Near-field Response Research Articles

Probing dark exciton navigation through a local strain landscape in a WSe2 monolayer

In WSe2 monolayers, strain has been used to control the energy of excitons, induce funneling, and realize single-photon sources. Here, we developed a technique for probing the dynamics of free excitons in nanoscale strain landscapes in such monolayers. A nanosculpted tapered optical fiber is used to simultaneously generate strain and probe the near-field optical response of WSe2 monolayers at 5 K. When the monolayer is pushed by the fiber, its lowest energy states shift by as much as 390 meV (>20% of the bandgap of a WSe2 monolayer). Polarization and lifetime measurements of these red-shifting peaks indicate they originate from dark excitons. We conclude free dark excitons are funneled to high-strain regions during their long lifetime and are the principal participants in drift and diffusion at cryogenic temperatures. This insight supports proposals on the origin of single-photon sources in WSe2 and demonstrates a route towards exciton traps for exciton condensation.

Ultrasensitive Frequency Shifting of Dielectric Mie Resonance near Metallic Substrate.

Dielectric resonators on metallic surface can enhance far-field scattering and boost near-field response having promising applications in nonlinear optics and reflection-type devices. However, the dependence of gap size between dielectric resonator and metallic surface on Mie resonant frequency is complex and desires a comprehensive physical interpretation. Here, we systematically study the effect of metallic substrate on the magnetic dipole (MD) resonant frequency at X-band by placing a high permittivity CaTiO3 ceramic block on metallic substrate and regulating their gap size. The simulated and experimental results show that there are two physical mechanisms to codetermine the metallic substrate-induced MD frequency. The greatly enhanced electric field pair in the gap and the coupling of MD resonance with its mirror image are decisive for small and large gaps, respectively, making the MD resonant frequency present an exponential blue shift first and then a slight red shift with increasing gap size. Further, we use the two mechanisms to explain different frequency shifting properties of ceramic sphere near metallic substrate. Finally, taking advantage of the sharp frequency shifting to small gaps, the ceramic block is demonstrated to accurately estimate the thickness or permittivity of thin film on metallic substrate through a governing equation derived from the method of symbolic regression. We believe that our study will help to understand the resonant frequency shifting for dielectric particle near metallic substrate and give some prototypes of ultrasensitive detectors.

Van der Waals materials as dielectric layers for tailoring the near-field photonic response of surfaces.

Epsilon near-zero photonics and surface polariton nanophotonics have become major fields within optics, leading to unusual and enhanced light-matter interaction. Specific dielectric responses are required in both cases, which can be achieved, e.g., via operation near a material's electronic or phononic resonance. However, this condition restricts operation to a specific, narrow frequency range. It has been shown that using a thin dielectric layer can adjust the dielectric response of a surface and, therefore, the operating frequency for achieving specific photonic excitations. Here, we show that a surface's optical properties can be tuned via the deposition/transference of ultra-thin layered van der Waals (vdW) crystals, the thicknesses of which can easily be adjusted to provide the desired response. In particular, we experimentally and theoretically show that the surface phonon resonance of a silica surface can be tuned by ∼50cm-1 through the simple deposition of nanometer-thick exfoliated flakes of black phosphorus. The surface properties were probed by infrared nanospectroscopy, and results show a close agreement with the theory. The black phosphorus-silica layered structure effectively acts as a surface with a tunable effective dielectric constant that presents an infrared response dependent on the black phosphorus thickness. In contrast, with a lower dielectric constant, hexagonal boron nitride does not significantly tune the silica surface phonon polariton. Our approach also applies to epsilon near-zero surfaces, as theoretically shown, and to polaritonic surfaces operating at other optical ranges.

Do Coronal Loops Oscillate in Isolation?

