Near-field Response Research Articles

Core-Shell Nanoparticle Resonances in Near-Field Microscopy Revealed by Fourier-Demodulated Full-Wave Simulations.

We present a detailed investigation of the near-field optical response of core-shell nanoparticles using Fourier-demodulated full-wave simulations, revealing significant modifications to established contrast mechanisms in infrared scattering-type scanning near-field optical microscopy (s-SNOM). Our work examined the complex interplay of geometrical and optical resonances within core-shell structures. Using a finite element method (FEM) simulation closely aligned with the actual s-SNOM measurement processes, we capture the specific near-field responses in these nanostructures. Our findings show that core-shell nanoparticles exhibit unexpected distinct resonance shifts and massively enhanced scattering driven by both the core and shell properties. This investigation not only advances the understanding of near-field interactions in complex nanosystems but also provides a refined theoretical framework to accurately predict the optical signatures of nanostructures with internal heterogeneity.

Revealing Mode Formation in Quasi-Bound States in the Continuum Metasurfaces via Near-Field Optical Microscopy.

Photonic metasurfaces offer exceptional control over light at the nanoscale, facilitating applications spanning from biosensing, and nonlinear optics to photocatalysis. Many metasurfaces, especially resonant ones, rely on periodicity for the collective mode to form, which makes them subject to the influences of finite size effects, defects, and edge effects, which have considerable negative impact at the application level. These aspects are especially important for quasi-bound state in the continuum (BIC) metasurfaces, for which the collective mode is highly sensitive to perturbations due to high-quality factors and strong near-field enhancement. Here, the mode formation in quasi-BIC metasurfaces on the individual resonator level using scattering scanning near-field optical microscopy (s-SNOM) in combination with a new image processing technique, is quantitatively investigated. It is found that the quasi-BIC mode is formed at a minimum size of 10×10-unit cells much smaller than expected from far-field measurements. Furthermore, it is shown that the coupling direction of the resonators, defects and edge states have pronounced influence on the quasi-BIC mode. This study serves as a link between the far-field and near-field responses of metasurfaces, offering crucial insights for optimizing spatial footprint and active area, holding promise for augmenting applications such as catalysis and biospectroscopy.

Analysis of Near-Field Characteristics on Improved Structures of Double-Slot Antipodal Vivaldi Antenna.

A characterization of near-field impulse responses based on electromagnetic (EM) near-field data from an EM solver to explore features of the propagation process on a well-known wideband traveling wave antenna-double-slot Vivaldi antenna-is presented in this article. The intensity, propagating time and partitional response characteristics facilitate interpretation of the propagation process and impacts of the antenna partitions on the process. The EM energy flows guided, reoriented and scattered along a sequence of antennas transmitting and radiating segments were recognized. The geometric features of near-field wavefront surfaces supported evaluation of the EM flow proportions and antenna directivity. Impact of the structural section on radiation was also assessed by the partitional far-field response characteristic in frequency and time domains. Supported by many complementary characteristics in the analyses, inherent features of the propagation process were emphasized and false flags were minimized. By this approach, the simplification for the near-field propagation model contributed to enhancing the insight of near-field propagation processes on the double-slot antipodal Vivaldi antennas and enabled optimizing the antenna structure details.

Prediction of directivity characteristics of piezoelectric macro-fiber composite interdigital transducers: a semi-analytical approach

