Multiple Emission Research Articles

Exploring the luminescent thermometer and optical storage applications in negative thermal quenching phosphor of BaSc2Ge3O10:Pr3+

The optical contactless thermometer demonstrates remarkable advantages over traditional contact thermometers. However, maintaining a strong optical signal output across a wide temperature range poses a challenge due to the thermal quenching effect. In this study, we aimed to overcome the limitation of low signal intensity in high-temperature applications by developing a Pr3+-doped BaSc2Ge3O10 (BSGO) phosphor with anti-thermal quenching properties. This phosphor was designed to ensure a stable and sufficiently strong light signal for accurate temperature measurements. The phosphor exhibited a negative thermal quenching effect, where the integrated emission intensity spanning from 450 nm to 800 nm increased from 173 K to 253 K, and the intensity at 353 K still remained stronger than at 173 K. Multiple 4f-4f transition emissions were observed in the phosphor, and the fluorescence intensity ratio (FIR) was utilized as a standard parameter for temperature evaluation ranging from 82 K to 353 K. At 82 K, the phosphor achieved maximum relative sensitivity (Sr) of 2.3% K−1. The presence of multiple traps with depths ranging from 1.09 eV to 1.50 eV not only supported luminescence with a negative thermal quenching effect but also resulted in long persistent luminescence (LPL), which was systematically investigated in this study.

Broadband and wide angle nonreciprocal thermal emission from Weyl semimetal structures

Nonreciprocal thermal emission is a cutting-edge technology that enables fundamental control over thermal radiation and has exciting applications in thermal energy harvesting. However, thus far one of the foremost challenges is making nonreciprocal emission operate over a broad wavelength range and for multiple angles. In this work, we solve this outstanding problem by proposing three different types of structures that always utilize only one Weyl semimetal (WSM) thin film combined with one or two additional dielectric or metallic layers and terminated by a metallic substrate. First, a tradeoff relationship between the magnitude and bandwidth of the thermal nonreciprocity contrast is established based on the thickness of the WSM film. Then, the bandwidth broadening effect is demonstrated via the insertion of a dielectric spacer layer that can also be fine-tuned by varying its thickness. Finally, further control on the resulting strong nonreciprocal thermal radiation is demonstrated by the addition of a thin metallic layer in the proposed few layer designs. The presented composite structures work for a broad frequency range and for multiple emission angles, resulting in highly advantageous properties for various nonreciprocal thermal radiation applications. Moreover, the proposed designs do not require any patterning and can be experimentally realized by simple deposition fabrication methods. They are expected to aid in the creation of broadband nonreciprocal thermal emitters that can find applications in new energy harvesting devices.

Aggregation-regulated room-temperature phosphorescence materials with multi-mode emission, adjustable excitation-dependence and visible-light excitation

Constructing room-temperature phosphorescent materials with multiple emission and special excitation modes is fascinating and challenging for practical applications. Herein, we demonstrate a facile and general strategy to obtain ecofriendly ultralong phosphorescent materials with multi-mode emission, adjustable excitation-dependence, and visible-light excitation using a single organic component, cellulose trimellitate. Based on the regulation of the aggregation state of anionic cellulose trimellitates, such as CBtCOONa, three types of phosphorescent materials with different emission modes are fabricated, including blue, green and color-tunable phosphorescent materials with a strong excitation-dependence. The separated molecularly-dispersed CBtCOONa exhibits blue phosphorescence while the aggregated CBtCOONa emits green phosphorescence; and the CBtCOONa with a coexistence state of single molecular chains and aggregates exhibits color-tunable phosphorescence depending on the excitation wavelength. Moreover, aggregated cellulose trimellitates demonstrate unique visible-light excitation phosphorescence, which emits green or yellow phosphorescence after turning off the visible light. The aggregation-regulated phenomenon provides a simple principle for designing the proof-of-concept and on-demand phosphorescent materials by using a single organic component. Owing to their excellent processability and environmental friendliness, the aforementioned cellulose-based phosphorescent materials are demonstrated as advanced phosphorescence inks to prepare various disposable complex anticounterfeiting patterns and information codes.

