Multipath Coupling Research Articles

Non-empirical calculations of NMR indirect carbon-carbon coupling constants. Part 6: propellanes.

A full set of carbon-carbon coupling constants have been calculated at the SOPPA level in the series of six most representative propellanes. Special attention was focused on spin-spin couplings involving both bridgehead carbons, and these data were rationalized in terms of the multipath coupling mechanism and hybridization effects. Many unknown couplings in the propellane frameworks were predicted with high reliability.

Non‐empirical calculations of NMR indirect carbon‐carbon coupling constants. Part 5: Bridged bicycloalkanes

AbstractAll possible J(C,C) of the bicarbocyclic frameworks together with J(C,H) and J(H,H) at bridgeheads in the series of six bridged bicycloalkanes, bicyclo[1.1.0]butane, bicyclo[2.1.0]pentane, bicyclo[3.1.0]hexane, bicyclo[2.2.0]hexane, bicyclo[3.2.0]heptane and bicyclo[3.3.0]octane, were calculated at the SOPPA level with correlation consistent Dunning sets cc‐pVTZ‐Cs augmented with inner core s‐functions and locally dense Sauer sets aug‐cc‐pVTZ‐J augmented with tight s‐functions and rationalized in terms of the multipath coupling mechanism and hybridization effects explaining many interesting structural trends. Copyright © 2003 John Wiley & Sons, Ltd.

Cross-coupling in coaxial cavity filters-a tutorial overview

This paper presents a tutorial overview of the use of coupling between nonadjacent resonators to produce transmission zeros at real frequencies in microwave filters. Multipath coupling diagrams are constructed and the relative phase shifts of multiple paths are observed to produce the known responses of the cascaded triplet and quadruplet sections. The same technique is also used to explore less common nested cross-coupling structures and to predict their behavior. A discussion of the effects of nonzero electrical length coupling elements is presented. Finally, a brief categorization of the various synthesis and implementation techniques available for these types of filters is given.

Additive multipath coupling between platinum and carbon in the framework of small ring systems

Additive multipath coupling between platinum and carbon in the framework of small ring systems