N-methylmorpholine-N-oxide Research Articles

Structure and properties of the cellulose fibres spun from imidazolium-based carboxylate functionalized zwitterionic liquid

Dissolution of cellulose without further derivatization has been an active area of research in recent years. There are still challenges in developing a commercially viable solvent system for the dissolution and regeneration of cellulose as films and fibres. We report here a process for making cellulose fibres through the dry-jet wet spinning method by utilizing aqueous zwitterionic liquid (ZIL), viz., (6-(1-(2-methoxyethyl) imidazol-3-io)-hexanoate), in which oxyethylene substituted imidazolium-based cation and a carboxylate anion is covalently tethered. Our results suggest that 11 % ZIL dope could be successfully prepared and spun under industrially viable process conditions. The resultant fibres have properties comparable to that of commercial-grade Lyocell fibres. Particularly, the cellulose fibres spun from a cellulose ZIL solution exhibited a denier of 1.2–1.6, a tenacity of 3.5–4.0 g per denier (gpd), and an elongation at break of 8–10 %, which is comparable to cellulose fibres produced using ionic liquid and N-methyl-morpholine-N-oxide (NMMO) solvent. Cellulose fibres obtained from zwitterionic liquid have a crystallinity of 60 %, which is comparable to Lyocell fibres. To the best of our knowledge, this is the first report to demonstrate the successful spinning of regenerated cellulose fibres using zwitterionic liquids with mechanical properties comparable to commercial Lyocell fibres.

Stretchable Composite Films Are Prepared by Using Cellulose Pulp with Differential Substitution of Carboxymethyl Cellulose and Thymol with an Infrared Heating Process for Packaging Application.

Herein, cellulose pulp (CP), carboxymethyl cellulose (CMC), and thymol-based eco-friendly, transparent, and flexible composite films are prepared. These materials dissolved well in an environment-friendly process in N-methyl morpholine N-oxide (NMMO) ionic liquids using infrared heating. Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and scanning electron microscopy (SEM) analyses are used to study the structure, microstructure, and morphology of the composite films. The thermal properties of the CP/CMC/thymol composites are thoroughly studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The thermal stability of the composites (T 5%-57.8-91.2 °C and T 10%-216.6-284.1 °C) significantly improves following the CMC addition. In each case, all the composite film exhibits unique T g (140.5-143.1 °C) values, as confirmed by DSC. The tensile strength of the cellulose pulp is 66.5 MPa, increasing to 78.4 MPa for the CP/CMC-1:0.5 composites and steadily increasing to 93.8 MPa with increasing CMC content. Similarly, CMC increases the EB of cellulose pulp from 9.3 to 7.4%. The water vapor permeability and swelling ratio values of the CP/CMC/thymol composites are in the range of 1.9-2.11 × 10-9 g/(m2·Pa·s) and 52.5-50.8° respectively. The CP, CMC, and thymol-based composite do not exhibit cytotoxicity to the aneuploid immortal keratinocyte cell line and demonstrate excellent antioxidant properties, for promising packaging and biomedical applications.

Cellulose Fiber with Enhanced Mechanical Properties: The Role of Co-Solvents in Gel-like NMMO System.

Cellulose has garnered attention in the textile industry, but it exhibits limitations in applications that require high strength and modulus. In this study, regenerated cellulose fiber with enhanced mechanical properties was fabricated from a gel-like N-methylmorpholine N-oxide (NMMO)-cellulose solution by modulating the intermolecular interaction and conformation of the cellulose chains. To control the interaction, two types of co-solvents (dimethyl acetamide (DMAc) and dimethyl formamide (DMF)) were added to the cellulose solutions at varying concentrations (10, 20, and 30 wt%). Rheological analysis showed that the co-solvents reduced the solution viscosity by weakening intermolecular interactions. The calculated distance parameter (Ra) in Hansen space confirmed that the co-solvent disrupted intermolecular hydrogen bonding within cellulose chains. The solutions were spun into fiber via a simple wet spinning process and were characterized by X-ray diffraction (XRD) and universal testing machine (UTM). The addition of co-solvent led to an increased crystallinity index (C.I.) owing to the extended cellulose chains. The modulus of the resulting fiber was increased when the co-solvent concentration was 10 wt%, regardless of the co-solvent type. This study demonstrates the potential for enhancing the mechanical properties of cellulose-based products by modulating the conformation and interaction of cellulose chains through the addition of co-solvent.

