Manganese Nanoparticles Research Articles

Nitrogen-doped polydopamine manganese nanoparticles with excellent oxidase-like activity for ultrafast detection of glutathione at room temperature

Glutathione (GSH) is an essential natural antioxidant, and plays a crucial role in the prevention of various diseases. Herein, a nitrogen-doped polydopamine manganese nanoparticle (N-PDA@Mn) was prepared and used as nanozyme sensor for the rapid and colorimetric detection of GSH. N-PDA@Mn demonstrated excellent oxidase-like activity (Km = 0.0841 mM and Vmax = 3.6 × 10-7 MS-1), exhibiting a rapid balance period of < 100 s. N-PDA@Mn could activate dissolved oxygen to primarily generate singlet-oxygen (1O2), which oxidized colorless 3,3′, 5, 5′-tetramethylbenzidine (TMB) to blue oxidized (ox-TMB). Because GSH could rapidly deplete 1O2, an ultrafast and colorimetric strategy was developed for GSH detection based on N-PDA@Mn. The GSH detection range was 0.5–100 μM, and the detection limit was 0.28 µM. Importantly, at room temperature, the detection time was only 30 s, which was short than that of previously reported GSH detection methods. Furthermore, a point-of-care testing (POCT) platform was designed by combining the N-PDA@Mn colorimetric sensor with a smartphone. Use the POCT platform, a broad linear detection range of 0.5–100 μM and a detection limit of 0.40 μM were obtained. Subsequently, the N-PDA@Mn colorimetric sensor and POCT platform were successfully used in the real-time and on-site quantification of GSH in human serum, achieving a high accuracy and good recovery. Therefore, the N-PDA@Mn-based methods could realize the rapid, on-site visualization, and economical detection of GSH, demonstrating their substantial potential for application in practical testing in fields of food and medicine.

Ocimum basilicum L. leaves extract-mediated green synthesis of MnO NPs: Phytochemical profile, characterization, catalytic and thrombolytic activities

ObjectiveThe goal of the present work was the identification and quantification of the phenolic profile of sweet basil using LC-ESI-MS and to evaluation the ability of this plant to synthesise manganese nanoparticles MnONPs and evaluation of their catalytic and thrombolytic activities. Material and methodsStandard procedures were used to extract bioactive molecules and test qualitative phytochemical substances. Phenolic compounds were identified and quantified using LC-ESI-MS. Furthermore, visual observation, UV–Vis and FT-IR spectroscopy, scanning and transmission electron microscopes (SEM and TEM), and XRD technique were used to verify the green synthesis of ObE-MnO NPs. Dye degradation of ObE-MnO NPs was studied using photocatalytic and sonocatalytic activities. Moreover, in vitro thrombolytic activity was evaluated by clot lysis. ResultsResults of phytochemical essays showed that the aqueous extract of Ocimum basilicum L. is very rich in different chemical compounds that reduce and stabilize NPs. The results of the characterization of MnONPs show that the formation of these particles was proven by UV–Vis spectrum with the absorption peak at 405 nm, and also by FTIR spectrum at 470-522 cm−1. The study also confirmed that the MnONPs were spherical in shape with an average size of 6.52 ± 0.88 nm using TEM and SEM analysis, and that their size was 13.4 nm, tetragonal, and crystalline by XRD data. Results of catalytique activity show at a time of 240 min, an efficacy level of 70.18% and 58.90% for the photocatalytic and sonocatalytic activities. Ocimum basilicum L. extract and ObE-MnO NPs demonstrated a significant higher percentage of clot lysis by 93.33% and 94.73% respectively. ConclusionIn conclusion, the synthesized NPs made with basil extract were satisfactorily characterized utilizing a range of analytical techniques. ObE-MnO NPs also exhibit efficient catalytic and thrombolytic activities, qualifying their high degree of safety for usage in the environmental, pharmacological and medicinal domains.

