Monolithic Fiber Research Articles

Monolithic linear array fiber end cap for spectral beam combination

In this study, a fusion splicing system that facilitates the splicing of a monolithic linear array fiber end cap is constructed. The fusion splicing thermal field of the end cap irradiated by a CO2 laser is theoretically simulated using the finite element method. The experimental fusion splicing temperature agrees well with the simulation results. The splicing strength, misalignment, and high-power withstanding capacity of the fusion-spliced monolithic linear 3-fiber end cap are investigated. The use of the fabricated device in a dual-grating spectral beam combination (SBC) is also demonstrated with three-channel laser beams, achieving a combined beam with near-diffraction-limited beam quality M2=1.101. It shows that the development of the monolithic linear array fiber end cap is meaningful for achieving a compact high-brightness SBC system.

Shell Distribution of Vitamin K3 within Reinforced Electrospun Nanofibers for Improved Photo-Antibacterial Performance.

Personal protective equipment (PPE) has attracted more attention since the outbreak of the epidemic in 2019. Advanced nano techniques, such as electrospinning, can provide new routes for developing novel PPE. However, electrospun antibacterial PPE is not easily obtained. Fibers loaded with photosensitizers prepared using single-fluid electrospinning have a relatively low utilization rate due to the influence of embedding and their inadequate mechanical properties. For this study, monolithic nanofibers and core-shell nanofibers were prepared and compared. Monolithic F1 fibers comprising polyethylene oxide (PEO), poly(vinyl alcohol-co-ethylene) (PVA-co-PE), and the photo-antibacterial agent vitamin K3 (VK3) were created using a single-fluid blending process. Core-shell F2 nanofibers were prepared using coaxial electrospinning, in which the extensible material PEO was set as the core section, and a composite consisting of PEO, PVA-co-PE, and VK3 was set as the shell section. Both F1 and F2 fibers with the designed structural properties had an average diameter of approximately 1.0 μm, as determined using scanning electron microscopy and transmission electron microscopy. VK3 was amorphously dispersed within the polymeric matrices of F1 and F2 fibers in a compatible manner, as revealed using X-ray diffraction and Fourier transform infrared spectroscopy. Monolithic F1 fibers had a higher tensile strength of 2.917 ± 0.091 MPa, whereas the core-shell F2 fibers had a longer elongation with a break rate of 194.567 ± 0.091%. Photoreaction tests showed that, with their adjustment, core-shell F2 nanofibers could produce 0.222 μmol/L ·OH upon illumination. F2 fibers had slightly better antibacterial performance than F1 fibers, with inhibition zones of 1.361 ± 0.012 cm and 1.296 ± 0.022 cm for E. coli and S. aureus, respectively, but with less VK3. The intentional tailoring of the components and compositions of the core-shell nanostructures can improve the process-structure-performance relationship of electrospun nanofibers for potential sunlight-activated antibacterial PPE.

Influence of high-carbon wire drawing method on its production efficiency

The issue of improving the production efficiency and competitiveness of high-carbon steel wire, determined by a rational ratio of quality and costs of its production, is an urgent task. The main way to solve it is the development and implementation of an effective technical process, the main elements of which are the technological process and equipment for its realization. Since the middle of the last century, domestic steel wire production has been operating on imported equipment, which significantly hampers the use of modern technological processes. This unfavorable situation has been aggravated at present by the imposition of severe economic sanctions by “unfriendly states”. The way out of this situation in the current production is the improvement of existing and introduction of new methods of wire drawing. According to the original methodology the analysis of the existing at one of the domestic enterprises route of drawing of high-carbon wire rope wire with a diameter of 1.70 mm from wire rod of 5.50 mm with the use of standard single monolithic fibers, twin monolithic fibers, roller fibers, as well as modules including roller and monolithic fibers (combined drawing) was carried out. The obtained results have shown that when using standard fibers, the drawing route should be designed with the minimum possible multiplicity, which will provide on the existing equipment to improve the quality of wire and reduce the cost of its production. The greatest efficiency is provided by the application of combined drawing: twofold reduction of drawing multiplicity, energy saving up to 30%, improvement of wire quality by creating a favorable stress-strain state when deforming the wire first in roller and then in monolithic drawing. In addition, in comparison with the roller fibers, the equipment is simplified and the costs of its purchase and operation are reduced. Recommendations on the directions of increasing the efficiency of production in the conditions of existing production, purchase of new imported and designing of domestic drawing equipment are given

Uncharged Monolithic Carbon Fibers Are More Sensitive to Cross-Junction Compression than Charged.

