Charge Modulation Research Articles

Condensed state physics in biology: Liquid crystal - semiconductor system

The possibility of application of condensed state physics methods for the study of biological objects is considered. The object of use is a cell with a liquid crystal as a model of a biological system - a living cell. The system of liquid crystal - semiconductor was experimentally investigated by methods of modulation spectroscopy. By determining the value of electric reflection, it is possible to judge about the state of surface polarization of liquid crystal. Exposure to an electric field changes the energy of the semiconductor’s zone structure, which leads to changes in the optical properties of both crystals. To investigate the optical modulation changes in our case, we used the method with the use of electrolyte KOH, which allowed us to measure the modulation of the spatial charge. The study of thin layers (up to 120 μm) of various nematic liquid crystals has shown that at values of electric fields comparable to the Fredericks transition threshold, the orientation angle of liquid crystal molecules changes due to the interaction of surface polarization with the external field, and an odd electro-optic effect is observed. If the value of the electric field is much larger than the threshold of the Fredericks transition, the electric moment, which depends nonlinearly on the field, predominates and leads to an even electro-optic effect. The results of the study are proposed to be used for the development of new drugs and materials with specified parameters for medicine.

Customizing precise, tunable, and universal cascade charge transfer chains towards versatile photoredox catalysis.

The core factors dictating the photocatalysis efficiency are predominantly centered on controllable modulation of anisotropic spatial charge transfer/separation and regulating vectorial charge transport pathways. Nonetheless, the sluggish charge transport kinetics and incapacity of precisely tuning interfacial charge flow at the nanoscale level are still the primary dilemma. Herein, we conceptually demonstrate the elaborate design of a cascade charge transport chain over transition metal chalcogenide-insulating polymer-cocatalyst (TIC) photosystems via a progressive self-assembly strategy. The intermediate ultrathin non-conjugated insulating polymer layer, i.e., poly(diallyl-dimethylammonium chloride) (PDDA), functions as the interfacial electron relay medium, and simultaneously, outermost co-catalysts serve as the terminal "electron reservoirs", synergistically contributing to the charge transport cascade pathway and substantially boosting the interfacial charge separation. We found that the insulating polymer mediated unidirectional charge transfer cascade is universal for a large variety of metal or non-metal reducing co-catalysts (Au, Ag, Pt, Ni, Co, Cu, NiSe2, CoSe2, and CuSe). More intriguingly, such peculiar charge flow characteristics endow the self-assembled TIC photosystems with versatile visible-light-driven photoredox catalysis towards photocatalytic hydrogen generation, anaerobic selective organic transformation, and CO2-to-fuel conversion. Our work would provide new inspiration for smartly mediating spatial vectorial charge transport towards emerging solar energy conversion.

Hydrophilicity and surface charge modulation of Ti3C2T x MXene based membranes for water desalination.

Lamellar membranes obtained by stacking 2D layers possess ample transport pathways due to their intricate network of interlayer gaps. This makes them suitable for molecular separation applications. However, controlling the surface chemistry of the nanochannels within the membrane to tune the desired transport properties of water and ions is challenging. Ti3C2T x has been considered for water desalination because of its hydrophilic surface and negative surface charge. Most of the studies of Ti3C2T x membranes have presented promising salt rejection values in forward osmosis mode, which is less practical for water purification. Here, we investigate two types of reverse osmosis MXene-based lamellar membranes consisting of Ti3C2T x nanosheets hybridized with (i) WS2 nanosheets and (ii) polyvinyl phosphonic acid (PVPA). When hydrophilic and flexible Ti3C2T x nanosheets are interleaved with softer and more hydrophobic WS2 nanosheets in 2 : 1 mass ratio, nano capillaries with Janus chemistry are created with comparable rejection to bare Ti3C2T x membrane and threefold higher permeance values. Further, we find that decorating Ti3C2T x nanosheets with anionic polymers improves salt rejection. Our Ti3C2T x /PVPA composite membranes reject ∼97% of divalent ions and ∼80% of monovalent ions with ∼0.2 Lm-2 h-1 bar-1 of water permeance when tested with brackish water, and exhibit significantly improved chlorine resistance and cost benefits over the commercial Toray membranes.