Green synthesized metal nanoparticle incorporated titania silica and its application in the photodegradation of Rhodamine B

Photocatalytic activity of Titania has a very intriguing mechanism with numerous potential uses such as air and water cleaning. The inclusion of silica improves its catalytic capabilities. The use of titania silica nanoparticles for photocatalytic activity in environmental applications is limited due to their activity in the UV region rather than the visible range. Titania silica nanoparticles were synthesised using the sol-gel method. Metal nanoparticles of vanadium, manganese and silver were synthesised and integrated into the titania silica using a green method. To clarify the structure property correlations for titania silica materials, several characterisation techniques such as SEM-EDAX, IR analysis, UV-Visible spectroscopy and XRD were applied. The photocatalytic activities of titania alone, titania silica and titania silica including the various metals were studied.

Synergy of atomic hydrogen reduction and reactive oxygen species oxidation over confined Mn bifunctional site for electrocatalytic deep mineralization

Traditional reduction or oxidation processes generating one−component free radicals face challenges in deep dechlorination and mineralization of chlorophenols from wastewater. Herein, an efficient electrocatalytic process has been developed, which couples atomic H* reduction with reactive oxidation species (•OH and 1O2) oxidation on a bifunctional cathode for 4 −chlorophenol (4 −CP) removal. The N − doped carbon nanotubes encapsulated manganese nanoparticles was fabricated as cathode, which could generate atomic H* , initiating nucleophilic hydrodechlorination in presence of confined MnO sites. Subsequently, electrophilic oxidation by generating mainly 1O2 on confined Mn7C3 sites and •OH on confined MnO sites, facilitating the oxidative processes. Experimental results and theory calculations demonstrated that reductive dechlorination and oxidative mineralization processes could mutually promote each other, resulting in an enhancement factor of 2.90. At pH 7, this process achieved 100 % removal for 4 −CP, 84 % dechlorination, 76 % total organic carbon (TOC) removal and low energy consumption (0.76 kWh g−1TOC) within 120 min. Notably, TOC for chlorophenols containing Cl substituents at different positions and real lake water containing 4 −CP could be almost completely removed. This research establishes confined non−noble bifunctional active sites that synergistically enhance reductive dechlorination and oxidative degradation processes, holding significant treatment potential for application in deep mineralization of organochlorine from water/wastewater.

Catalytic Transfer Hydrogenation of Carbonyls by SILP-Supported Manganese Nanoparticles

Catalytic Transfer Hydrogenation of Carbonyls by SILP-Supported Manganese Nanoparticles

Electrochemical sensing of palmitic acid in guava oil using a surface modified with reduced graphene oxide-decorated manganese nanoparticles and electropolymerized poly(L-serine) film

Palmitic acid (PA) is a fatty acid that has important properties including anti-inflammatory and antitumor activity and can be applied in various industrial sectors. In this work, the first electrochemical sensor based on a surface containing reduced graphene oxide and manganese nanoparticles and molecularly imprinted p-Ser for detection in guava oil is electro synthesized and characterized electrochemically, spectroscopically, and microscopically. Under optimized conditions, an analytical curve was constructed, obtaining two linear ranges 2.0×10−12 mol L−1 to 1.0×10−11 mol L−1 and 1.0×10−11 mol L−1 to 1.0×10−10 mol L−1. The limit of detection (LOD) and amperometric sensitivity (AS) were estimated to be 8.6 × 10−13 mol L−1 and 6.2 × 105 μA L mol L−1, respectively. Interference assays indicated that the device is highly selective for PA detection. Then, the electrochemical sensor was applied to a real sample, demonstrating excellent performance for the quantification of PA in guava seed oil, showing excellent selectivity, sensitivity, and high stability.

High Manganese Content of Lipid NanoMn (LNM) by Microfluidic Technology for Enhancing Anti-Tumor Immunity.

Immunotherapy is a clinically effective method for treating tumors. Manganese can activate the cGAS-STING signaling pathway and induce an anti-tumor immune response. However, its efficacy is hindered by non-specific distribution and low uptake rates. In this study, we employed microfluidic technology to design and develop an innovative preparation process, resulting in the creation of a novel manganese lipid nanoparticle (LNM). The lipid manganese nanoparticle produced in this process boasts a high manganese payload, excellent stability, the capacity for large-scale production, and high batch repeatability. LNM has effectively demonstrated the ability to activate the cGAS-STING signaling pathway, induce the production of pro-inflammatory cytokines, and inhibit tumor development. Notably, LNM does not require combination chemotherapy drugs or other immune activators. Therefore, LNM presents a safe, straightforward, and efficient strategy for anti-tumor immune activation, with the potential for scalable production.