Textile-based wearable robotics increasingly integrates sensing and energy materials to enhance functionality, particularly in physiological monitoring, demanding higher-performing and abundant robotic textiles. Among the alternatives, activated carbon cloth stands out due to its monolithic nature and high specific surface area, enabling uninterrupted electron transfer and energy storage capability in the electrical double layer, respectively. Yet, the potential of monolithic activated carbon cloth electrodes (MACCEs) in wearables still needs to be explored, particularly in sensing and energy storage. MACCE conductance increased by 29% when saturated with Na2SO4 aqueous electrolyte and charged from 0 to 0.375 V. MACCE was validated for measuring pressure up to 28 kPa at all assessed charge levels. Electrode sensitivity to compression decreased by 30% at the highest potential due to repulsive forces between like charges in electrical double layers at the MACCE surface, counteracting compression. MACCE's controllable sensitivity decrease can be beneficial for garments in avoiding irrelevant signals and focusing on essential health changes. A MACCE charge-dependent sensitivity provides a method for assessing local electrode charge. Our study highlights controlled charging and electrolyte interactions in MACCE for multifunctional roles, including energy transmission and pressure detection, in smart wearables.

1.7 W holmium-doped fluoroindate fiber laser at 3920 nm.

A monolithic fiber laser emitting 1.7 W at 3920 nm is experimentally demonstrated in a Ho3+:InF3 fiber. The cavity comprises a pair of highly reflective fiber Bragg gratings written in the active fiber with the femtosecond phase-mask scanning technique and is spliced to the pump diode with a robust silica-to-fluoride fiber splice. This work is an important step toward high-power all-fiber laser operating in the vicinity of 4 µm.

Failures of laminates under nonpenetrative impacts

Various failures of laminates under low-velocity impacts without penetration are simulated systematically with a limited number of inputs, all measurable following existing standards without any data calibration. No iteration is required to determine any of the failures investigated in this work. Any two adjacent lamina (primary) layers are inserted with a matrix (secondary) layer, whose stresses are modified through two modification coefficients (MCs). The MCs are determined through peak loads of double cantilever beam and end-notched flexure tests on unidirectional laminates, and their weak sensitivity to sample dimensions is shown. Delamination is reproduced by deleting failed secondary-layer elements. The homogenized stresses of fiber and matrix obtained by Bridging Model are converted into true values through the author’s true stress theory to estimate constituent-induced intralaminar failures, such as fiber breakage, matrix crack and interface debonding, against the monolithic fiber or matrix strengths measured independently. Primary- layer elements attaining a fatal failure (fiber breakage or matrix crack accompanied with a critical strain condition) are deleted before an impact termination corresponding to separation of the impactor from target. The predicted delamination areas and impact force, displacement and energy histories for the laminates of three lamination angles under different impact energies agree well with our measured counterparts, validating the efficiency of the simulation.

Demonstration of hundred-watt-level near-diffraction-limited monolithic fiber laser near 980 nm with step-index double-cladding Yb-doped fiber

In this paper, a hundred-watt-level near-diffraction-limited step-index Yb-doped fiber (YDF) laser near 980 nm is demonstrated firstly, to the best of our knowledge. By using the 11.7-W 979-nm single-mode seed light, the in-band amplified spontaneous emission (ASE) is well suppressed and the maximum output power of 101.5 W with the beam quality (M2 factor) of 1.285 was obtained. This work does not only propose an effective method for the suppression of in-band ASE, but also provides a cost-effective solution of hundred-Watt-level near-diffraction-limited fiber lasers near 980 nm.

Fast response multi-segment anti-resonant hollow-core fiber methane sensor at 1687 nm

Typically, hollow-core fiber (HCF)-based laser gas sensing systems use a single monolithic fiber as a gas cell. This results in a tradeoff between sensitivity which requires long optical fiber and sensor’s response time, that grows with the fiber length. Here we present a simple approach to solve this issue with new all-fiber modular gas cell design. The setup uses modified fiber mating sleeves to connect multiple HCFs in series, with optical loss of typically from 2 to 3 dB per connection. By injecting the sample gas at every second HCF-to-HCF connection, all HCF segments are filled simultaneously. We demonstrated the setups with two and four HCF segments, each with a length of 1.35 m. Laser absorption spectroscopy of methane near 1687 nm is used for setup characterization. Using the inlet pressure of 2 bar, the gas filling time is reduced over 13 times, from 77.9 s for a monolithic fiber, to only 5.9 s for the four-segment design (total HCF length of 5.4 m). With the pressure increased to 3 bar, the response time is further decreased to 3.6 s. Pressure buildup and drawdown times in the HCF were also examined.

