Concentration Of Nanoparticles Research Articles

Antimicrobial Activity of Green Synthesized Silver and Copper Oxide Nanoparticles against the Foodborne Pathogen Campylobacter jejuni.

Campylobacter jejuni is a major cause of global foodborne illnesses. To develop alternative antimicrobial strategies against C. jejuni, this study designed and optimized the green synthesis of metallic nanoparticles (NPs) with intracellular components of the medicinal fungus Ganoderma sessile to provide the needed reducing and stabilizing agents. NPs were characterized by transmission electron microscopy and dynamic light scattering, and the quasi-spherical NPs had sizes of 2.9 ± 0.9 nm for the copper oxide NPs and 14.7 ± 0.6 nm for the silver NPs. Surface charge assessment revealed zeta potentials of -21.0 ± 6.5 mV and -24.4 ± 7.9 mV for the copper oxide and silver NPs, respectively. The growth inhibition of C. jejuni by the NPs occurred through attachment to the outer cell membrane and subsequent intracellular internalization and resulted in minimum inhibitory concentrations of the silver NPs at 6 µg/mL and copper oxide NPs at 10 µg/mL. On the other hand, a differential ROS production caused by silver and copper NPs was observed. In summary, this research presents the first demonstration of using green synthesis with the medicinal fungus G. sessile to produce metallic NPs that effectively inhibit C. jejuni growth, providing a sustainable and effective approach to the traditional use of antimicrobials.

Heat transfer evaluation of combined nanofluids in vertical annulus: An experimental and artificial neural network approach

Enhancing the thermal properties of the working fluid is a practical way to improve heat transfer performance. One of the suggested fluids for this purpose is nanofluids, which are suspensions of nanoparticles within a base fluid. Nanofluids have the potential to operate as a primary coolant or as an emergency coolant in a nuclear reactor. This paper investigates the thermal performance of a homogeneous hybrid nanofluid of Al2O3 and TiO2 in deionized water. The thermo-hydraulic performance of the nanofluid is analyzed in a high-pressure test loop capable of 25 bar pressure. The test section has an annular geometry, generating a cosine heat flux pattern. This flux pattern is representative of nuclear reactor cores. The experimental study is conducted to investigate the effects of nanoparticle concentration and Reynolds number on the heat transfer performance of nanofluids. The results show that increasing these two parameters significantly improved heat transfer. Specifically, raising the nanoparticle concentration from 0% to 1% leads to a reduction in surface temperature of 19% and 8% at Reynolds numbers of 825 and 4128, respectively. The calculated Nusselt numbers are compared with correlations from previous studies. Furthermore, an artificial neural network model is developed to predict heat transfer data for the studied system. The model consists of a single-layer feed-forward neural network trained with the stochastic gradient descent algorithm. To determine the optimal network, the number of neurons is optimized and evaluated based on the network's predictability. The neural network model demonstrates substantial improvements over previous experimental correlations (MAPE <2.5% and MSE <0.001).

Enhancement of CuO/Si Solar Cell Efficiency by Cu2O Doping Prepared Via Thermal Evaporation Technique

CuO:Cu2O/Si heterojunctions have been prepared with different concentrations of Cu2O nanoparticles using the thermal evaporation technique. The X-ray diffraction (XRD) results show that the prepared films are polycrystalline with orthorhombic structure and preferential orientation (110) direction along the [Formula: see text] axis at [Formula: see text], which corresponds to the pure CuO with crystallite size 18[Formula: see text]nm, while the particle size ranged from 14[Formula: see text]nm to 34 nm (resulted from SEM test). The optical properties were studied by recording the absorbance spectra using the UV–visible spectrophotometer. The absorbance increased with Cu2O doping. The high values of the energy gap refer to the quantization effect. The electrical properties including the Hall effect were studied. CuO:Cu2O/Si heterojunctions have been prepared at different concentrations. [Formula: see text]–[Formula: see text] characteristics show that the Cu2O doping increases the energy conversion efficiency by retarding the electron–hole recombination and the improved device performance is caused by the high short-circuit current ([Formula: see text] and open circuit voltage ([Formula: see text] and found that the highest efficiency ([Formula: see text] at doping 0.006 Cu2O 3.471% with [Formula: see text] of 2.20[Formula: see text]V, [Formula: see text] of 0.0170[Formula: see text]mA cm[Formula: see text] and F.F of 0.6497 at [Formula: see text][Formula: see text]mW/cm2.

