One of the critical factors affecting the development of 3D concrete printing (3DCP) is the challenging issue of in-situ reinforcement. Engineered Cementitious Composites (ECC) are printable self-reinforced materials, and their application in 3DCP technology can facilitate de-steelisation. However, traditional ECC materials pose certain concerns for sustainable environmental development. The integration of Limestone Calcined Clay Cement (LC3) suitable for 3DCP into ECC (LC3-ECC) presents an ideal solution to the aforementioned challenges. Moreover, conducting comprehensive research into its size effects is an essential step from experimentation to engineering application. A thorough exploration of the size effects of 3D printed LC3-ECC in compression, shear, and flexural fracture aspects is conducted to derive size effect laws. The relationship between the anisotropic mechanical properties and size effects has been established. The mold-cast LC3-ECC precisely follows the Bažant size effect law (SEL). The fiber orientation effect enhances bridging efficiency, leading to the fact that the mechanical properties of certain printed LC3-ECC are hardly affected by the size effect. The mechanical performance of some printed LC3-ECC depends on interlayer strength, making its primary reason for size effect not in the Fracture Process Zone (FPZ) energy release, hence closer to the Multifractal Scaling Law (MFSL). LC3-ECC exhibits weak anisotropy in mechanical properties, showing satisfactory stability. However, under flexural fracture behavior, the anisotropic size effect is higher, necessitating careful consideration in structural design.
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