Abstract Images of the solar corona by extreme-ultraviolet telescopes reveal elegant arches of glowing plasma that trace the corona’s magnetic field. Typically, these loops are preferentially illuminated segments of an arcade of vaulted field lines and such loops are often observed to sway in response to nearby solar flares. A flurry of observational and theoretical effort has been devoted to the exploitation of these oscillations with the grand hope that seismic techniques might be used as probes of the strength and structure of the corona’s magnetic field. The commonly accepted viewpoint is that each visible loop oscillates as an independent entity and acts as a one-dimensional wave cavity for magnetohydrodynamic kink waves. We argue that for many events, this generally accepted model for the wave cavity is fundamentally flawed. In particular, the 3D magnetic arcade in which the bright loop resides participates in the oscillation. Thus, the true wave cavity is larger than the individual loop and inherently multidimensional. We derive the skin depth of the near-field response for an oscillating loop and demonstrate that most loops are too close to other magnetic structures to oscillate in isolation. Further, we present a simple model of a loop embedded within an arcade and explore how the eigenmodes of the arcade and the eigenmodes of the loop become coupled. In particular, we discuss how distinguishing between these two types of modes can be difficult when the motions within the arcade are often invisible.

Binary Plasmonic Assembly Films with Hotspot-Type-Dependent Surface-Enhanced Raman Scattering Properties.

Tuning and controlling the plasmon coupling of noble metal nanoparticles are significant for enhancing their near-field and far-field responses. In this work, a novel heterogeneous plasmonic assembly with a controllable hot spot model was proposed by the conjugation of Au nanospheres (NSs) and Au@Ag core-shell nanocube (NC) films. Three hotspot configurations including point-to-point type, point-to-facet type, and facet-to-facet type were fabricated and transformed simply by adjusting the doping ratio of nanoparticles in the co-assembly film. Expectedly, the localized surface plasmon resonance (LSPR) property and surface-enhanced Raman scattering (SERS) performance of the binary assembly film exhibit distinct diversity due to the change in the hotspot conformation. Interestingly, the point-to-facet hotspot in hybrid assembly films can provide the most extraordinary enhancement for SERS behavior compared with single-component Au NS and Au@Ag NC plasmonic assemblies, which is further confirmed by the finite-different time-domain simulation results of dimer nanostructures. In addition, the two-dimensional binary assemblies of Au NS doping in Au@Ag NCs with excellent sensitivity and high reproducibility were successfully applied in the identification of ketamine. This work opens a new avenue toward the fabrication of plasmonic metal materials with collective LSPR properties and sensitive SERS behavior.

Near-Field Imaging and Time-Domain Dynamics of Photonic Topological Edge States in Plasmonic Nanochains.

Time-domain dynamic evolution properties of topological states play an important role in both fundamental physics study and practical applications of topological photonics. However, owing to the absence of available ultrafast time-domain dynamic characterization methods, studies have mostly focused on the frequency-domain-based properties, and there are few reports demonstrating the time-domain-based properties. Here, we measured the dynamic near-field responses of plasmonic topological structures of gold nanochains with the configuration of the Su-Schrieffer-Heeger model by using ultrahigh spatial-temporal resolution photoemission electron microscopy. The dephasing time of plasmonic topological edge states increases with increasing the bulk lattice number that has a threshold requirement and finally reaches saturation. We directly revealed through simulation that there is a transient bulk state in the evolution of topological edge states, that is, the energy undergoes relaxation from oscillation between the bulk lattice and the edge. This work shows a new perspective of time-domain dynamic topological photonics.

Dynamic Tuning of Moiré Excitons in a WSe2/WS2 Heterostructure via Mechanical Deformation.

Moiré superlattices in van der Waals (vdW) heterostructures form by stacking atomically thin layers on top of one another with a twist angle or lattice mismatch. The resulting moiré potential leads to a strong modification of the band structure, which can give rise to exotic quantum phenomena ranging from correlated insulators and superconductors to moiré excitons and Wigner crystals. Here, we demonstrate the dynamic tuning of moiré potential in a WSe2/WS2 heterostructure at cryogenic temperature. We utilize the optical fiber tip of a cryogenic scanning near-field optical microscope (SNOM) to locally deform the heterostructure and measure its near-field optical response simultaneously. The deformation of the heterostructure increases the moiré potential, which leads to a red shift of the moiré exciton resonances. We observe the interlayer exciton resonance shifts up to 20 meV, while the intralayer exciton resonances shift up to 17 meV.

Tuning of Optical Phonons in α-MoO3-VO2 Multilayers.