Polaron absorption in aligned conjugated polymer films: breakdown of adiabatic treatments and going beyond the conventional mid-gap state model.

This study provides the first experimental polarized intermolecular and intramolecular optical absorption components of field-induced polarons in regioregular poly(3-hexylthiophene-2,5-diyl), rr-P3HT, a polymer semiconductor. Highly aligned rr-P3HT thin films were prepared by a high temperature shear-alignment process that orients polymer backbones along the shearing direction. rr-P3HT in-plane molecular orientation was measured by electron diffraction, and out-of-plane orientation was measured through series of synchrotron X-ray scattering techniques. Then, with molecular orientation quantified, polarized charge modulation spectroscopy was used to probe mid-IR polaron absorption in the ℏω = 0.075 - 0.75 eV range and unambiguously assign intermolecular and intramolecular optical absorption components of hole polarons in rr-P3HT. This data represents the first experimental quantification of these polarized components and allowed long-standing theoretical predictions to be compared to experimental results. The experimental data is discrepant with predictions of polaron absorption based on an adiabatic framework that works under the Born-Oppenheimer approximation, but the data is entirely consistent with a more recent nonadiabatic treatment of absorption based on a modified Holstein Hamiltonian. This nonadiabatic treatment was used to show that both intermolecular and intramolecular polaron coherence break down at length scales significantly smaller than estimated structural coherence in either direction. This strongly suggests that polaron delocalization is fundamentally limited by energetic disorder in rr-P3HT.

A real-time early warning method for electric vehicle fast charging safety based on multiple time scales

Abstract This paper puts forward the support technology of fast charging supply and demand matching in charging stations and analyzes the common large-capacity electrochemical energy storage technical parameters in charging stations. For the safety of electric vehicle charging, the thermal reaction and thermal runaway processes of power batteries are introduced. Design the electric vehicle charging state monitoring and safety warning methods, and select the multi-timescale ARIMA algorithm to build the electric vehicle charging safety warning model. The sliding window method is used to process the residual mean and residual standard deviation of electric vehicle charging data to improve prediction data and decrease the chance of misjudging pre- and alarms. Combined with the evaluation standard of the safety early warning model, set reasonable pre- and alarm thresholds using the residual analysis method. The safety warning model designed in this paper is verified by different charging fault warnings. Different charging fault warning examples show that the ARIMA-based charging safety early warning model proposed in this paper can be good for the charging facility’s output voltage, output current, and charging module temperature faults for early warning to ensure that the warning is carried out before the alarm of the actual fault information, to protect the charging safety of electric vehicles.

Surface charge modulation boosts electrocatalytic water splitting over iridium catalysts on a polyimide support.

Developing high-performance iridium (Ir)-based catalysts with minimal precious Ir metal is a significant but challenging step towards the acidic oxygen evolution reaction (OER). Here, we report a high-performance OER catalyst with Ir nanoparticles on a polyimide support, where the polyimide support can effectively modulate the electronic structures of the Ir active sites for decreased thermodynamic barriers, but also enrich the local proton concentration near the Ir active sites, enhancing the OER rates.

Direct observation of charge modulation in nanoprecipitates by 4D STEM

Direct observation of charge modulation in nanoprecipitates by 4D STEM

Atomically precise metal nanoclusters combine with MXene towards solar CO2 conversion.