Study of Mesoporous Zr-TiO2 Catalyst with Rich Oxygen Vacancies for N-Methylmorpholine Oxidation to N-Methylmorpholine-N-oxide.

A series of Zr-TiO2 catalysts were prepared using a facile sol-gel method and were used for N-methylmorpholine (NMM) oxidation to N-methylmorpholine-N-oxide (NMMO). The structure features of Zr-TiO2 catalysts were studied in detail through a variety of characterization methods, such as XRD, SEM, N2 adsorption-desorption isotherms, XPS, EPR, and O2-TPD. As-obtained 5%Zr-TiO2 catalysts had superior catalytic performance and stability with a 97.6% NMMO yield at 40 °C, which related to Zr doping, a higher surface area, more oxygen vacancies, and oxygen chemisorption on the catalytic surface. This work provides an efficient preparation strategy of TiO2-based catalysts for selective oxidation reactions by a facile method.

Antibacterial cellulose solution-blown nonwovens modified with salicylic acid microcapsules using NMMO as solvent

Solution blowing process was used to prepare cellulose nonwovens, by using N-methyl morpholine-N-oxide (NMMO) as solvent, and salicylic acid (SA) microcapsules as antibacterial additives. The structure and properties of cellulose nonwovens modified with different SA microcapsules contents were compared and evaluated. The results showed that more uniform and denser web structure was formed with the increase of SA microcapsules content, the average fiber diameter of cellulose nonwoven increased from 1.99 μm to 2.65 μm. The air flow resistance and filtration efficiency of cellulose nonwovens increased with addition of SA microcapsules, whereas the mechanical properties, and wearing comfort including air permeability, moisture vapor transfer rate, and softness of cellulose nonwovens decreased slightly, under the same basis weight. SA microcapsules modified cellulose nonwovens exhibited good sustained-release behavior and antimicrobial activity against Escherichia coli. The higher SA microcapsules content in cellulose nonwovens, the faster release rate and the higher antimicrobial activity. The cellulose solution-blown nonwovens modified with SA microcapsules are expected to find applications in medical and healthcare fields due to its antibacterial activity and biodegradability.

High tensile regenerated cellulose fibers via cyclic freeze-thawing enabled dissolution in phosphoric acid for textile-to-textile recycling of waste cotton fabrics

Recycling of waste cotton fabrics (WCFs) is a desirable solution to address the problems brought up by fast fashion, but it remains challenging due to inherent limitations in preparing stable and spinnable dopes by dissolving high molecular weight cellulose efficiently and cost effectively. Herein, we show that despite the prevailing concerns of cellulose degradation via glycosidic hydrolysis when dissolved in acids, fast and non-destructive direct dissolution of WCFs in aqueous phosphoric acid (a.q. PA) could be realized using a cyclic freeze-thawing procedure, which combined with subsequent adjustment of degree of polymerization (DP) and degassing yielded stable and spinnable dopes. Regenerated cellulose fibers (RCFs) with favorable tensile strength (414.2 ± 14.3 MPa) and flexibility (15.4 ± 1.5 %) could be obtained by carefully adjusting the coagulation conditions to induce oriented and compact packing of the cellulose chains. The method was shown to be conveniently extended to dissolve reactively dyed WCFs, showing great potential as a cheap and green alternative to heavily explored ionic liquids (ILs) and N-methylmorpholine-N-oxide (NMMO)-based systems for textile-to-textile recycling of WCFs.

Development of Cellulose Microfibers from Mixed Solutions of PAN-Cellulose in N-Methylmorpholine-N-Oxide.

Mixed solutions of PAN with cellulose in N-methylmorpholine-N-oxide (NMMO) were prepared. Systems with a fraction of a dispersed phase of a cellulose solution in NMMO up to 40% are characterized by the formation of fibrillar morphology. The fibrils created as the mixed solution is forced through the capillary take on a more regular order as the cellulose content in the system drops. The systems' morphology is considered to range from a heterogeneous two-phase solution to regular fibrils. The generated morphology, in which the cellulose fibrils are encircled by the PAN, can be fixed by spinning fibers. Cellulose fibrils have a diameter of no more than a few microns. The length of the fibrils is limited by the size of the fiber being formed. The process of selectively removing PAN was used to isolate the cellulose microfibrils. Several techniques were used to evaluate the mechanical properties of isolated cellulose microfibers. Atomic force microscopy allowed for the evaluation of the fiber stiffness and the creation of topographic maps of the fibers. Cellulose microfibers have a higher Young's modulus (more than 30 GPa) than cellulose fibers formed in a comparable method, which affects the mechanical properties of composite fibers.