The employment of guided waves for structural health monitoring applications has attracted substantial attention in recent years. Piezoelectric transducers are frequently employed in these systems for elastic wave generation and acquisition. Their dynamic properties, i.e., direction-dependent frequency characteristics, are an important feature for designing a reliable monitoring strategy. Although analysis of the transducer directivity pattern can be performed using finite element models, these usually tend to be computationally very expensive, especially, for parametric and optimization studies. In this paper, a semi-analytical methodology is proposed that can predict the far-field responses of complex transducers of arbitrary shape and structure mounted on elastic plates. The approach reported here couples analytical far-field predictions with a local FE model evaluating the traction field generated by the transducer. Thus, the FE model captures the near-field responses, while the analytical part predicts the far-field responses. The implementation of this semi-analytical method requires development of analytical and numerical frameworks. The former includes computation of dispersion curves of the inspected plate, the stress and displacement profiles of wave modes and the excitability curves, while the latter includes estimation of the traction field between the transducer and the plate using the FE model. Owing to the popularity of piezoelectric macro-fiber composite (MFC) interdigital transducers, in this paper, we apply the proposed method to simulate the directivity patterns of the MFC IDTs of different configurations. To validate the reliability of the proposed method the simulated patterns are compared with experimental results obtained using Laser Doppler Vibrometer (LDV).

Symmetry-breaking-induced off-resonance second-harmonic generation enhancement in asymmetric plasmonic nanoparticle dimers

Abstract The linear and nonlinear optical properties of metallic nanoparticles have attracted considerable experimental and theoretical research interest. To date, most researchers have focused primarily on exploiting their plasmon excitation enhanced near-field and far-field responses and related applications in sensing, imaging, energy harvesting, conversion, and storage. Among numerous plasmonic structures, nanoparticle dimers, being a structurally simple and easy-to-prepare system, hold significant importance in the field of nanoplasmonics. In highly symmetric plasmonic nanostructures, although the odd-order optical nonlinearity of the near-surface region will be improved because of the enhanced near-fields, even-order nonlinear processes such as second-harmonic generation (SHG) will still be quenched and thus optically forbidden. Under this premise, it is imperative to introduce structural symmetry breaking to realize plasmon-enhanced even-order optical nonlinearity. Here, we fabricate a series of nanoparticle dimers each composed of two gold nanospheres with different diameters and subsequently investigate their structural asymmetry dependent linear and nonlinear optical properties. We find that the SHG intensities of gold nanosphere dimers are significantly enhanced by structural asymmetry under off-resonance excitation while the plasmonic near-field enhancement mainly affects SHG under on-resonance excitation. Our results reveal that symmetry breaking will play an indispensable role when designing novel coupled plasmonic nanostructures with enhanced nonlinear optical properties.

Giant Terahertz Birefringence in an Ultrathin Anisotropic Semimetal.

Manipulating the polarization of light at the nanoscale is key to the development of next-generation optoelectronic devices. This is typically done via waveplates using optically anisotropic crystals, with thicknesses on the order of the wavelength. Here, using a novel ultrafast electron-beam-based technique sensitive to transient near fields at THz frequencies, we observe a giant anisotropy in the linear optical response in the semimetal WTe2 and demonstrate that one can tune the THz polarization using a 50 nm thick film, acting as a broadband wave plate with thickness 3 orders of magnitude smaller than the wavelength. The observed circular deflections of the electron beam are consistent with simulations tracking the trajectory of the electron beam in the near field of the THz pulse. This finding offers a promising approach to enable atomically thin THz polarization control using anisotropic semimetals and defines new approaches for characterizing THz near-field optical response at far-subwavelength length scales.

All-optical subcycle microscopy on atomic length scales.

Bringing optical microscopy to the shortest possible length and time scales has been a long-soughtgoal, connecting nanoscopic elementary dynamics with the macroscopic functionalities of condensed matter. Super-resolution microscopy has circumvented the far-field diffraction limit by harnessing optical nonlinearities1. By exploiting linear interaction with tip-confined evanescent light fields2, near-field microscopy3,4 has reached even higher resolution, prompting a vibrant research field by exploring the nanocosm in motion5-19. Yet the finite radius of the nanometre-sized tip apex has prevented access to atomic resolution20. Here we leverage extreme atomic nonlinearities within tip-confined evanescent fields to push all-optical microscopy to picometric spatial and femtosecond temporal resolution. On these scales, we discover an unprecedented and efficient non-classical near-field response, in phase with the vector potential of light and strictly confined to atomic dimensions. This ultrafast signal is characterized by an optical phase delay of approximately π/2 and facilitates direct monitoring of tunnelling dynamics. We showcase the power of our optical concept by imaging nanometre-sized defects hidden to atomic force microscopy and by subcycle sampling of current transients on a semiconducting van der Waals material. Our results facilitate access to quantum light-matter interaction and electronic dynamics at ultimately short spatio-temporal scales in both conductive and insulating quantum materials.