Atomically precise metal nanoclusters (NCs) have been deemed a new generation of photosensitizers for light harvesting on account of their quantum confinement effect, peculiar atom-stacking mode, and enriched catalytic active sites. Nonetheless, to date, precise charge modulation over metal NCs has still been challenging considering their ultra-short carrier lifetime and poor stability. In this work, we conceptually demonstrate the integration of metal NCs with MXene in transition metal chalcogenide (TMC) photosystems via a progressive, exquisite, and elegant interface design to trigger tunable, precise and high-efficiency charge motion over metal NCs, stimulating a directional carrier transport pathway. In this customized ternary heterostructured photosystem, metal NCs function as light-harvesting antennas, MXene serves as a terminal electron reservoir, and the TMC substrate provides suitable energy level alignment for retracting photocarriers of metal NCs, giving rise to a spatial cascade charge transport route and markedly boosting charge separation efficiency. The interface configuration and energy level alignment engineering synergistically contribute to the considerably enhanced visible-light-driven photocatalytic CO2-to-CO reduction performance of the metal NCs/TMCs/MXene heterostructure. The intermediate active species during the photocatalytic CO2 reduction are unambiguously determined, based on which the photocatalytic mechanism is elucidated. Our work will provide an inspiring idea to bridge the gap between atomically precise metal NCs and MXene in terms of controllable charge migration for solar-to-fuel conversion.

Modulating selective ionic enrichment and depletion zones in straight nanochannels via the interplay of surface charge modulation and electric field mediated fluid-thickening.

We report the possibilities of achieving highly controlled segregation of ion-enriched and ion-depleted regions in straight nanochannels. This is achieved via harnessing the interplay of an axial gradient of the induced transverse electric field on account of electrical double layer phenomenon and the localized thickening of the fluid because of intensified electric fields due to the large spatial gradients of the electrical potential in extreme confinements. By considering alternate surface patches of different charge densities over pre-designed axial spans, we illustrate how these effects can be exploited to realize selectively ion-enriched and ion-depleted zones. Physically, this is attributed to setting up of an axial concentration gradient that delves on the ionic advection due to the combined effect of an externally applied electric field and induced back-pressure gradient along the channel axis and electro-migration due to the combinatorial influences of the applied and the induced electrostatic fields. With an explicit handle on the pertinent parameters, our results offer insights on the possible means of imposing delicate controls on the solute-enrichment and depletion phenomena, a paradigm that remained unexplored thus far.

Electronic and spin states at edges of finite p-orbital helical atomic chain.

In connection to the chiral-induced spin selectivity effect, we theoretically analyze the electronic and spin states of edges of a finite p-orbital helical atomic chain with the intra-atomic spin-orbit interaction. This model can host the spin-filtering state in which two up-spins propagate in one direction and two down-spins propagate in the opposite direction without breaking the time-reversal symmetry (TRS). The enhancement of charge modulations concentrated at the edges due to the evanescent states is induced, although the spin density is absent because of the TRS. A Zeeman field at an edge of the atomic chain, which breaks the TRS, yields a finite spin polarization, whose direction depends on the chirality of the molecule. The chirality change induces a reasonable amount of the energy difference, which may provide an insight into the enantioselective adsorption of chiral molecules on the ferromagnetic surface.

Electrochemical Framework for Dynamic Tracking of Soil Organic Matter (SOM)