Synthesis of Multiple Emission Carbon Dots from Dihydroxybenzoic Acid via Decarboxylation Process.

Carbon dots (CDs), as a new zero-dimensional carbon-based nanomaterial with desirable optical properties, exhibit great potential for many application fields. However, the preparation technique of multiple emission CDs with high yield is difficult and complex. Therefore, exploring the large-scale and straightforward synthesis of multicolor CDs from a simple carbon source is necessary. In this work, the solvent-free method prepares a series of multicolor emission CDs from dihydroxybenzoic acid (DHBA). The maximum emission wavelengths are 408, 445, 553, 580, and 610 nm, respectively, covering the visible light region. The 2,4- and 2,6-CDs possess the longer emission wavelength caused by the 2,4-, and 2,6-DHBA easily undergo decarboxylation to form the larger sp2 domain graphitized structure. These CDs incorporated with g-C3N4 can significantly improve the photocatalytic water-splitting hydrogen production rate by extending the visible light absorption and enhancing the charge separation efficiency. The long-wavelength emission CDs can further enhance photocatalytic activity primarily by improving visible light absorption efficiency.

Color-Tunable Ultralong Organic Phosphorescence: Commercially Available Triphenylmethylamine for UV-Light Response and Anticounterfeiting.

Due to the unclear mechanism and lack of effective design for color-tunable ultralong organic phosphorescence (UOP) in a single-component molecule, the development of new types of single-component UOP materials with color-tunable property remains challenging. Herein, commercially available triphenylmethylamine-based single-component phosphors featuring color-tunablity and ultralong lifetime (0.56 s) are reported. The changed afterglow colors from cyan to orange were observed after different wavelengths of UV excitation. Crystal structure and calculation studies show that multiple emission centers in the aggregated states may be responsible for the color-tunablity. In addition, visual probing of UV light (from 260 to 370 nm) and colorful anti-counterfeiting were conducted. More importantly, UV light ranging from 350 to 370 nm could be detected with the minimal interval of 2 nm. The findings provide a new type of single-component color-tunable UOP materials and shed new light on mechanism and design for such materials.

Observation of tunable persistent luminescence in XAl2O4: Eu2+ (X=Ca, Sr) doped borate glass for efficient optical information storage

Eu2+ doped XAl2O4 (X = Ca, Sr) phosphor is usually prepared to study the monochromatic afterglow emission in a single crystal field, but the tunable afterglow emission with multiple emission bands in polycrystal fields has hardly been explored. In this paper, by fine-tuning the ratio of calcium carbonate to strontium carbonate in the borate matrix, Eu2+ ions are introduced into CaAl2O4 and SrAl2O4 crystals in different concentrations. Results review that reduction-induced oxygen vacancy defects distribute shallow or deep near Eu2+ 5d state to obtain the tunable polychromatic long afterglow emission from green to indigo to dark blue. Also, the additional red emission from Eu3+ in the borate glass matrix further enriches the luminescent characteristics by equipping the samples with tunable photoluminescence from yellow-green, yellow to purple. Such material is proved to have good optical information storage ability, which is expected to promote the development of long persistent luminescence materials.

Photoluminescence Study of As Doped p-type HgCdTe Absorber for Infrared Detectors Operating in the Range up to 8 µm

A HgCdTe photodiode grown by chemical vapor deposition (MOCVD) on a GaAs substrate operating in the long-wave infrared (LWIR) range was characterized using photoluminescence (PL) measurements. At high temperatures, the PL spectrum originates from a free-carrier emission and might be fitted by a theoretical expression being the product of the density of states and the Fermi–Dirac distribution. At low temperatures, the PL spectrum consists of multiple emission peaks that do not originate solely from the energy gap. Such spectra are not unambiguous to interpret due to the prominence of different optical transitions. Spectral response (SR) measurements were used to determine the energy gap (Eg) and extract the band-to-band transition from the PL spectra. PL peaks visible within the band gap were fitted by a Gaussian distribution. To identify the sources of individual emission peaks, excitation power dependence analysis was conducted. Band-to-band, free-to-bound, acceptor-bound exciton, and defect-bound exciton transitions were identified. At low temperatures, transitions are mainly impurity-related, with shallow impurity levels estimated to be 6 meV and 16 meV for the donor and acceptor, respectively, while deep-level impurities were associated with VHg. The latter transition with an energy of about 78 meV does not vary with temperature. Its relative positions with respect to the energy gap is 0.8 Eg at 18 K and 0.67 Eg at 80 K.