Effect of multi ferrites nanoparticles added Terminalia bellirica biodiesel on diesel engine: Combustion, performance, and emission studies

The objective of current investigation is to assess the diesel engine performance, combustion, and emissions fuelled with bismuth ferrite codoped with zinc and manganese (BZnFMO) nanoparticles dispersed Terminalia bellirica biodiesel. BZnFMO nanoparticles were uniformly dispersed in B20 together with the surfactant and the dispersant at a concentration of 50 ppm and 75 ppm, respectively, and the stability of the nanoparticles in B20 was evaluated by UV photo spectroscopy. In addition, the experimental analysis of all nano-fuel samples was tested on diesel engines with different injection timing (i.e. 21°bTDC, 23°bTDC and 25°bTDC). The addition of nanoparticles in B20 led to an improvement in performance and combustion properties while simultaneously reducing emissions. The dispersion of BZnFMO nanoparticles in B20 led to a significant improvement in cylinder pressure (CP), cumulative heat release rate (CHRR), rate of pressure rise (RoPR) and brake thermal efficiency (BTE), while reducing brake specific fuel consumption (BSFC), carbon monoxide (CO), unburnt hydrocarbons (UHC), nitrogen oxides (NOx) and diesel engine smoke opacity. The increase in injection timing also led to an improvement in performance and combustion characteristics, as well as a reduction in emissions, with the exception of NOx. At 25°bTDC, a CP of 71.14 bar, a CHRR of 3.27 J/°CA and a RoPR of 5.3 bar/°CA were found, while BTE and BSFC were 35.03 % and 0.391 kg/kWh, respectively for B20 + 75 ppm BZnFMO + 75 ppm TWEEN 80. The values for CO, UHC, NOx, smoke opacity and nitrogen oxides were 0.01 %, 22 ppm, 826 ppm and 35.85 % respectively.

Olive leaf extract green-formulated manganese nanoparticles: Characterization and antioxidant, cytotoxicity and anti-breast carcinoma properties

Olives are rich in many plant compounds; Antioxidants in olives protect against the occurrence of many cardiovascular diseases, blood pressure, diabetes, various types of cancers and tissue damage caused by free radicals. These antioxidant compounds include oluropine, hydroxytyrosol, tyrosol, oleanolic acid, and quercetin. Recent studies have focused on the therapeutic efficacies of manganese nanoparticles mediated by medicinal plants. The study investigated the characteristics of green manganese nanoparticles formulated using olive leaf extract on breast carcinoma cells. The nanoparticles were analyzed using FE-SEM, XRD, FT-IR, and UV–Vis techniques. The formation of manganese nanoparticles was confirmed by observing bands at 219 and 290 nm. The Mn-O vibration can be identified by the peaks observed at 516 and 610 cm−1. The peaks at 72.69, 60, 53.26, 44.97, 40.25, 34.83, and 28.48 corresponding to manganese nanoparticles (444), (440), (510), (420), (400), (222), and (220) diffraction planes, indicate the manganese nanoparticles formation. The MTT assay was employed to evaluate the anti-breast carcinoma effects (on CAMA-1 and MCF-7 cells) as well as the cytotoxicity effects (on HUVEC cell line) of manganese NPs. Results from the DPPH test showed that MnNPs and BHT at doses of 231 and 84 μg/ml were able to eliminate 50 % of radicals. The findings from the MTT experiment indicate that over 3 days, the cancer cells percentage that survived decreased proportionally to the increase in nanoparticle concentration. Furthermore, the data demonstrate that the cancer cells survival rate decreased with the rise in nanoparticle concentration, ultimately reaching a point where no viable cells were observed at a concentration of 1000 μg/ml. The most effective cytotoxicity was observed at a concentration of 1000 μg/ml. The MTT findings indicate that the IC50 values are 173 and 256 µg/ml, representing the concentration of nanoparticles at which half of the CAMA-1 and MCF-7 breast carcinoma cells in the culture medium are eradicated. Analysis of the gene expression levels of PIK3, AKT, and mTOR, linked to the mTOR pathway, in addition to Bax, Bcl2, and Caspase-3, demonstrates that copper nanoparticles efficiently control PC14 cell apoptosis and proliferation by regulating the PI3K-Akt-mTOR signaling pathway. The mTOR pathway could potentially be related to the suppression of the cell cycle and the initiation of apoptosis due to nanoparticles.