Soil Health parameters serve as excellent surrogate measures towards assessing environmental quality and understanding effects of climate change mitigation via carbon sequestration. Soil health monitoring in the near past has been highly qualitative and speculative with more recent advancements still trying to fill the void of determining a holistic soil profile through phantom based measurements. In fields and crop-circles, testing methods to perform in-situ profiling however from one lab is likely to vary with another and hence results are not universally compatible. Additionally, these normalized techniques ideally involve empirical approaches, extensive sample preparation which adds on to a temporal factor along with equipment for extraction and subsequently-analysis. Even with the upcoming research breakthroughs in non-destructive approaches like spectroscopy and tomography-based models, there is a barrier in-terms of equipment complexity and availability as well as high costs and high logistical overhead.There are a wide number of redox systems present in soil that exist in reduced state under ideal conditions (submerged). While Carbon monitoring would be highly beneficial in the field, an overall sense of the organic matter nutrients present in soil denoted as soil organic matter understanding would offer a wholistic manner of surveying soil and environmental health. In this work, faradaic and non-faradaic measurements are utilized to determine threshold changes in soil electrochemical activity due to presence of various electroactive substances present in the matrix. First, a galvanostatic approach using the chronopotentiometry modality was applied to a soil slurry system- ‘test’ sample to which different levels (w/v %) of the following amendments were added to see how the effective charge modulation can be visualized. Utilizing this experimental framework as preliminary information- A hypothesized mechanism of interaction between the RTIL (Room Temperature Ionic-Liquid) modified electrode and the OM functional moieties based on hydrogen bonding and pi-pi interactions captured using charge-based (chronocoulometry) and interfacial mapping-based (electrochemical impedance spectroscopy) method is utilized to design and test a first-of-a-kind electrochemical soil organic matter (SOM) sensor. Figure 1. Chronopotentiometric characterization of soil organic matter using an RTIL modified electrode. Figure 1

PyBEST: Improved functionality and enhanced performance

PyBEST: Improved functionality and enhanced performance

MnF2 Surface Modulated Hollow Carbon Nanorods on Porous Carbon Nanofibers as Efficient Bi-Functional Oxygen Catalysis for Rechargeable Zinc-Air Batteries.

Developing highly efficient bi-functional noble-metal-free oxygen electrocatalysts with low-cost and scalable synthesis approach is challenging for zinc-air batteries (ZABs). Due to the flexible valence state of manganese, MnF2 is expected to provide efficient OER. However, its insulating properties may inhibit its OER process to a certain degree. Herein, during the process of converting the manganese source in the precursor of porous carbon nanofibers (PCNFs) to manganese fluoride, the manganese source is changed to manganese acetate, which allows PCNFs to grow a large number of hollow carbon nanorods (HCNRs). Meanwhile, manganese fluoride will transform from the aggregation state into uniformly dispersed MnF2 nanodots, thereby achieving highly efficient OER catalytic activity. Furthermore, the intrinsic ORR catalytic activity of the HCNRs/MnF2@PCNFs can be enhanced due to the charge modulation effect of MnF2 nanodots inside HCNR. In addition, the HCNRs stretched toward the liquid electrolyte can increase the capture capacity of dissolved oxygen and protect the inner MnF2, thereby enhancing the stability of HCNRs/MnF2@PCNFs for the oxygen electrocatalytic process. MnF2 surface-modulated HCNRs can strongly enhance ORR activity, and the uniformly dispersed MnF2 can also provide higher OER activity. Thus, the prepared HCNRs/MnF2@PCNFs obtain efficient bifunctional oxygen catalytic ability and high-performance rechargeable ZABs.

Modular Gating of Ion Transport by Postsynthetic Charge Transfer Complexation in a Metal-Organic Framework.

Nature's design of biological ion channels that demonstrates efficient gating and selectivity brings to light a very promising model to mimic and design for achieving selective and tunable ion transport. Functionalized nanopores that permit modulation of the pore wall charges are a compelling approach to gain control over the ion transport mechanism through the pores. This makes way for employing a noncovalent supramolecular approach for attaining charge reversal of the MOF pore walls using donor-acceptor pairs that can demonstrate strong charge transfer interactions. Herein, robust Zr4+-based mesoporous MOF-808 was postsynthetically modified into an anion-selective nanochannel (MOF-808-MV) by modification with dicationic viologen-based motifs. Charge modulation and even reversal of the MOF-808-MV pore walls were then explored taking advantage of strong charge transfer interactions between the grafted dicationic viologen acceptor moieties and anionic, π-electron-rich donor guest molecules such as pyranine (PYR) and tetrathiafulvalene tetrabenzoic acid (TTF-TA). Tunability of the MOF pore charge from positive to neutral to negative was achieved via simple methodologies such as diffusion control in case of guest molecule like PYR and by pH modulation for pH-responsive guest like TTF-TA. This results in a concomitant modulation in the selectivity of the nanochannel, rendering it from anion-selective to ambipolar to cation-selective. Furthermore, as a real-time application of this ion channel, Na+ ion conductivity (σ = 3.5 × 10-5 S cm-1) was studied at ambient temperature.