Preparation of full-color carbon quantum dots with multiple emission centers

In recent years, carbon dots have attracted more and more attention due to their unique advantages, but there has been a great controversy about the study of their mechanism. A clear mechanism is of great importance for the structural design of carbon dots. To investigate the photoluminescence mechanism of carbon dots, full-color carbon dots with multiple emission centers were successfully prepared by using citric acid and water-soluble aniline blue. It is shown that the red shift of emission wavelength is attributed to the synergistic effect of N and O-related surface functional groups and quantum size. The successful preparation of cold white light diodes from mixed trichromatic carbon dots indicates that this type of carbon dot has important applications in light-emitting devices.

A mixed-integer linear programming model for sustainable blood supply chain problems with shelf-life time and multiple blood types

The blood supply chain (BSC) is a complex system with optimization challenges, whose activities impact carbon emissions and the environment, especially with regard to the disposal of expired blood bag waste. This study proposes a new mixed-integer linear programming (MILP) model that considers multiple echelons, multiple blood types, transportation and production emissions, and blood bag shelf life to maximize profit in the blood supply chain system. The model is applied to a real-world case study. The research results confirmed that the model could mitigate the BSC challenges. We also conducted sensitivity analysis of patient demand parameters, blood production capacity, selling price, and shelf life to investigate the impact of the key factors affecting the total profit, costs, carbon emissions, and number of obsolete products.

A list-mode multi-energy window low-count SPECT reconstruction method for isotopes with multiple emission peaks

BackgroundSingle-photon emission computed tomography (SPECT) provides a mechanism to perform absorbed-dose quantification tasks for alpha-particle radiopharmaceutical therapies (alpha-RPTs). However, quantitative SPECT for alpha-RPT is challenging due to the low number of detected counts, the complex emission spectrum, and other image-degrading artifacts. Towards addressing these challenges, we propose a low-count quantitative SPECT reconstruction method for isotopes with multiple emission peaks.MethodsGiven the low-count setting, it is important that the reconstruction method extracts the maximal possible information from each detected photon. Processing data over multiple energy windows and in list-mode (LM) format provide mechanisms to achieve that objective. Towards this goal, we propose a list-mode multi energy window (LM-MEW) ordered-subsets expectation–maximization-based SPECT reconstruction method that uses data from multiple energy windows in LM format and include the energy attribute of each detected photon. For computational efficiency, we developed a multi-GPU-based implementation of this method. The method was evaluated using 2-D SPECT simulation studies in a single-scatter setting conducted in the context of imaging [^{223}Ra]RaCl{_2}, an FDA-approved RPT for metastatic prostate cancer.ResultsThe proposed method yielded improved performance on the task of estimating activity uptake within known regions of interest in comparison to approaches that use a single energy window or use binned data. The improved performance was observed in terms of both accuracy and precision and for different sizes of the region of interest.ConclusionsResults of our studies show that the use of multiple energy windows and processing data in LM format with the proposed LM-MEW method led to improved quantification performance in low-count SPECT of isotopes with multiple emission peaks. These results motivate further development and validation of the LM-MEW method for such imaging applications, including for alpha-RPT SPECT.

Capacitated lot sizing problem with periodic carbon emission constraints and multiple resources

We study the single item capacitated lot sizing problem with multiple resources and periodic carbon emission constraints that impose an upper bound for the average emission per product produced in any period. Although the uncapacitated version of this problem can be solved in polynomial time, generalisation of the problem including the resource capacities is NP-Hard, in general. We present important structural properties for the optimal solutions of the problem. We consider the special cases with two resources and under non-speculative costs, construct the piecewise linear total production cost function when the resource capacities, and the emission and cost parameters are time-invariant, and develop a polynomial time dynamic programming algorithm (DP) to solve them. Then, we generalise the procedure to construct the total production cost function and the DP for the general setting with fixed number of capacitated resources. We test our algorithm for different problem instances, and compare it with a commercial solver and a DP available in the literature for solving the lot sizing problem with piecewise concave production cost functions. The results reveal that our DP outperforms the other one, and it performs better than the commercial solver when the number of breakpoints of the total production cost function is small.