Impact of surfactants on SWCNT dispersion in N-methylmorpholine N-Oxide for cellulose dissolution

A well dispersed slurry of single-walled carbon nanotube (SWCNT) and 60 % hydrated N-methylmorpholine N-oxide (NMMO) solution was prepared by probe sonicator. The proper dispersion of carbon nanotube (CNT) has been verified by optical microscope by varying the sonication time. Further, the slurry was concentrated to 76 % (for cellulose dissolution) and during this process some agglomeration of CNTs has been observed. The dispersion of CNT aggregation was checked by addition of surfactants like sodium dodecyl sulfate (SDS) and sodium dodecyl benzene sulfonate (SDBS) (with 2 % (w/w) with respect to CNT) to the surface of CNT. SDBS is giving better dispersion as compared to SDS when the slurry is heated to obtain 76 % NMMO as checked by optical microscope and UV–Vis spectrophotometer to get quantitative amount of dispersed CNT. 88 % dispersion has been obtained in case of SDBS-assisted CNT after heating followed by centrifugation of the concentrated solution. Similarly, 78 % dispersion has been observed in case of SDS-assisted CNT and 46 % dispersion in case of CNT without any surfactant. The stronger dispersion ability of SDBS could improve its use for SWCNT separation in NMMO solution which can be used further for cellulose dissolution to prepare lyocell fiber.

Structure Formation by 3D-Printing of Cellulose from Cellulose-NMMO-Water Solutions: Analysis of Extrusion, Regeneration, and Drying Stages.

Processing cellulose from 4-methyl morpholine n-oxide (NMMO)-water solutions is a completely circular route that produces biodegradable cellulose fibers or films while recovering reusable NMMO [Guo, Y.; Cai, J.; Sun, T.; Xing, L.; Cheng, C.; Chi, K.; Xu, J.; Li, T. The purification process and side reactions in the N-methylmorpholine-N-oxide (NMMO) recovery system. Cellulose 2021, 28(12), 7609-7617]. Despite proven success in two-dimensional applications, challenges in transitioning to three-dimensional objects arise from the critical changes that cellulose undergoes during deposition, regeneration, and postregeneration stages. While emphasizing the critical diffusion-driven precipitation during regeneration, this investigation explores the influence of extrusion temperature, printing alignment, regeneration, and drying processes on interfilament fusion, bonding, shape integrity, and mechanical properties. Three distinct drying processes: ambient, vacuum, and freeze-drying were investigated. Tensile and flexural bending tests provided insight into the delamination of dried specimens. Ambient and vacuum drying enhanced the properties of specimens, while freeze-drying resulted in a more stable shape. The findings contribute to advancing the understanding of 3D-printing cellulose from NMMO solutions, addressing crucial aspects of the extrusion, regeneration, and drying stages for enhanced applications in sustainable manufacturing.

Reusable Magnetite Nanoparticle (Fe3O4 NP) Catalyst for Selective Oxidation of Alcohols under Microwave Irradiation.

Iron oxide nanoparticles (NPs) are nontoxic and abundant materials which have long been investigated as reusable catalysts in oxidation reactions, but their use so far has been hampered by a low selectivity. Here, unsupported iron oxide NPs have been found to successfully catalyze the microwave-assisted oxidation of primary and secondary alcohols to their respective aldehydes and ketones with a high selectivity when N-methylmorpholine N-oxide was used as the terminal oxidant. The crystalline phase and size of the iron-based catalyst have a drastic effect on its activity, with small magnetite (Fe3O4) NPs being the optimal catalyst for this reaction. The nanocatalyst could be easily recovered by magnetoseparation and successfully recycled four times without any need for special pretreatment or reactivation step and with a minimal loss of activity. The subsequent loss of activity was attributed to the transition from magnetite (Fe3O4) to maghemite (γ-Fe2O3), as confirmed by X-ray diffraction, Fourier transform infrared, and X-ray absorption near-edge spectroscopy. The nanocatalyst could then be reactivated by the high-temperature microwave treatment and used again for the microwave-assisted oxidation reaction.