Manganese Nanoparticles: Synthesis, Mechanisms of Influence on Plant Resistance to Stress, and Prospects for Application in Agricultural Chemistry.

Manganese (Mn) is an important microelement for the mineral nutrition of plants, but it is not effectively absorbed from the soil and mineral salts added thereto and can also be toxic in high concentrations. Mn nanoparticles (NPs) are less toxic, more effective, and economical than Mn salts due to their nanosize. This article critically reviews the current publications on Mn NPs, focusing on their effects on plant health, growth, and stress tolerance, and explaining possible mechanisms of their effects. This review also provides basic information and examples of chemical, physical, and ecological ("green") methods for the synthesis of Mn NPs. It has been shown that the protective effect of Mn NPs is associated with their antioxidant activity, activation of systemic acquired resistance (SAR), and pronounced antimicrobial activity against phytopathogens. In conclusion, Mn NPs are promising agents for agriculture, but their effects on gene expression and plant microbiome require further research.

Synthesis, Characterization, and Catalytic Application of Colloidal and Supported Manganese Nanoparticles.

Colloidal and supported manganese nanoparticles were synthesized following an organometallic approach and applied in the catalytic transfer hydrogenation (CTH) of aldehydes and ketones. Reaction parameters for the preparation of colloidal nanoparticles (NPs) were optimized to yield small (2-2.5 nm) and well-dispersed NPs. Manganese NPs were further immobilized on an imidazolium-based supported ionic phase (SILP) and characterized to evaluate NP size, metal loading, and oxidation states. Oxidation of the Mn NPs by the support was observed resulting in an average formal oxidation state of +2.5. The MnOx@SILP material showed promising performance in the CTH of aldehydes and ketones using 2-propanol as a hydrogen donor, outperforming previously reported Mn NPs-based CTH catalysts in terms of metal loading-normalized turnover numbers. Interestingly, MnOx@SILP were found to lose activity upon air exposure, which correlates with an additional increase in the average oxidation state of Mn as revealed by X-ray absorption spectroscopic studies.

Alternative method for rhamnolipids quantification using an electrochemical platform based on reduced graphene oxide, manganese nanoparticles and molecularly imprinted Poly(L-Ser)

Rhamnolipids (RHLs) are promising biosurfactants with important applications in several industrial segments. These compounds are produced through biotechnological processes using the bacteria Pseudomonas Aeruginosa. The main methods of analyzing this compound are based on chromatographic techniques. In this study, an electrochemical sensor based on a platform modified with reduced graphene oxide, manganese nanoparticles covered with a molecularly imprinted poly (L-Ser) film was used as an alternative method to quantify RHL through its hydrolysis product, acid 3-hydroxydecanoic acid (3-HDA). The proposed sensor was characterized microscopically, spectroscopically and electrochemically. Under optimized experimental conditions, an analytical curve was obtained in the linear concentration range from 2.0 × 10−12 mol L−1 to 1.0 × 10−10 mol L−1. The values estimated of LOD, LOQ and AS were 8.3 × 10−13 mol L−1, 2.7 × 10−12 mol L−1and 1.3 × 107 A L mol−1, respectively. GCE/rGO/MnNPs/L-Ser@MIP exhibits excellent selectivity, repeatability, and high stability for the detection of 3-HDA. Furthermore, the developed method was successfully applied to the recognition of the hydrolysis product (3-HDA) of RHLs obtained from guava agro-waste. Statistical comparison between GCE/rGO/MnNPs/L-Ser@MIP and HPLC method confirms the accuracy of the electrochemical sensor within a 95% confidence interval.