Enhanced Photocatalytic Degradation of Rhodamine B Using ZnO Microspheres Decorated with Ag Nanoparticles

Zinc oxide (ZnO) has demonstrated significant potential as a photocatalyst for the wastewater treatment. However, its wide bandgap leads to inefficient light utilization and rapid carrier recombination, which inhibits its photocatalytic activity. To overcome these limitations, we employed a hydrothermal method to synthesize Ag/ZnO composite microspheres with different concentrations of Ag nanoparticles. By utilizing Ag complexed with ZnO, the Ag/ZnO composite photocatalysts were made to have a narrower bandgap and a broadened light response range, as well as the red-shift phenomenon at the absorption edge. In addition, Ag nanoparticles can act as electron traps to efficiently capture electrons and minimize the recombination of photoexcited carriers for improved photocatalytic performance. Compared with other concentrations of ZnO microspheres and pure ZnO microspheres, the 5% Ag/ZnO composite microspheres exhibited excellent degradation performance when exposed to a xenon lamp, with 90.1% degradation of rhodamine B (RhB) solution in 100[Formula: see text]min. Incorporating trapping agents in experimental studies has indicated that the RhB degradation process is significantly influenced by •O[Formula: see text], while the impact of •OH and h[Formula: see text] were relatively weak. Thus, Ag/ZnO nanocomposites hold great promise as materials for use in wastewater treatment.

Optimizing germination conditions of Ghaf seed using ZnO nanoparticle priming through Taguchi method analysis

Ghaf, a resilient tree in arid environments, plays a critical role in ecological restoration, desertification mitigation, and cultural heritage preservation. However, the seeds’ inherent challenges, notably their hard outer coating restricting germination, emphasize the pressing need for innovative strategies. This work aimed to investigate the optimization of Ghaf seed germination process through seed priming with ZnO nanoparticles treatment (duration (t), concentration (c), temperature (T), and agitation (a), employing the Taguchi method for efficient experimental design. Furthermore, the study includes Analysis of Variance (ANOVA), analysis for the regression model to assess the significance of predictor variables and their interactions, thereby strengthening the statistical validity of our optimization approach. Notably, it revealed that concentration is a pivotal influencer in optimization of Ghaf seed germination. The results showed that the concentration of ZnO nanoparticles has no linear relation with any other parameters. To verify the outcomes, validation tests were performed utilizing the predicted optimal parameters. The observed low error ratio, falling within the range of 1 to 6%, confirmed the success of the Taguchi methodology in identifying optimal levels of the factors chosen. Significantly, ZnO-primed seeds showcased a remarkable enhancement in Ghaf seed germination, increasing from 15 to 88%. This study introduces a novel approach utilizing ZnO nanoparticle treatment optimized through the Taguchi method, significantly enhancing seed germination rates of Ghaf seeds and offering a promising avenue for sustainable agricultural practices in arid environments.

Fractional dynamics of entropy generation in unsteady mixed convection of a reacting nanofluid over a slippery permeable plate in Darcy–Forchheimer porous medium

AbstractThis paper presents a theoretical investigation of the inherent irreversibility in unsteady fractional time derivative mixed convection of a reacting nanofluid with heat and mass transfer mechanism over a slippery permeable plate embedded in a Darcy–Forchheimer porous medium. The model fractional partial differential equations are obtained based on conservation laws and numerically solved using the implicit finite difference scheme. The study displays and discusses the effects of various emerging parameters on the overall flow structure, such as velocity profiles, temperature distribution, nanoparticles concentration profiles, skin friction, Nusselt number, Sherwood number, entropy generation rate, and Bejan number. It was found that an increase in dimensionless time and fractional parameters leads to a decrease in both the entropy generation rate and the Bejan number. The study revealed that fractional order derivatives can capture intrinsic memory effects, non‐local behaviour, and anomalous diffusion in the nanofluid flow process. This can ultimately lead to better engineering system design and control.