Near-Field Photoluminescence of WS<sub>2</sub> and MoS<sub>2</sub> Monolayers, Grown by Chemical Vapor Deposition

Monolayer triangular WS2 and MoS2 islands grown by chemical vapor deposition was investigated by near-field photoluminescence (nano-PL) enhanced by the metallized atomic force microscope (AFM) tip. To achieve maximum near-field response from WS2 and MoS2 materials fabricated Au and Ag metallized AFM tips were used. Maximum nano-PL responds from the islands is observed under the resonant conditions when the energy of the localized surface plasmon of the metallized probe coincides with the energy of the exciton luminescence of the WS2 and MoS2 materials. Nano-PL mapping of the exciton response allows visualizing structural defects and determine the local thickness changes of monolayer islands with nanometer spatial resolution.

Analysis of Near-Field Magnetic Responses on ZrTe5 through Cryogenic Magneto-THz Nano-Imaging

One manifestation of light-Weyl fermion interaction is the emergence of chiral magnetic effects under magnetic fields. Probing real space magnetic responses at terahertz (THz) scales is challenging but highly desired, as the local responses are less affected by the topologically trivial inhomogeneity that is ubiquitous in spatially averaged measurements. Here, we implement a cryogenic THz microscopy instrument under a magnetic field environment—a task only recently achieved. We explore the technical approach of this system and characterize the magnetic field’s influence on our AFM operation by statistical noise analysis. We find evidence for local near-field spatial variations in the topological semimetal ZrTe5 up to a 5-Tesla magnetic field and obtain near-field THz spectra to discuss their implications for future studies on the chiral magnetic effect.

Seismic response of RC bridges under near-fault ground motions: A parametric investigation

Natural disasters such as earthquakes can potentially harm bridges and incur significant socioeconomic losses. This study examines the effect of near-fault ground motions on reinforced concrete bridges, specifically the variation in the seismic performance with the height, aspect ratio, and longitudinal reinforcement. A suite of 332 near-fault ground motions is used to evaluate the performance of 60 bridge models in OpenSees, and the seismic responses are measured in terms of pier curvature ductility, maximum bearing deformation, and deck displacement. Linear regression analysis is used to generate probabilistic seismic demand models and fragility curves corresponding to different damage states. Expected behaviors are displayed within the models grouped with respect to height classes. Since the column diameters are based on aspect ratios, the effect of taller columns reduces the exceedance probabilities. This brought forward a need to define the damage states for tall columns in a manner different from short or medium columns. Moreover, this study underscores the need to update HAZUS fragility median values for near-field seismic response of RC bridges.

Noise mitigation in rectangular jets through plasma actuator-based shear layer control