Eco-Friendly synthesis of manganese nanoparticles from Syzygium aromaticum and study of their biological activities

Different metallic nanoparticles are being explored, but manganese nanoparticles (MnNPs) have not yet been studied extensively. In this study, MnNPs were synthesized by a plant-based (clove extract) method, and the synthesized MnNPs were physically characterized using different techniques. SEM analysis showed a size range of MnNPs between 100 nm and 500 nm with spherical shapes. XRD analysis showed the crystalline nature of MnNPs. The PDI of 0.872 and the zeta potential at 10 mV indicate that the MnNPs are aggregated and polydispersed. MnNPs showed a maximum zone of inhibition against Staphylococcus aureus, i.e. 30 mm. The DPPH assay confirmed the radical scavenging ability of nanoparticles with an IC50 of 51.18 µg/ml. The alpha-amylase and alpha-glucosidase assays indicated that green synthesized MnNPs can act as an anti-diabetic agent with 26.65 µg/ml and 27.37 µg/ml IC50 values, respectively. In conclusion, this work exhibited a cost-effective and non-toxic method of MnNPs synthesis with potential biomedical applications.

Assessment of the oxidative stress intensity and the integrity of cell membranes under the manganese nanoparticles toxicity in wheat seedlings

A response to manganese nanoparticles was studied in seedlings of two wheat cultivars and a model system of plant cell membranes. Nanoparticles at concentrations of 125 and 250 mg/ml were applied foliar. The application of NPs enhanced the content of Mn in plant cells, indicating its penetration through the leaf surface. The stressful effect in the plant cells was estimated based on changes in the activity of antioxidant enzymes, content of chlorophylls and starch. MnNPs evoked no significant changes in the leaf morphology, however, an increase in enzyme activity, starch accumulation, and a decrease in chlorophyll synthesis indicated the stress occurrence. Moreover, a rise in the electrokinetic potential of the chloroplast membrane surface and the reconstruction of their hydrophobic parts toward an increase in fatty acid saturation was found.

Burn wound healing using adipose-derived mesenchymal stem cells and manganese nanoparticles in polycaprolactone/gelatin electrospun nanofibers in rats.

Wound healing is a major therapeutic concern in regenerative medicine. The current study aimed to investigate the second-degree burn wound treatment in rats using rat adipose- derived stem cells (ADSCs) and manganese nanoparticles (MnO2-NPs) in a polycaprolactone/gelatin electrospun nanofiber scaffold. After the synthesis of nanoparticles and electrospinning of nanofibers, the SEM analysis, contact angle, mechanical strength, blood compatibility, porosity, swelling, biodegradability, cell viability, and adhesion assays were performed. According to the results, the PCL/Gel/5%MnO2-NPs nanofiber (Mn-5%) was determined to be the most suitable scaffold. The ADSCs-seeded Mn-5% scaffolds were applied as a burn wound dressing. The wound closure rate, IL-1β, and IL-6 level, hydroxyproline, and glycosaminoglycans content were measured, and the hematoxylin and eosin, Masson's trichrome, and immunohistochemistry stainings were carried out. Based on the results, in Mn+S (ADSCs+PCL/Gel/5%MnO2-NPs nanofiber) and N+S (ADSCs+PCL/Gel nanofiber) groups, the IL-6 and IL-1β levels were reduced, and the percentage of wound closure, glycosaminoglycans, and hydroxyproline content were increased compared to the control group (P<0.05). Also, the lowest amount of α-SMA was observed in these two groups, demonstrating stem cells' role in reducing α-SMA levels and thus preventing fibrosis. Moreover, the amount of α-SMA in the Mn+S group is lower than in the N+S group and, is closer to healthy skin. According to histology results, the best type of treatment was observed in the Mn+S group. In conclusion, the ADSCs-seeded PCL/Gel/5%MnO2-NPs scaffold demonstrated considerable therapeutic effects in burn wound healing.

Sc, Zr, Hf, and Mn Metal Nanoparticles: Reactive Starting Materials for Synthesis Near Room Temperature.