Pyro-Phototronic Effect Enhanced MXene/ZnO Heterojunction Nanogenerator for Light Energy Harvesting

The coupling of pyroelectricity, semiconductor, and optical excitation yields the pyro-phototronic effect, which has been extensively utilized in photodetectors. It can also enhance the performance of light energy harvesting nanogenerators. In this work, a pyro-phototronic effect-enhanced MXene/ZnO heterojunction nanogenerator has been successfully demonstrated, which can harvest broadband light energy (from deep UV to near-infrared) and still operate at 200 °C. The morphology of the ZnO layer and the MXene layer’s thickness have been further optimized for better light energy harvesting performance. For the optimized heterojunction nanogenerator, the responsivity can be improved from ~0.2 mA/W to ~3.5 mA/W by pyro-phototronic effect, under 0.0974 mW/cm2 365 nm UV illumination. Moreover, the coupling of pyro-phototronic and piezo-phototronic effects in MXene/ZnO heterojunction nanogenerators has been investigated. The results indicate that only a small tensile strain could improve the nanogenerator’s performance. The working mechanisms have been carefully analyzed, and the modulation of piezoelectric charges on the Schottky barrier height is found to be the key factor. These results demonstrate the enormous potential of the pyro-phototronic effect in light energy harvesting nanogenerators and illustrate the coupling of pyro-phototronic and piezo-phototronic effects for further performance improvement.

Condensation of preformed charge density waves in kagome metals

Charge density wave (CDW) is a spontaneous spatial modulation of charges in solids whose general microscopic descriptions are yet to be completed. Kagome metals of AV3Sb5 (A = K, Rb, Cs) provide a chance to realize CDW intertwined with dimensional effects as well as their special lattice. Here, based on a state-of-the-art molecular dynamics simulation, we propose that their phase transition to CDW is a condensation process of incoherently preformed charge orders. Owing to unavoidable degeneracy in stacking charge orders, phases of preformed orders on each layer are shown to fluctuate between a limited number of states with quite slower frequencies than typical phonon vibrations until reaching their freezing temperature. As the size of interfacial alkali atom increases, the fluctuations are shown to counterbalance the condensation of orderings, resulting in a maximized transition temperature for RbV3Sb5. Our results resolve controversial observations on their CDWs, highlighting a crucial role of their interlayer interactions.

Decoupling rheology from particle concentration by charge modulation: Aqueous graphene-clay dispersions

HypothesisAqueous graphene dispersions are usually obtainable by treating the surface of graphene chemically or physically. In these dispersions, the rheological properties (e.g., viscosity) are governed by a direct coupling to the graphene concentration, which limits their applicability. An alternative approach for dispersing graphene is trapping them in a viscoelastic-network formed by a co-dispersed charged fibrous-clay, Sepiolite. Contrary to surface treatment, the rheological properties of these dispersions are set by the clay particles. The rheology of charged-colloidal dispersions is governed by various parameters, including interparticle interactions. Hence, the rheology of the dispersion could be modulated by changing the clay surface charge without compromising the dispersed graphene concentration. ExperimentalThe surface charge of Sepiolite was modulated either by charge-screening (by NaCl added to the solution) or by surface-charging (by attachment of highly charged ions, e.g., HexaMetaPhosphate, HMP−) and the effect on rheology and graphene concentration was assessed. In particular, loading the dispersion with HMP− yielded low viscosity, storage, and loss moduli (two orders of magnitude lower than the corresponding HMP−-free dispersion) while the graphene concentration was maintained. We demonstrate that by this charge-modulation approach, reaching the rheological requirements of different applications without compromising on graphene concentration is plausible.