Mixed convective flow analysis of a Maxwell fluid with double diffusion theory on a vertically exponentially stretching surface

It observers that an object is submerged in a liquid, more pressure is applied to its bottom surface than its top surface, as a result pressure rises within depth of fluids. A buoyancy force is generated due to the pressure difference. In the current investigation, the mathematical formulation of bio-convective stagnation point flow of a radiative Maxwell fluid with multiple slip effect on an exponentially porous stretching surface is analyzed thoroughly. The buoyancy assisting and opposing conditions with magnetic field are discussed in the current investigation. Moreover, the energy and concertation equations are formulated by the utilization of Cattaneo–Christov theory and non-uniform heat source/sink. The flow model is developed in the form of partial derivatives, then use the similarity variables to convert the physical system into nonlinear ordinary derivative. The nonlinear system is tackled numerically with the help of Bvp4c approach on the MATLAB. The graphical upshots for various emerging parameter are observed with two aspects: buoyancy assisting λ>0\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\left( {\\lambda > 0} \\right)$$\\end{document} and buoyancy opposing λ<0\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\left( {\\lambda < 0} \\right)$$\\end{document}. The observation shows that the greater values of mixed convection parameter improves the fluid velocity for assisting flow λ>0\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\left( {\\lambda > 0} \\right)$$\\end{document}, while declining trend is noticing for opposing flow situation λ>0\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\left( {\\lambda > 0} \\right)$$\\end{document}. Further, it is worth noticing that stronger inputs of thermal and concentration relaxation parameter yield lesser thermal and concentration diffusivity, which reduces the temperature and nanoparticles concentration.

Measuring Concentration of Nanoparticles in Polydisperse Mixtures Using Interferometric Nanoparticle Tracking Analysis.

Quantitative measurements of nanoparticle concentration in liquid suspensions are in high demand, for example, in the medical and food industries. Conventional methods remain unsatisfactory, especially for polydisperse samples with overlapping size ranges. Recently, we introduced interferometric nanoparticle tracking analysis (iNTA) for high-precision measurement of nanoparticle size and refractive index. Here, we show that by counting the number of trajectories that cross the focal plane, iNTA can measure concentrations of subpopulations in a polydisperse mixture in a quantitative manner and without the need for a calibration sample. We evaluate our method on both monodisperse samples and mixtures of known concentrations. Furthermore, we assess the concentration of SARS-CoV-2 in supernatant samples obtained from infected cells.

Optimizing heat transport in a permeable cavity with an isothermal solid block: Influence of nanoparticles volume fraction and wall velocity ratio

Abstract This study examines the influence of wall velocity ratio on mixed convective heat transport in a permeable cavity containing an isothermal solid block at its center. The analysis considers the characteristics of various flow variables, i.e., Darcy number, wall velocity ratio, Richardson number, and volume fraction of suspended nanoparticles, on heat transport and material flow characteristics. The principal equations are solved implementing the semi-implicit method for pressure linked equations algorithm, and the outcomes are compared with existing literature. The study shows that rising estimations of Darcy number, velocity ratio, Richardson number, and nanoparticles volume fraction lead to improved heat transfer rates. For example, at high Richardson number (100) and solid volume fraction (0.05), increasing the velocity ratio from 0.5 to 1.5 results in a 6% (5%) upsurge in heat transport rate. Conversely, at smaller Richardson number (0.01), the heat transport rate upsurges by 29% (28%). Similarly, at high Darcy numbers and low wall velocity ratios, a 3% (4%) escalate in heat transport rate is observed with an increase in nanoparticles concentration from 0 to 0.05, while a 9% (8%) increase in thermal performance is achieved at low Darcy numbers. The study emphasizes the importance of optimizing the combination of nanoparticles volume fraction, Darcy number, velocity ratio, and Richardson number to maximize thermal performance in the porous cavity.