Zerovalent scandium, zirconium, hafnium, and manganese nanoparticles are prepared by reduction of ScCl3, ZrCl4, HfCl4, and MnCl2 with lithium or sodium naphthalenide in a one-pot, liquid-phase synthesis. Small-sized monocrystalline nanoparticles are obtained with diameters of 2.4 ± 0.2 nm (Sc), 4.0 ± 0.9 nm (Zr), 8.0 ± 3.9 nm (Hf) and 2.4 ± 0.3 nm (Mn). Thereof, Zr(0) and Hf(0) nanoparticles with such size are shown for the first time. To probe the reactivity and reactions of the as-prepared Sc(0), Zr(0), Hf(0), and Mn(0) nanoparticles, they are exemplarily reacted in the liquid phase (e.g., THF, toluene, ionic liquids) with different sterically demanding, monodentate to multidentate ligands, mainly comprising O-H and N-H acidic alcohols and amines. These include isopropanol (HOiPr), 1,1'-bi-2-naphthol (H2binol), N,N'-bis(salicylidene)ethylenediamine (H2salen), 2-mercaptopyridine (2-Hmpy), 2,6-diisopropylaniline (H2dipa), carbazole (Hcz), triphenylphosphane (PPh3), N,N,N',N'-tetramethylethylenediamine (tmeda), 2,2'-bipyridine (bipy), N,N'-diphenylformamidine (Hdpfa), N,N'-(2,6-diisopropylphenyl)-2,4-pentanediimine ((dipp)2nacnacH), 2,2'-dipydridylamine (Hdpa), and 2,6-bis(2-benzimidazolyl)pyridine (H2bbp). As a result, 22 new compounds are obtained, which frequently exhibit a metal center coordinated only by the sterically demanding ligand. Options and restrictions for the liquid-phase syntheses of novel coordination compounds using the oxidation of base-metal nanoparticles near room temperature are evaluated.

Physiological effects of manganese nanoparticles on Alloxan-Induced Diabetes Mellitus in Adult Male Rats

This study was conducted on the creation of the nanopolitan manganese particles and the study of the physiological effect of the nanopolitan magnes.The results or indicators of blood sugar showed the confirmation of low levels of sugar in the group of diabetes treatment by giving oral throughout the experiment period (28 days. In addition to the high percentage of insulin in the affected group and the treatment of Mn-NPs compared to the affected (positive) control group during the study period. The current study aimed to achieve preventive effects against diabetes. It turned out that eating the nanoparticles and within the permissible concentration 2 mg /kg per day reduces blood sugar and contributes to losing weight, as its consumption is related to a decrease in the risk of type 2 diabetes and reduces the level Blood Glucose in Adult Male Rats.

Dietary manganese nano-particles improves gene regulation and biochemical attributes for mitigation of lead and ammonia toxicity in fish

In the present study, we explored the capability of manganese nanoparticles (Mn-NPs) to alleviate the toxicity induced by lead (Pb) and ammonia (NH3) toxicity in Oreochromis niloticus (GIFT strain). The experiment followed a completely randomized design, including a control group (Mn-NPs-0 mg kg−1 diet) and groups exposed to Pb and NH3 alongwith Mn-NPs at 2 and 3 mg kg−1. Cortisol levels were significantly elevated in Pb + NH3 group whereas reduced by Mn-NPs diets. Gene expressions of HSP 70, iNOS, CYP 450, and Cas 3a were notably upregulated by Pb + NH3 group and downregulated by Mn-NPs diets. The cellular metabolic enzymes were affected by Pb + NH3 exposure and mitigated by Mn-NPs diets. The liver and kidney exhibited reduced activities of catalase, superoxide dismutase, and glutathione-s-transferase with Mn-NPs diets. Concurrently, immune-related genes such as total immunoglobulin (Ig) and tumor necrosis factor (TNFα) were upregulated in the Mn-NPs-fed groups. Growth performance indicators, including weight gain %, feed conversion ratio, specific growth rate, protein efficiency ratio, and relative feed intake were adversely affected by Pb + NH3 stress but improvement with Mn-NPs diets. Genes associated with growth performance, such as growth hormone (GH), growth hormone regulatory (GHR1), and myostatin, exhibited enhancements in response to Mn-NPs diets. Digestive enzymes, including protease and amylase were also enhanced by Mn-NPs diets. Additionally, Mn-NPs diets led to a reduction in the bioaccumulation of lead. This study aims to investigate the role of Mn-NPs in mitigating the effects of lead and ammonia toxicity on fish by examining various biochemical and gene regulatory factors to enhance fish wellbeing.