Innovative plasticization technique for talc-powder reinforced wheat-starch biomass composite plastics with enhanced mechanical strength

N-methyl-morpholine-N-oxide (NMMO) was initially created as a plasticizer for starch to produce thermoplastic wheat starch. Subsequently, talc powder was used as a reinforcing filler to enhance the mechanical strength of thermoplastic biomass-based composite plastics. The chemical structure, crystal structure, and microscopic morphology were analyzed using Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. Additionally, the thermal properties were explored through thermogravimetric analysis, differential scanning calorimetry, and dynamic mechanical analysis. The hydrated NMMO plasticizer demonstrated an outstanding plasticizing effect on starch, resulting in a composite with remarkable mechanical properties. In fact, the pure thermoplastic wheat starch plasticized with hydrated NMMO exhibited the highest mechanical strength recorded so far, with a tensile strength of up to 9.4 MPa. In addition, talcum powder displayed a noticeable reinforcing effect. When the talcum powder content reached 30 wt%, the targeted composite achieved a tensile strength of 20.5 MPa and a Young's modulus of 177.9 MPa. These values were 118 % and 48 % higher, respectively, than those of the pure thermoplastic starch sample. This innovative plasticizing method opens up a new avenue for the development of high-mechanical-strength thermoplastic biomass-based composite plastics with promising potential applications.

Accelerated Weathering Testing (AWT) and Bacterial Biodegradation Effects on Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV)/Rapeseed Microfiber Biocomposites Properties.

In the context of sustainable materials, this study explores the effects of accelerated weathering testing and bacterial biodegradation on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV)/rapeseed microfiber biocomposites. Accelerated weathering, simulating outdoor environmental conditions, and bacterial biodegradation, representing natural degradation processes in soil, were employed to investigate the changes in the mechanical, thermal and morphological properties of these materials during its post-production life cycle. Attention was paid to the assessment of the change of structural, mechanical and calorimetric properties of alkali and N-methylmorpholine N-oxide (NMMO)-treated rapeseed microfiber (RS)-reinforced plasticized PHBV composites before and after accelerated weathering. Results revealed that accelerated weathering led to an increase in stiffness, but a reduction in tensile strength and elongation at break, of the investigated PHBV biocomposites. Additionally, during accelerated weathering, the crystallinity of PHBV biocomposites increased, especially in the presence of RS, due to both the hydrolytic degradation of the polymer matrix and the nucleating effect of the filler. It has been observed that an increase in PHBV crystallinity, determined by DSC measurements, correlates with the intensity ratio I1225/1180 obtained from FTIR-ATR data. The treatment of RS microfibers increased the biodegradation capability of the developed PHBV composites, especially in the case of chemically untreated RS. All the developed PHBV composites demonstrated faster biodegradation in comparison to neat PHBV matrix.

N‐methylmorpholine‐N‐oxide molecules coated ammonium polyphosphates for dope spinning of flame‐retardant lyocell fiber

AbstractLyocell fiber, hailed as the “verdant filament of the 21st century,” boasts elevated tensile strength, environmentally conscientious production practices, and innate biodegradability. Nonetheless, its intrinsic combustibility constitutes a noteworthy impediment to its pervasive utilization across textile and industrial domains. In a concerted effort to surmount this challenge, ammonium polyphosphate (APP) underwent modification through the infusion of N‐methylmorpholine‐N‐oxide (NMMO) molecules, amplifying its dispersibility within lyocell solutions. The resultant NMMO‐coated ammonium polyphosphate (NAPP) underwent meticulous characterization of both its structure and properties. Remarkably, lyocell fiber impregnated with 30% NAPP exhibited exemplary flame retardancy, enduring through 30 laundering cycles. Notably, its tensile strength remained notably robust at 139 MPa, demonstrating a mere 6.1% reduction in comparison to its pristine lyocell counterpart. This study delineates a promising trajectory for the fabrication of mechanically resilient lyocell fibers endowed with commendable flame‐retardant attributes.Highlights The raw material is waste cotton textiles, prepared on a green basis. The use of ultrasonic mixing and low‐speed stirring defoaming method and the use of room temperature spinning advantage of the production of flame retardant lyocell fiber. The amount of flame retardant is small, and the mechanical strength is reduced to a lesser extent. Good flame‐retardant effect and excellent water washing resistance.