Push-Pull Bridged Distyrylbenzene with Highly Bright Solid-State Red-Orange Aggregation-Induced Emission.

Multiple emission colors in solid-state organic fluorophores with the same main skeleton are essential for improving the performance of light-emitting devices/materials. Specifically, emission in the red/near-infrared region is of great importance in the biological field. Previously, we developed di-bridged-distyrylbenzene DBDB[7] with high-brightness solid-state blue and aggregation-induced emissions (AIE) by introducing the bridging structures of a seven-membered ring into the vinylene groups of distyrylbenzene (DSB). Herein, we synthesize MNDBDMeODB[7] (1), which features substituted methoxy and malononitrile groups as donor and acceptor groups, respectively, in DBDB[7]. In solvents more polar than THF, MNDSDMeOB (3), which has the same main skeleton as 1 but without bridges, shows no emission in the solid state, whereas 1 exhibits highly bright red-orange emission in the solid state owing to the suppression of intermolecular electronic interactions by the bridges and the AIE property. We also synthesize MNDSD(EHO)B (2) in which the methoxy groups of 3 are replaced by ethylhexyloxy groups, thus disrupting the crystallinity of the molecule. 2 exhibits positive fluorescence solvatochromism and has a high fluorescence quantum yield in the solid state as a red-emitting DSB derivative. The solid-state emission properties of 1 and 2 will improve the applicability of DSBs and functionalities of light-emitting devices/materials.

Curved Nanographenes: Multiple Emission, Thermally Activated Delayed Fluorescence, and Non-Radiative Decay.

The intriguing and rich photophysical properties of three curved nanographenes (CNG 6, 7, and 8) are investigated by time-resolved and temperature-dependent photoluminescence (PL) spectroscopy. CNG 7 and 8 exhibit dual fluorescence, as well as dual phosphorescence at low temperature in the main PL bands. In addition, hot bands are detected in fluorescence as well as phosphorescence, and, in the narrow temperature range of 100-140 K, thermally activated delayed fluorescence (TADF) with lifetimes on the millisecond time-scale is observed. These findings are rationalized by quantum-chemical simulations, which predict a single minimum of the S1 potential of CNG 6, but two S1 minima for CNG 7 and CNG 8, with considerable geometric reorganization between them, in agreement with the experimental findings. Additionally, a higher-lying S2 minimum close to S1 is optimized for the three CNG, from where emission is also possible due to thermal activation and, hence, non-Kasha behavior. The presence of higher-lying dark triplet states close to the S1 minima provides mechanistic evidence for the TADF phenomena observed. Non-radiative decay of the T1 state appears to be thermally activated with activation energies of roughly 100meV and leads to disappearance of phosphorescence and TADF at T>140K.

A brown dwarf donor and an optically thin accretion disc with a complex stream impact region in the period-bouncer candidate BW Sculptoris

ABSTRACT We present an analysis of multi-epoch spectroscopic and photometric observations of the WZ Sge-type dwarf nova BW Scl, a period-bouncer candidate. We detected multiple irradiation-induced emission lines from the donor star allowing the radial velocity variations to be measured with high accuracy. Also, using the absorption lines Mg ii 4481 Å and Ca ii K originated in the photosphere of the accreting white dwarf (WD), we measured the radial velocity semi-amplitude of the WD and its gravitational redshift. We find that the WD has a mass of 0.85 ± 0.04 M⊙, while the donor is a low-mass object with a mass of 0.051 ± 0.006 M⊙, well below the hydrogen-burning limit. Using NIR data, we put an upper limit on the effective temperature of the donor to be ≲1600 K, corresponding to a brown dwarf of T spectral type. The optically thin accretion disc in BW Scl has a very low luminosity ≲4 × 1030 erg s−1 which corresponds to a very low-mass accretion rate of ≲7 × 10−13 M⊙ yr−1. The outer parts of the disc have a low density allowing the stream to flow down to the inner disc regions. The brightest part of the hotspot is located close to the circularization radius of the disc. The hotspot is optically thick and has a complex elongated structure. Based on the measured system parameters, we discuss the evolutionary status of the system.