Development of the supercapacitor efficiency of the two-dimensional graphene oxide decorated by nano magnetite through building novel nanocomposites using nanoparticles of cobalt, manganese, vanadium, and zirconium oxides

The targeting of the current work is enhancing the supercapacitor efficiency of the magnetite nanocomposite with graphene oxide (GO) nanostructure via the addition of metal oxide nanoparticles (NPs) such as cobalt, manganese, vanadium, and zirconium for building a novel nano combination. The sol/gel method is utilized to fabricate the nanocomposites, and the potentiostat device measures the electrochemical performances. The supercapacitors of the magnetite (Fe3O4) NPs that decorate the graphene oxide (GO) surface and the modified electrode building have been examined by different tests for supercapacitor applications, and are studied via the impedance spectroscopy (EIS) data that confirm the building progress of the electron transfer and surface structure that enable it to be a favorable candidate for supercapacitors applications. The areal capacitance (Carea) of NCPs was measured and presented at 622.65 mFcm−2 (GO@Fe3O4), 62.428 mFcm−2 (GO@ Fe3O4.Co3O4), 388.4 mFcm−2 (GO@ Fe3O4.Mn3O4), 851.1 mFcm−2 (GO@Fe3O4.V4O7), 966.4 mFcm−2 (GO@Fe3O4.ZrO2). The NCPs have capacitance values related to CPE (C = 9.404 nF/cm2), GO@Fe3O4 (C = 40.886 nF/cm2), GO@Fe3O4.Co3O4 (C = 13.17 nF/cm2), GO@Fe3O4.Mn3O4 (C = 17.56 nF/cm2), GO@Fe3O4.V4O7 (C = 126.9 nF/cm2), and GO@Fe3O4.ZrO2 (C = 183.6 nF/cm2). By adding cobalt, manganese, vanadium, and zirconium metal oxide NPs, the new building electrodes have capacitance at 13.17, 17.56, 183.6, and 126.9 nF/cm2, respectively. The capacitance retention finished at 100 cycles is recorded and exhibited good cycle stability. From the results, the fabricated NCPS electrodes are a promising candidate for supercapacitor manufacturing applications and other applications such as water treatment.

A comprehensive study on the performance and emission analysis in diesel engine via optimization of novel ternary fuel blends: Diesel, manganese, and diethyl ether

Ecosystem degradation and fossil fuel depletion are the two foremost concerns to look for alternative fuels. Rapid population growth is primarily accountable for higher consumption of fossil fuel sources, although engine technology is achieving milestones in terms of fuel efficiency and lower exhaust emissions in order to contribute towards a sustainable environment. The main root cause of global warming is carbon dioxide emissions; therefore, it is imperative to assess the impact of alternative fuels in diesel engines with an aim to minimize carbon emissions. A current study deals with the reduction of carbon emissions and improvement of efficiency through addition of manganese nano-additive to di-ethyl ether and diesel fuel blend in particulate form. Fuel blends were formed by adding various proportions of manganese to high-speed diesel fuel and stirring the mixture while heating it for 10 min. The blends were then tested in diesel engines at two distinct loads and five engine speed ranges. Emission analyzer was used to ascertain the CO2 output of engine. At higher loads for 10 % diethyl ether in diesel, the increase in brake thermal efficiency was 24.19, 28.17 and 26.86 % when the manganese amount in blend was changed as 250 mg, 375 mg and 500 mg respectively. On the other side CO2 emissions increase by 11.57, 30.52 and 20.33 % for manganese concentrations of 250 mg, 375 mg and 500 mg respectively. Analysis performed with Design Expert 13 showed that the desirability was 0.796 for a blend of 375 mg manganese at 1300 rpm and 4500 W load with 33.0611 % BTE, 334.011kg/kWh BSFC, 67.8821Nm torque, and 6.072 % CO2. Therefore, it can be deduced that manganese nanoparticle blends improved engine performance but CO2 emissions also increase which can be responsible for global warming and it should be reduced through catalytic converters.