Olefin dihydroxylation mediated by Os-Zn-Al hydrotalcite-like catalyst: The scope and reactivity using various co-oxidants

The heterogeneous oxidation of olefins to vicinal diols was investigated using an Os-Zn-Al hydrotalcite-like catalyst (HTlc). The Os-Zn-Al HTlc was synthesised by the co-precipitation method and characterised fully using XRD, FT-IR, TEM, SEM, ICP-OES and BET surface area measurements. The ability of the synthesised Os-Zn-Al HTlc to catalytically dihydroxylate olefins to vicinal diols using various co-oxidants (air, NMO, K3Fe(CN)6, H2O2 and t-BuOOH) was investigated. The focus was mostly on N-methylmorpholine N-oxide (NMO) and K3Fe(CN)6 since they are well established co-oxidants for osmium catalysed dihydroxylation. When NMO was used, 100 % olefin conversion was achieved for all olefins tested. While, 100% conversion was only achieved with electron rich olefins when K3Fe(CN)6 was used as co-oxidant. Recyclability and leaching tests were done, and it was found that the catalyst could be recycled at least 3 times in the NMO system and the K3Fe(CN)6-K2CO3 system was found to be truly heterogeneous.

Regenerated cellulose/polyethyleneimine composite aerogel for efficient and selective adsorption of anionic dyes

With the requirement of sustainable development in modern society, it is urgent to develop the environmentally friendly adsorbents for selective filtration and separation of toxic dyes from hazardous wastewater. Herein, a stable, reusable, and highly compressible three-dimensional regenerated cellulose/polyethyleneimine composite aerogel (RC/PCA) was successfully prepared directly using cheap cotton pulp as raw material and N-methyl morpholine-N-oxide (NMMO) as the “green” solvent, in which the regenerated cellulose (RC) with hydroxyl groups converted from cotton can interact with polyethyleneimine (PEI) with amine groups. After further crosslinking of RC, PEI and glutaraldehyde (GA), the RC/PCA can be used to selectively absorb anionic dyes from the ternary mixed dye system, which maximal adsorption capacity for methyl orange (MO) can be up to 980.39 mg/g. Moreover, the obtained stable RC/PCA can be repeatedly used at least 50 times for the removal of MO (20 mg/L) with a high filtration efficiency of 99.8 %. The kinetics and isothermal adsorption data were described via the pseudo-second-order kinetic model and Langmuir model. Therefore, this research proposes a novel strategy for developing low-cost, highly efficient, regenerated cellulose-based adsorbents to extract organic dyes from wastewater for potential practical applications.

Regenerated bacterial cellulose fibres

The global shortage of cotton for textile production, forces the exploitation of forests´ lignocellulosic biomass to produce man-made cellulosic fibres (MMCF). This has a considerable environmental impact, pressing the textile industry to search for new sustainable materials and to the development of sustainable recycling processes. Bacterial cellulose (BC), an exopolysaccharide produced by fermentation, could represent such an alternative. In particular, we tested the possibility of improving the mechanical properties of cellulose filaments with a low degree of polymerization (DP) by combining them with high DP from BC, so far exploited to little extent in the textile field.In this work, BC with different degrees of polymerization (DPcuaxam) (BCneat: 927; BCdep:634 and BCblend: 814) were dissolved in N-methylmorpholine-N-oxide (NMMO) and their spinnability was studied. The rheological behaviour of the dopes was assessed and all were found to be spinnable, at suitable concentrations (BCneat:9.0 %; BCdep:12.2 %; BCblend:10.5 %). A continuous spinning was obtained and the resulting filaments offered similar mechanical performance to those of Lyocell. Further, the blending of BC pulps with different DPs (BCblend, obtained by combining BCneat and BCdep) allowed the production of fibres with higher stiffness (breaking tenacity 56.4 CN.tex−1) and lower elongation (8.29 %), as compared to samples with more homogeneous size distribution (neat BC and depolymerized BC).

A SIMULATION OF EVAPORATION DISSOLUTION PROCESS FOR A LYOCELL SOLUTION IN A VERTICAL WIPED FILM EVAPORATOR (1: SIMULATION OF FLOW PROCESS FOR SOLUTION)

Vertical wiped film evaporators (VWFE) have found wide application in chemical, food and especially, fiber industries. In this paper, a mathematical simulation is represented for the vacuum evaporation dissolution process of Lyocell solution (reed cellulose, N-Methylmorpholine N-oxide (NMMO) solvent, water) in VWFE. The Turbulent Flow model in geometries with rotating parts and the frozen rotor approach in COMSOL Multi-physics 5.4 were used for simulation of the solution flow in VWFE. Comparing the obtained simulation results with experimental details, we show the effect of our simulation method.