Merging the properties of VO2 and van der Waals (vdW) materials has given rise to novel tunable photonic devices. Despite recent studies on the effect of the phase change of VO2 on tuning near-field optical response of phonon polaritons in the infrared range, active tuning of optical phonons (OPhs) using far-field techniques has been scarce. Here, we investigate the tunability of OPhs of α-MoO3 in a multilayer structure with VO2. Our experiments show the frequency and intensity tuning of 2 cm-1 and 11% for OPhs in the [100] direction and 2 cm-1 and 28% for OPhs in the [010] crystal direction of α-MoO3. Using the effective medium theory and dielectric models of each layer, we verify these findings with simulations. We then use loss tangent analysis and remove the effect of the substrate to understand the origin of these spectral characteristics. We expect that these findings will assist in intelligently designing tunable photonic devices for infrared applications, such as tunable camouflage and radiative cooling devices.

Local near-field optical response of gold nanohole excited by propagating plasmonic excitations

The remote excitation of a localized surface plasmons (LSP) by the propagating plasmonic excitations, i.e., propagating surface plasmons (PSP), receives increasing attention in recent years. Here, we study the local near-field optical response of the gold nanohole, which support LSP, remotely excited by the PSP (PSP-LSP) and the results show that this optical response of the gold nanohole relates to the excitation field, the local near-field optical spectra show a redshift phenomenon, but the intrinsic frequency of LSP remains invariant. We attribute this spectral redshift phenomenon of the PSP-LSP to the dominating effects of the PSP. A weak dependence of the resonant wavelength peak on the size of a nanostructure has been observed. Moreover, it is found that the dephasing time of the PSP-LSP is longer than the case directly excited by the laser field, and it presents a decreased trend with the increasing distance from the PSP launching location. The results in this work can be used to improve the efficiency of remote excitations and provide a new path to prolong the dephasing time of the enhanced resonant field.

The FDTD Analysis of Near-Field Response for Microgroove Structure With Standing Wave Illumination for the Realization of Coherent Structured Illumination Microscopy

Abstract Microstructures are widely used in the manufacture of functional surfaces. An optical-based super-resolution, non-invasive method is preferred for the inspection of surfaces with massive microstructures. The structured illumination microscopy (SIM) uses standing-wave illumination to reach optical super-resolution. Recently, coherent SIM is being studied. It can obtain not only the super-resolved intensity distribution but also the phase and amplitude distribution of the sample surface beyond the diffraction limit. By analysis of the phase-depth dependency, the depth measurement for microgroove structures with coherent SIM is expected. FDTD analysis is applied for observing the near-field response of microgroove under the standing-wave illumination. The near-field phase shows depth dependency in this analysis. Moreover, the effects from microgroove width, the incident angle, and the relative position between the standing-wave peak and center of the microgroove are investigated. It is found the near-field phase change can measure depth until 200 nm (aspect ratio 1) with an error of up to 20.4 nm in the case that the microgroove width is smaller than half of the wavelength.

Probing electron transport in plasmonic molecular junctions with two-photon luminescence spectroscopy

Abstract Plasmonic core–molecule–shell (CMS) nanojunctions provide a versatile platform for studying electron transport through conductive molecules under light excitation. In general, the impact of electron transport on the near-field response of CMS nanojunctions is more prominent than on the far-field property. In this work, we use two-photon luminescence (TPL) spectroscopy to probe the effect of electron transport on the plasmonic properties of gold CMS nanojunctions. Theoretical calculations show that the TPL response of such nanojunctions is closely related to the near-field enhancement inside the metal regions, and can be strongly affected by the electron transport through the embedded molecules. TPL excitation spectroscopy results for three CMS nanojunctions (0.7, 0.9 and 1.5 nm junction widths) reveal no perceivable contribution from their low-energy plasmon modes. This observation can be well explained by a quantum-corrected model, assuming significant conductance for the molecular layers and thus efficient charge transport through the junctions. Furthermore, we explore the charge transport mechanism by investigating the junction width dependent TPL intensity under a given excitation wavelength. Our study contributes to the field of molecular electronic plasmonics through opening up a new avenue for studying quantum charge transport in molecular junctions by non-linear optical spectroscopy.

An equivalent circuit based electro-vibro-acoustic model of a cylindrical transducer array.

