In this paper, the high-temperature rheological behavior of 1420 aluminum–lithium alloy under experimental conditions (temperatures of 350–475 °C and strain rates of 0.01–10 s−1) was systematically investigated using a Gleeble-3500 thermal simulation tester (temperature 350~475 °C, strain rate of 0.01~10 s−1). Based on the flow stress curves of this alloy, four different types of high-temperature constitutive models of the alloy were constructed: the Arrhenius (AR) model, the Modified Johnson–Cook (MJC) model, the Modified Zerilli–Armstrong (MZA) model, and the VOCE model. The prediction accuracy of the four constitutive models was compared, and the response of the accuracy of the four constitutive models to the deformation parameters (temperature, deformation rate, and strain) was analyzed. The results showed that the VOCE, AR, and MZA models had high overall prediction accuracy with average absolute relative error (AARE) of 1.8933%, 3.9912%, and 7.8422%, respectively. The VOCE model could achieve the prediction of large strain deformation resistance under small strain with small batch experimental conditions for the corresponding conditions. The AR model had optimal prediction accuracy for the high-rate deformation process. The MJC model had the optimal prediction accuracy for the low-temperature low-rate deformation process. The MZA model had better prediction accuracy for the low-rate high-temperature deformation process. The 1420 aluminum–lithium alloy process parameters selection area constitutive model matching diagram was constructed.
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