Multiple sources emission inventory closely integrated with atmospheric environment management: A case study of Guangdong, China

The framework design and compilation methods of air emission inventory cannot connect multiple sets of environmental management statistics. The environmental statistics with different emission results increase the difficulty of policy making by the administrative departments. Based on the existing statistical system of environmental management in Guangdong Province, this study combines traditional compilation method of atmospheric pollution source emission inventory to optimize the classification system of air emission inventory and the integration based on multi-source data of environmental management. The study proposes a four-level classified pollution source system of national economy with Guangdong characteristics as well as a calculation method of multi-source data fusion supporting annually updating. Taking 2020 emission inventory formation as an example, results show that the emissions of SO2, NOx, VOCs, NH3, PM2.5, PM10 and CO in Guangdong Province are about 180, 985, 1,989, 390, 270, 750 and 2844 thousand tons respectively. In this case, SO2 and CO mainly come from industrial sources, NOx and PM2.5 mainly come from mobile sources, VOCs mainly come from natural sources, NH3 mainly comes from agricultural sources, and PM10 mainly comes from dust sources. The study raises a method of uncertainty grading evaluation and conducts a simulation verification of emission inventory accuracy. Results suggest that the emission inventory can reflect the emission status in 2020, but the quality of environmental management data of residential sources, dust sources and eastern Guangdong region still needs to be improved, and the pollution source control strategy of such sources or the region needs to be strengthened.

Retrospective Ultrasound Doppler Quantification Using a Single Acquisition in Healthy Adults

Using an experimental tool for retrospective ultrasound Doppler quantification-with high temporal resolution and large spatial coverage-simultaneous flow and tissue measurements were obtained. We compared and validated these experimental values against conventional measurements to determine if the experimental acquisition produced trustworthy tissue and flow velocities. We included 21 healthy volunteers. The only exclusion criterion was the presence of an irregular heartbeat. Two ultrasound examinations were performed for each participant, one using conventional and one using experimental acquisition. The experimental acquisition used multiple plane wave emissions combined with electrocardiography stitching to obtain continuous data with over 3500 frames per second. With two recordings covering a biplane apical view of the left ventricle, we retrospectively extracted selected flow and tissue velocities. Flow and tissue velocities were compared between the two acquisitions. Statistical testing showed a small but significant difference. We also exemplified the possibility of extracting spectral tissue Doppler from different sample volumes in the myocardium within the imaging sector, showing a decrease in the velocities from the base to the apex. This study demonstrates the feasibility of simultaneous, retrospective spectral and color Doppler of both tissue and flow from an experimental acquisition covering a full sector width. The measurements were significantly different between the two acquisitions but were still comparable, as the biases were small compared to clinical practice, and the two acquisitions were not done simultaneously. The experimental acquisition also enabled the study of deformation by simultaneous spectral velocity traces from all regions of the image sector.

Sequential Multistep Excited-State Structural Transformations in N,N'-Diphenyl-dihydrodibenzo[a,c]phenazine Fluorophores.

We demonstrate that a single polycyclic π-scaffold can undergo sequential multistep excited-state structural evolution along the bent, planar, and twisted conformers, which coexist to produce intrinsic multiple fluorescence emissions in room-temperature solution. By installing a methyl or trifluoromethyl group on the ortho-site of N,N'-diphenyl-dihydrodibenzo[a,c]phenazine (DPAC), the enhanced steric effects change the fluorescence emission of DPAC from a dominant red band to well-resolved triple bands. The ultra-broadband triple emissions of ortho-substituted DPACs range from ≈350 to ≈850 nm, which is unprecedented for small fluorophores with molecular weight of <500. Ultrafast spectroscopy and theoretical calculations clearly reveal that the above dramatic changes originate from the influence of steric hindrance on the shape of excited state potential energy surface (S1 PES). Compared to the steep S1 PES of parental DPAC, the introduction of ortho-substituent is shown to make the path of structural evolution in S1 wider and flatter, so the ortho-substituted derivatives exhibit slower structural transformations from bent to planar and then to twisted forms, yielding intrinsic triple emission. The results provide the proof of concept that the bent, planar, and twisted emissive states can coexist in the same S1 PES, which greatly expand the fundamental understanding of the excited-state structural relaxation.

