The greenhouse effect of fossil fuel combustion and factories is becoming more serious. And it causes various negative effects on the Earth. It would cause sea level rise, melting glaciers, and extreme climate changes. Many efforts have been put into researching stable materials to absorb greenhouse gases, especially carbon dioxide. The article introduces the design strategies of MOF (MOF) materials for efficient carbon dioxide capture and separation. The major obstacle is the design of a facile synthesis strategy for the mass production of efficient MOF materials. And the stability and the adsorbability of MOF materials is an important points. This article illustrates the reasons for the emergence of MOF materials, their development and modification, and their performance. Modification and functionalization of MOF materials will be a reliable way to improve MOF materials in the future. This paper hopes to facilitate the application of MOF-based materials in large-scale gas adsorption and stimulate the elimination of greenhouse gases.