ENTEROBACTER CLOACAE LIPOPOLYSACCHARIDE EXPORT SYSTEM PROTEIN (LPTC) GENE EXPRESSION VARIATION VIA EXPOSE TO BIOSYNTHESIZED ZINC OXIDE NANOPARTICLES

Synthetic nanoparticles (NPs) have become more widely used in the disinfection and health sectors owing to their ability to effectively penetrate biological systems. Recent research has demonstrated the ability of microbial proteins and enzymes to function as reducing agents throughout the NP-production process, providing a different option to chemical and physical techniques. This method not only saves money and is effective, but also has the least possible environmental impact. This work used Lactobacillus spp., as the reducing and capping agent to create zinc oxide nanoparticles, (ZnO NPs). Numerous analytical techniques were employed to examine the generated ZnO NPs; these techniques include ultraviolet–visible spectroscopy (UV–vis), scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). As an opportunistic pathogenic bacterium, Enterobacter cloaca possesses several virulence characteristics that enable it to infiltrate target tissues. However, bacteria can become resistant to antibiotics, which in turn makes treating bacterial infections becomes more difficult. With the development of science at the biotechnology level, using zinc oxide ZnO NPs on isolates of Enterobacter cloacae, we conducted research in the promising field of nanotechnology. The impact of three different concentrations of ZnO NPs on the gene expression of Enterobacter cloaca lipopolysaccharide transport (Lpt) proteins in isolates obtained from some patients suffering of various infections was investigated. Bacteria with the highest multidrug resistance were selected for further analysis. Expression of LptC gene was reduced significantly at concentration of 125 mg/mL (P &lt; 0.01) for all the isolate that treated with ZnO NPs.

An ecofriendly approach to bioremediate nickel oxide nanoparticles using a macrofungus, Pleurotus fossulatus.

Nowadays, nickel oxide nanoparticles are in great demands owing to their use in many sectors. These nanoparticles may release into aquatic environment from different industries and cause negative effect on aquatic flora and fauna. Therefore, an effective and efficient method is required to remove these nanoparticles from contaminated water. Hence, the aim of this study was to bioremediate nickel oxide nanoparticles using a macrofungus, Pleurotus fossulatus, and to analyze its impact on fungal physiology. For this purpose, fungal spawns were inoculated in malt dextrose agar media containing different concentrations of nickel oxide nanoparticles (24mg/l, 48mg/l, and 100mg/l) as well as control group (having no nickel oxide nanoparticles) and allowed to grow for a period of 20days. Fungal mycelia as well as media were collected at different time intervals (5th day, 10th day, 15th day, and 20th day) for evaluation of Ni concentration and different biochemical parameters. Ni removal efficiency of P. fossulatus from media was found to be highest in 48mg/l (66.98%) followed by 24mg/l (60.83%) and 100mg/l (18.03%), respectively. Increased level of metallothionein, lipid peroxidation, activity of different antioxidant enzymes (superoxide dismutase, catalase, glutathione s transferase, glutathione reductase), activity of ligninolytic enzymes (laccase, lignin peroxidase, manganese peroxidase), and shift in FTIR spectra were also reported in mycelia cultured in malt dextrose agar media containing nickel oxide nanoparticles. This study suggests that P. fossulatus has great efficiency to remediate nanoparticles from contaminated water and it can be utilized as potential agent in wastewater treatment plants by different industries.