Molecular mechanism of cellulose dissolution in N-methyl morpholine-N-oxide: A molecular dynamics simulation study

N-methyl morpholine-N-oxide (NMMO) is the only commercialised solvent to dissolve cellulose and produce lyocell. However, the molecular mechanism of NMMO-induced cellulose solubilisation is unknown which limits further process development. In this work, and for the first time the complete dissolution process of a large cellulose bunch was simulated in NMMO monohydrate using long microsecond molecular dynamic simulations. The dissolution process was also simulated in 1-ethyl-3-methylimidazolium acetate (EmimAc) as an efficient ionic liquid in cellulose dissolution and the results were compared with the aqueous conditions. While the cellulose bunch showed a stable and insoluble structure in pure water, it was completely and efficiently dissolved in both NMMO monohydrate and EmimAc. It was shown that the dissolution time of cellulose in NMMO monohydrate is almost twice that in EmimAc, which is in agreement with the experimental observations. Although it is revealed that hydrogen bonding is the main driving force of cellulose dissolution in NMMO monohydrate, one cannot explain the complete molecular mechanism of NMMO-induced cellulose dissolution only by considering hydrogen bonds. A straightforward molecular mechanism was proposed, in which the interactions of NMMO molecules, not with cellulose, but with the other NMMO molecules play a critical role in the dissolution process.

Profitable and environmentally responsible recycling of fibers and reactive dyes from afterlife cotton textiles via controlled dye hydrolysis, fiber swelling and dissolution

We have developed sustainable cotton recycling to provide high-quality cellulose fibers as well as dyes. Because of the lack of simple, non-destructive, and environmentally responsible discoloration technologies, recycled cellulosic products have lower and inconsistent quality and thus limited values. For example, recycling cotton via the spinning of colored cotton into colored cellulose fibers faces challenges since dyes seriously disrupt the spinnability of cellulose dopes. Here, we demonstrate a clean technology to completely recycle all reactive dyed cotton and dyes via controlled dye hydrolysis, fiber swelling, and dissolution. Controlled dye hydrolysis cleaved the covalent bonds between reactive dyes and cellulose. Fiber swelling in N-Methylmorpholine N-oxide (NMMO)/water almost eliminated the physical interactions between dyes and cellulose. As a result, dyes, with different functional groups and chromogenic structures, were separated from cotton. The discolored cotton in NMMO demonstrated desirable spinnability without adding any new cellulose pulp. The high molecular weight makes 100% recycled lyocell fibers tougher than wood-derived lyocell. Separated reactive dyes, with unchanged chromogenic structures, demonstrate desirable dyeability as acid dyes. Recycling cotton is cost-effective to obtain cellulose pulp, the starting materials to produce lyocell, compared to the classic Kraft wood process. The NMMO was recyclable and provided consistent results of cotton discoloration for at least 5 use cycles.

Direct dissolution of unbleached pulp from corncob and wheat straw in N-methylmorpholine-N-oxide

Lignocellulose, as a kind of abundant natural resource, continuously developed to convert high value-added biological products is of great significance. Herein, we report a N-methylmorpholine-N-oxide (NMMO) solvent system to completely dissolve unbleached pulp to prepare a renewable lignin-containing cellulose film. The viscosity of the completely dissolved cellulose solution was measured using a high-pressure rotary rheometer. The shear viscosity exceeded 85 Pa·s at a shear rate of 1.62 s−1. It exhibited shear-thinning non-Newtonian fluid behavior with increasing shear rate. CF-WS had excellent tensile strength (>73 MPa), and exhibited unique optical properties of high transmittance in the visible region and high shielding performance in the ultraviolet region. When the thickness is only 0.016 mm, the UV shielding rate exceeds 75 % (λ < 380 nm). The structure of the bioplastic was revealed by SEM, XPS, and Raman spectroscopy. Directly dissolving lignocellulose in NMMO aqueous solution is expected to yield bioplastics with high strength and biodegradability. It is a potential substitute for petrochemical plastics and provides a possible way for the utilization of agricultural waste.