A computational analysis is performed to study the three-dimensional response of rectangular shear layers to plasma actuator-based control, in the context of sound mitigation of supersonic non-axisymmetric jets. A Mach $1.5$ rectangular jet with an aspect ratio $2:1$ is controlled using experimentally informed actuation patterns, referred to as M0, M1, M2, M3, M ${\rm \pi}$ and M+/ $-$ 1. While the first five progressively increase the phase difference between successive actuators thus enhancing three-dimensionality of the shear layer structures, the latter corresponds to the flapping mode of the jet. A preliminary linear analysis identifies that the frequency, $St\sim 1$ , has a relatively high overall amplification within the baseline shear layer, and is hence utilized for control in the subsequent nonlinear simulations. Each actuation reveals unique near-field vortical and acoustic responses that have a profound impact on far-field noise levels. The M0 actuation induces circumferentially interconnected strong streamwise vortices, while M1 actuation enhances the circumferential variability in the coherent structures. The M2 actuation encompasses both these effects, and along with a very low tonal impact of forcing, produces the most desirable far-field noise mitigation ( ${\sim }2.6\,{\rm dB}$ ), contributed by a broadband reduction around the column-mode peak of the baseline jet. Beyond M2 actuation, effectiveness of control saturates, particularly along the direction of peak noise radiation. Through a near-field analysis of the acoustic component, the efficacy of M2 actuation is attributed to the attenuation of the radiative efficiency of the jet, including reduced energy in the supersonic phase speeds, and redistribution of energy into the higher helical modes. Further, it curtails the nonlinear difference interactions in the plume that energize column-mode frequencies, which often appear as strong intermittent sound-producing events. While the shear layer turbulent kinetic energy decreases with actuation, the controlled jets show minimal variations in mean flow properties, particularly under M2 actuation, suggesting this to be a promising small-perturbation-based noise control strategy.

Advanced Terahertz Refractive Sensing And Fingerprint Recognition Through Metasurface-Excited Surface Waves.

High-sensitive metasurface-based sensors are essential for effective substance detection and insightful bio-interaction studies, which compress light in subwavelength volumes to enhance light-matter interactions. However, current methods to improve sensing performance always focus on optimizing near-field response of individual meta-atom, and fingerprint recognition for bio-substances necessitates several pixelated metasurfaces to establish a quasi-continuous spectrum. Here, a novel sensing strategy is proposed to achieve Terahertz (THz) refractive sensing, and fingerprint recognition based on surface waves (SWs). Leveraging the long-range transmission, strong confinement, and interface sensitivity of SWs, a metasurface-supporting SWs excitation and propagation is experimentally verified to achieve sensing integrations. Through wide-band information collection of SWs, the proposed sensor not only facilitates refractive sensing up to 215.5°/RIU, but also enables the simultaneous resolution of multiple fingerprint information within a continuous spectrum. By covering 5µm thickness of polyimide, quartz and silicon nitride layers, the maximum phase change of 91.1°, 101.8°, and 126.4° is experimentally obtained within THz band, respectively. Thus, this strategy broadens the research scope of metasurface-excited SWs and introduces a novel paradigm for ultrasensitive sensing functions.

Nanoscale Infrared Spectroscopic Characterization of Extended Defects in 4H-Silicon Carbide.

Extended defects in wide-bandgap semiconductors have been widely investigated using techniques providing either spectroscopic or microscopic information. Nano-Fourier transform infrared spectroscopy (nano-FTIR) is a nondestructive characterization method combining FTIR with nanoscale spatial resolution (∼20 nm) and topographic information. Here, we demonstrate the capability of nano-FTIR for the characterization of extended defects in semiconductors by investigating an in-grown stacking fault (IGSF) present in a 4H-SiC epitaxial layer. We observe a local spectral shift of the mid-infrared near-field response, consistent with the identification of the defect stacking order as 3C-SiC (cubic) from comparative simulations based on the finite dipole model (FDM). This 3C-SiC IGSF contrasts with the more typical 8H-SiC IGSFs reported previously and is exemplary in showing that nanoscale spectroscopy with nano-FTIR can provide new insights into the properties of extended defects, the understanding of which is crucial for mitigating deleterious effects of such defects in alternative semiconductor materials and devices.

Extrinsic chirality tailors Stokes parameters in simple asymmetric metasurfaces.

