A series of Bronsted–Lewis acids bifunctionalized heteropolyacid based ionic liquids hybrid solid acid catalysts (BLA-HPA-ILs) were synthesized by combining the Bronsted acidic ionic liquid [Bis–Bs–BDMAEE]HPW12O40 with metallic oxide in different composition ratios and applied in the esterification of cyclohexene to cyclohexyl acetate. Among the synthesized catalysts, the 1/2Cu[Bis–Bs–BDMAEE]HPW12O40 catalyst with Bronsted and Lewis acidities shown the most excellent catalytic performance for the esterification of cyclohexene with acetic acid. The BLA-HPA-ILs catalysts were characterized by elemental analysis, FT-IR, Py-IR, TG, 1H NMR, SEM and EDX. The effects of reaction temperature, catalyst dosage, and initial reactant molar ratio has been investigated in detail. A pseudohomogeneous (PH) kinetic model was used to correlate the kinetic data in the temperature range of 333.15–363.15 K, and the kinetic parameters were estimated, indicating the results calculated by the kinetic model are well coincidence with the experimental results. Moreover, as a heterogeneous reaction catalyst, 1/2Cu[Bis–Bs–BDMAEE]HPW12O40 could be easily recovered by a simple treatment and reused six times without any obvious decrease in catalytic activity, displaying good reusability.