PI Controller Based Power Factor Correction Circuit for Plug-in Hybrid Electric Vehicle Using Solar Charging Module

The electrical vehicle requires power without losses or harmonics. The proposed method utilizes PV (photovoltaic)solar module as an input source, a converter of boost DC-DC buck incorporate for power peaks maximum in getting with MPPT approach, and the SPWM (Sinusoidal Pulse Width Modulation) inverter improves the performance by option shift in phase shift varying on the circuit. This aims to reduce the total harmonics distortion, losses switching, and improve the power factor. By varying the module of PV irradiances and temperature, the power is generated and it is peak power for utilizing maximum with MPPT (Maximum Power Point Tracking) that has been tracked. The Buck-Boost PFC (power factor correction) converter is used; when it performs the active state of PV, the Buck mode is utilized; if no power supplies the circuit, the boost mode will act to supply the SPWM inverter mode. Here the PI controller is applied for reducing the harmonics and stores on charging unit of EVs. The result simulated obtains the circuit electricity utilized by source result, which improves the performance by the effective charging station, which is applicable for EVs charging module. Overall, the method proposed is done with MATLAB/Simulink tool with the adaptation of 2018a.

Graphene Oxide-Mediated Regulation of Volume Exclusion and Wettability in Biomimetic Phosphorylation-Responsive Ionic Gates.

Replicating phosphorylation-responsive ionic gates via artificial fluidic systems is essential for biomolecular detection and cellular communication research. However, current approaches to governing the gates primarily rely on volume exclusion or surface charge modulation. To overcome this limitation and enhance ion transport controllability, we introduce graphene oxide (GO) into nanochannel systems, simultaneously regulating the volume exclusion and wettability. Moreover, inspired by (cAMP)-dependent protein kinase A (PKA)-regulated L-type Ca2+ channels, we employ peptides for phosphorylation which preserves them as nanoadhesives to coat nanochannels with GO. The coating boosts steric hindrance and diminishes wettability, creating a substantial ion conduction barrier, which represents a significant advancement in achieving precise ion transport regulation in abiotic nanochannels. Leveraging the mechanism, we also fabricated a sensitive biosensor for PKA activity detection and inhibition exploration. The combined regulation of volume exclusion and wettability offers an appealing strategy for controlled nanofluidic manipulation with promising biomedical applications in diagnosis and drug discovery.

Identification and characterization of deep nitrogen acceptors in β-Ga2O3 using defect spectroscopies

The ability to achieve highly resistive beta-phase gallium oxide (β-Ga2O3) layers and substrates is critical for β-Ga2O3 high voltage and RF devices. To date, the most common approach involves doping with iron (Fe), which generates a moderately deep acceptor-like defect state located at EC-0.8 eV in the β-Ga2O3 bandgap. Recently, there has been growing interest in alternative acceptors, such as magnesium (Mg) and nitrogen (N), due to their predicted deeper energy levels, which could avoid inadvertent charge modulation during device operation. In this work, a systematic study that makes direct correlations between the introduction of N using ion implantation and the observation of a newly observed deep level at EC-2.9 eV detected by deep-level optical spectroscopy (DLOS) is presented. The concentration of this state displayed a monotonic dependence with N concentration over a range of implant conditions, as confirmed by secondary ion mass spectrometry (SIMS). With a near 1:1 match in absolute N and EC-2.9 eV trap concentrations from SIMS and DLOS, respectively, which also matched the measured removal of free electrons from capacitance-voltage studies, this indicates that N contributes a very efficiently incorporated compensating defect. Density functional theory calculations confirm the assignment of this state to be an N (0/−1) acceptor with a configuration of N occupying the oxygen site III [NO(III)]. The near ideal efficiency for this state to compensate free electrons and its location toward the midgap region of the β-Ga2O3 bandgap demonstrates the potential of N doping as a promising approach for producing semi-insulating β-Ga2O3.