Sequential Multistep Excited‐State Structural Transformations in N,N′‐Diphenyl‐dihydrodibenzo[a,c]phenazine Fluorophores

AbstractWe demonstrate that a single polycyclic π‐scaffold can undergo sequential multistep excited‐state structural evolution along the bent, planar, and twisted conformers, which coexist to produce intrinsic multiple fluorescence emissions in room‐temperature solution. By installing a methyl or trifluoromethyl group on the ortho‐site of N,N′‐diphenyl‐dihydrodibenzo[a,c]phenazine (DPAC), the enhanced steric effects change the fluorescence emission of DPAC from a dominant red band to well‐resolved triple bands. The ultra‐broadband triple emissions of ortho‐substituted DPACs range from ≈350 to ≈850 nm, which is unprecedented for small fluorophores with molecular weight of &lt;500. Ultrafast spectroscopy and theoretical calculations clearly reveal that the above dramatic changes originate from the influence of steric hindrance on the shape of excited state potential energy surface (S1 PES). Compared to the steep S1 PES of parental DPAC, the introduction of ortho‐substituent is shown to make the path of structural evolution in S1 wider and flatter, so the ortho‐substituted derivatives exhibit slower structural transformations from bent to planar and then to twisted forms, yielding intrinsic triple emission. The results provide the proof of concept that the bent, planar, and twisted emissive states can coexist in the same S1 PES, which greatly expand the fundamental understanding of the excited‐state structural relaxation.

Solar-wind electron precipitation on weakly magnetized bodies: The planet Mercury

Rocky objects in the Solar System (such as planets, asteroids, moons, and comets) undergo a complex interaction with the flow of magnetized, supersonic plasma emitted from the Sun called solar wind. We address the interaction of such a flow with the planet Mercury, considered here as the archetype of a weakly magnetized, airless, telluric body immersed in the solar wind. Due to the lack of dense atmosphere, a considerable fraction of solar-wind particles precipitate on Mercury. The interaction processes between precipitating electrons and other nonionized parts of the system remain poorly understood. Shading light on such processes is the goal of this work. Using a 3D fully kinetic self-consistent plasma model, we show for the first time that solar-wind electron precipitation drives (i) efficient ionization of multiple neutral exosphere species and (ii) emission of X-rays from the surface of the planet. We conclude that, compared to photoionization, electron-impact ionization should not be considered a secondary process for the H, He, O, and Mn exosphere. Moreover, we provide the first, independent evidence of X-ray aurora-like emission on Mercury using a numerical approach.

Observing the onset of the accretion wake in Vela X-1

High-mass X-ray binaries (HMXBs) offer a unique opportunity to investigate accretion onto compact objects and the wind structure in massive stars. A key source for such studies is the bright neutron star HMXB Vela X-1 whose convenient physical and orbital parameters facilitate analyses and in particular enable studies of the wind structure in HMXBs. Here, we analyse simultaneous XMM-Newton and NuSTAR observations at ϕorb ≈ 0.36–0.52 and perform time-resolved spectral analysis down to the pulse period of the neutron star based on our previous NuSTAR-only results. For the first time, we are able to trace the onset of the wakes in a broad 0.5–78 keV range with a high-time resolution of ~283 s and compare our results with theoretical predictions. We observe a clear rise in the absorption column density of the stellar wind NH,1 starting at orbital phase ~0.44, corresponding to the wake structure entering our line of sight towards the neutron star, together with local extrema throughout the observation, which are possibly associated with clumps or other structures in the wind. Periods of high absorption reveal the presence of multiple fluorescent emission lines of highly ionised species, mainly in the soft-X-ray band between 0.5 and 4 keV, indicating photoionisation of the wind.