ia in the NIR.