Innovative insights into nanofluid-enhanced gear lubrication: Computational and experimental analysis of churn mechanisms

This study offers unique insights into the churn lubrication mechanism in gear transmission systems through the utilization of nanofluids for the first time. Various performance parameters of the prepared nanofluid lubrication oil are measured, along with the discussion of suspension stability. Based on the overset mesh method and VOF multiphase flow model, a rotating fluid domain calculation model considering the nanofluid-air two-phase is proposed. The high-speed nanofluid lubrication experiment platform is established to track churn phenomena and identify the oil volume fraction on the gear surface. Comparing simulation results with experimental data confirms the calculation accuracy in depicting oil flow and churn lubrication. Result shows that the interaction between droplets and the gear surface involves splash, rebound, adhesion, and diffusion. The nanofluid exhibits improved adsorption, resulting in a higher oil volume fraction. When the rotation speed is increased, intensified oil spatter and atomization are observed. The ranking of nanofluid lubrication performance is Al2O3, SiO2, Fe3O4, CuO, and TiO2 particles, which are approximately aligned with contact angle magnitudes. For 3 % nanoparticles concentration, less oil is swung off, more is drawn into the gear meshing zone, and subsequently squeezed out. Image recognition results align with numerical simulation, indicating that the oil distribution of nanofluid is better than that of base fluid lubrication. This work serves as a foundational exploration for future nanofluid lubrication and heat dissipation, offering insights into preventing oil film rupture, tooth surface wear, gluing and other failure mechanisms.

The Effect of Soft Nanoparticle Size and Concentration on Wear Behavior in Mixed Lubrication Conditions

The Effect of Soft Nanoparticle Size and Concentration on Wear Behavior in Mixed Lubrication Conditions

Improved solar still productivity using PCM and nano- PCM composites integerated energy storage

The study investigates the impact of Phase Change Material (PCM) and nano Phase Change Materials (NPCM) on solar still performance. PCM and a blend of NPCM are placed within 12 copper tubes submerged in 1 mm of water to enhance productivity. Thermal performance is assessed across four major scenarios with a fixed water level of 1 mm in the basin. These scenarios include the conventional still, equipped with 12 empty copper rods and 142 g of PCM in each tube, as well as stills with NPCM Samples 1 and 2. Sample 1 contains 0.75% nanoparticle concentration plus 142 g of PCM in the first 6 tubes, while Sample 2 features 2% nanoparticle concentration plus 142 g of PCM in the subsequent 6 tubes. Aluminum oxide (Al2O3) nanoparticles ranging in size from 20 to 30 nm are utilized, with paraffin wax (PW) serving as the latent heat storage (LHS) medium due to its 62 °C melting temperature. The experiments are conducted under the local weather conditions of Vaddeswaram, Vijayawada, India (Latitude-80.6480 °E, Longitude-16.5062 °N). A differential scanning calorimeter (DSC) is utilized to examine the thermal properties, including the melting point and latent heat fusion, of the NPCM compositions. Results demonstrate that the addition of nanoparticles enhances both the specific heat capacity and latent heat of fusion (LHF) in PCM through several mechanisms, including facilitating nucleation, improving energy absorption during phase change, and modifying crystallization behavior within the phase change material. Productivity and efficiency measurements reveal significant improvements: case 1 achieves 2.66 units of daily production and 46.23% efficiency, while cases 2, 3, and 4 yield 3.17, 3.58, and 4.27 units of daily production, respectively. Notably, the utilization of NPCM results in a 60.37% increase overall productivity and a 68.29% improvement in overall efficiency.

Bioconvective reversible (an esterification process) Casson nanofluid flow over a radiative spinning disc with microorganism

This study describes the Casson (a non-Newtonian fluid) nanofluid bioconvection flow across a spinning disc in the presence of gyrotactic microorganisms, many slips and thermal radiation. Also, the flow is considered as a reversible flow. The esterification process is taken into account. Using the proper variables, a system of extremely nonlinear PDEs is converted into a system of ODEs. To arrive to the solution of such equations, a numerical approach is used. Using the bvp4c approach, nonlinear flow equations can be numerically solved. Investigated are the effects of different numbers on the thermal field, volumetric concentration of nanoparticles and microbiological field. The key characteristics of the parameters in relation to the profiles of the velocity, temperature, concentration and microorganisms are graphically assessed with appropriate physical effects. A graphical explanation is provided for the wall shear stress, local Nusselt number, local Sherwood number and local motile density number. Rate of motile density number shows a prominent difference between reversible and irreversible flows for Brownian motion and Peclet number. The results of the theoretical simulations have dynamic applications in the fields of biotechnology and thermal engineering.