Cylindrical transducer arrays are used in many applications such as SONAR, depth sounding, ultrasound imaging, etc. This study developed the equivalent circuit (EC)-based-model of a cylindrical array with theoretical acoustic coupling. The electro-mechanical-acoustic coupling impedance matrix was first constructed to determine the response of the array. The electrical and mechanical impedances of the individual transducers were obtained by the EC model. The acoustic radiation impedances were obtained by the theoretical model. The cylindrical array is modeled by coupling the EC model and acoustic radiation impedances. The acoustic transfer matrix was then constructed using the theoretical method to determine both the far-field and near-field acoustic responses. The characteristics of the transducer array were represented with the electrical admittance, velocity response as a function of the voltage, transmit voltage response, beam pattern, and normalized pressure curve. To verify the proposed model, the analysis results were successfully compared to those of the fully coupled finite element model. Due to its high accuracy and computational efficiency, the proposed EC-based-model is expected to be useful for the conceptual design stage, which requires frequent design changes.

Estimating the Peak Longitudinal Near-Field Seismic Response of an Isolated Bridge Using Basic Pulse Motions

The peak dynamic responses of a typical isolated bridge under basic pulse motions and a set of near-field (NF) earthquake records were investigated in this study. A numerical model of the isolated bridge was constructed and validated using seismic response measurements. Nonlinear time-history analyses were conducted for the isolated bridge by considering various post-yield stiffness ratios of the isolators and dominant pulse periods of the ground motions. The analysis results revealed that the peak pulse response and mean-plus-one standard deviation of the peak NF seismic response had similar trends of variation with the stiffness ratio. The ratio of the mean-plus-one standard deviation of the peak NF seismic response to the peak pulse response was described using a simple empirical formula. Using this formula, the NF seismic response of the isolated bridge could be estimated from the one-cycle Type-A pulse motion. The aforementioned ratio was approximated to 0.75 if the pulse period was larger than 6 s. However, the aforementioned ratio varied from 0.1 to 0.5 when the post-yield stiffness ratio varied from 0.1 to 0.45 if the pulse period was 1 s.

Effect of sample anisotropy on scanning near-field optical microscope images

Scattering-type scanning near-field optical microscopy (s-SNOM) has been widely used to characterize strongly correlated electronic, two dimensional, and plasmonic materials, and it has enormous potential for biological applications. Many of these materials exhibit anisotropic responses that complicate the extraction of dielectric constants from s-SNOM measurements. Here, we generalize our recently developed approach for retrieving the near-field scattering signal from isotropic systems and apply it to anisotropic dielectrics. Specifically, we compare our theoretical results with experimental measurements on modestly anisotropic sapphire that exhibit strong resonances at the infrared frequency range. Good agreement with the experimental result is found. Our result is important for understanding the near-field response of low damping, anisotropic polaritonic states in dielectric media.

Topological-Insulator-Based Gap-Surface Plasmon Metasurfaces

Topological insulators (TIs) have unique highly conducting symmetry-protected surface states while the bulk is insulating, making them attractive for various applications in condensed matter physics. Recently, topological insulator materials have been tentatively applied for both near- and far-field wavefront manipulation of electromagnetic waves, yielding superior plasmonic properties in the ultraviolet (UV)-to-visible wavelength range. However, previous reports have only demonstrated inefficient wavefront control based on binary metasurfaces that were digitalized on a TI thin film or non-directional surface plasmon polariton (SPP) excitation. Here, we numerically demonstrated the plasmonic capabilities of the TI Bi2Te3 as a material for gap–surface plasmon (GSP) metasurfaces. By employing the principle of the geometric phase, a far-field beam-steering metasurface was designed for the visible spectrum, yielding a cross-polarization efficiency of 34% at 500 nm while suppressing the co-polarization to 0.08%. Furthermore, a birefringent GSP metasurface design was studied and found to be capable of directionally exciting SPPs depending on the incident polarization. Our work forms the basis for accurately controlling the far- and near-field responses of TI-based GSP metasurfaces in the visible spectral range.

Calibration to Mitigate Near-Field Antennas Effects for a MIMO Radar Imaging System.

