As an indispensable part of the Internet of Vehicles (IoV), unmanned aerial vehicles (UAVs) can be deployed for target positioning and navigation in the space–air–ground-integrated network (SAGIN) environment. Maritime target positioning is very important for the safe navigation of ships, hydrographic surveys, and marine resource exploration. Traditional methods typically exploit satellites to locate marine targets in the SAGIN environment, and the location accuracy does not satisfy the requirements of modern ocean observation missions. In order to localize the marine target, we develop a system architecture in this article, which contains UAVs integrated with monostatic multiple-input–multiple-output (MIMO) radars. The main thrust is to estimate the direction-of-arrival (DOA) via MIMO radar. Herein, we consider a general scenario that unknown mutual coupling exist and a novel sparse reconstruction algorithm is proposed. The mutual coupling matrix (MCM) is adopted with the help of its special structure, we formulate the data model as a sparse representation form. Then, two novel matrices, a weighted matrix, and a reduced-dimensional matrix are constructed to reduce the computational complexity and enhance the sparsity, respectively. Thereafter, a sparse constraint model is constructed using the concept of optimal weighted subspace fitting (WSF). Finally, the DOA estimation of maritime targets can be achieved by reconstructing the support of a block sparse matrix. Based on the DOA estimation results, multiple UAVs are used to cross-locate marine targets multiple times, and an accurate marine target position is achieved in the SAGIN environment. Numerical results are carried out, which demonstrates the effectiveness of the proposed DOA estimator, and the multi-UAV cooperative localization system can realize accurate target localization.