Secondary metabolite profile of Streptomyces spp. changes when grown with the sub-lethal concentration of silver nanoparticles: possible implication in novel compound discovery.

The decline of new antibiotics and the emergence of multidrug resistance in pathogens necessitates a revisit of strategies used for lead compound discovery. This study proposes to induce the production of bioactive compounds with sub-lethal concentrations of silver nanoparticles (Ag-NPs). A total of Forty-two Actinobacteria isolates from four Saudi soil samples were grown with and without sub-lethal concentration of Ag-NPs (50µgml-1). The spent broth grown with Ag-NPs, or without Ag-NPs were screened for antimicrobial activity against four bacteria. Interestingly, out of 42 strains, broths of three strains grown with sub-lethal concentration of Ag-NPs exhibit antimicrobial activity against Staphylococcus aureus and Micrococcus luteus. Among these, two strains S4-4 and S4-21 identified as Streptomyces labedae and Streptomyces tirandamycinicus based on 16S rRNA gene sequence were selected for detailed study. The change in the secondary metabolites profile in the presence of Ag-NPs was evaluated using GC-MS and LC-MS analyses. Butanol extracts of spent broth grown with Ag-NPs exhibit strong antimicrobial activity against M. luteus and S. aureus. While the extracts of the controls with the same concentration of Ag-NPs do not show any activity. GC-analysis revealed a clear change in the secondary metabolite profile when grown with Ag-NPs. Similarly, the LC-MS patterns also differ significantly. Results of this study, strongly suggest that sub-lethal concentrations of Ag-NPs influence the production of secondary metabolites by Streptomyces. Besides, LC-MS results identified possible secondary metabolites, associated with oxidative stress and antimicrobial activities. This strategy can be used to possibly induce cryptic biosynthetic gene clusters for the discovery of new lead compounds.

Numerical study on the synergistic effects of ultrasonic transducers and nano-enhanced phase change material in CPU thermal management

This study numerically investigates the effectiveness of concurrently applying nano-enhanced phase change material (NEPCM) and an ultrasonic field for the thermal management of a pin fin heat sink. The role of the NEPCM is to absorb heat from the heat sink wall, while the ultrasonic field generated by ultrasonic transducers facilitates the accelerated melting of the NEPCM. The study investigated how varying the number of ultrasonic transducers positioned near each side wall of the square cross-section heat sink, along with adjusting the concentration of nanoparticles in the NEPCM, impacts the heat sink's performance. The total power consumption of the transducers is assumed to be constant and an increase in their number is associated with a decrease in the power consumption of each transducer. It was observed that raising the number of transducers and lowering the nanoparticle concentration both contributed to a decrease in the CPU's highest temperature. Additionally, it was found that by using the combination of ultrasonic field and NEPCM, the average temperature of CPU can be reduced by 12.33–15.91 °C to the case without the ultrasonic field. Moreover, raising the number of transducers and lowering the nanoparticle concentration both contributed to a decrease in the CPU's average temperature.

Influence of activation energy and variable thermal conductivity on magneto-convective nonlinear thermo-radiative Casson nanofluid containing motile microorganisms over a sinusoidal surface