Metasurfaces tailor electromagnetic confinement at the nanoscale and can be appropriately designed for polarization-dependent light-matter interactions. Adding the asymmetry degree to the desing allows for circular polarizations of opposite handedness to be differently absorbed or emitted, which is of interest in fields spanning from chiral sensing to flat optics. Here, we show that simple, low-cost asymmetric metasurfaces can control Stokes parameters in the transmitted far-field. With only 50 nm of asymmetric plasmonic shells on self-assembled polystyrene nanospheres, our metasurfaces allow for great spectral and incident angle tunability. We first investigated broadband extrinsic chirality in metasurfaces with asymmetric plasmonic semishells; we found high extinction circular dichroism (CD) in the near-infrared range. We then excited it with linear polarization and performed hyperspectral Stokes polarimetry on the transmitted field. We showed that the S3 parameter follows the behavior of CD in extinction, and that the output field position on the Poincaré sphere can be widely controlled by using the incidence angle and wavelength. Furthermore, simulations agreed well with the experiments and showed how the near-field chiro-optical response influences the extrinsic chiral behavior in absorption and the polarization state of the transmitted field.

Far-field, near-field and photothermal response of plasmonic twinned magnesium nanostructures.

Magnesium nanoparticles offer an alternative plasmonic platform capable of resonances across the ultraviolet, visible and near-infrared. Crystalline magnesium nanoparticles display twinning on the (101̄1), (101̄2), (101̄3), and (112̄1) planes leading to concave folded shapes named tents, chairs, tacos, and kites, respectively. We use the Wulff-based Crystal Creator tool to expand the range of Mg crystal shapes with twinning over the known Mg twin planes, i.e., (101̄x), x = 1, 2, 3 and (112̄y), y = 1, 2, 3, 4, and study the effects of relative facet expression on the resulting shapes. These shapes include both concave and convex structures, some of which have been experimentally observed. The resonant modes, far-field, and near-field optical responses of these unusual plasmonic shapes as well as their photothermal behaviour are reported, revealing the effects of folding angle and in-filling of the concave region. Significant differences exist between shapes, in particular regarding the maximum and average electric field enhancement. A maximum field enhancement (|E|/|E0|) of 184, comparable to that calculated for Au and Ag nanoparticles, was found at the tips of the (112̄4) kite. The presence of a 5 nm MgO shell is found to decrease the near-field enhancement by 67% to 90% depending on the shape, while it can increase the plasmon-induced temperature rise by up to 42%. Tip rounding on the otherwise sharp nanoparticle corners also significantly affects the maximum field enhancement. These results provide guidance for the design of enhancing and photothermal substrates for a variety of plasmonic applications across a wide spectral range.

Plasmon-induced magnetic anapole mode assisted strong field enhancement.

Optical metamaterials, sensing, nonlinear optics, and surface-enhanced spectroscopies have witnessed the remarkable potential of the anapole mode. While dielectric particles with a high refractive index have garnered significant attention in recent years, the exploration of plasmonic anapole modes with intense localized electric field enhancements in the visible frequency range remains limited. In this study, we present a theoretical investigation on the relationship between the strongest near-field response and magnetic anapole modes, along with their substantial enhancement of Raman signals from probing molecules. These captivating findings arise from the design of a practical metallic oblate spheroid-film plasmonic system that generates magnetic anapole resonances at frequencies within the visible-near-infrared range. This research not only sheds light on the underlying mechanisms in a wide range of plasmon-enhanced spectroscopies but also paves the way for innovative nano-device designs.

Near-field modeling of the head-related transfer function by using the dummy head sound source

Various approaches based on direct measurement have been used to obtain the precise headrelated transfer function (HRTF). However, several problems persist, such as scattering of sound source and distance effect, which are related to the measurement configuration. In this work, the modified dummy head having two sound sources located at the ear positions is applied as the sound source reciprocally to overcome the trouble. By using the near-field acoustic holography, the sound sources located in the ear holes are reconstructed from the measured data in the near-field hologram. One can predict the acoustic transfer function between the ear holes and the field positions at any point using the recovered source information described in spherical harmonics. The obtained transfer function is valid for predicting the binaural response from any sound source position. This configuration is possible to measure the near-field response with the relatively small scattering effect because of the low Helmholtz number of microphones. The far-field reconstruction of HRTF is also possible with the near-field measurement data using acoustical holography. The proposed method is demonstrated with the modified B&K HATS system, in which the microphones in the ear holes are replaced by pipe sources connected to the loudspeaker.