Emission Wavelength Limits of a Continuous-Wave Thulium-Doped Fiber Laser Source Operating at 1.94 µm, 2.09 µm or 2.12 µm

We present a thulium-doped single-oscillator monolithic fiber laser emitting successively at three wavelengths, especially at unusual long wavelengths as 2.09 µm and even at 2.12 µm. The 793 nm core absorption of 8.42 dB/m allows for achieving a slope efficiency higher than 43% both at 1.94 µm and 2.09 µm. The operation of the laser at 1.94 µm, 2.09 µm, and 2.12 µm is compared by using different fiber Bragg gratings to push the limit of thulium ions emission above 2.05 µm. This is the first demonstration of emission exceeding wavelengths of 2.1 µm of an only thulium-doped fiber laser, to the best of our knowledge.

Hydrophilic and hydrophobic drug release from core (polyvinylpyrrolidone)-sheath (ethyl cellulose) pressure-spun fibers

A core-sheath structure is one of the methods developed to overcome the challenges often faced when using monolithic fibers for drug delivery. In this study, fibers based on polyvinylpyrrolidone (core) and ethyl cellulose (sheath) were successfully produced using a novel core-sheath pressure-spinning process. For comparison, these two polymers were also processed into as blend fibers. All samples were then investigated for their performances in releasing water-soluble ampicillin (AMP) and poorly water-soluble ibuprofen (IBU) model drugs. Scanning electron,digital and confocal microscopy confirmed that fibers with a core-sheath structure were successfully made. Fourier transform infrared spectroscopy showed the success of the pressure-spinning technique in encapsulating AMP/IBU in all fiber samples. Compared to blend fibers, the core-sheath fibers had better performance in encapsulating both water-soluble and poorly water-soluble drugs. Moreover, the core-sheath structure was able to reduce the initial burst release and provided a better sustained release profile than the blend fiber analog. In conclusion, the pressure-spinning method was capable of producing core-sheath and blend fibers that could be used for the loading of either hydrophilic or hydrophobic drugs for controlled drug delivery systems.

Theoretical study of filtered and amplified PRBS phase modulation for SBS suppression in a 2.5 kW, 10 GHz monolithic fiber amplifier

We report a theoretical and experimental study on stimulated Brillouin scattering (SBS) suppression in a monolithic fiber amplifier with filtered and amplified pseudo-random binary sequence (PRBS) phase modulation. Theoretically, we use a time-dependent three-wave coupled nonlinear system considering both active fiber and passive fiber to describe the acoustic phonon, laser, and Stokes characteristics in a fiber amplifier. The SBS threshold power after filtered PRBS phase modulation is numerically evaluated to obtain the optimal parameters, and the time-averaged distributions of the counter-pump power, laser power, and Stokes power at different positions along the fiber length of the fiber system are simulated. Also, we established a four-stage fiber amplifier system to verify our theory. The configuration of the fiber amplifier system includes a filtered and amplified PRBS phase-modulated single-frequency fiber laser, a three-stage pre-amplifier, and a counter-pumping main stage, subsequently. 2.5 kW output power with an FWHM linewidth of 9.63 GHz is accomplished by a domestic ytterbium-doped double-clad fiber with core/cladding diameters of 20.2/400 µm. The reflectivity of the main stage is 0.049‰ at the maximum output power, which indicates the proposed architecture is under the SBS threshold. The experiments verify the accuracy of the theoretical model, which provides a reliable reference for evaluating the SBS suppression capability of the high-power narrow-linewidth fiber amplifier phase modulated by the filtered and amplified PRBS signal.

