Multicolor Pixel Research Articles

Colloidal quantum-dot light emitting diodes with bias-tunable color

Although the performance of quantum-dot-based light emitting diodes (QLEDs) has been significantly enhanced over the past years, conventional full-color QLED displays still rely on the side-by-side pattern techniques of red (R)/green (G)/blue (B) quantum dots (QDs). Such lateral integration of multi-color pixels imposes technological difficulty in the development of high-resolution displays due to limited pixel density and fill factors. Herein, we demonstrate the development of full-color QLEDs with bias-tunable emission spectra by engineering mixed R/G/B QDs as light emitting layers. In Commission Internationale de l’Eclairage (CIE) chromaticity coordinates, QLEDs with bias-tunable color exhibit wide color variation ranging from red (0.649, 0.330) to green (0.283, 0.305) to blue (0.255, 0.264) upon increasing voltages and can be tuned to emit white light (0.316, 0.325). More importantly, the fabricated multi-color QLEDs show high luminance approaching 10 3 cd m − 2 and superior external quantum efficiency of 13.3%. Benefitting from the wide spectral tunability and light emitting efficiency, we believe the proposed multi-color QLEDs have great application prospects for both displays and lighting.

All‐Solution Processed Multicolor Patterning Technique of Perovskite Nanocrystal for Color Pixel Array and Flexible Optoelectronic Devices

AbstractIn the present study, a new patterning method is introduced through the surface modification and stabilization of perovskite nanocrystals, which is compatible with conventional photolithography process based on all‐solution processes. Chemically designed gel‐type silica‐coated CsPbX3 (X = Br, I, etc.) perovskite nanocrystals combined with dip coating method are introduced to form stable and uniform films. Analyses of the physical and chemical states of nanocrystals and investigation of the kinetics in silica formation are conducted. In an optimized condition, physically uniform and chemically stable perovskite thin films are deposited on various substrates such as flexible, stretchable substrates, or even nonflat objects. By adopting these advantages and developing stable photolithographic chemicals, the high resolution patterns are successfully patterned with green and red emitting CsPbBr3 and CsPbBr3I3−x perovskites with the size down to 5 µm of radius and even a multicolor pixel array which can be used for the color filter, light converting or detecting applications. Flexible white light emitting diode is also fabricated with a large color gamut coverage. This work provides a fundamental understanding of perovskite nanocrystals, and also offers a technological breakthrough enabling various optoelectronic applications.

Ultrahigh resolution and color gamut with scattering-reducing transmissive pixels

While plasmonic designs have dominated recent trends in structural color, schemes using localized surface plasmon resonances and surface plasmon polaritons that simultaneously achieve high color vibrancy at ultrahigh resolution have been elusive because of tradeoffs between size and performance. Herein we demonstrate vibrant and size-invariant transmissive type multicolor pixels composed of hybrid TiOx-Ag core-shell nanowires based on reduced scattering at their electric dipolar Mie resonances. This principle permits the hybrid nanoresonator to achieve the widest color gamut (~74% sRGB area coverage), linear color mixing, and the highest reported single color dots-per-inch (58,000~141,000) in transmission mode. Exploiting such features, we further show that an assembly of distinct nanoresonators can constitute a multicolor pixel for use in multispectral imaging, with a size that is ~10-folds below the Nyquist limit using a typical high NA objective lens.

Patterning Multicolor Hybrid Perovskite Films via Top-Down Lithography.

Lead-halide perovskites have attracted great attention due to their excellent optoelectronic properties, with rapid progress being made in their performance as light-emitting diodes (LEDs), photodiodes, and solar cells. Demonstrating large scale, high-resolution patterning of perovskites is a key enabling step to unlock their full potential for a range of optoelectronic applications. However, the development of a successful top-down lithography fabrication procedure has so far been hampered by the incompatibility of perovskite films with the solvents used during lithographic processes. Here, we perform a study on the effect of different lithographic solvents on perovskite films and use this insight to develop photolithography and electron-beam lithography procedures for patterning perovskite films. This procedure uses standard resists at low temperatures and achieves micron-scale features with flat tops. Furthermore, we expand this platform to produce arrays of multicolor pixels for potential commercial perovskite LED display applications.

Spatial Mapping of Myeloid Cells and Macrophages by Multiplexed Tissue Staining.