The activation energy of convective-radiative nanoliquids with sinusoidal walls has garnered significant academic interest in recent years. This focus arises due to the pivotal applications of nanoparticles in thermal engineering, industrial processes, and medical sciences. This article investigates the magnetohydrodynamic heat transfer characteristics of Casson nanofluids containing microorganisms influenced by an oscillatory surface. The study incorporates temperature-dependent viscosity and utilizes Buongiorno’s mathematical model to account for nonlinear thermal radiation, Brownian motion, and thermophoretic effects from using nanomaterials in Casson fluids. These effects enhance thermal conductivity, improving the heat transportation phenomenon while considering gyrotactic microorganism density distributions. The boundary layer flow problem is formulated using partial differential equations and associated boundary conditions, subsequently numerically simulated using the bvp4c function. The investigation explores the thermal behavior of nanoparticles in the presence of bioconvection phenomena, Lorentz force, chemical reactions, and activation energy. As a result, this model addresses variable thermal conductivity and bioconvection aspects in Casson nanofluids over a sinusoidal surface. Numerically computed results for the Nusselt number, motile density, and Sherwood number provide insights into several essential features. The findings reveal that an increase in the Casson fluid parameter correlates with a decreased velocity profile. The assumptions of variable thermal conductivity and temperature-dependent viscosity prove more effective in raising the temperature of nanoparticles. The nanoparticle concentration profile rises noticeably for smaller Schmidt number Sc values when the activation energy parameter is higher than larger Sc values. Additionally, the presence of microorganisms in Casson nanofluids leads to increased temperatures due to an elevation in the bioconvection Rayleigh number. Moreover, heightened oscillating frequency parameters decrease nanoparticle concentration and microorganism density. Including activation energy and oscillating frequency parameters further enhances the understanding of nanoparticle concentration and microorganism density dynamics, offering valuable contributions to theoretical research and practical applications across multiple interdisciplinary fields.

Effect of ZrO2 nanoparticles on the self-lubrication behavior of the linseed oil-loaded microcapsule/ epoxy composite coatings

Smart polymeric coatings play a crucial role in protecting steel surfaces from corrosion and wear. One of progressive smart behavior is self-healing behavior especially in self-healing epoxy coatings. Creating or improving the second smart behavior is known as a new trend for these smart materials. This study aims to investigate the effects of ZrO2 nanoparticles on the self-lubricating behavior as the second smart behavior of the linseed oil-loaded microcapsule/epoxy composite coatings. To do so, the in-situ polymerization method was used for the synthesis of linseed oil-loaded microcapsule. Results showed that the average size of prepared linseed oil-loaded microcapsules was 563 nm. The composite coatings were prepared by different content of ZrO2 nanoparticles (0, 3, 6, 9, 12, and 15 wt%) and constant content of linseed oil-loaded microcapsules (5 wt%). The tribological performance of samples was studied using pin-on-disk test. The worn surface of the samples was also studied using field emission scanning electron microscope (FESEM) images. Results proved that the frictional coefficient and wear rate of the samples were significantly decreased by increasing the concentrations of the ZrO2 nanoparticles up to 9 wt%. The lowest friction coefficient and wear rate values of 0.085 and 0.142 × 10−6 mm3/Nm were obtained for 5 wt% linseed oil-loaded microcapsules/epoxy with 9 wt% ZrO2 which were about 82 % and 88 % lower than those of pure epoxy coating.

A Self-foaming Strategy to Construct Small Mo2C Nanoparticles Decorated 3D Carbon Foams as Superior Electromagnetic Wave Absorbing Materials with Strong Corrosion Resistance.

3D macroporous carbon-based foams are always considered as promising candidates for high-performance electromagnetic (EM) wave absorbing materials due to the collaborative EM contribution and salutary structure effect. However, the uneven distribution of heterogeneous EM components and the cumbersome preparation process have become key issues to hinder their performance improvement and practical popularity. Herein, the fabrication of 3D carbon foam decorated with small and highly dispersed Mo2C nanoparticles is realized by an innovative self-foaming strategy. The foaming mechanism can be attributed to the decomposition of nitrate during the softening process of organic polymers. The good dispersion of Mo2C nanoparticles boosts interfacial polarization significantly. After regulating the content of Mo2C nanoparticles, the optimal Mo2C/CF-x exhibits good EM absorption performance, whose minimum reflection loss intensity value can reach up to -72.2dB, and effective absorption bandwidth covers 6.7GHz with a thickness of 2.30mm. Very importantly, the resultant Mo2C/CF-x exhibits hydrophobicity and strong acidic anticorrosion, and a long-time treatment in HCl solution (6.0molL-1) produces negligible impacts on their EM functions. It is believed that this extraordinary feature may render Mo2C/C foams as qualified and durable EM wave absorbing materials (EWAMs) under rigorous conditions.