Application of novel metal organic framework-deep eutectic solvent/molecularly imprinted polymer multiple monolithic fiber for solid phase microextraction of amphetamines and modafinil in unauthorized medicinal supplements with GC-MS

The goal of this research is the development of multiple monolithic fiber-solid phase microextraction (MMF-SPME) using a new integrated fiber for the determination of amphetamine derivatives and modafinil from unauthorized medicinal supplements. For this purpose, a monolithic fiber of metal organic framework MIL-Al (53)-deep eutectic solvent (DES)/molecularly imprinted polymers (MOF-DES/MIP) was synthesized. To find optimum microextraction conditions gas chromatography-mass spectrometer (GC-MS) was used and the influences of effective variables were investigated using one factor at a time method. After that, the significant variables were optimized using a Box-Behnken design (BBD) combined with a desirability function (DF). Under optimized conditions (desorption solvent=1500 µL of 1-octanol, pH=3.5, extraction time=35 min, [NaCl]=0% w/v and stirring rate=600 rpm), calibration graphs of analytes were linear in a concentration range of 0.1–400 μg L−1 with correlation coefficients > 0.9966. Limits of detection and quantification were in the ranges of 0.023–0.033 μg L−1 and 0.088–0.113 μg L−1, respectively. This procedure was successfully employed in determining target analytes in spiked and unspiked unauthorized medicinal supplement samples with recoveries ranging from 95.14 to 104.63%.

Topological Conversion of Nickel Foams to Monolithic Single‐Atom Catalysts

AbstractSingle‐atom catalysts have emerged as a promising class of catalysts due to their tailored coordination environments on the support, which can improve a variety of catalytic reactions, making them a highly desirable research subject in materials science with significant potential for industrial applications. However, traditional synthesis methods mainly obtain low‐yield powder catalysts without macroscopic mechanical strength, and also require tedious procedures, limiting their practicability. Here, monolithic carbon fibers are prepared with single atomic Ni sites directly from bulk metal. The synchronous support growth and metal diffusion realizes the effective atomization of nickel foam, and the innovative strategy of topological growth within a confined space results in robust and tough monolith. The application of this single‐atom‐monolith is demonstrated as a free‐standing electrode for highly efficient electrochemical CO2 reduction. The proposed synthesis strategy allows feasible preparation of functional single‐atom catalysts for potential industrial applications with advantages of using low‐cost raw materials, enabling large‐scale production, and providing processable, moldable monolithic materials.

Fiber, monolithic fiber and twisted fiber structures: efficient microwave absorption via surface-modified carbon nanotube buckypaper/silicon carbide-based self-sealing layered composites

A variety of self-sealing layered fiber substrates are constructed, and the substrates are converted into absorbers by cladding modification. Microwaves are scattered in all directions at multiple angles in the self-sealing layered fiber structures.

Experimental and numerical study of a monolithic single-oscillator thulium-doped fiber laser in continuous-wave regime

Experimental and numerical study of a monolithic single-oscillator thulium-doped fiber laser in continuous-wave regime

4.6 kW linearly polarized and narrow-linewidth monolithic fiber amplifier based on a fiber oscillator laser seed

In this work, a record output power of 4.6 kW linearly polarized and narrow-linewidth fiber amplifier based on an optimized fiber oscillator laser (FOL) seed was realized by employing a homemade polarization-maintaining Yb-doped fiber (PMYDF), corresponding to a slope efficiency of 79.5% and a 3 dB linewidth of 0.3452 nm. Through an effective strategy relying on decreasing the transmission fiber length from 200 m to 120 m and adding a chirped and tilted fiber Bragg grating (CTFBG), the stimulated Raman scattering (SRS) effects were well-suppressed. By applying the forward combiner with the interconnection between the pump arms into the MOPA system, the MI threshold is increased by more than 560 W and the slope efficiency of the upgraded MOPA system is boosted by 5%. During the experimental process of power amplification, the polarization extinction ratio (PER) remains higher than 15 dB, and a near-diffraction-limited output beam at the laser power of 2980 W was measured with the M2x = 1.314 and M2y = 1.311.

2 × 4.5 kW bidirectional output near-single-mode quasi-continuous wave monolithic fiber laser

Quasi-continuous wave (QCW) laser has a very broad application in the industrial field, especially in additive manufacturing, surface treatment, laser cutting, laser cleaning, and laser drilling. Compared with the unidirectional fiber laser, the bidirectional output can be achieved two ports high power output with only one resonator, which can greatly reduce the industrial cost. However, there are few researches on QCW fiber lasers with bidirectional output. Here, we optimized and demonstrated a bidirectional output QCW laser with output power of 2 × 4.5 kW based on a double-clad ytterbium-doped fiber with a core/cladding diameter of 25/400 μm. The peak power at both ends reached 4515 W and 4694 W, respectively. The Raman suppression ratio at both ends of A and B is about 12 dB, and the beam quality factor M2 is about 1.37 and 1.42, respectively. The corresponding optical-to-optical efficiency is 79%. To the best of our knowledge, this is the highest peak power of QCW laser with near-single-mode beam quality in a bidirectional structure laser.