An array of phenotypically diverse myeloid cells and macrophages (MC&M) resides in the tumor microenvironment, requiring multiplexed detection systems for visualization. Here we report an automated, multiplexed staining approach, named PLEXODY, that consists of five MC&M-related fluorescently-tagged antibodies (anti - CD68, - CD163, - CD206, - CD11b, and - CD11c), and three chromogenic antibodies, reactive with high- and low-molecular weight cytokeratins and CD3, highlighting tumor regions, benign glands and T cells. The staining prototype and image analysis methods which include a pixel/area-based quantification were developed using tissues from inflamed colon and tonsil and revealed a unique tissue-specific composition of 14 MC&M-associated pixel classes. As a proof-of-principle, PLEXODY was applied to three cases of pancreatic, prostate and renal cancers. Across digital images from these cancer types we observed 10 MC&M-associated pixel classes at frequencies greater than 3%. Cases revealed higher frequencies of single positive compared to multi-color pixels and a high abundance of CD68+/CD163+ and CD68+/CD163+/CD206+ pixels. Significantly more CD68+ and CD163+ vs. CD11b+ and CD11c+ pixels were in direct contact with tumor cells and T cells. While the greatest percentage (~70%) of CD68+ and CD163+ pixels was 0–20 microns away from tumor and T cell borders, CD11b+ and CD11c+ pixels were detected up to 240 microns away from tumor/T cell masks. Together, these data demonstrate significant differences in densities and spatial organization of MC&M-associated pixel classes, but surprising similarities between the three cancer types.

Large‐Area Lasing and Multicolor Perovskite Quantum Dot Patterns

AbstractHerein, a novel orthogonal lithography process is reported to pattern all‐inorganic perovskite CsPbX3 (X = Cl, Br, I) quantum dot (QD) arrays which cannot be patterned with traditional approaches. This approach involves a combination of fluorinated polymer and solvent to resolve issues of polar–nonpolar solvent constraints thus enabling the fabrication of complex patterns with high optical gain and multicolor emission. This approach is utilized to fabricate high‐resolution large‐area arrays of microdisk lasers and multicolor (binary and ternary emission) pixels. The optical cavity modes of CsPbBr3 QD microdisk lasers are readily controlled by tuning the disk size, where the mode spacing decreases while the number of modes increases with increasing disk diameter. Finally, the versatility of this approach for the integration of environmentally sensitive QDs with different emission signatures and composition on the same chip, while achieving high‐density, high‐resolution large‐area QD arrays with multicolor pixels, is demonstrated.

All Dielectric Transmissive Structural Multicolor Pixel Incorporating a Resonant Grating in Hydrogenated Amorphous Silicon

All dielectric transmissive type polarization-tuned structural multicolor pixels (MCPs) are proposed and demonstrated based on a one-dimensional hydrogenated amorphous silicon (a-Si:H) grating integrated with a silicon nitride waveguide. Both bandpass and bandstop transmission filtering characteristics in the visible regime, centered at the same wavelength, have been achieved by tailoring the structural parameters including the duty ratio of the grating and the thickness of the dielectric waveguide. For the three manufactured MCPs, the transmission peak exceeds 70% for the transverse electric (TE) polarization and 90% for the transverse magnetic (TM) polarization as observed at the resonance and off-resonance wavelength, respectively. The polarization-switched transmissions are attributed to the guided mode resonance initiated by the interaction of the a-Si:H grating and the dielectric waveguide. A broad color palette covering the entire visible band was successfully realized from a suite of MCPs with varying grating pitches. The proposed structural color pixels are expected to facilitate the construction of dynamic displays, image sensors, optical data storage, security tags, and so forth.

Strain-induced red-green-blue wavelength tuning in InGaN quantum wells

Monolithically integrating multi-color pixels from a standard InGaN quantum well active region was demonstrated with a wavelength tuning range of 178 nm. Nanopillar structures were fabricated to enable the wavelength tuning. Strain induced wavelength shift was investigated both experimentally and theoretically. A simple one-dimensional strain relaxation model was shown to accurately predict the wavelength shift as a function of the nanopillar diameter. The strain relaxation was found to depend on the indium composition in the quantum well. No noticeable increase of the defect density was observed after the strain relaxation process.

Tunable Infrared Emission From Printed Colloidal Quantum Dot/Polymer Composite Films on Flexible Substrates

A simple and robust device structure for a flexible, multicolor infrared (IR) display is described. The display operates by optical downconversion of AC-driven blue phosphor electroluminescence using different-sized, IR-emitting colloidal quantum dots. Deposition of the IR emissive layer via inkjet printing facilitates side-by-side multicolor pixel definition with low material losses.

Inkjet‐Printed Multicolor Arrays of Highly Luminescent Nanocrystal‐Based Nanocomposites

Inkjet technology is a compelling method for the flexible and cost-effective printing of functional inks. We show that nanocomposite solutions based on polystyrene and differently sized core/shell-type nanocrystals (NCs) formed by a CdSe core coated with a shell of ZnS (CdSe@ZnS) in a single solvent, chloroform, can be reliably dispensed into luminescent, multicolor pixel arrays. This study demonstrates the relevance of parameters like polymer concentration and nozzle diameter, highlighting how the optimal conditions to print NCs embedded in 5 wt% polystyrene nanocomposite are given by a 70-microm-diameter nozzle. The obtained structures show that the bright size-dependent emission of the NCs in the nanocomposite is retained in the printed pixels.