A calibration method for a high-resolution hybrid MIMO turntable radar imaging system is presented. A line of small metal spheres is employed as a test pattern in the calibration process to measure the position shift caused by undesired antenna effects. The unwanted effects in the antenna near-field responses are analysed, modelled and significantly mitigated based on the symmetry and differences in the responses of the MIMO configuration.

Validity of Machine Learning in the Quantitative Analysis of Complex Scanning Near-Field Optical Microscopy Signals Using Simulated Data

Scattering-type scanning near-field optical microscope (s-SNOM) is a modern technique for subdiffractional optical imaging and spectroscopy. Over the past two decades, tremendous efforts have been devoted to modeling complex tip-sample interactions in s-SNOM, aimed at understanding the electrodynamics of materials at the nanoscale. However, due to complexities in analytical methods and the limited computation power for fully numerical simulations, compromises must be made to facilitate the modeling of tip-sample interaction, such as using quasistatic approximation or unrealistic tip geometries. $\mathrm{In}$ this paper, we apply a variety of widely utilized machine-learning methods, including k nearest neighbor and feed-forward neural network etc. to study the phase-resolved spectroscopic near-field response. With only a small set of training data, which is simulated using the finite-dipole model, we demonstrate that the relation between the experimental near-field signal and sample optical constant can be one to one mapped without the need for tip modeling: for a given material with a moderate dielectric function, its complex near-field spectrum can be accurately determined within the mid-IR spectral range, and vice versa. Our preliminary study sets the stage for future exploration using real experimental data. Our method is beneficial for processing the increasing amount of data accumulated across many research groups and especially useful for user facilities such as synchrotron-based national laboratories where a large amount of data is generated on a daily basis.

Prediction of the thermal-hydraulic-mechanical response of a geological repository at large scale and sensitivity analyses

To better understand the Thermal-Hydraulic-Mechanical (THM) response of the rock caused by the high-level radioactive waste (HLW) released heat in the Callovo-Oxfordian formation (COx) in the near-field and far-field areas, a series of coupled THM modelling is performed. This study presents a case study based on the French geological repository for HLW (Cigéo project) to better assess modelling of deep geological repositories (DGR) within the DECOVALEX-2019 framework. In this study, the proposed coupled THM model, implemented in the platform of COMSOL, is validated by comparing the modelled THM results for a point heat source in an infinite rock mass with an analytical solution. It is also validated by comparing its thermal component for the Base Case with accurate results calculated using another numerical method. To shorten the calculation time, the DGR is modelled using six cuboid blocks representing 162 HLW cells and only six central HLW cells of interest modelled in detail. This simplification is validated. This model can easily be used to model not only the near-field THM response of the rock but also the far-field THM response. The influence of the boundary conditions applied on the gallery wall, HLW cell walls, and external surfaces of the model and the influence of different vertical dimensions of the geometry are studied. The sensitivity analyses of the THM parameters of COx on the THM response at different locations are performed. The influence of using a 2-dimensional (2D) model to represent a 3-dimensional (3D) repository is also investigated.

Bearing and range estimation with an exact source‐sensor spatial model

In sensor array processing literature, near-field bearing and range estimation algorithms generally use spherical wavefront to model only array sensors’ phase response (sometimes with Fresnel approximation) and assume equality in amplitude response. Ignoring the range dependent amplitudes, though facilitating the algorithmic development, will cause systematic estimation errors due to model mismatch. By taking the spherical wavefront amplitude into account, a new bearing and range estimation algorithm for locating multiple near-field sinusoid sources is presented. With the estimation of the near-field sensor array's response vector, closed-form formulas for bearing and range estimates are derived from its magnitude, or phase, or both. The problem of estimation ambiguity is discussed as well. Cramér-Rao bound is also derived to serve as a benchmark for performance study.

Terahertz Near-Field Response in Graphene Ribbons

Results are reported of an experimental study of the scattering and near-field interaction of a terahertz electromagnetic field with graphene ribbons near the metallic probe of an atomic-force microscope. It is shown that the near-field terahertz scattering in ribbons is enhanced in comparison with that in the case of an unstructured graphene. Resonance peaks at 0.2–1.6 THz appear in the spectra of terahertz radiation scattering on graphene ribbons in the presence of the probe, which is possibly due to the interaction of the radiation with plasmons in the ribbons.