Monolithic tapered Yb-doped fiber chirped pulse amplifier delivering 126 μJ and 207 MW femtosecond laser with near diffraction-limited beam quality

In this work, a high-energy and high peak power chirped pulse amplification system with near diffraction-limited beam quality based on tapered confined-doped fiber (TCF) is experimentally demonstrated. The TCF has a core numerical aperture of 0.07 with core/cladding diameter of 35/250 µm at the thin end and 56/400 μm at the thick end. With a backward-pumping configuration, a maximum single pulse energy of 177.9 μJ at a repetition rate of 504 kHz is realized, corresponding to an average power of 89.7 W. Through partially compensating for the accumulated nonlinear phase during the amplification process via adjusting the high order dispersion of the stretching chirped fiber Bragg grating, the duration of the amplified pulse is compressed to 401 fs with a pulse energy of 126.3 μJ and a peak power of 207 MW, which to the best of our knowledge represents the highest peak power ever reported from a monolithic ultrafast fiber laser. At the highest energy, the polarization extinction ratio and the M2 factor were respectively measured to be ~ 19 dB and 1.20. In addition, the corresponding intensity noise properties as well as the short- and long-term stability were also examined, verifying a stable operation of the system. It is believed that the demonstrated laser source could find important applications in, for example, advanced manufacturing and photomedicine.Graphical

Development of FEMAXI-ATF for analyzing PCMI behavior of SiC cladded fuel under power ramp conditions

FEMAXI-ATF is being developed for fuel performance modeling of SiC cladded UO2 fuel with focuses on modeling pellet-cladding mechanical interactions (PCMI). The code considers probability distributions of mechanical strengths of monolithic SiC (mSiC) and SiC fiber reinforced SiC matrix composite (SiC/SiC), while it models pseudo-ductility of SiC/SiC and propagation of cladding failures across the wall thickness direction in deterministic manner without explicitly modeling cracks based on finite element method in one-dimensional geometry. Some hypothetical BWR power ramp conditions were used to test sensitivities of different model parameters on the analyzed PCMI behavior. The results showed that propagation of the cladding failure could be modeled by appropriately reducing modulus of elasticities of the failed wall element, so that the mechanical load of the failed element could be re-distributed to other intact elements. The probability threshold for determination of the wall element failure did not have large influence on the predicted power at failure when the threshold was varied between 25 % and 75 %. The current study is still limited with respect to mechanistic modeling of SiC failure as it only models the propagation of the cladding wall element failure across the homogeneous continuum wall without considering generations and propagations of cracks.

A 5 kW Nearly-Single-Mode Monolithic Fiber Laser Emitting at ~1050 nm Employing Asymmetric Bi-Tapered Ytterbium-Doped Fiber

Limited by stimulated Raman scattering (SRS), amplified spontaneous emission (ASE) and transverse mode instability (TMI), it is challenging to achieve high-power laser output in ytterbium-doped fiber (YDF) lasers with operating wavelengths less than 1060 nm. In high-power fiber lasers, bi-tapered YDF can provide a balance between the suppression of SRS and TMI. In this work, we designed and fabricated a new double-cladding asymmetric bi-tapered YDF to suppress ASE and SRS in the 1050 nm monolithic fiber laser. The asymmetric bi-tapered YDF has an input end with a core/cladding diameter of ~20/400 μm, a middle section with a core/cladding diameter of ~30/600 μm and an output end with a core/cladding diameter of ~25/500 μm. The working temperature of the non-wavelength-stabilized 976 nm laser diodes was optimized to improve the TMI threshold. An output power of over 5 kW with an efficiency of 83.1% and a beam quality factor M2 of about 1.47 were achieved. To the best of our knowledge, this represents the highest power nearly-single mode in 1050 nm fiber lasers. This work demonstrates the potential of asymmetric bi-tapered YDF for achieving a high-power laser with high beam quality in 1050 nm fiber lasers.