Infrared nano-imaging of Dirac magnetoexcitons in graphene.

Magnetic fields can have profound effects on the motion of electrons in quantum materials. Two-dimensional electron systems subject to strong magnetic fields are expected to exhibit quantized Hall conductivity, chiral edge currents and distinctive collective modes referred to as magnetoplasmons and magnetoexcitons. Generating these propagating collective modes in charge-neutral samples and imaging them at their native nanometre length scales have thus far been experimentally elusive. Here we visualize propagating magnetoexciton polaritons at their native length scales and report their magnetic-field-tunable dispersion in near-charge-neutral graphene. Imaging these collective modes and their associated nano-electro-optical responses allows us to identify polariton-modulated optical and photo-thermal electric effects at the sample edges, which are the most pronounced near charge neutrality. Our work is enabled by innovations in cryogenic near-field optical microscopy techniques that allow for the nano-imaging of the near-field responses of two-dimensional materials under magnetic fields up to 7 T. This nano-magneto-optics approach allows us to explore and manipulate magnetopolaritons in specimens with low carrier doping via harnessing high magnetic fields.

Integrating collapsible plasmonic gaps on near-field probes for polarization-resolved mapping of plasmon-enhanced emission in 2D material.

Scanning near-field optical microscopy (SNOM) is an important technique used to study the optical properties of material systems at the nanoscale. In previous work, we reported on the use of nanoimprinting to improve the reproducibility and throughput of near-field probes including complicated optical antenna structures such as the 'campanile' probe. However, precise control over the plasmonic gap size, which determines the near-field enhancement and spatial resolution, remains a challenge. Here, we present a novel approach to fabricating a sub-20 nm plasmonic gap in a near-field plasmonic probe through the controlled collapse of imprinted nanostructures using atomic layer deposition (ALD) coatings to define the gap width. The resulting ultranarrow gap at the apex of the probe provides a strong polarization-sensitive near-field optical response, which results in an enhancement of the optical transmission in a broad wavelength range from 620 to 820 nm, enabling tip-enhanced photoluminescence (TEPL) mapping of 2-dimensional (2D) materials. We demonstrate the potential of this near-field probe by mapping a 2D exciton coupled to a linearly polarized plasmonic resonance with below 30 nm spatial resolution. This work proposes a novel approach for integrating a plasmonic antenna at the apex of the near-field probe, paving the way for the fundamental study of light-matter interactions at the nanoscale.

Near-Field Channel Estimation in Mixed LoS/NLoS Environments for Extremely Large-Scale MIMO Systems

Accurate channel model and channel estimation are essential to empower extremely large-scale MIMO (XL-MIMO) in 6G networks with ultra-high spectral efficiency. With the sharp increase in the antenna array aperture of the XL-MIMO scenario, the electromagnetic propagation field will change from far-field to near-field. Unfortunately, due to the near-field effect, most of the existing XL-MIMO channel models fail to describe mixed line-of-sight (LoS) and non-line-of-sight (NLoS) path components simultaneously. In this paper, a mixed LoS/NLoS near-field XL-MIMO channel model is proposed to match the practical near-field XL-MIMO scenario, where the LoS path component is modeled by the geometric free space propagation assumption while NLoS path components are modeled by the near-field array response vectors. Then, to define the range of near-field for XL-MIMO, the MIMO Rayleigh distance (MIMO-RD) and MIMO advanced RD (MIMO-ARD) is derived. Next, a two stage channel estimation algorithm is proposed, where the LoS path component and NLoS path components are estimated separately. Moreover, the Cramér-Rao lower bound (CRLB) of the proposed algorithm is derived in this paper. Numerical simulation results demonstrate that, the proposed two stage scheme is able to outperform the existing methods in both the theoretical channel model and the QuaDRiGa channel emulation platform.